Optical emission and electron capture of rare-earth trivalent ions located at distinct sites in SnO(2) thin films

We present photoluminescence and decay of photo excited conductivity data for sol-gel SnO(2) thin films doped with rare earth ions Eu(3+) and Er(3+), a material with nanoscopic crystallites. Photoluminescence spectra are obtained under excitation with several monochromatic light sources, such as Kr(+) and Ar(+) lasers, Xe lamp plus a selective monochromator with UV grating, and the fourth harmonic of a Nd: YAG laser (4.65eV), which assures band-to-band transition and energy transfer to the ion located at matrix sites, substitutional to Sn(4+). The luminescence structure is rather different depending on the location of the rare-earth doping, at lattice symmetric sites or segregated at grain boundary layer, where it is placed in asymmetric sites. The decay of photo-excited conductivity also shows different trapping rate depending on the rare-earth concentration. For Er-doped films, above the saturation limit, the evaluated capture energy is higher than for films with concentration below the limit, in good agreement with the different behaviour obtained from luminescence data. For Eu-doped films, the difference between capture energy and grain boundary barrier is not so evident, even though the luminescence spectra are rather distinct.

Air-sea interaction studies at the station occupied by R/V Sirius

The transfer formulas are used to compute hourly values of sensible and latent heat exchanges for the period July 29 to July 31, 1974. Also, values of eddy shearing stress at the sea surface, Bowen's ratio and dissipation of kinetic energy are computed. The data used cover part of the GATE period for station 20 occupied by the Brazilian Naval Ship R/V Sirius in the Equatorial Atlantic (0730 N 4000 W). The variations in the computed values are studied in relation to rainfall and the synoptic situation. © 1980 D. Reidel Publishing Co.

Transient non-Darcy forced convective heat transfer from a flat plate embedded in a fluid-saturated porous medium

Transient non-Darcy forced convection on a flat plate embedded in a porous medium is investigated using the Forchheimer-extended Darcy law. A sudden uniform pressure gradient is applied along the flat plate, and at the same time, its wall temperature is suddenly raised to a high temperature. Both the momentum and energy equations are solved by retaining the unsteady terms. An exact velocity solution is obtained and substituted into the energy equation, which then is solved by means of a quasi-similarity transformation. The temperature field can be divided into the one-dimensional transient (downstream) region and the quasi-steady-state (upstream) region. Thus the transient local heat transfer coefficient can be described by connecting the quasi-steady-state solution and the one-dimensional transient solution. The non-Darcy porous inertia works to decrease the velocity level and the time required for reaching the steady-state velocity level. The porous-medium inertia delays covering of the plate by the steady-state thermal boundary layer. © 1990.

Approximate solution for non-Darcy transient film condensation in a porous medium

The problem of non-darcian transient film condensation adjacent to a vertical flat plate embedded in a porous medium has been considered. The governing equation for the boundary layer thickness was obtained by an integral method and solved approximately by the method of integral relations. It is shown that the results are in good agreement with those obtained exactly by the method of characteristics.

Approximate solution for non-darcy transient film condensation in a porous medium

The problem of non-darcian transient film condensation adjacent to a vertical flat plate embedded in a porous medium has been considered. The governing equation for the boundary layer thickness was obtained by an integral method and solved approximately by the method of integral relations. It is shown that the results are in good agreement with those obtained exactly by the method of characteristics.

A study of the effect of overshooting deep convection on the water content of the TTL and lower stratosphere from Cloud Resolving Model simulations

Simulations of overshooting, tropical deep convection using a Cloud Resolving Model with bulk microphysics are presented in order to examine the effect on the water content of the TTL (Tropical Tropopause Layer) and lower stratosphere. This case study is a subproject of the HIBISCUS (Impact of tropical convection on the upper troposphere and lower stratosphere at global scale) campaign, which took place in Bauru, Brazil (22° S, 49° W), from the end of January to early March 2004. Comparisons between 2-D and 3-D simulations suggest that the use of 3-D dynamics is vital in order to capture the mixing between the overshoot and the stratospheric air, which caused evaporation of ice and resulted in an overall moistening of the lower stratosphere. In contrast, a dehydrating effect was predicted by the 2-D simulation due to the extra time, allowed by the lack of mixing, for the ice transported to the region to precipitate out of the overshoot air. Three different strengths of convection are simulated in 3-D by applying successively lower heating rates (used to initiate the convection) in the boundary layer. Moistening is produced in all cases, indicating that convective vigour is not a factor in whether moistening or dehydration is produced by clouds that penetrate the tropopause, since the weakest case only just did so. An estimate of the moistening effect of these clouds on an air parcel traversing a convective region is made based on the domain mean simulated moistening and the frequency of convective events observed by the IPMet (Instituto de Pesquisas Meteorológicas, Universidade Estadual Paulista) radar (S-band type at 2.8 Ghz) to have the same 10 dBZ echo top height as those simulated. These suggest a fairly significant mean moistening of 0.26, 0.13 and 0.05 ppmv in the strongest, medium and weakest cases, respectively, for heights between 16 and 17 km. Since the cold point and WMO (World Meteorological Organization) tropopause in this region lies at ∼ 15.9 km, this is likely to represent direct stratospheric moistening. Much more moistening is predicted for the 15-16 km height range with increases of 0.85-2.8 ppmv predicted. However, it would be required that this air is lofted through the tropopause via the Brewer Dobson circulation in order for it to have a stratospheric effect. Whether this is likely is uncertain and, in addition, the dehydration of air as it passes through the cold trap and the number of times that trajectories sample convective regions needs to be taken into account to gauge the overall stratospheric effect. Nevertheless, the results suggest a potentially significant role for convection in determining the stratospheric water content. Sensitivity tests exploring the impact of increased aerosol numbers in the boundary layer suggest that a corresponding rise in cloud droplet numbers at cloud base would increase the number concentrations of the ice crystals transported to the TTL, which had the effect of reducing the fall speeds of the ice and causing a ∼13% rise in the mean vapour increase in both the 15-16 and 16-17 km height ranges, respectively, when compared to the control case. Increases in the total water were much larger, being 34% and 132% higher for the same height ranges, but it is unclear whether the extra ice will be able to evaporate before precipitating from the region. These results suggest a possible impact of natural and anthropogenic aerosols on how convective clouds affect stratospheric moisture levels.

