Geochemistry and minerals at DSDP Legs 68-70 Holes

The compositions of natural glasses and phenocrysts in basalts from Deep Sea Drilling Project Sites 501, 504, and 505, near the Costa Rica Rift, constitute evidence for the existence of a periodically replenished axial magma chamber that repeatedly erupted lavas of remarkably uniform composition. Magma compositions were affected by three general components: (1) injected magmas carrying (in decreasing order of abundance) Plagioclase, olivine, and chrome-spinel phenocrysts (spinel assemblage); (2) injected magmas carrying Plagioclase, clinopyroxene, and olivine phenocrysts, but no spinel (clinopyroxene assemblage); and (3) moderately evolved hybrids in the magma chamber itself. The compositions of the injected phenocrysts and minerals in glomerocrysts are as follows: Plagioclase - An85-94; olivine - Fo87-89; clinopyroxene - high Cr2O3 (0.7-1.1%), endiopside (Wo42En51Fs7), and aluminous chromian spinel (Cr/Cr + Al = 0.3). These minerals resemble those thought to occur in upper mantle sources (9 kbars and less) of ocean-ridge basalts and to crystallize in magmas near those sources. In the magma chamber, more sodic Plagioclase (An79-85), less magnesian olivine (Fo81-86) and low-Cr2O3 (0.1-0.4%) clinopyroxene formed rims on these crystals, grew as other phenocrysts, and formed cumulus segregations on the walls and floors of the magma chamber. In the spinel-assemblage magmas, magnesiochromite (Cr/Cr + Al = 0.4-0.5) also formed. Some cumulus segregations were later entrained in lavas as xenoliths. The glass compositions define 16 internally homogeneous eruptive units, 13 of which are in stratigraphic order in a single hole, Hole 504B, which was drilled 561.5 meters into the ocean crust. These units are defined as differing from each other by more than analytical uncertainty in one or more oxides. However, many of the glass groups in Hole 504B show virtually no differences in TiO2 contents, Mg/Mg + Fe2+, or normative An/An + Ab, all of which are sensitive indicators of crystallization differentiation. The differences are so small that they are only apparent in the glass compositions; they are almost completely obscured in whole-rock samples by the presence of phenocrysts and the effects of alteration. Moreover, several of the glass units at different depths in Hole 504B are compositionally identical, with all oxides falling within the range of analytical uncertainty, with only small variations in the rest of the suite. The repetition of identical chemical types requires (1) very regular injection of magmas into the magma chamber, (2) extreme similarity of injected magmas, and (3) displacement of very nearly the same proportion of the magmas in the chamber at each injection. Numerical modeling and thermal considerations have led some workers to propose the existence of such conditions at certain types of spreading centers, but the lava and glass compositions at Hole 504B represent the first direct evidence revealed by drilling of the existence of a compositionally nearly steady-state magma chamber, and this chapter examines the processes acting in it in some detail. The glass groups that are most similar are from clinopyroxene-assemblage lavas, which have a range of Mg/Mg + Fe2"1" of 0.59 to 0.65. Spinel-assemblage basalts are less evolved, with Mg/Mg + Fe2+ of 0.65 to 0.69, but both types have nearly identical normative An/An + Ab (0.65-0.66). However, the two lava types contain megacrysts (olivine, Plagioclase, clinopyroxene) that crystallized from melts with Mg/Mg + Fe2+ values of 0.70 to 0.72. Projection of glass compositions into ternary normative systems suggests that spinel-assemblage magmas originated deeper in the mantle than clinopyroxene-assemblage magmas, and mineral data indicate that the two types followed different fractionation paths before reaching the magma chamber. The two magma types therefore represent neither a low- nor a high-pressure fractionation sequence. Some of the spinel-assemblage magmas may have had picritic parents, but were coprecipitating all of the spinel-assemblage phenocrysts before reaching the magma chamber. Clinopyroxene-assemblage magmas did not have picritic parents, but the compositions of phenocrysts suggest that they originated at about 9 kbars, near the transition between plagioclase peridotite and spinel peridotite in the mantle. Two glass groups have higher contents of alkalis, TiO2, and P2O5 than the others, evidently as a result of the compositions of mantle sources. Eruption of these lavas implies that conduits and chambers containing magmas from dissimilar sources were not completely interconnected on the Costa Rica Rift. The data are used to draw comparisons with the East Pacific Rise and to consider the mechanisms that may have prevented the eruption of ferrobasalts at these sites.

