Tailoring of structures and permeation properties of asymmetric nanocomposite cellulose acetatesilver membranes

Cellulose acetate (CA)-silver (Ag) nanocomposite asymmetric membranes were prepared via the wet-phase inversion method by dispersing polyvinylpirrolydone-protected Ag nanoparticles in the membrane casting solutions of different compositions. Silver nanoparticles were synthesized ex situ and added to the casting solution as a concentrated aqueous colloidal dispersion. The effects of the dispersion addition on the structure and on the selective permeation properties of the membranes were studied by comparing the nanocomposites with the silver-free materials. The casting solution composition played an important role in the adequate dispersion of the silver nanoparticles in the membrane. Incorporation of nanoscale silver and the final silver content resulted in structural changes leading to an increase in the hydraulic permeability and molecular weight cut-off of the nanocomposite membranes. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41796.

Modification of cell volume and proliferative capacity of Pseudokirchneriella subcapitata cells exposed to metal stress

The impact of metals (Cd, Cr, Cu and Zn) on growth, cell volume and cell division of the freshwateralga Pseudokirchneriella subcapitata exposed over a period of 72 h was investigated. The algal cells wereexposed to three nominal concentrations of each metal: low (closed to 72 h-EC10values), intermediate(closed to 72 h-EC50values) and high (upper than 72 h-EC90values). The exposure to low metal concen-trations resulted in a decrease of cell volume. On the contrary, for the highest metal concentrations anincrease of cell volume was observed; this effect was particularly notorious for Cd and less pronouncedfor Zn. Two behaviours were found when algal cells were exposed to intermediate concentrations ofmetals: Cu(II) and Cr(VI) induced a reduction of cell volume, while Cd(II) and Zn(II) provoked an oppositeeffect. The simultaneous nucleus staining and cell image analysis, allowed distinguishing three phases inP. subcapitata cell cycle: growth of mother cell; cell division, which includes two divisions of the nucleus;and, release of four autospores. The exposure of P. subcapitata cells to the highest metal concentrationsresulted in the arrest of cell growth before the first nucleus division [for Cr(VI) and Cu(II)] or after thesecond nucleus division but before the cytokinesis (release of autospores) when exposed to Cd(II). Thedifferent impact of metals on algal cell volume and cell-cycle progression, suggests that different toxic-ity mechanisms underlie the action of different metals studied. The simultaneous nucleus staining andcell image analysis, used in the present work, can be a useful tool in the analysis of the toxicity of thepollutants, in P. subcapitata, and help in the elucidation of their different modes of action.

Large-area homogeneous periodic surface structures generated on the surface sputtered boron carbide thin films by femtosecond laser processing

Amorphous and crystalline sputtered boron carbide thin films have a very high hardness even surpassing that of bulk crystalline boron carbide (≈41 GPa). However, magnetron sputtered B-C films have high friction coefficients (C.o.F) which limit their industrial application. Nanopatterning of materials surfaces has been proposed as a solution to decrease the C.o.F. The contact area of the nanopatterned surfaces is decreased due to the nanometre size of the asperities which results in a significant reduction of adhesion and friction. In the present work, the surface of amorphous and polycrystalline B-C thin films deposited by magnetron sputtering was nanopatterned using infrared femtosecond laser radiation. Successive parallel laser tracks 10 μm apart were overlapped in order to obtain a processed area of about 3 mm2. Sinusoidal-like undulations with the same spatial period as the laser tracks were formed on the surface of the amorphous boron carbide films after laser processing. The undulations amplitude increases with increasing laser fluence. The formation of undulations with a 10 μm period was also observed on the surface of the crystalline boron carbide film processed with a pulse energy of 72 μJ. The amplitude of the undulations is about 10 times higher than in the amorphous films processed at the same pulse energy due to the higher roughness of the films and consequent increase in laser radiation absorption. LIPSS formation on the surface of the films was achieved for the three B-C films under study. However, LIPSS are formed under different circumstances. Processing of the amorphous films at low fluence (72 μJ) results in LIPSS formation only on localized spots on the film surface. LIPSS formation was also observed on the top of the undulations formed after laser processing with 78 μJ of the amorphous film deposited at 800 °C. Finally, large-area homogeneous LIPSS coverage of the boron carbide crystalline films surface was achieved within a large range of laser fluences although holes are also formed at higher laser fluences.

