922 resultados para Historia País Vasco ..-s.XVII fuentes


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Este libro trata de explicar con claridad y sencillez la forma canónica de Kronecker de haces de matrices para la relación de equivalencia estricta. El tema es importante para los ingenieros, físicos, químicos, economistas y otros científicos que estudian sistemas lineales con control, por lo que una introducción asequible y rigurosa se echa de menos. También esperamos que el libro sea de utilidad para los matemáticos en un segundo curso de álgebra lineal como complemento natural del estudio de la forma canónica de Jordan. La forma canónica de Kronecker es llamada igualmente de Weierstrass-Kronecker, ya que Weierstrass desarrolla la teoría de los divisores elementales y Kronecker la de los índices minimales. Desde un punto de vista epistemológico e histórico deben relacionarse estas teorías con el estudio geométrico de los haces de cónicas y cuádricas para la formación del estudiante de matemáticas. Este libro no intenta establecer estas conexiones. Al lector que desee proseguir en los precedentes históricos le recomendamos el libro sobre historia de las matemáticas de Bourbaki y también artículos de Robert Thompson, Frank Uhlig y otros en la revista Linear Algebra and Its Applications en los años 1980.

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Crónica jurisprudencial y legislativa correspondiente al segundo semestre de 2014 en materia de lengua y derecho.

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785p. -- De forma paralela al proceso de investigación para esta Tesis el investigador llevó a cabo un documental de 80 minutos de duración, titulado "Oteiza y el Centro Cultural Alhóndiga. Proyecto estético para Bilbao". Este documental está elaborado a partir de las entrevistas arriba señaladas, así como de material audiovisual inédito sobre este proyecto. El documental está expuesto de forma permanente en el Museo Jorge Oteiza (Alzuza, Navarra)

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[EN] Store brands account for and important market share in the Spain and a further increase in expected in the next years due to the downturn. However, there is lack of research on store brand customer-based Brand Equity. This study attempts to propose an integrated model of Brand Equity in store or retailer brands, based on Aaker s well-known conceptual model. We propose a consumer-based model, including the main sources or dimensions of Brand Equity and considering the intention to purchase as a consequence. Based on a sample of 362 consumers and 5 store brands, structural equation modeling is used to test research hypotheses. The results obtained reveal that store brand awareness, loyalty along with store brand perceived quality have a significant influence on consumers intention to purchase store brands. Our study suggests that marketers and marketing managers from retailing companies should carefully consider the Brand Equity components when designing their brand strategies, and develop marketing activities in order to enhance their brands awareness.

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La Geología es la ciencia que estudia la Tierra en su conjunto, su composición, estructura y origen, así como los fenómenos que han tenido lugar en el pasado o que se producen en la actualidad y que han dejado sus huellas en las rocas. Pero, ¿por qué necesita la sociedad a los geólogos? A continuación se citan algunas de las principales razones: - Los geólogos recopilan e interpretan información de la superficie terrestre y del subsuelo, lo que permite establecer la historia pasada del planeta, sus cambios previsibles y su relación con el resto del sistema solar. - La sociedad requiere para su subsistencia recursos naturales (metálicos, no metálicos, hídricos y combustibles fósiles). La labor de los geólogos es determinante para la localización de nuevos yacimientos y para establecer las guías de una explotación y gestión respetuosa con el medio ambiente. - La elaboración de cartografías geológicas permite identificar potenciales zonas de riesgo y acotar distintos usos del suelo; es decir, es esencial para la planificación del territorio y para proponer estrategias de desarrollo sostenible en una región. - La educación en Geología y el buen uso de la información geológica contribuye a salvar vidas y a reducir las pérdidas económicas originadas por catástrofes naturales tales como terremotos, tsunamis, erupciones volcánicas, inundaciones y desprendimientos, así como a desarrollar proyectos de construcción, obras públicas, etc. Con las actividades propuestas se pretende dar a conocer algunos aspectos básicos de distintas especialidades de las Ciencias Geológicas. Para ello se han organizado cuatro sesiones destinadas a realizar una pequeña inmersión en el campo de la Paleontología, la Mineralogía, la Petrología y la Tectónica.

