980 resultados para IgM anti-glicolipido fenolico-I (IgM ANTI GF-I) UltramicroELISA


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[Geb. 5. Juli 87 Ostrowo; Wohnort: Posen; Staatsangeh.: Preussen; Vorbildung: Auguste-Viktoria-G. Posen Reife 07; Studium: Theol. u. Phil. Halle 3, Lausanne I, Heidelberg 4 S.; Rig. 12. Mai II.]

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On verso: Joel Unangst

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Thesis (Master's)--University of Washington, 2016-06

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Thesis (Master's)--University of Washington, 2016-06

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[GRAPHICS] The major cuticular hydrocarbons from the cane beetle species Antitrogus parvulus are 4,6,8,10,16-penta- and 4,6,8,10,16,18-hexamethyldocosanes, I and 2, respectively. Stereoisomers of 2,4,6,8-tetramethylundecanal of established relative stereochemistry were derived from 2,4,6-trimethylphenol and were then coupled with appropriate methyl-substituted phosphoranes 62 and 25 to furnish alkenes, which on reduction provided diastereomers of I and 2, respectively. Capillary gas chromatography, mass spectrometry, and high resolution C-13 NMR spectroscopy confirmed 1 as either 84a or 84b and 2 as either 15a or 15b. The novelty of these structures and their relative stereochemistry is briefly related to polyketide assembly.