Multiscale Treatment of Thin-Film Lubrication

A multiscale technique that combines an atomistic description of the interfacial (near) region with a coarse-grained (continuum) description of the far regions of the solid substrates is proposed. The new hybrid technique, which represents an advance over a previously proposed dynamically-constrained hybrid atomistic-coarse-grained treatment (Wu et al.J. Chem. Phys., 120, 6744, 2004), is applied to a two-dimensional model tribological system comprising planar substrates sandwiching a monolayer film. Shear–stress profiles (shear stress versus strain) computed by the new hybrid technique are in excellent agreement with “exact” profiles (i.e. those computed treating the whole system at the atomic scale).

The interaction between poly(vinylpyrrolidone) and reversed micelles of water/AOT/n-heptane

The interactions between poly(vinylpyrrolidone) (PVP) and the reversed micelles composed of water, AOT, and n-heptane are investigated with the aid of phase diagram, measurements of conductivity and viscosity, Fourier transform infrared (FTIR) spectrum, and dynamic light scattering (DLS). The phase diagrams of water/AOT/heptane in the presence of and absence of PVP are given. The conductivity of the water/AOT/heptane reversed micelle without PVP initially increases and then decreases with the increase of water content, ω0 (the molar ratio of water to AOT), while the plots of conductivity (K) versus ω0 of the reversed micelle in the presence of PVP depend on the PVP concentrations. The plot of K versus ω0 with 2.0%wt PVP is similar to that without PVP. Only the ω0,max (the water content that the maximum conductivity corresponds to) is larger than that without PVP. Nevertheless, the conductivity of the reversed micelle containing more than 4%wt PVP always rises with the increase of the water content in the measured range. The DLS results indicate that the hydrodynamic radius (Rh) in the presence and absence of PVP rises with the increase of ω0. The plots with PVP and without PVP have almost the same value when ω0<17; and after that, it quickly increases with the increase of ω0. It is interesting to find that there is almost no effect of the PVP concentration on the viscosity and Rh of the reversed micelle at ω0 = 15. The FTIR results suggest that the contents of SO3--bound water and Na+-bound water both decrease with PVP added, while the content of the bulky-like water increases. However, the trapped water in the hydrophobic chain of the surfactant is nearly unaffected by PVP. It is also found from the FTIR that the carbonyl group stretching vibration of AOT is fitted into two sub-peaks, which center at 1740 and 1729 cm-1, corresponding to the trans and cis conformations of AOT, respectively.

Microstructural evolution and formation of nanocrystalline intermetallic compound during surface mechanical attrition treatment of cobalt

Nanocrystalline intermetallic Co3Fe7 was produced on the surface of cobalt via surface mechanical attrition (SMA). Deformationinduced diffusion entailed the formation of a series of solid solutions. Phase transitions occurred depending on the atomic fraction of Fe in the surface solid solutions: from hexagonal close-packed (<4% Fe) to face-centered cubic (fcc) (4-11% Fe), and from fcc to body-centered cubic (>11% Fe). Nanoscale compositional probing suggested significantly higher Fe contents at grain boundaries and triple junctions than grain interiors. Short-circuit diffusion along grain boundaries and triple junctions dominate in the nanocrystalline intermetallic compound. Stacking faults contribute significantly to diffusion. Diffusion enhancement due to high-rate deformation in SMA was analyzed by regarding dislocations as solute-pumping channels, and the creation of excess vacancies. Non-equilibrium, atomic level alloying can then be ascribed to deformation-induced intermixing of constituent species. The formation mechanism of nanocrystalline intermetallic grains on the SMA surface can be thought of as a consequence of numerous nucleation events and limited growth. (C) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

On the interaction of water waves and seabed by the porous medium model

The interaction of water waves and seabed is studied by using Yamamoto's model, which takes into account the deformation of soil skeletal frame, compressibility of pore fluid flow as well as the Coulumb friction. When analyzing the propagation of three kinds of stress waves in seabed, a simplified dispersion relation and a specific damping formula are derived. The problem of seabed stability is further treated analytically based on the Mohr-Coulomb theory. The theory is finally applied to the coastal problems in the Lian-Yun Harbour and compared with observations and measurements in soil-wave tank with satisfactory results.

Tidal oscillations at the head of Monterey Submarine Canyon and their relation to oceanographic sampling and the circulation of water in Monterey Bay. Annual report, Part 6, September 1972

During a 25-hour hydrographic times series at two stations near the head of Monterey Submarine Canyon, an internal tide was observed with an amplitude of 80 to 115 m in water depths of 120 and 220 m respectively. These large oscillations produced daily variations in hydrographic and chemical parameters that were of the same magnitude as seasonal variations in Monterey Bay. Computed velocities associated with the internal tide were on the order of 10 em/sec, and this tidally induced circulation may have a significant role in the exchange of deep water between Monterey Submarine Canyon and the open ocean. (PDF contains 49 pages)

The Rise and Fall of Water Net (Hydrodictyon reticulatum) in New Zealand

During the late 1980s to early 1990s a range of aquatic habitats in the central North Island of New Zealand were invaded by the filamentous green alga, water net Hydrodictyon reticulatum (Linn. Lagerheim). The alga caused significant economic and recreational impacts at major sites of infestation, but it was also associated with enhanced invertebrate numbers and was the likely cause of an improvement in the trout fishery. The causes of prolific growth of water net and the range of control options pursued are reviewed. The possible causes of its sudden decline in 1995 are considered, including physical factors, increase in grazer pressure, disease, and loss of genetic vigour.

Evaluation of Water hyacinth and Paddy Straw Waste for Culture of Oyster Mushrooms

Waterhyacinth ( Eichhornia crassipes (Mart.) Solms.) was evaluated at ratios of 25, 50 and 75% with paddy straw ( Oryza sativa L.) for oyster mushroom ( Pleurotus sajor-caju) cultivation. There was an increase in yield with decreasing ratio waterhyacinth.

Influence of water temperature on the efficacy of diquat and endothall versus curlyleaf pondweed

determine the impact of water temperature on the efficacy of the contact herbicides diquat (6,7-dihydrodipyrido [1,2- α:2’,1’-c] pyrazinediium ion) and endothall (7-oxabicyclo [2.2.1] heptane-2,3-dicarboxylic acid) for control of the exotic nuisance species curlyleaf pondweed (Potamogeton crispus L.) across a range of water temperatures.

Influence of Water Depth on the Rate of Expansion of Giant Cutgrass Populations and Management Implications

Giant cutgrass ( Zizaniopsis miliacea (Michx.) Doell. & Asch.), a tall emergent grass native to the southeastern United States, was studied in Lake Seminole where it formed large expanding stands, and Lake Alice where it was confined to a stable narrow fringe.