987 resultados para Hf
Resumo:
Nuclear collisions recreate conditions in the universe microseconds after the Big Bang. Only a very small fraction of the emitted fragments are light nuclei, but these states are of fundamental interest. We report the observation of antihypertritons-comprising an antiproton, an antineutron, and an antilambda hyperon-produced by colliding gold nuclei at high energy. Our analysis yields 70 +/- 17 antihypertritons (3/Lambda(H) over bar) and 157 +/- 30 hypertritons (H-3(Lambda)). The measured yields of H-3(Lambda) (3/Lambda(H) over bar) and He-3 ((3)(He) over bar) are similar, suggesting an equilibrium in coordinate and momentum space populations of up, down, and strange quarks and antiquarks, unlike the pattern observed at lower collision energies. The production and properties of antinuclei, and of nuclei containing strange quarks, have implications spanning nuclear and particle physics, astrophysics, and cosmology.
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We present measurements of the charge balance function, from the charged particles, for diverse pseudorapidity and transverse momentum ranges in Au + Au collisions at root S-NN = 200 GeV using the STAR detector at RHIC. We observe that the balance function is boost-invariant within the pseudorapidity coverage vertical bar-1.3, 1.3 vertical bar. The balance function properly scaled by the width of the observed pseudorapidity window does not depend on the position or size of the pseudorapidity window. This scaling property also holds for particles in different transverse momentum ranges. In addition, we find that the width of the balance function decreases monotonically with increasing transverse momentum for all centrality classes. (c) 2010 Elsevier B.V. All rights reserved.
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Well-aligned TiO2/Ti nanotube arrays were electrochemically formed in a HF solution for different anodization times. Field emission scanning electron microscopy (FE-SEM) images reveal that anodization time had a great influence on the morphology of TiO2/Ti nanotube arrays. The composition of resulting nanotubes was analyzed by X-ray photoelectron spectroscopy (XPS). Field emission properties of the prepared samples with different morphologies were investigated by the Fowler-Nordheim (F-N) theory. The results indicate that the morphology can affect field emission behaviors. TiO2/Ti nanotube arrays with clear, uniform, and short nanotubes display moderate field emission properties, and have the better turn-on field of 4.6 V/mu m and good field emission stability. (C) 2010 Elsevier B.V. All rights reserved.
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We present the multiplicity and pseudorapidity distributions of photons produced in Au + Au and Cu + Cu collisions at root(NN)-N-s = 62.4 and 200 GeV. The photons are measured in the region -3.7 < eta < -2.3 using the photon Multiplicity detector in the STAR experiment at RHIC. The number of photons produced per average number of participating nucleon pairs increases with the beam energy and is independent of (lie collision centrality. For collisions with similar average numbers of participating nucleons the photon multiplicities are observed to be similar for An + Au and Cu + Cu collisions at a given beam energy. The ratios of the number of charged particles to photons in the measured pseudorapidity range are found to be 1.4 +/- 0.1 and 1.2 +/- 0.1 for root(NN)-N-s = 62.4 and 200 GeV, respectively. The energy dependence of this ratio could reflect varying contributions from baryons to charged particles, while mesons are the dominant contributors to photon production in the given kinematic region. The photon pseudorapidity distributions normalized by average number of participating nucleon pairs, when plotted as a function of eta-Y-beam, are found to follow a longitudinal scaling independent of centrality and colliding ion species at both beam energies. (C) 2009 Elsevier B.V. All rights reserved.
Resumo:
The alpha-decay half-lives of nuclei in the ground states and Isomeric states have been calculated within the WKB approximation and Royer's formulas. The barrier in the quasimolecular shape path is determined within a generalized liquid drop model (GLDM). in which the centrifugal potential energy has been introduced to study the unfavored a-decay The agreement between the calculated results and experimental data indicates the reliability of studying alpha-decay of isomeric states with the generalized liquid drop model We find that their is no significant difference of preformation probability between Isomeric states and the corresponding ground states generally in favored alpha-decay Additionally. we extended Royer's formulas by taking account of the role of centrifugal harrier to study the unfavored alpha-decay, and some predicts oil the a decay half-lives of Isomers are made Finally. the effects of angular momontum transfer and Q(alpha) on alpha-decay half-life have been discussed Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved
Resumo:
The unified fission model (UFM) combining with the phenomenological assault frequency has been carried out to investigate the proton-radioactivity half-lives of spherical proton emitters. The results are in good agreement with the experimental data and other theoretical values, and newly observed spherical proton emitters have been analyzed. Finally, the effect of angular momentum transfer on half-life of proton emission has been discussed in detail and a formula can be used to describe this relationship.