Multi-strand narrative structures: a filmic game of multiple players

Session 7: Playing with Roles, images and improvising New States of Awareness, 3rd Global Conference, 1st November – 3rd November, 2014, Prague, Czech Republic.

Multiobjective optimization of viscoelastic laminated sandwich structures using the Direct MultiSearch method

A multiobjective approach for optimization of passive damping for vibration reduction in sandwich structures is presented in this paper. Constrained optimization is conducted for maximization of modal loss factors and minimization of weight of sandwich beams and plates with elastic laminated constraining layers and a viscoelastic core, with layer thickness and material and laminate layer ply orientation angles as design variables. The problem is solved using the Direct MultiSearch (DMS) solver for derivative-free multiobjective optimization and solutions are compared with alternative ones obtained using genetic algorithms.

Single side damage simulations and detection in beam-like structures

Beam-like structures are the most common components in real engineering, while single side damage is often encountered. In this study, a numerical analysis of single side damage in a free-free beam is analysed with three different finite element models; namely solid, shell and beam models for demonstrating their performance in simulating real structures. Similar to experiment, damage is introduced into one side of the beam, and natural frequencies are extracted from the simulations and compared with experimental and analytical results. Mode shapes are also analysed with modal assurance criterion. The results from simulations reveal a good performance of the three models in extracting natural frequencies, and solid model performs better than shell while shell model performs better than beam model under intact state. For damaged states, the natural frequencies captured from solid model show more sensitivity to damage severity than shell model and shell model performs similar to the beam model in distinguishing damage. The main contribution of this paper is to perform a comparison between three finite element models and experimental data as well as analytical solutions. The finite element results show a relatively well performance.

Acompanhamento de direção de obras de reconstrução na Mouraria

Relatório de Estágio para obtenção do grau de mestre em Engenharia Civil na Área de Especialização de Edificações

Sulfonated Schiff base copper(ii) complexes as efficient and selective catalysts in alcohol oxidation: syntheses and crystal structures

The reaction between 2-aminobenzenesulfonic acid and 2-hydroxy-3-methoxybenzaldehyde produces the acyclic Schiff base 2-[(2-hydroxy-3-methoxyphenyl) methylideneamino] benzenesulfonic acid (H2L center dot 3H(2)O) (1). In situ reactions of this compound with Cu(II) salts and, eventually, in the presence of pyridine (py) or 2,2'-bipyridine (2,2'-bipy) lead to the formation of the mononuclear complexes [CuL(H2O)(2)] (2) and [CuL(2,2'-bipy)]center dot DMF center dot H2O (3) and the diphenoxo-bridged dicopper compounds [CuL(py)](2) (4) and [CuL(EtOH)](2)center dot 2H(2)O (5). In 2-5 the L-2-ligand acts as a tridentate chelating species by means of one of the O-sulfonate atoms, the O-phenoxo and the N-atoms. The remaining coordination sites are then occupied by H2O (in 2), 2,2'-bipyridine (in 3), pyridine (in 4) or EtOH (in 5). Hydrogen bond interactions resulted in R-2(2) (14) and in R-4(4)(12) graph sets leading to dimeric species (in 2 and 3, respectively), 1D chain associations (in 2 and 5) or a 2D network (1). Complexes 2-5 are applied as selective catalysts for the homogeneous peroxidative (with tert-butylhydroperoxide, TBHP) oxidation of primary and secondary alcohols, under solvent-and additive-free conditions and under low power microwave (MW) irradiation. A quantitative yield of acetophenone was obtained by oxidation of 1-phenylethanol with compound 4 [TOFs up to 7.6 x 10(3) h(-1)] after 20 min of MW irradiation, whereas the oxidation of benzyl alcohol to benzaldehyde is less effective (TOF 992 h(-1)). The selectivity of 4 to oxidize the alcohol relative to the ene function is demonstrated when using cinnamyl alcohol as substrate.