Optical and transport properties of rare-earth trivalent ions located at different sites in sol-gel SnO2

Photoluminescence and photo-excited conductivity data as well as structural analysis are presented for sol-gel SnO2 thin films doped with rare earth ions Eu3+ and Er3+, deposited by sol-gel-dip-coating technique. Photoluminescence spectra are obtained under excitation with various types of monochromatic light sources, such as Kr+, Ar+ and Nd:YAG lasers, besides a Xe lamp plus a selective monochromator with UV grating. The luminescence fine structure is rather different depending on the location of the rare-earth doping, at lattice symmetric sites or segregated at the asymmetric grain boundary layer sites. The decay of photo-excited conductivity also shows different trapping rate depending on the rare-earth concentration. For Er-doped films, above the saturation limit, the evaluated capture energy is higher than for films with concentration below the limit, in good agreement with the different behaviour obtained from luminescence data. For Eu-doped films, the difference in the capture energy is not so evident in these materials with nanoscocopic crystallites, even though the luminescence spectra are rather distinct. It seems that grain boundary scattering plays a major role in Eu-doped SnO2 films. Structural evaluation helps to interpret the electro-optical data. © 2010 IOP Publishing Ltd.

Mean surface temperature prediction models for broiler chickens-a study of sensible heat flow

Body surface temperature can be used to evaluate thermal equilibrium in animals. The bodies of broiler chickens, like those of all birds, are partially covered by feathers. Thus, the heat flow at the boundary layer between broilers' bodies and the environment differs between feathered and featherless areas. The aim of this investigation was to use linear regression models incorporating environmental parameters and age to predict the surface temperatures of the feathered and featherless areas of broiler chickens. The trial was conducted in a climate chamber, and 576 broilers were distributed in two groups. In the first trial, 288 broilers were monitored after exposure to comfortable or stressful conditions during a 6-week rearing period. Another 288 broilers were measured under the same conditions to test the predictive power of the models. Sensible heat flow was calculated, and for the regions covered by feathers, sensible heat flow was predicted based on the estimated surface temperatures. The surface temperatures of the feathered and featherless areas can be predicted based on air, black globe or operative temperatures. According to the sensible heat flow model, the broilers' ability to maintain thermal equilibrium by convection and radiation decreased during the rearing period. Sensible heat flow estimated based on estimated surface temperatures can be used to predict animal responses to comfortable and stressful conditions. © 2013 ISB.

An analysis of diurnal cycles in the mass of ambient aerosols derived from biomass burning and agro-industry

Strong diurnal cycles in ambient aerosol mass were observed in a rural region of Southeast Brazil where the trace composition of the lower troposphere is governed mainly by emissions from agro-industry. An optical particle counter was used to record size-segregated aerosol number concentrations between 13 May 2010 and 15 March 2011. The data were collected every 10 min and used to calculate aerosol mass concentrations. Aerosol samples were also collected onto filters during daytime (10:00-16:00 local time) and nighttime (20:00-06:00) periods, for subsequent analysis of soluble ions and water-soluble organic carbon. Biomass burning aerosols predominated during the dry winter, while secondary aerosols were most important in the summer rainy season. In both seasons, diurnal cycles in calculated aerosol mass concentrations were due to the uptake of water by the aerosols and, to a lesser extent, to emissions and secondary aerosol formation. In neither season could the observed mass changes be explained by changes in the depth of the boundary layer. In the summer, nighttime increases in aerosol mass ranged from 2.7-fold to 81-fold, depending on particle size, while in the winter, the range was narrower, from 2.2-fold to 9.5-fold, supporting the possibility that the presence of particles derived from biomass burning reduced the overall ability of the aerosols to absorb water. Key Points Diurnal cycle of agro-industrial aerosol mass governed by humidity Biomass burning emissions act to suppress particle growth Need to consider diurnal mass cycles in aerosol dry deposition models ©2013. American Geophysical Union. All Rights Reserved.