Resumo:
Concise methods are proposed to study proton radioactivity. The spectroscopic factor is obtained from relativistic mean field (RMF) theory combined with the BCS method (RMF+BCS). The assault frequency is estimated by a quantum mechanical method considering the structure of the parent nucleus. The penetrability is calculated by the WKB approximation. No additional parameters are introduced. The extracted experimental spectroscopic factors are compared with those from the calculations by the RMF+BCS, and the agreement is good, implying that the present methods work quite well for proton radioactivity. Predictions are provided for some most possible proton emissions, which may be useful for future experiments.
Resumo:
The alpha decay constant is the product of the penetrability P and assault frequency nu(0) in the fission-like model. An effective assault frequency P-nu replacing the previous assault frequency nu(0) is introduced for improvement of a fission-like model named the generalized liquid drop model (GLDM) to describe the nuclear alpha decay process more accurately. Two analytical formulae are proposed for the effective assault frequency due to experimental data within the GLDM. The improved model can be used to give accurate calculations for alpha decay half-lives.
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The properties of the Z = 117 isotopic chain are studied within the framework of the axially deformed relativistic mean field theory (RMFT) in the blocked BCS approximation. The ground-state properties, such as binging energies, deformations as well as the possible.. decay energies and lifetimes are calculated with the parameter set of NL-Z2 and compared with results from the finite range droplet model. The analysis by RMFT shows that the isotopes in the range of mass number A = 291 similar to 300 exhibit higher stability, which suggests that they may be promising nuclei to be hopefully synthesized in the lab among the nuclei Z = 117.
