768 resultados para Ionic Liquid. tetrafluoroborate. 1-methylimidazole. hydrogen production


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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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The purpose of this work is to study the incorporation of hydrogen production (Case A) and the process of gasification of sugarcane bagasse associated with combined cycle gas turbine and steam turbine (Case B) for Distillery Pioneers process. These technologies can be used to improve the energy supply in the sugarcane mill. Initially the processes for obtaining sugar and ethanol from sugarcane is discussed, with a theoretical introduction to hydrogen, the process of steam reforming and gasification of biomass (bagasse) by inserting a turbine associated with the recovery boiler gas. Subsequently makes up the energy and exergy analysis of the incorporation of the above technologies. In end stage makes it an ecological analysis considering or not the carbon cycle (photosynthesis), to determine the levels of emissions of pollutants, carbon dioxide equivalent, indicators of pollution and ecological efficiencies associated with technological developments proposed. It is concluded that hydrogen production by steam reforming of ethanol and gasification of bagasse are viable alternatives from the point of view of technical and environmental applications in the biofuels industry, contributing to the development of the sector in the country

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This work studies the incorporation of new technologies in the sugarcane sector. Are considered the ethanol steam reforming and the gasification of sugarcane bagasse(by-product) processes associated with combined cycle systems (Gas Turbine + Steam Turbine), aggregating hydrogen production and increased electricity supply in the sector, respectively. To verify the technical feasibility of the incorporation processes was performed a thermodynamic analysis, considering data from a typical Brazilian Sugar Cane Industry. In another step the economic viability study of the hydrogen production process was made, with consideration on hydrated and anhydrous ethanol steam reform, comparing the cost of hydrogen production. Also considered studies of economic engineering of the gasification process and the generation of electricity associated. As conclusions, it follows that the ethanol steam reforming is a great alternative for hydrogen production, presenting production cost relatively low, especially when is considered the steam reforming of hydrated ethanol. For the gasification process associated with combined cycle, can be observed an increase of 8.56 times of the electricity production in the sugar cane industry, indicating a positive annual saving when the sales price of the supply electricity is greater than 0.070 US$/kWh. Finally it can be concluded that the incorporation of these new processes allow greater profitability and operational flexibility of Brazilian sugarcane mills

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Introduces technical, economic and environmentally competitive solutions in the energy market is a great challenge for society. This work examines each of these aspects considering the production of electrolytic hydrogen with energy from wind power, solar and hydropower, in order to ensure an overview of this energy carrier. Initially, an assessment of the technical aspects is made addressing existing electrolysers technologies, its main characteristics and differences. The geographical distribution of wind, solar and hydroelectric potential in Brazil is also mapped, and a configuration scheme of a hydrogen production system is discussed. Subsequently, the economic analysis calculates the cost of investment in the alkaline electrolyser of 60 Nm³ / h, similar to the Brazilian bus powered by hydrogen project, coordinated by EMTU. Since the main input of electrolysis is electricity, is analyzed the latest energy auctions of each primary source and it is calculated the cost of production of the wind, solar and hydropower hydrogen. Postponed to this, are investigated the intrinsic environmental impacts of electricity generation process, proposing a readjustment of an indicator of ecological efficiency for the production of hydrogen. Finally, the work discusses the concept of externalities and demonstrates how the incorporation of external costs can leverage the hydrogen economy. In short, it is evident that the wind and hydroelectric hydrogens are more promising compared to solar hydrogen, whether in the economic aspect, because it achieved lower costs, whether in the environmental aspect, because it reached the highest ecological efficiency

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Pós-graduação em Agronomia (Horticultura) - FCA

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Pós-graduação em Agronomia (Horticultura) - FCA

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Background: Cladocera is an important group of freshwater zooplankton, and the species plays an important role in energy transfer and in aquatic food webs. Oxyurella longicaudis is a Chydoridae species that has been recorded in North and South America. The aim of this study is to investigate the life cycle aspects of parthenogenetic females of O. longicaudis cultured in laboratory under controlled conditions: temperature (23 degrees C +/- 05 degrees C), photoperiod (12 h light/12 h dark), food supply, and reconstituted water.Results: Embryonic development duration (2.3 +/- 0.5 days), post-embryonic development (5.2 +/- 0.69 days), mean fecundity (two eggs female(-1) brood(-1)), total egg production (22.55 +/- 3.98 eggs), average longevity (58 days), and body growth of the species were recorded. We also report the first DNA barcode for O. longicaudis isolated in Brazil, which will allow for easy identification in future zooplankton community studies. The analysis shows a genetic divergence of around 7% between our Brazilian isolate and O. longicaudis isolates from Mexico.Conclusions: The time of embryonic and post-embryonic development of O. longicaudis was higher than that of the other species of the same family, which contributed to lower total egg production throughout its life cycle. The genetic divergence appears to be sufficient to classify the two isolates as different species.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Pós-graduação em Engenharia Mecânica - FEG