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Dónde, con quién y de qué vivir son cuestiones clave a la hora de explicar las estrategias familiares, y también los ejes de este libro. Tras explicitar sus premisas teóricas y plantear las líneas generales en la evolución de la ciudad, Iruñea-Pamplona, el libro se estructura en tres capítulos que analizan cada una de las estas preguntas. Por un lado, el autor constata la importancia de la inmigración y analiza las lógicas familiares que guían estos movimientos, así como su influencia en la realidad lingüística urbana. En segundo lugar estudia las diferencias sociales en la formación de los hogares, apreciando un fortalecimiento de la familia obrera en los inicios de la industrialización. Por último se centra en la participación de los diferentes miembros de la familia en el mercado laboral, prestando especial atención al empleo femenino, los valores de género subyacentes y la feminización de la pobreza. Se trata de una investigación sobre estrategias familiares, que también pretende reflexionar sobre el papel de los valores familiares en el mantenimiento del orden social.

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Desde su creación en 1976 la Sociedad Española de Antropología Física (SEAF) viene celebrando sus congresos bienales de forma ininterrumpida en distintas ciudades españolas. Estos encuentros, destinados a la discusión de los avances y resultados de las investigaciones bioantropológicas, suponen un foro de debate científico en el que participan investigadores de diversas áreas interesados en los estudios de Antropología Física, promoviendo la interacción entre especialistas e investigadores en formación. Asimismo, y dado el interés que esta disciplina despierta en la sociedad en general, la celebración de los Congresos de la SEAF permite mostrar las novedades acontecidas en el ámbito de la ciencia bioantropológica, facilitando la difusión del conocimiento más allá de la esfera académica. En este marco de reuniones científicas, los profesores del área de Antropología Física de la Facultad de Ciencia y Tecnología de la Universidad del País Vasco-Euskal Herriko Unibertsitatea (UPV/EHU) han sido los encargados de organizar el XVIII Congreso de la SEAF, celebrado en Bilbao durante los días 19 a 21 de junio de 2013. Este libro recoge las ponencias y principales comunicaciones presentadas en el XVIII Congreso, seleccionadas para su publicación y agrupadas en diferentes bloques temáticos que recogen algunas de los conocimientos actuales de la investigación bioantropológica: Ecología Humana, Biología Esquelética y Antropología Forense Paleoantropología y Primatología, y Diversidad Genética Humana. Se ha pretendido mostrar algunas de las cuestiones más relevantes actualmente y la proyección futura de la investigación en Antropología biológica, encaminada tanto al cuestionamiento de paradigmas (como la preponderancia de África en la evolución humana o la existencia de una única especie humana a partir del Pleistoceno Superior, entre otros), como a la comprensión de la relación fenotipo-genotipo, entre otras cuestiones de gran importancia para la reconstrucción de la historia evolutiva de nuestra especie. Sirvan las ponencias invitadas como ejemplo del nuevo enfoque de algunas áreas de la investigación en Antropología.

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Nerea Aresti ha analizado la contribución de científicos e intelectuales católicos en la modernización de la sociedad española, probando que la categoría de género es fundamental para el análisis de la historia. Nuevas imágenes de masculinidad y feminidad basadas en principios biológicos y médicos se constituyeron en una pieza clave de la cultura liberal. En este proceso, figuras como Gregorio Marañón magnificaron la diferencia sexual a expensas de la igualdad, ayudando a crear una noción de liberalismo totalmente peculiar. Este libro no es un libro más. Se trata de un estudio brillante que representa un verdadero punto de inflexión en su campo.

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Cuando se aborda el estudio de la teoría del estado o del derecho se investiga desde una perspectiva androcéntrica, fruto del sistema patriarcal en el que estamos inmersas e inmersos investigadoras e investigadores, de manera que se obvia la presencia o ausencia de las mujeres en el ámbito de estudio del que se trate. Y el estudio de la historia de las mujeres es necesario para cualquier investigación que pretenda referirse a la humanidad entera. Hay muchos trabajos que abordan el estudio de las materias que aquí se tratan, pero ninguno de ellos se ocupa de manera sistemática o detallada de la participación de las mujeres en ese momento histórico o en la elaboración de los conceptos que sirven de base a nuestros actuales estados constitucionales.

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Índice: - Sobre museos, redes sociales y tecnología 2.0 (Alex Ibáñez Etxeberria). - Sitios web y museos: nuevas aplicaciones para el aprendizaje informal (Mikel Asensio, Elena Asenjo y Alex Ibáñez Etxeberria). - From headphones to microphones: mobile social media in the museum as distributed network (Nancy Proctor). - Mobile learning y patrimionio: aprendiendo historia con mi teléfono, mi GPS y mi PDA (Alex Ibáñez Etxeberria, Mikel Asensio y José Miguel Correa). - Digital asset management strategies for multi-platform content delivery (Titus Bicknell). - Redes sociales y museos participativos: la irrupción de las tecnologías 2.0 en la sociedad y su aplicación en los museos a través del caso de Arazi (Juan José Aranburu).