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The in medium nucleon-nucleon (N N) cross sections in isospin asymmetric nuclear matter at various densities are investigated in the frame work of Brueckner-Hartree-Fock theory with the Bonn B two-body nucleon-nucleon inter action supplemented with a new version microscopic three-body force (TBF). The TBF depresses the amplitude of cross sections at high density region. At low densities, the proton-proton and neutron-neutron cross sections decrease while the proton-neutron one increases as the asymmetry increases. But the sensitivity of the N N cross sections to the isospin a symmetry are reduced with the increasing density.
Resumo:
目前,数字化成像技术已经被引入X射线医学诊断中替代传统的胶片技术。已经得到人们的广泛认可。然而,目前大多数成像探测器依赖进口,且受制于几个大公司的高价位独家垄断。为了实现X射线数字成像系统的国产化生产,我们跟踪国际最新研究动态,进行了硅阵列闪烁屏X-射线探测器的试研发。这篇论文是对关键技术硅阵列闪烁屏的制备工艺的研究报道。为了形成阵列结构,我们对n型硅在氢氟酸(HF)中电化学蚀刻过程进行了研究,取决于蚀刻参数,电化学过程在无刻图硅上可以形成多孔硅及抛光硅。通过光刻掩膜的限制及各项异性蚀刻过程获得了用于形成硅孔阵列的锥形初始坑,并通过对硅的电化学蚀刻参数的研究,制备出了孔距37µm,深度300nm的阵列管坑,这种孔具有高的深宽比。由于蚀刻硅在阳极偏压下硅的溶解是以正载流子的供给为基础的,而n型硅中空穴是少子,为了实现硅的电化学蚀刻,采用了光激发产生空穴的方法,并通过对蚀刻硅背面镀铝二次光刻制备网格状电极的方法,解决了高阻硅电化学蚀刻中的欧姆接触问题,实现了整个蚀刻区内孔的均匀生长。另外通过自建的高温装置,对CsI的填充工艺进行了探索,从而实现了闪烁屏制备工艺的全方位研究
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我们利用流体动力学宏观理论与HF微观理论对同位旋标量多极巨共振能量随温度的变化机制做了讨论。首先用流体动力学方法导出了同位旋标量多极巨共振能量随温度变化的一般关系式。公式表明巨共振能量随温度的变化受制于热核体积膨胀和核子平均动能增加两个因素之间的竟争,它们分别使共振能减小和增加。接着又用Skyrme-HF方法得到了核半径系数和核子平均动能随温度变化的关系式。最后得到同位旋标量多极巨共振能量随温度变化的一个简单关系式。体积膨胀和核子平均动能增加这两种因素的影响大体互相抵消,最终导致热核同位旋标量多极巨共振能量基本不随温度变化。我们用Boltzmann-Nordherin-Vlasov方程数值计算和分析了重离子反应中单极巨共振OMR的形成与衰减。为了系统地比较入射能、碰撞参数对不同反应系统GMR的形成与衰减的影响,我们计算了不同条件下不同重离子反应系统的四极矩、动能和单极矩随时间的演化。计算表明,1)GMR能量与入射能和碰撞参数无关,仅仅是核子数的函数。2) 入射能愈大GMR形成稍有提前,GMR振幅也越大但OMR振幅衰减越快GMR消亡越早。3) 碰撞参数越大GMR振幅越小GMR消亡越早。4) GMR在40fm/c左右形成,依照入射能和碰撞参数的不同在200到400fm/c后消亡,入射能愈大或碰撞参数愈大GMR消亡越早。概括地讲,GMR能量是核子数的光滑函数,与入射能或激发能无关;入射能越大GMR振幅越大,GMR形成时间稍早但衰减和消亡更快。我们用经典唯象输运模型和量子输运模型讨论了核系统扩张过程中OQR模式的密度涨落并用它们来模拟系统的集体行为。我们讨论了集体坐标Q与集体动量P的涨落随时间的演化。计算显示集体变量Q的涨落发展主要取决于通过随机驱动力引入的初始统计涨落,统计涨落与量子涨落行为相似。在核系统扩张阶段耗散与涨落机制对于动量分布的影响是重要的。量子涨落在初值中已经存在,对于低温系统,量子涨落所起的作用尤为重要,它能够缩短涨落达到特定值的临界时间,从而在动力学对称性破缺中发挥重要作用。由于量子涨落的作用,处于spinodal状态的核系统将更早地分解。我们也讨论了双核系统GDR的形成与性质,还探讨了GDR宽度随温度变化的机制。
Resumo:
本论文从内容上可以分为两大部分:第一部分:对近球形核~(143)Pm高自旋态进行的在束γ研究。这一部分是本文的重点。利用能量为82和90 MeV的~(19)F束流,通过融合蒸发反应~(128)Te (~(19)F,4nγ) ~(143)Pm布局~(143)Pm的高自旋态。利用联合在束装置(JIBGE)的10套带BGO反康的HPGe探测器进行了标准在束γ谱学测量,包括γ射线的激发函数、γ单谱、γ-γ-t符合谱以及DCO测量。在已有工作的基础上,建立了~(143)Pm激发能高达10.5 MeV,自旋约为(61/2)h的高自旋态能级结构。观测到了28条新的跃迁能级和48条新的γ射线。对两个已知的同质异能态寿命进行了提取,并在8 MeV激发能附近进行了高自旋态同质异能态的搜索。以~(142)Nd,~(144)Sm为核实,用零级弱耦合模型对~(143)Pm的晕态能级结构进行了定量的解释。