785 resultados para Lighter trivalent lanthanides


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The use of ceramic materials in ballistic armor is considerable. Such materials can be very harder and lighter than metallic materials commonly used and it presents advantages to replace metallic materials when necessary toughness can be achieved. However, as SiC and Al2O3 ceramic, traditionally used for shielding, still have high manufacturing cost or low density do not have enough to shield applications such as aircraft. An alternative is the glass-ceramics, ceramics obtained by controlled crystallization of glasses, whose properties can be adjusted by choosing the chemical composition of glass, heat treatment of crystallization and special treatments such as ion exchange on the surface, resulting in increased mechanical strength . The objective of this project is to study the kinetics of crystallization of a glass composition based on cordierite (2MgO.2Al2O3.5SiO2), low density and high hardness, for the manufacture of glass-ceramics for ballistic tests. Shown in this report are results of heat treatment of crystallization and characterization by thermal analysis (DSC) glass obtained previously, indicating uneven distribution of crystals, and drying, weighing, mixing of raw materials and a new fusion of glass, the same composition

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Technology is growing interest in the use of composites, due to the requirement of lighter materials and more resistant, factors essential to meet the project specifications and reduce the operational cost. In the production of high performance structural composites, considering the aerospace criteria, the domestic industry has shown interest in the process of resin transfer molding (RTM) for reproducibility and low cost. This process is suitable for producing components of polymeric composites with relatively simple geometries, consistent thicknesses, high quality finish with no size limitations. The objective of this work was machined carbon steel to make a matched-die tooling for RTM and produce two composite plates of epoxy resin and carbon fiber fabric with and without induced discontinuities, which were compared towards their impregnation with ultrasound, their properties via tensile tests and thermal analysis. In ultrasonic inspection, it was found good impregnation of the preform of both composites. In the thermal analysis it was possible to check the degradation temperature of the composites, the glass transition temperature and it was found that the composites showed no effective cure cycles, but presented good performance in the tensile test when compared with aluminum alloy 7050 T7451 . The results showed that the injection strategy was appropriate since the laminate exhibited a good quality for the proposed application

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With the increasing demand for electricity, the retraining of transmission lines is necessary despite environmental restrictions and crossings in densely populated areas to build new transmission and distribution lines. Solution is reuse the existent cables, replacing the old conductor cables for new cables with higher capacity power transmission, and control of sag installed. The increasing demand for electrical power has increased the electric current on the wires and therefore, it must bear out temperatures of 150°C or more, without the risk of the increasing sag beyond the established limits. In the case of long crossings or densely populated areas, sag is due to high weight of the cable on clearance. The cable type determines the weight, sag, height and the towers dimensions, which are the items that most influence the investment of the transmission line. Hence, to reduce both cost of investment and maintenance of the line, the use of a lighter cable can reduce both number and the height of the towers, with financial return on short and long term. Therefore, in order to increase the amount of transmitted energy and reduce the number of built towers and sag, is recommended in the current work substitute the current core material (steel or aluminium) for alternatives alloys or new materials, in this case a composite, which has low density, elevated stiffness (elasticity module), thus apply the pultruded carbon fiber with epoxy resin as matrix systems and perform the study of the kinetics of degradation by thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC), according to their respective standards

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The weight of a vehicle has always been considered an extreme important factor, because it interferes in the performance, steering, consume, environmental impact, wear of components, among the others. Because of the new demand, consume reduction aim and gases emission increased the necessity to manufacture lighter vehicles, guaranteeing the complying with the gas emission international law. Besides the legal demand, the low weight will certainly be essential for the competitiveness for the next generation of vehicles. It is with this thinking the composite materials have been introduced in the automobilist industry, because those materials show an excellent relation of strength/weight, providing a reduction of consume and the increase of load capacity. Those factors justify the increase of interest of industry and the necessity of optimization of those materials and of their process. For this research, the field of application will be the Baja SAE Project, a project that is fully developed by engineering students, where they build a prototype single seat, off-road category, for use on hilly slopes with obstacle. This research aims to study two key components of the prototype are made of composite materials, analyzing all the processing. In addition, there is the analysis of the viability of this production parts to a Baja SAE vehicle, in order to increase their performance and reduce their weight without reducing the safety and robustness of the prototype. It was possible to achieve weight reduction of the steering subsystem with manufacturing the flywheel hybrid composite (carbon/glass) and the replacement of SAE 1010 steel by hybrid composite (carbon/aramid) in CVT box. The importance of this study is to obtain a good project for the vehicle of technical and scientific manner, contributing to the know-how to the team and providing a basis for optimization for upcoming projects

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Pós-graduação em Agronomia (Produção Vegetal) - FCAV

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Seeking to meet the requirements: relatively low cost of materials and wide applicability in the automotive industry. The best option was the steel Dual Phase (DP), because that is lighter, have high formability, meet the cost requirements and applicability, steel Dual Phase (DP) came to meet these requirements with its two-phase microstructure, ferrite and martensite microstructure who claim to respect and mechanical properties. In this context, the aim of this study was to correlate the microstructure revealed in metallography to the mechanical properties observed in hardness and tensile tests. The microstructure is revealed by etching in 2% nital and then captured images of the sample were processed in ImageJ software to aid in determining the volume fraction of the phases present. Therefore, the mechanical properties were evaluated with respect to volume fraction of the steel layers and analyzed DP 600 together with the mechanical properties obtained by Rockwell hardness test and tensile test. With the values of the mechanical properties calculated and tested, it was possible to describe the method of metallography, as the attack phase and counts, so that it can use this relationship tested/calculated property as a qualitative analytical tool. The method used for the correlation between the microstructure and mechanical properties confirmed the importance of the phases present in the Dual Phase steel to obtain the desired mechanical properties in the application of the steel

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Tin dioxide (SnO2) thin films doped with Eu3+, are deposited by the sol-gel-dip-coating process on top of GaAs films, which is deposited by resistive evaporation on glass substrate. This heterojunction assembly presents luminescence from the rare-earth ion, unlike the SnO2 deposition directly on a glass substrate, where emissions from the Eu3+ transitions are absent. The Eu3+ transitions are clearly identified and are similar to the observation on SnO2 pressed powder (pellets), thermally treated at much higher temperatures. However, in the form of heterojunction films, the Eu emission comes along a broad band, located at higher energy compared to Eu3+ transitions, which is blue-shifted as the thermal annealing temperature increases. The size of nanocrystallites points toward quantum confinement or electron transfer between oxygen vacancies, originated from the disorder in the material, and trivalent rare-earth ions, which present acceptor-like character in this matrix. This electron transfer may relax for higher temperatures in the case of pellets, and the broad band is eliminated.