Luxembourg and Portions of Belgium, Germany, and France, 1705 (Image 2 of 4) (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Le Duché de Luxembourg divisé en Quartier Walon, et Allemand : dans chacun desquels sont diviséz, les Seigneuries, Prevostés et Comtés. Le Duché de Bouillon ; le Comté de Namur et le Pays entre Sambre et Meuse, Dedié au Roy par son tres-humble, tres-obeissant, tres-fidele sujet et serviteur Hubert Jaillot, Geographe du Roy. It was published by chez l'auteur, joignant les grands Augustins, aux deux Globes, avec privilége du roy in 1705. Scale [ca. 1:143,370]. Covers Luxembourg and portions of Belgium, Germany, and France. This layer is image 2 of 4 total images of the four sheet source map, representing the northeast portion of the map. Map in French.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Europe Lambert Conformal Conic coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, roads, cities and other human settlements, fortifications, territorial and administrative boundaries, ground cover, and more. Relief shown pictorially. This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Luxembourg and Portions of Belgium, Germany, and France, 1705 (Image 3 of 4) (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Le Duché de Luxembourg divisé en Quartier Walon, et Allemand : dans chacun desquels sont diviséz, les Seigneuries, Prevostés et Comtés. Le Duché de Bouillon ; le Comté de Namur et le Pays entre Sambre et Meuse, Dedié au Roy par son tres-humble, tres-obeissant, tres-fidele sujet et serviteur Hubert Jaillot, Geographe du Roy. It was published by chez l'auteur, joignant les grands Augustins, aux deux Globes, avec privilége du roy in 1705. Scale [ca. 1:143,370]. Covers Luxembourg and portions of Belgium, Germany, and France. This layer is image 3 of 4 total images of the four sheet source map, representing the southwest portion of the map. Map in French.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Europe Lambert Conformal Conic coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, roads, cities and other human settlements, fortifications, territorial and administrative boundaries, ground cover, and more. Relief shown pictorially. This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Luxembourg and Portions of Belgium, Germany, and France, 1705 (Image 4 of 4) (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Le Duché de Luxembourg divisé en Quartier Walon, et Allemand : dans chacun desquels sont diviséz, les Seigneuries, Prevostés et Comtés. Le Duché de Bouillon ; le Comté de Namur et le Pays entre Sambre et Meuse, Dedié au Roy par son tres-humble, tres-obeissant, tres-fidele sujet et serviteur Hubert Jaillot, Geographe du Roy. It was published by chez l'auteur, joignant les grands Augustins, aux deux Globes, avec privilége du roy in 1705. Scale [ca. 1:143,370]. Covers Luxembourg and portions of Belgium, Germany, and France. This layer is image 4 of 4 total images of the four sheet source map, representing the northwest portion of the map. Map in French.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Europe Lambert Conformal Conic coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, roads, cities and other human settlements, fortifications, territorial and administrative boundaries, ground cover, and more. Relief shown pictorially. This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Coasts, Black Sea and Sea of Marmara Regions, 1803 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Umriss des Schwarzen Meeres des Bosphorus, des Propontes, des Hellesponts, des Archipelagus nebst den Küsten, nach den neuesten Bericht von D.F. Sotzmann ; gestochen von Heinrich Kliewer. It was published by Oehmigke in 1803. Scale [ca. 1:5,500,000]. Covers the Black Sea and Sea of Marmara regions. Map in German. The image inside the map neatline is georeferenced to the surface of the earth and fit to the World Miller Cylindrical projected coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, cities and other human settlements, territorial boundaries, shoreline features, and more. Relief shown by hachures. Includes inset map of the Sea of Marmara and 4 views of the fortifications of the Dardanelles Strait (Turkey).This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Andover (including North Andover and part of Lawrence), Massachusetts, 1830 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: A plan of Andover taken for the town, by Moses Dorman, Jr. It was published by Pendleton's Lithogy. in 1830. Scale [ca. 1:41,140]. Covers the towns of Andover and North Andover and a portion of the City of Lawrence, Massachusetts.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Massachusetts State Plane Coordinate System, Mainland Zone (in Feet) (Fipszone 2001). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, or other information associated with the principal map. This map shows features such as roads, drainage, public buildings, schools, churches, cemeteries, industry locations (e.g. mills, factories, mines, etc.), private buildings with names of property owners, town boundaries and more. Relief is shown by hachures.This layer is part of a selection of digitally scanned and georeferenced historic maps of Massachusetts from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of regions, originators, ground condition dates (1755-1922), scales, and purposes. The digitized selection includes maps of: the state, Massachusetts counties, town surveys, coastal features, real property, parks, cemeteries, railroads, roads, public works projects, etc.

West Springfield (including Agawam and part of Holyoke), Massachusetts, 1831 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: A plan of West Springfield, by J. Lathrop. It was published by Pendleton's Lithogy. in Aug. 1831. Scale [1:39,600]. Covers the towns of West Springfield, Agawam, and a portion of Holyoke, Massachusetts. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Massachusetts State Plane Coordinate System, Mainland Zone (in Feet) (Fipszone 2001). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, or other information associated with the principal map. This map shows features such as roads, drainage, public buildings, schools, churches, cemeteries, industry locations (e.g. mills, factories, mines, etc.), private buildings with names of property owners, town and town parish boundaries and more. Relief is shown by hachures. This layer is part of a selection of digitally scanned and georeferenced historic maps of Massachusetts from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of regions, originators, ground condition dates (1755-1922), scales, and purposes. The digitized selection includes maps of: the state, Massachusetts counties, town surveys, coastal features, real property, parks, cemeteries, railroads, roads, public works projects, etc.