计算表明,直到激发能Ex = 6.77 MeV,自旋宇称J~π = (37/2~+)的晕态能级都可以用弱耦合模型进行很好的解释。但是,对于更高激发能的能级,组态情况要复杂的多,有出现N = 82中子闭壳打破的可能。同时,利用大基壳模型OXBASH程序对其能级结构进行了计算和讨论,其结果支持弱耦合模型的假设。第二部分:利用中能重离子的多核子转移反应,(~(186)W-2p + 2n),(~(238)U-2p + 2n)对丰中子核~(186)Hf和~(238)Th进行了合成和鉴别。测量它们的半衰期分别为(2.6 ± 1.2) min和 (9.4 ± 2.0) min,与用质子一中子准粒子随机相近似方法的预言值是相符的。同时,对β延发裂变先驱核~(230)Ac进行了实验研究。观测到了它的两个裂变事件,得到~(230)Acβ延发裂变几率为(1.19 ± 0.85) * 10~(-8)。从而使~(230)Ac成为世界上第一种被确认了的基态β延发裂变先驱核。
Resumo:
本论文主要进行了奇奇核~(166)Lu、~(168)Lu和奇中子核~(87)Zr的高自旋态的研究工作,对它们高自旋态的一些物理现象进行了讨论。并且首次对1/2~-[541](direct X)vi_(13/2)组态带的系统学规律进行了总结。主要由以下三个部分组成:~(166,168)Lu高自旋态的研究在最近有关形变奇奇核高自旋态的研究工作中,随着实验上π1/2-[541](direct X)vi_(13/2)带自旋的确定,人们发现除了130区的兀h_(11/2)(direct X)vh_(11/2)和160区的兀h_(11/2)(direct X)vi_(13/2)组态带低自旋旋称反转以外,π1/2~-[541](direct X)vi_(13/2)带的低自旋也是反转的,该转动带低自旋旋称反转现象引起了人们的很大的兴趣并得到很广泛的研究,为了通过π1/2~-[541](direct X)vi_(13/2)带与已知自旋和宇称的基态和一些低激发态相连,确定该转动带的自旋,人们付出了很大的努力。特别是最近几年,一些实验上自旋的确定,使得研究π1/2~-[541](direct X)vi_(13/2)组态带低自旋旋称反转的系统学规律成为可能。需要指出的是在以前的研究结果中,~(166)Lu的π1/2~-[541](direct X)vi_(13/2)组态带的能级摆动规律与相邻奇奇核该组态带的能级摆动规律严重不符,澄清该疑点是我们重新研究该核的主要动力之一。在以前~(168)Lu的研究工作中,只在~(168)Lu中发现两个带,但其中只有晕带的组态得到指定,根据带结构和旋称劈裂的大小估计另一个带极有可能是π1/2~-[541](direct X)vi_(13/2)带。为了澄清以上这些疑点和得到π1/2~-[541](direct X)vi_(13/2)组态带的系统学规律,我们重新研究了。~(166,168)Lu的高自旋态。另外(h_(11/2)_p(i_(13/2))_n组.态带的低自旋旋称反转是一个广为人知的物理现象,但在以前的有关~(166)Lu的结果中对(h_(11/2))_p(i_(13/2))_n组态带白旋的确定与该组态带低自旋旋称反转系统规律相反,这也是我们对~(166)Lu重新研究的一个原因。实验是在北京中国原子能科学研究院HI-13串列加速器上进行的,分别利用入射能量为97MeV和92MeV的~(19)F束通过熔合蒸发反应~(152)Sm(~(19)F,~5n)~(166)Lu和~(154)Sm(~(19)F5n)~(168)Lu布居了~(166)Lu和~(168)Lu的高自旋态。用十台HpGe探测器组成的探测阵列进行γ-γ符合测量,对~(166)Lu和~(168)Lu分别记录了约1.27 * 10~8和0.25 * 10~8个两重和两重以上的符合事件。在~(166)Lu中,共发现了五条转动带,根据它们的顺排在0.28MeV均没有出现上弯,意味着它们的中子均占居i_(13/2)轨道,同时根据在~(165)Lu和~(167)Lu只发现基于9/2~-[514]、7/2~-[404]、1/2~-[541]、1/2~+[411]和5/2~+[402]轨道的转动带及在~(165)Yb和~(167)Hf中晕带均为5/2~+[642]的事实,那么由上述质子轨道和中子轨道组成的转动带是本文发现的五条带的最可能的侯选者。本实验中观察到的五条转动带分别基于7/2~+[404](direct X)5/2~+[642]、9/2~-[514](direct X)5/2~+[642]、1/2~-[541](direct X)5/2~+[642]、5/2~+[402](direct X)5/2~+[642]和1/2~+[642](direct X)5/2~+[642]轨道的转动带。和以前的数据相比主要有以下几点改进:(A)在以前的结果中,包括2000年新发表的有关~(166)Lu的文章,他们均把本文~(166)Lu纲图中(5)和(6)退激系列归属于π1/2~-[541](direct X)v5/2~+[642]转动带,而在本文中通过符合关系一个新的退激系列(7)被发现,根据(6)和(7)之间的符合关系、带交叉频率、γ射线强度和B(M1)/B(E2)的比值等关系,本文认为新发现的退激系列(7)与(6)组成新的π1/2~-[541](direct X)v5/2~+[642]转动带.