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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The objective of this work was to evaluate the energy and economic efficiency indexes per unit of cotton agro-ecosystem area in family production systems of Paraguay and Brazil; and, to establish a relationship between the energy and economic. Typologies presented by the Program to Support Small Cotton Holdings (Paraguay), and by the National Program for Strengthening Family Agriculture (Brazil). Family systems of the two countries were identified; these are located from Paraguay (San Juan–CA) and from Brazil (Leme–SP). To construct the energy expenditure structure of the cotton agro-ecosystem, as well as to assess the economic efficiency, the mean values obtained were considered, when they presented similarities in production systems and they were within the typology proposed in this study. From the technical itinerary observed the Paraguayan agro-ecosystem depended (fossil fuel 56.76%) and industrial source (35.99%). Thus, the energy balance of the agricultural stage was established, which attained a value of 17,740.69 MJ ha-1; an energy efficiency of 5.28, and a cultural efficiency of 3.04. The Brazilian agro-ecosystem depended on energy from industrial source (insecticides 39.82%) and from fossil fuel (33.59%); it reached an energy balance of 19,547.88 MJ ha-1; an energy efficiency of 2.12, and a cultural efficiency index of 0.71. In the economic and energy indicator ratio, with regard to the months referring to the harvest time, that is to say, March, April, and May, the maximum economic efficiency indicator of paraguay was attained in the month of May (1,00), and from Brazil in the month of May (1,71). Both production systems analyzed were presented efficient, however, dependent of external circumstances and non-renewable energy sources.

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The objective of this work was to evaluate the energy and economic efficiency indexes per unit of cotton agro-ecosystem area in family production systems of Paraguay and Brazil; and, to establish a relationship between the energy and economic. Typologies presented by the Program to Support Small Cotton Holdings (Paraguay), and by the National Program for Strengthening Family Agriculture (Brazil). Family systems of the two countries were identified; these are located from Paraguay (San Juan–CA) and from Brazil (Leme–SP). To construct the energy expenditure structure of the cotton agro-ecosystem, as well as to assess the economic efficiency, the mean values obtained were considered, when they presented similarities in production systems and they were within the typology proposed in this study. From the technical itinerary observed the Paraguayan agro-ecosystem depended (fossil fuel 56.76%) and industrial source (35.99%). Thus, the energy balance of the agricultural stage was established, which attained a value of 17,740.69 MJ ha-1; an energy efficiency of 5.28, and a cultural efficiency of 3.04. The Brazilian agro-ecosystem depended on energy from industrial source (insecticides 39.82%) and from fossil fuel (33.59%); it reached an energy balance of 19,547.88 MJ ha-1; an energy efficiency of 2.12, and a cultural efficiency index of 0.71. In the economic and energy indicator ratio, with regard to the months referring to the harvest time, that is to say, March, April, and May, the maximum economic efficiency indicator of paraguay was attained in the month of May (1,00), and from Brazil in the month of May (1,71). Both production systems analyzed were presented efficient, however, dependent of external circumstances and non-renewable energy sources.

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The castor bean is an oilseed crop of outstanding importance in Brazil and worldwide. Besides the wide application in chemical industry, is important due to its tolerance to drought, making it a viable crop for the semi-arid region of Brazil, where there are few agricultural alternatives. However, this culture is not unique to semi-arid region and is also planted with excellent results in various regions of the country. The study aimed to evaluate the effects of liming and potassium fertilization on the crop of castor bean. The experiment was conducted in a greenhouse in a randomized complete block randomized in a factorial 3 x 2, where the first factor consisted of potassium (0, 30 and 60 kg ha-1) and in the presence or absence lime to raise the base saturation to 60%. It was found that liming in combination with an intermediate dose of K2O (30 kg ha-1) elevates the production of dry mass of the area, however not change the concentration nutrients in the castor bean.