Der Schwermineral-Gehalt von Saale-zeitlichen Moränen- und Schmelzwasser-Ablagerungen des Münsterlandes

This article is a first summary of the heavy-mineral content of moraine and meltwater deposits of the Saalian glaciation in the Münsterland and its northeastern extension (NW Germany). In the beginning the appearance and distribution of both types of sediments are described (E. Speetzen), then the heavy mineral composition of selected outcrops is reported and the results are compared (D. Henningsen). Generally the predominant heavy minerals are garnet, minerals of the epidote group, zircon, and ordinary hornblende. The heavy mineral contents of moraine sediments sometimes are similar to that of meltwater deposits, in other cases they are different. Obviously there exists no relation between the heavy mineral composition and various advances of the Scandinavian ice sheet and their sediments, the content of heavy minerals rather depends on local influences.

Schwermineral-Untersuchungen in quartär-zeitlichen Sanden nordwestlich von Hannover

A total of 117 samples of quarternary sediments, mostly sands, from a region NW of Hannover (Lower Saxony) has been investigated with regard to their content of heavy minerals. The absolute percentage of transparent heavy minerals approximates 0.2 Vol.%. If several samples of glaciofluvial sands (Drenthe-stage) or dune sands (Late Weichsel-stage to Holocene) are taken from one outcrop they show great similarities in their heavy minerals contents. Glaciofluvial sands of the Elster-stage evidently have less Garnet, Hornblende and minerals of volcanic origin (Augite, partly also Orthopyroxenes, Oxyhornblende and Olivine) than those of the Drenthe-stage, Weichsel-stage, and the Holocene. All these groups hold nearly the same average assemblages of heavy mineral, thus indicating that within the Drenthe-stage or later material from north and from south has been mixed and/or reworked. In the area investigated the proportions of heavy minerals do not help to identify either the stratigraphic position or the way of deposition of different sandy sediments younger than the Elster-stage. The distributional pattern of several heavy minerals point out that Kyanite, Hornblende and Epidote have been transported predominantly from the north, whereas Garnet and Staurolite have sources both in the north and the south. Tourmaline, Apatite and the minerals of volcanic origin mainly must be derived from the south. All results obtained in the region examined should not be transferred to other zones of the lowlands of Northern Germany automatically.

Die mittelpleistozäne Flußentwicklung im nordöstlichen Harzvorland: Petrographie, Terrassenstratigraphie

The present study deals with the evolution of the middle Pleistocene river system in the north-eastern foreland of the Harz Mtns. Sediments of the middle fluvial terrace level (early Saalian time) are the main objectives. By using these sediments supplementary with some results of upper fluvial terrace level (early Elesterian time or older) the fluvial palaeogeography within the area has been reconstructed. The sediments were investigated with respect to their gravel spectra, heavy mineral record, sedimentary structures and altitude above the recent river beds. Due to the resulting specifics the sediments have been attributed to particular rivers in the area. Furthermore it is possible to distinguish between fluvial sediments and Elsterian as well as Saalian fluvioglacial deposits. Together with discernible middle or upper terrace characteristics this led to a spatio-temporal reconstruction of the palaeo river system of the Harz Mtns. It revealed that not only during upper terrace sedimentation but even while middle terraces were deposited the rivers partly diversed. These river diversions were mainly caused by hydrodynamic changes reflecting interaction of the fluvial system with Elsterian and Saalian ice shield formation in the north. The Rivers Ecker, Ilse, Rammelsbach, Holtemme, Goldbach, Bode, Selke and Eine were affected by this development as follows: Upper terrace level formation: • The Ecker River formerly ran between its recent river bed and that of the Use River in direction to the Großer Fallstein Mtn. • The Use River flowed to the NE towards the Huy Mtn. • The Goldbach River and the Holtemme River mutually ran to the NW south of the Huy Mtn. After uniting with the Use River and Ecker River it ran south of the Großer Fallstein Mtn. Middle terrace level formation: • The Ecker River flowed far more NE. • Near to the Harz Mtns. the Use River flowed more in the E. The tributary junction of the Rammelsbach River was located far more downstream. Thereafter the Use River ran to the N between Huy Mtn. and Großer Fallstein Mtn. to end up flowing in the area of the Großes Bruch. • The Holtemme River kept its course. Its recent tributary the Goldbach River flowed to the NE and joined the Bode River after leaving the Harz Mtn. Range. • The Eine River ran to the NW when passing todays city of Aschersleben. After flowing together with the Selke River in the area of the Seeländerei it became a tributary to the Bode River. • The Bode River within the recent tributary junction of the Holtemme ran far more in the W. In the area of the Espenbruch it flowed eastwards to the Saale River. The following general implications resulted out of the study: • The so called “mixed sediments” sensu Rosenberger & Altermann (1975) have now been interpreted as proximal fluvioglacial deposits. • High altitudes of middle terrace fluvial deposits in the courses of the Ecker River and Use River were formerly assigned to post middle Pleistocene uplift of the Großer Fallstein Mtn. (Feldmann, 2002). The present study suggests that the unusual high altitudes should rather be attributed to post middle terrace level erosion of the shortened Ilse- Rammelsbach river system or fluvioglacial processes below the glacier. • Within the north-eastern foreland of the Harz Mtns. middle terrace level deposits have previously been subdivided by cryoturbation horizons or short-term progradation of Saalian glaciation. This is not supported by own results for the examined area.