以前的结果的错误在于把属于1/2~-[541](direct X)5/2~+[642]转动带的α = 0与1/2~-[541](direct X)5/2~+[642]转动带的α = 0误归于一个带,这就澄清了原文献中π1/2~-[541](direct X)v5/2~+[642]转动带能级摆动规律与相邻奇奇核该组态带能级摆动规律不符的疑点,同时把原文献中误归于π1/2~-[541](direct X)v5/2~+[642]转动带的那一个退激系列(5)重新指定为1/2~+[411](direct X)5/2~+[642]带(α = 0);(B)通过分析实验数据、跃迁能量系统学和运用顺排相加性规则对以前实验中建立的9/2~-[514](direct X)5/2~+[642]和7/2~+[404](direct X)5/2~+[642]带的自旋进行了重新指定,把它们的自旋在原文的基础上加1个单位,澄清了以前的有关~(166)Lu结果中对9/2~-[514](direct X)5/2~+[642]组态带自旋的确定与该组态带低自旋旋称反转事实相反的疑点;(C)新发现了基于9/2~-[541](direct X)5/2~+[642]组态的转动带。在~(168)Lu中,共观察到了四条转动带,分别是π1/2~-[541](direct X)v5/2~+[642]、7/2~+[404](direct X)5/2~+[642]、 9/2~-[514](direct X)5/2~+[642]和7/2~+[404](direct X)5/2~-[523](本文新建立的带)带,本文对其中晕带7/2~+[404](direct X)5/2~+[642]的K值取值与原文献中的取值不同,并根据能量系统学和带头激发能指出不同的原因。 除以上所述外,本文还给出了~(166)Lu和~(168)Lu各γ射线的强度、转动参数A、较强γ射线的DCO值、分支比和B(M1)/B(E2)等实验值。基于实验和理论预期的B(M1)/B(E2)比值的比较、各带带交叉行为、顺排相加性、带头激发能和转动参数A对各带的组态和自旋进行了指定。最后通过对实验上对~(162,164)Tm、~(174)Ta和~(176)Re的π1/2~-[541](direct X)vi_(13/2)组态带p-n剩余相互作用信息的提取,指出奇质子核中1/2~-[541]带的带交叉频率相对相邻偶偶核的延迟约三分之一到一半左右,其原因是由于p-n剩余相互作用所造成的(包含了对效应和形变变化的CSM模型能够解释另一半的偏离),可以定性的认为正是由于形变、对相互作用的变化和剩余p-n相互作用三者相结合导致了整个的1/2~-[541]带中带交叉频率的偏离。旋称反转机制综述和πh_(932)(direct X)vi_(l3/2)组态的系统学首先对导致旋称反转的各种机制做一简单回顾,同时对ππh,u2⑩vi,钔组态带系统学规律做一简单总结,总结了πh_(11/2)(direct X)Vi_(13/2)组态带的跃迁能量系统学规律。在最近,随着~(162)Tm、~(164)Tm、~(174)Ta和~(176)Re等几个奇奇核中半退耦带1/2~-[541](direct X)vi_(13/2)的自旋通过实验方法的确定,人们惊奇的发现在上述这些核~(162)Tm、~(164)Tm、~(174)Ta和~(176)Re)中半退耦带1/2~-[541](direct X)vi_(13/2)在低自旋区都是旋称反转的。人们就会很自然的回头去看那些在该区已经布居1/2~-[541](direct X)vi_(l3/2)组态带的那些核,结果发现对于该组态带的自旋的指定是很杂乱无章的,有些自旋的确定即不符合能量系统学又与顺排相加性规则相悖,如在~(172)Ta和~(178)Re中(值得指出的是有关这两个核的文章均是在十年前发表的),自旋的指定明显与最近发表的该区πhg_(9/2)(direct X)vi_(13/2)组态带自旋不符,本文通过能量系统学和顺排相加性对~(172)Ta和~(178)Re的1/2~-541](direct X)vi_(13/2)组态带自旋做了修改,分别增加了3h和h。本文通过对最新结果~(162)Tm、~(164)Tm、~(170)Lu、~(170,174,176)Ta、~(176)Re、~(180)Ir)和以前的结果(~(172)Ta和~(178)Re)及本文的结果(~(166,168)Lu)对上述12个核的1/2~-[541](direct X)vi_(13/2)组态带的S(I) = E(I)-E(I-1)- E(I + 2)-E(I + 1)-E(I - 1)-E(I - 2)]/2~I的变化图的分析,继A ≈ 130区7πh_(11/2)(direct X)vh_(11/2)组态带和A ≈ 160区πh_(11/2)(direct X)vi_(13/2)组态带的系统学规律以后,首次总结出A ≈ 170区π1/2~-541](direct X)vi_(13/2)组态带的系统学规律:反转点的自旋随N的增加而增加,随Z的增加而减小,与πh_(11/2)(direct X)和πh_(11/2)(direct X)vi_(13/2)转动带的系统学规律很相似,即反转点自旋均随中子和质子单调地变化。