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A lo largo de la historia, la actividad física ha tenido una importante presencia en el comportamiento diario de los seres humanos, siendo diferentes las funciones, interpretaciones y motivaciones de dicha práctica, pero siempre, asociadas a un carácter existencial. Este concepto ha ido evolucionando a lo largo del tiempo, identificándolo en sus inicios con una actividad condicionada y vinculada de forma significativa a la cultura propia de los pueblos que lo practicaban, hasta convertirse en un fenómeno de masas, con implicaciones sociológicas y económicas difíciles de explicar. En este sentido, se ha podido constatar que, durante los últimos años, ha existido un especial interés por parte de los organismos públicos para conocer y valorar la práctica deportiva en Gipuzkoa.

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Geologia Lurra aztertzen duen zientzia da: lurraren osaera, egitura eta jatorria, eta bai arroketan aztarnak utzi dituzten iraganeko edo gaur egungo gertaerak ere. Baina, zergatik du gizarteak geologoen beharra? Hona hemen zenbait arrazoi: - Geologoek lurrazalari eta lurpeari buruzko informazioa bildu, eta interpretatu egiten dute. Informazio horrek guztiak ahalbidetzen du planetaren iraganeko historia, Lurrean aurreikus daitezkeen aldaketak eta gure planetak Eguzki-sistemarekin duen harremana finkatzea. - Gizarteak beharrezkoak ditu baliabide naturalak (metalikoak, ez-metalikoak, ura eta erregai fosilak). Geologoen parte-hartzea erabakigarria da hobi berriak aurkitzeko eta ingurumena zaintzen duten baliabide naturalen ustiapen eta kudeaketarako irizpideak ezartzeko. - Kartografia geologikoen bidez arrisku-eremuak identifikatu eta lurzoruaren erabilerak mugatzen dira. Geologoak beharrezkoak dira, beraz, lurraldearen planifikaziorako eta garapen iraunkorrerako estrategiak garatzeko. - Geologiaren ezagutzak eta informazio geologikoaren erabilera egokiak laguntzen dute bizitzak salbatzen eta lurrikarak, tsunamiak, erupzio bolkanikoak, uholdeak eta lurjausiak bezalako katastrofe naturalek eragindako diru-galerak murrizten. Halaber laguntzen dute eraikuntza-proiektuak, herri-lanak eta abar garatzen ere. Proposatutako jardueren bitartez, Zientzia Geologikoen adar desberdinen oinarrizko zenbait alderdi ezagutzera eman nahi ditugu. Horretarako, lau saio antolatu ditugu Paleontologia, Mineralogia, Petrologia eta Tektonika arloetan murgiltzeko.