Metal ions and protein folding: conformational and functional interplay

Dissertation presented to obtain a PhD degree in Biochemistry at Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa

Evolution and biogenesis of microtubule-derived structures

Dissertação apresentada para obtenção do grau de Doutor em Biologia Celular pelo Instituto de Tecnologia Química e Biológica da Universidade Nova de Lisboa

Projeto de uma ponte atirantada rodoferroviária sobre o rio Lima, Viana do Castelo

Trabalho académico com o objetivo do autor desenvolver um estudo prévio e um projeto de uma travessia sobre o rio Lima, na cidade de Viana do Castelo constituída por uma ponte de tirantes rodoferroviária. O projeto académico visa, também, desenvolver e compreender: os conceitos básicos, as metodologias de conceção, e o funcionamento de estruturas desse género. O motivo principal da escolha do tema é a necessidade de uma alternativa à ponte Eiffel em Viana do Castelo, e juntando o facto de em Portugal não existir nenhuma obra de arte de tirantes rodoferroviária até ao presente, seria interessante estudar e projetar uma estrutura rodoferroviária de tirantes. Das diversas possibilidades de sistemas estruturais estudados, adotou-se uma ponte que acomodará 4 vias rodoviárias e 2 vias ferroviárias, com um desenvolvimento total de 660 metros, constituída por dois vãos laterais com 165 metros cada um, e com um vão central de 330 metros. A obra de arte será em semi-leque com dois planos de tirantes, ancorados a duas torres de betão em Y invertido de altura aproximadamente de 110 metros. O tabuleiro será duplo misto aço-betão, constituído por duas vigas trianguladas do tipo Warren, e por carlingas, afastadas entre si de 15 metros com secções tubulares metálicas de espessura variável. As carlingas ao nível superior suportam a laje de betão, que constitui a rodovia, e inferiormente, suportam outra laje de betão para a parte ferroviária. O trabalho inicia-se com o enquadramento conceptual geral da envolvente da obra de arte, seguidamente com apresentação da evolução histórica ao longo do tempo das pontes de tirantes, e à apresentação de algumas pontes rodoferroviárias de tirantes. É realizada uma análise preliminar, onde se estudam as restrições, as condicionantes, o local de implantação, e o sistema da configuração geométrica a adotar na conceção estrutural. São descritos todos os tipos de materiais, equipamentos a utilizar, bem como as suas características mecânicas necessárias para o cálculo estrutural. A quantificação das ações e das combinações de cálculo efetuaram-se de acordo com as normas em vigor nacionais e europeias, designadamente os Eurocódigos das várias especialidades e o Regulamento de Segurança e Ações para Estruturas de Edifícios e Pontes. Efetuou-se um pré-dimensionamento e uma otimização de vários sistemas estruturais possíveis de todos os elementos estruturais, tendo em conta variáveis de estudo como a economia e a resistência estrutural das secções, por forma a chegar à solução final. A estrutura foi discretizada e analisada num modelo estático tridimensional num programa de cálculo automático. A análise de resultados foi efetuada longitudinalmente para a verificação dos Estados Limites Últimos e Estados Limites de Utilização dos elementos estruturais que constituem a ponte. Foi ainda efetuada uma estimativa orçamental da ponte no rio Lima na cidade de Viana do Castelo.

Metal ions modulate the folding and stability of the tumor suppressor protein S100A2

Febs Journal (2009)276:1776-1786

Estrutura metálica do teto falso da sala de comando da central Venda Nova III – acompanhamento da conceção, fabrico e montagem

O primeiro objetivo deste relatório, que adiante se desenvolve, é apresentar o trabalho realizado para a obtenção de conhecimentos que justifiquem a atribuição do grau de mestre em engenharia, no ramo das construções. O estágio, que a este trabalho dá sustentação, foi feito na empresa Metaloviana, onde foi possível acompanhar as várias fases de conceção, fabrico e montagem de um teto falso, designadamente na sala de comando da central Venda Nova III, de aproveitamento hidroelétrico. Tendo Portugal objetivos cada vez mais ambiciosos na utilização de energias renováveis, aproveitando, entre outros, os recursos hídricos para a produção de eletricidade, a EDP Produção fez estudos onde verificou que a realização de reforços de potência em aproveitamento já existentes, seria uma forma economicamente bastante atrativa e ao mesmo tempo responderia às crescentes solicitações energéticas. É neste âmbito que se insere o Reforço de Potência em Venda Nova III. A empresa Metaloviana, com instalações fabris em Viana do Castelo, tem todo um historial e capacidade, reconhecida nacional e internacionalmente. Este, confere a certeza de ter acompanhado um trabalho de ponta, devidamente creditado e fundamentado numa qualidade e mérito, por demais reconhecido.

Life-cycle performance of structures: combining expert judgment and results of inspection

Life-Cycle Civil Engineering – Biondini & Frangopol

Vibration control with shape-memory alloys in civil engineering structures

Dissertação apresentada à Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa para obtenção do grau de Doutor em Engenharia Civil