Mineral element and heavy metal poisoning in animals

Mineral elements are essential to animal health, survival and production because they are part of physiological, structural, catalytic and regulatory organism functions. Therefore, they should be present in diet. However, these minerals when ingested in excessive doses due to errors in balancing mineral supplements and/or complete ration, intake of plants with high mineral concentration, resulting from addition of fertilizers, herbicides, insecticides and fungicides in pasture or tillage where plants and/or grains will be used to feed animals, decomposition of urban and industrial wastes, leaks and accidental spills of pollutants may result in accumulation of toxic mineral elements in the environment poisoning the animals and may lead them to death. However, toxic doses, physiological changes during poisoning, symptoms and mineral concentration in tissues of poisoned animals to confirm diagnosis are not completely known. Thus, this study reviews mineral element doses that some authors considered toxic for animals intake, as its concentration in tissues of poisoned animals and its physiological effects, symptoms, diagnostic procedures and treatment for poisoning by cadmium, lead, copper, chromium, iodine, manganese, molybdenum, selenium and zinc.

Effect of organic mineral supplementation on the egg quality of semi-heavy layers in their second cycle of lay

This study was carried out to evaluate the effects of dietary trace mineral levels and sources on egg quality parameters of second-cycle semi-heavy layers. A number of 360 72-week-old layers were submitted to forced molting. Upon return of lay (83 weeks of age), birds were distributed according to a completely randomized experimental design of six treatments with six replicates of 10 birds each. The control treatment consisted of 0.10% dietary supplementation of trace minerals from inorganic sources, which was proportionally replaced by five levels (110, 100, 90, 80, 70%) of an organic trace mineral supplement containing 30, 30, 40, 6, 0.61, and 0.3 g/kg product of Zn, Fe, Mn, Cu, I, and Se, respectively. All diets contained equal protein, energy, and amino acid levels. Every 28 days of the experimental period (112 days) four eggs per replicate were collected for egg quality evaluation. The following parameters were evaluated: specific gravity, yolk, albumen and eggshell percentages, yolk index, Haugh units, and eggshell thickness and breaking strength. One sample per replicate, consisting of the pool of the yolks of three eggs collected at the end of each experimental period, was used to assess protein and mineral (Ca, P, Cu, Fe, Mn, and Zn) contents. The results were submitted to ANOVA, and means to the test of Tukey at 5% significance level. The evaluated trace mineral levels and sources did not influence any of the studied egg quality parameters. It was concluded that reducing organic trace mineral supplementation in up to 70% relative to 100% inorganic trace mineral supplementation does not affect egg parameters and therefore, can be applied to the diet of semi-heavy layers in their second cycle of lay.