通过对各种理论模型的研究发现三轴形变、科里奥利力、带交叉与自反转和p-n相互作用在奇奇核中都有可能导致旋称反转,包含有p-n相互作用的粒子-转子模型在πh_(11/2)(direct X)和vh_(11/2)、πh_(11/2)和π1/2 ~-[541](direct X)vi_(13/2)组态带中的旋称反转上取得了某些成功,表明p-n相互作用在解释奇核低自旋反转现象中起着很重要的作用。通过对实验上π1/2~-[541](direct X)vi_(13/2)组态带旋称反转点与文献中理论计算值的比较,得出p-n相互作用强度的变化可能是导致π1/2~-[541](direct X)vi_(13/2)组态带症称反转点变化主要原因的结论。过渡区核~(87)Zr的高自旋态研究在A≈80区,许多原子核的中子和质子数都处在28和50两个满壳层之间,对于这些核而言,任何一种核子数的改变都有可能导致核形状的显著变化。有研究结果表明,对于40≤Z≤45的核来讲,N=46是变形核向球形核变化的转折点。在40≤N≤50区,对Zr(Z=40)同位素系列中诸原子核能级结构伴随中子数改变而发生的变化的研究将会帮助我们了解这个形状变化的过程。我们所研究的~(87)Zr含有47个中子,就处于这个过渡区。实验是在北京中国原子能科学研究院HI-13串列加速器上进行的,利用入射能量为118MeV的~(32)S束通过~(58)Co(~(32)S,3pn)~(87)Zr熔合蒸发反应布居。~(87)Zr的高自旋态,实验用的靶为附有Ta衬的厚度1082μg/cm~2的~(59)Co箔。用7台HpGe探测器组成的探测阵列进行γ-γ符合测量。同时采用一个小平面光子探测器探测低能γ射线。本实验记录了约1.5 * 10。个两重以上的符合事件,建立了自旋直到37/2和43/2的能级纲图。研究的结果表明:~(87)Zr与相邻同中子奇A核的正宇称低激发能级之间存在着很强的相似性,而与相邻奇A核同位素相比,结构变化明显, 这可能表明在该核区对核形变的影响中子占主要地位,质子影响较小。激发能随中子变化的比值图呈阶梯状,认为R ≈ 1.5,R_x ≈ 2.0和R_x ≥ 2.2分别代表核形变的三个区域,即球型核、过渡区核和形变核。通过与相邻(Z,N + 1)偶偶核低激发态能级相比较的方法对各低激发能级组态的主要成分进行了估计,发现随自旋的增加,出现了各能级组态之间的混杂。
Resumo:
The construction and evaluation of an on-column etched fused-silica porous junction for on-line coupling of capillary isoelectric focusing (CIEF) with capillary zone electrophoresis (CZE) are described. Where two separation columns were integrated on a single piece of fused-silica capillary through the etched similar to4 to 5-mm length porous junction along the capillary. The junction is easily prepared by etching a short section of the capillary wall with HF after removing the polyimide coating. The etched section becomes a porous glass membrane that allows only small ions related to the background electrolyte to pass through when high voltage is applied across the separation capillary. The primary advantages of this novel porous junction interface over previous designs (in which the interface is usually formed by fracturing the capillary followed by connecting the two capillaries with a section of microdialysis hollow fiber membrane) are no dead volume, simplicity, and ruggedness, which is particularly well suited for an on-line coupling capillary electrophoresis-based multiple dimensional separation system. The performance of the 2D CIEF-CZE system constructed by such an etched porous junction was evaluated by the analyses of protein mixtures.