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[EN] This PhD work started in March 2010 with the support of the University of the Basque Country (UPV/EHU) under the program named “Formación de Personal Investigador” at the Chemical and Environmental Engineering Department in the Faculty of Engineering of Bilbao. The major part of the Thesis work was carried out in the mentioned department, as a member of the Sustainable Process Engineering (SuPrEn) research group. In addition, this PhD Thesis includes the research work developed during a period of 6 months at the Institut für Mikrotechnik Mainz GmbH, IMM, in Germany. During the four years of the Thesis, conventional and microreactor systems were tested for several feedstocks renewable and non-renewable, gases and liquids through several reforming processes in order to produce hydrogen. For this purpose, new catalytic formulations which showed high activity, selectivity and stability were design. As a consequence, the PhD work performed allowed the publication of seven scientific articles in peer-reviewed journals. This PhD Thesis is divided into the following six chapters described below. The opportunity of this work is established on the basis of the transition period needed for moving from a petroleum based energy system to a renewable based new one. Consequently, the present global energy scenario was detailed in Chapter 1, and the role of hydrogen as a real alternative in the future energy system was justified based on several outlooks. Therefore, renewable and non-renewable hydrogen production routes were presented, explaining the corresponding benefits and drawbacks. Then, the raw materials used in this Thesis work were described and the most important issues regarding the processes and the characteristics of the catalytic formulations were explained. The introduction chapter finishes by introducing the concepts of decentralized production and process intensification with the use of microreactors. In addition, a small description of these innovative reaction systems and the benefits that entailed their use were also mentioned. In Chapter 2 the main objectives of this Thesis work are summarized. The development of advanced reaction systems for hydrogen rich mixtures production is the main objective. In addition, the use and comparison between two different reaction systems, (fixed bed reactor (FBR) and microreactor), the processing of renewable raw materials, the development of new, active, selective and stable catalytic formulations, and the optimization of the operating conditions were also established as additional partial objectives. Methane and natural gas (NG) steam reforming experimental results obtained when operated with microreactor and FBR systems are presented in Chapter 3. For these experiments nickel-based (Ni/Al2O3 and Ni/MgO) and noble metal-based (Pd/Al2O3 and Pt/Al2O3) catalysts were prepared by wet impregnation and their catalytic activity was measured at several temperatures, from 973 to 1073 K, different S/C ratios, from 1.0 to 2.0, and atmospheric pressure. The Weight Hourly Space Velocity (WHSV) was maintained constant in order to compare the catalytic activity in both reaction systems. The results obtained showed a better performance of the catalysts operating in microreactors. The Ni/MgO catalyst reached the highest hydrogen production yield at 1073 K and steam-to-carbon ratio (S/C) of 1.5 under Steam methane Reforming (SMR) conditions. In addition, this catalyst also showed good activity and stability under NG reforming at S/C=1.0 and 2.0. The Ni/Al2O3 catalyst also showed high activity and good stability and it was the catalyst reaching the highest methane conversion (72.9 %) and H2out/CH4in ratio (2.4) under SMR conditions at 1073 K and S/C=1.0. However, this catalyst suffered from deactivation when it was tested under NG reforming conditions. Regarding the activity measurements carried out with the noble metal-based catalysts in the microreactor systems, they suffered a very quick deactivation, probably because of the effects attributed to carbon deposition, which was detected by Scanning Electron Microscope (SEM). When the FBR was used no catalytic activity was measured with the catalysts under investigation, probably because they were operated at the same WHSV than the microreactors and these WHSVs were too high for FBR system. In Chapter 4 biogas reforming processes were studied. This chapter starts with an introduction explaining the properties of the biogas and the main production routes. Then, the experimental procedure carried out is detailed giving concrete information about the experimental set-up, defining the parameters measured, specifying the characteristics of the reactors used and describing the characterization techniques utilized. Each following section describes the results obtained from activity testing with the different catalysts prepared, which is subsequently summarized: Section 4.3: Biogas reforming processes using γ-Al2O3 based catalysts The activity results obtained by several Ni-based catalysts and a bimetallic Rh-Ni catalyst supported on magnesia or alumina modified with oxides like CeO2 and ZrO2 are presented in this section. In addition, an alumina-based commercial catalyst was tested in order to compare the activity results measured. Four different biogas reforming processes were studied using a FBR: dry reforming (DR), biogas steam reforming (BSR), biogas oxidative reforming (BOR) and tri-reforming (TR). For the BSR process different steam to carbon ratios (S/C) from 1.0 to 3.0, were tested. In the case of BOR process the oxygen-to-methane (O2/CH4) ratio was varied from 0.125 to 0.50. Finally, for TR processes different S/C ratios from 1.0 to 3.0, and O2/CH4 ratios of 0.25 and 0.50 were studied. Then, the catalysts which achieved high activity and stability were impregnated in a microreactor to explore the viability of process intensification. The operation with microreactors was carried out under the best experimental conditions measured in the FBR. In addition, the physicochemical characterization of the fresh and spent catalysts was carried out by Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), N2 physisorption, H2 chemisorption, Temperature Programmed Reduction (TPR), SEM, X-ray Photoelectron Spectroscopy (XPS) and X-ray powder Diffraction (XRD). Operating with the FBR, conversions close to the ones predicted by thermodynamic calculations were obtained by most of the catalysts tested. The Rh-Ni/Ce-Al2O3 catalyst obtained the highest hydrogen