THE DESIGN AND SYNTHESIS OF SILOXANE PRECURSORS FOR CHIRAL PERIODIC MESOPOROUS ORGANOSILICA MATERIALS

The development of cost-effective and reliable methods for the synthesis and separation of asymmetric compounds is paramount in helping to meet society’s ever-growing demand for chiral small molecules. Of these methods, chiral heterogeneous supports are particularly appealing as they allow for the reuse of the chiral source. One such support, based on the synergy between chiral organic units and structurally stable inorganic silicon scaffolds are periodic mesoporous organosilicas (PMOs). In the work described herein, I examine some of the factors governing the transmission of chirality between chiral dopants and prochiral bulk phases in chiral PMO materials. In particular, the exploration of 1,1’-binaphthalene-bridged chiral dopants with a focus on the point of attachment into the materials. Moreover, the effects of ordering in the materials are examined and reveal that chirality transfer is more facile in materials with molecular-scale order then those containing amorphous walls. Secondly, the issues surrounding the synthesis and purification of aryl-triethoxysilanes as siloxane precursors are addressed. Both the introduction of a two-carbon linker and the direct attachment of allyl and mixed allyldiethoxysilane species are explored. This work demonstrates that allyldiethoxysilanes are ideal, in that they are stable enough to permit facile synthesis, while still being able to hydrolyze completely to produce well-ordered materials. Lastly, the production of new bulk phases for chiral PMO materials is examined by introducing new prochiral nitrogen-containing siloxane precursors. Biphenyldiamine and bipyridine-bridged siloxane precursors are readily synthesized on reasonable scales. Their use as the bulk siloxane precursor in the production of PMO materials however, is precluded by insufficient gelation and additional siloxane precursors are necessary for the production of ordered materials. In addition to the research detailed above that forms the body of this thesis, two short works are appended. The first details the production of polythiophene assemblies mediated through coordination nanospaces, while the second explores the production of N-heterocyclic carbene functionalized gold nanoparticles through ligand exchange.

(Table T1) Depths and ages of datum levels at ODP Leg 182 sites

The first and last appearances of Quaternary planktonic foraminifers in the Great Australian Bight were evaluated using datum levels from magnetostatigraphy, oxygen isotope stratigraphy, and calcareous nannofossil biostratigraphy to determine whether they were synchronous or diachronous with open-ocean biostratigraphic events. The first appearance of Globorotalia truncatulinoides is diachronous at 1.6-1.7 Ma at Site 1127 and 1.1-1.2 at Sites 1129 and 1132, similar to other local appearances in high latitudes. All other datum levels, however, are synchronous with open-ocean events, including the first appearance of Globorotalia hirsuta and the last appearances of Globorotalia tosaensis and pink Globigerinoides ruber in the Indo-Pacific region. A local reappearance of Gt. hirsuta at ~0.12 Ma and the disappearance of Globorotalia crassaformis at ~0.10 Ma were found to be useful for local biostratigraphy. Age control at the bottom of all of the sections is poor at this time, but results suggest that sedimentation recommenced starting at ~1.9 Ma above the regional unconformity that marks the base of seismostratigraphic Sequence 2. Sediment accumulation is distinctly reduced in the lower Pleistocene compared to the upper Pleistocene, perhaps in part because of processes associated with several omission surfaces.

Stable carbon isotope record and geochemistry of late Miocene-early Pliocene sediments from DSDP Site 90-590 in the Tasman Sea

Biogenic components of sediment accumulated at high rates beneath frontal zones of the Indian and Pacific oceans during the late Miocene and early Pliocene. The delta13C of bulk and foraminiferal carbonate also decreased during this time interval. Although the two observations may be causally linked, and signify a major perturbation in global biogeochemical cycling, no site beneath a frontal zone has independent records of export production and delta13C on multiple carbonate phases across the critical interval of interest. Deep Sea Drilling Project (DSDP) site 590 lies beneath the Tasman Front (TF), an eddy-generating jetstream in the southwest Pacific Ocean. To complement previous delta13C records of planktic and benthic foraminifera at this location, late Neogene records of CaCO3 mass accumulation rate (MAR), Ca/Ti, Ba/Ti, Al/Ti, and of bulk carbonate and foraminiferal delta13C were constructed at site 590. The delta13C records include bulk sediment, bulk sediment fractions (<63 µm and 5-25 µm), and the planktic foraminifera Globigerina bulloides, Globigerinoides sacculifer (with and without sac), and Orbulina universa. Using current time scales, CaCO3 MARs, Ca/Ti, Al/Ti and Ba/Ti ratios are two to three times higher in upper Miocene and lower Pliocene sediment relative to overlying and underlying units. A significant decrease also occurs in all delta13C records. All evidence indicates that enhanced export production - the 'biogenic bloom' - extended to the southwest Pacific Ocean between ca. 9 and 3.8 Ma, and this phenomenon is coupled with changes in delta13C - the 'Chron C3AR carbon shift'. However, CaCO3 MARs peak ca. 5 Ma whereas elemental ratios are highest ca. 6.5 Ma; foraminiferal delta13C starts to decrease ca. 8 Ma whereas bulk carbonate delta13C begins to drop ca. 5.6 Ma. Temporal discrepancies between the records can be explained by changes in the upwelling regime at the TF, perhaps signifying a link between changes in ocean-atmosphere circulation change and widespread primary productivity.

Inducing the development and adoption of socially efficient automotive technology. Final report.

Transportation Systems Center, Cambridge, Mass.

Sourcebook on transit-related environmental regulations: requirements affecting the acquisition and maintenance of transit vehicles and facilities. Final report.

Federal Transit Administration, Washington, D.C.

Splash and spray suppression: technological developments in the design and testing of spray reduction devices for heavy trucks. Report to Congress.

Mode of access: Internet.