Heavy metals in Oxisols amended with biosolids and cropped with maize in a long-term experiment

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Geochemistry and structural formulas of heavy minerals from sands and sandstones of ODP Leg 126 samples

Lower Oligocene to Pleistocene volcaniclastic sands and sandstones recovered around the Izu-Bonin Arc during Ocean Drilling Program Leg 126 were derived entirely from Izu-Bonin Arc volcanism. Individual grains consist of volcanic glass, pumice, scoria, basaltic or andesitic fragments, plagioclase, pyroxene, and minor olivine and hornblende. In Pliocene-Pleistocene samples plagioclase and heavy minerals in the volcaniclastic sands and sandstones are present in the following abundances: plagioclase > orthopyroxene > clinopyroxene > pigeonite > olivine. In contrast, plagioclase and heavy minerals found in Oligocene-Miocene samples occur in the following order: plagioclase > clinopyroxene > orthopyroxene > hornblende. The low concentration of Al, Ti, and Cr in calcium-rich clinopyroxenes in Oligocene to Holocene sediments suggests that the sources of the volcaniclastic detritus were nonalkalic igneous rocks. There are, however, some distinctive differences in the chemical composition of pyroxene between the Pliocene-Pleistocene and Oligocene-Miocene volcaniclastic sands and sandstones. Orthopyroxene belongs to the hypersthene-ferrohypersthene series (Fe-rich) in Pliocene-Pleistocene sediments, and the bronzitehypersthene series (Mg-rich) in Oligocene-Miocene sediments. Clinopyroxene is characterized by augite and pigeonite in Pliocene-Pleistocene sediments, and by the diopside-augite series in Oligocene-Miocene sediments. Mineral assemblages and mineral chemistry of the volcaniclastic sands and sandstones reflect those of the volcanic source rocks. Therefore, the observed changes in mineralogy record the historical change in volcanism of the Izu-Bonin Arc. The mineralogy is consistent with the geochemistry of the volcaniclastic sands and sandstones and the geochemistry of forearc volcanic rocks of the Izu-Bonin Arc since the Oligocene.

Lithic grain and mineral composition of sand and sandstones from the Japan and Mariana forearc and backarc (Table 3)

One hundred and twenty point counts of Oligocene to Recent sands and sandstones from DSDP sites in the Japan and Mariana intraoceanic forearc and backarc basins demonstrate that there is a clear compositional difference between the continentally influenced Japan forearc and backarc sediments, and the totally oceanic Mariana forearc and backarc sediments. Japan forearc sediments average 10 QFL%Q, 0.82 P/F, 2 Framework%Mica, 74 LmLvLst%Lv, and 19 LmLvLst%Lst. In contrast, the Mariana forearc and backarc sediments average 0 QFL%Q, 1.00 P/F, 0 Framework%Mica, 98 LmLvLst%Lv, and 1 LmLvLst%Lst. Sediment compositions in the Japan region are variable. The Honshu forearc sediments average 5 QFL%Q, 0.94 P/F, 1 Framework%Mica, 82 LmLvLst%Lv, and 15 LmLvLst%Lst. The Yamato Basin sediments (DSDP Site 299) average 13 QFL%Q, 0.70 P/F, 3 Framework%Mica, 78 LmLvLst%Lv, and 14 LmLvLst%Lst. The Japan Basin sediments (DSDP Site 301) average 24 QFL%Q, 0.54 P/F, 9 Framework%Mica, 58 LmLvLst%Lv, and 21 LmLvLst%Lst. P/F and Framework%Mica are higher in the Yamato Basin sediments than in the forearc sediments due to an increase in modal potassium content of volcanic rocks from east to west, on the island of Honshu. Site 301 possesses a higher QFL%Q and LmLvLst%Lst, and lower LmLvLst%Lv than Site 299 because it receives sediment from the Asian mainland as well as the island of Honshu. DSDP Site 293 sediments, in the Mariana region, average 0.97 P/F, 1 Framework%Mica, 13 LmLvLst%Lm and 83 LmLvLst%Lv, due to their proximity to the island of Luzon. The remaining Mariana forearc and backarc sediments show a uniform composition.

Mineral composition of 0.1-0.05 mm grain size fraction from the surface layer of bottom sediments in the West European province of the Atlantic Ocean

Rock material sampled from the Mir manned deep-sea submersibles and by dradges, grabs, and sediment cores over a vast area of the North Atlantic was analyzed to show that this material is of continental origin, unlike original rocks of the ocean floor. It is proved to be related to iceberg rafting during Quaternary glaciations. Independent data on distribution and composition of sandy and silty grains in sediment cores also support this relation to the recent glaciation. New criteria for identification of iceberg rock matter in pelagic sediments are presented on the base of analysis of all available data.