Effects of cold fronts on MODIS-derived sensible and latent heat fluxes in Itumbiara reservoir (Central Brazil)

In this work we investigate the cold front passage effects on sensible and latent heat flux in a tropical hydroelectric reservoir. The study area, Itumbiara reservoir (Goiás State/Brazil) at the beginning of the austral winter, is characterized by the presence of a weak thermal stratification and the passage of several cold fronts from higher latitudes of South America. Sensible and latent heat fluxes were estimated considering the atmospheric boundary layer stability. In situ and MODIS water surface temperature data were used to adjust the coefficients for momentum and heat exchanges between water and atmosphere and spatialize the sensible and latent heat fluxes. The results showed that during a cold front event the sensible heat flux can be up to five times greater than the flux observed before. The latent heat flux tends to decrease during the cold front but increase again after the passage. The highest values of heat loss were observed at littoral zone and some Reservoir's embayment. The heat loss intensification can be separated in two moments: first, during the cold front passage, when the wind speed increases and the air temperature decreases; second, after the cold front passage, with air humidity decreasing. This can be considered a key process to understanding the heat loss in the Itumbiara reservoir. © 2013 COSPAR. Published by Elsevier Ltd. All rights reserved.

Análise do campo térmico de cidades de médio porte: estudo de caso no pólo textil de Americana - SP

Pós-graduação em Geografia - IGCE

Caracterização de regimes de umidade em regiões tropicais: comparação entre floresta e savana

Este trabalho tem como objetivo investigar um método de classificação de regimes de umidade, baseado na caracterização de diferentes “estados” da Camada Limite Atmosférica Tropical (CLAT), tanto acima de uma área de floresta quanto acima de uma área de savana, de acordo com a metodologia proposta por Mahrt (1991). A partir dessa classificação é elaborado um aperfeiçoamento da mesma que incorpora tanto uma análise da estabilidade termodinâmica da CLAT para a área de floresta, quanto uma investigação sobre a contribuição da Energia Potencial Disponível para Convecção (CAPE) para a classificação dos regimes de umidade. Para essas análises foram utilizados dados de radiossondagens e de torres micrometeorológicas, coletados durante o período menos chuvoso de cada região. Esses dados foram obtidos durante experimentos de campo realizados nas áreas de estudo, sendo que para a área de floresta (Caxiuanã) se utilizaram os dados do experimento COBRA-PARÁ (realizado no período de 06 a 13/11 de 2006), enquanto que para a área de savana (Daly Waters) se utilizaram os dados do experimento “KOORIN” (realizado no período de 15/07 a 13/08 de 1974, na Austrália). A comparação entre os regimes de umidade de cada região sugere que, caso houvesse a savanização da Amazônia, a mesma apresentaria uma atmosfera seca, com a maior parte da energia utilizada para o aquecimento dessa atmosfera, com baixos índices de evapotranspiração, menores taxas de precipitação e inexistência de CAPE. Por outro lado, a análise da estabilidade da atmosfera para Caxiuanã mostrou que, contrariamente ao observado em experimentos na Amazônia Ocidental, na Amazônia Oriental, durante o experimento COBRA-PARÁ, os maiores valores de CAPE ocorreram às 18:00 HL, possivelmente, em decorrência da convergência de umidade que provém da baía de Caxiuanã através da circulação de brisa terrestre. Isso indica que nessa região os máximos de CAPE estiveram associados predominantemente aos campos de umidade e não aos de temperatura. Para essas condições de CLAT “perturbada” o espaço de fase proposto por Mahrt (1991) não caracteriza muito bem regimes de umidade associados a grandes valores da CAPE.

Estrutura eletrônica e propriedades elétricas fotoinduzidas em filmes finos de SnO2 com dopagem de Sb, e formação de heteroestruturas com TiO2

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

A Multiple-Vortex Tornado in Southeastern Brazil

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Land use and thermal comfort in the county of Ourinhos, SP

This study aims to analyze the thermal comfort in urban areas for different land uses. The ENVImet microclimatic model has been used for urban boundary layer simulation, providing the following thermal comfort indexes: PMV (Predicted Mean Vote) and PPD (Predicted Percentage of Dissatisfaction). The chosen area covers the central area in the city of Ourinhos, located in southeastern Brazilian city, with subtropical climate. Four simulations were accomplished: an area with real buildings and vegetation on site, a “grassy” area where buildings have been replaced by grass in the central area, another grassy area, known as “grass/tree”, with additional trees in, and a final area called “Park” also grassy, where trees were added all over the area. The structures which showed thermal comfort within the ISO 7730 standards were the grassy area with no trees at 9 a.m., and a paved area, as well as the park area at 3 p.m. Other situations have presented values of PMV and PPD off the limits required by the rules; they were very close to those values. The only point that presented a far cry from the comfort required was the spot in the asphalt at 9 a.m. The other situations showed PMV and PPD values not far from the limits of comfort. Only the point on the asphalt showed values far from the limit of comfort at 9 a.m.