production yield in DR. In BSR process, the Ni/Ce-Al2O3 catalyst achieved the best activity results operating at S/C=1.0. In the case of BOR process, the Ni/Ce-Zr-Al2O3 catalyst showed the highest reactants conversion values operating at O2/CH4=0.25. Finally, in the TR process the Rh-Ni/Ce-Al2O3 catalyst obtained the best results operating at S/C=1.0 and O2/CH4=0.25. Therefore, these three catalysts were selected to be coated onto microchannels in order to test its performance under BOR and TR processes conditions. Although the operation using microreactors was carried out under considerably higher WHSV, similar conversions and yields as the ones measured in FBR were measured. Furthermore, attending to other measurements like Turnover Frequency (TOF) and Hydrogen Productivity (PROD), the values calculated for the catalysts tested in microreactors were one order of magnitude higher. Thus, due to the low dispersion degree measured by H2-chemisorption, the Ni/Ce-Al2O3 catalyst reached the highest TOF and PROD values. Section 4.4: Biogas reforming processes using Zeolites L based catalysts In this section three type of L zeolites, with different morphology and size, were synthesized and used as catalyst support. Then, for each type of L zeolite three nickel monometallic and their homologous Rh-Ni bimetallic catalysts were prepared by the wetness impregnation method. These catalysts were tested using the FBR under DR process and different conditions of BSR (S/C ratio of 1.0 and 2.0), BOR (O2/CH4 ratio of 0.25 and 0.50) and TR processes (at S/C=1.0 and O2/CH4=0.25). The characterization of these catalysts was also carried out by using the same techniques mentioned in the previous section. Very high methane and carbon dioxide conversion values were measured for almost all the catalysts under investigation. The experimental results evidenced the better catalytic behavior of the bimetallic catalysts as compared to the monometallic ones. Comparing the catalysts behavior with regards to their morphology, for the BSR process the Disc catalysts were the most active ones at the lowest S/C ratio tested. On the contrary, the Cylindrical (30–60 nm) catalysts were more active under BOR conditions at O2/CH4=0.25 and TR processes. By the contrary, the Cylindrical (1–3 µm) catalysts showed the worst activity results for both processes. Section 4.5: Biogas reforming processes using Na+ and Cs+ doped Zeolites LTL based catalysts A method for the synthesis of Linde Type L (LTL) zeolite under microwave-assisted hydrothermal conditions and its behavior as a support for heterogeneously catalyzed hydrogen production is described in this section. Then, rhodium and nickel-based bimetallic catalysts were prepared in order to be tested by DR process and BOR process at O2/CH4=0.25. Moreover, the characterization of the catalysts under investigation was also carried out. Higher activities were achieved by the catalysts prepared from the non-doped zeolites, Rh-Ni/D and Rh-Ni/N, as compared to the ones supported on Na+ and Cs+ exchanged supports. However, the differences between them were not very significant. In addition, the Na+ and Cs+ incorporation affected mainly to the Disc catalysts. Comparing the results obtained by these catalysts with the ones studied in the section 4.4, in general worst results were achieved under DR conditions and almost the same results when operated under BOR conditions. In Chapter 5 the ethylene glycol (EG) as feed for syngas production by steam reforming (SR) and oxidative steam reforming (OSR) was studied by using microchannel reactors. The product composition was determined at a S/C of 4.0, reaction temperatures between 625°C and 725°C, atmospheric pressure and Volume Hourly Space Velocities (VHSV) between 100 and 300 NL/(gcath). This work was divided in two sections. The first one corresponds to the introduction of the main and most promising EG production routes. Then, the new experimental procedure is detailed and the information about the experimental set-up and the measured parameters is described. The characterization was carried out using the same techniques as for the previous chapter. Then, the next sections correspond to the catalytic activity and catalysts characterization results. Section 5.3: xRh-cm and xRh-np catalysts for ethylene glycol reforming Initially, catalysts with different rhodium loading, from 1.0 to 5.0 wt. %, and supported on α-Al2O3 were prepared by two different preparation methods (conventional impregnation and separate nanoparticle synthesis). Then, the catalysts were compared regarding their measured activity and selectivity, as well as the characterization results obtained before and after the activity tests carried out. The samples prepared by a conventional impregnation method showed generally higher activity compared to catalysts prepared from Rh nanoparticles. By-product formation of species such as acetaldehyde, ethane and ethylene was detected, regardless if oxygen was added to the feed or not. Among the catalysts tested, the 2.5Rh-cm catalyst was considered the best one. Section 5.4: 2.5Rh-cm catalyst support modification with CeO2 and La2O3 In this part of the Chapter 5, the catalyst showing the best performance in the previous section, the 2.5Rh-Al2O3 catalyst, was selected in order to be improved. Therefore, new Rh based catalysts were designed using α-Al2O3 and being modified this support with different contents of CeO2 or La2O3 oxides. All the catalysts containing additives showed complete conversion and selectivities close to the equilibrium in both SR and OSR processes. In addition, for these catalysts the concentrations measured for the C2H4, CH4, CH3CHO and C2H6 by-products were very low. Finally, the 2.5Rh-20Ce catalyst was selected according to its catalytic activity and characterization results in order to run a stability test, which lasted more than 115 hours under stable operation. The last chapter, Chapter 6, summarizes the main conclusions achieved throughout this Thesis work. Although very high reactant conversions and rich hydrogen mixtures were obtained using a fixed bed reaction system, the use of microreactors improves the key issues, heat and mass transfer limitations, through which the reforming reactions are intensified. Therefore, they seem to be a very interesting and promising alternative for process intensification and decentralized production for remote application.

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Tesis doctoral originalmente defendida en la Universidad de Deusto el 29-09-2000