Curing, defects and mechanical performance of fiber-reinforced composites

Tradicionalmente, la fabricación de materiales compuestos de altas prestaciones se lleva a cabo en autoclave mediante la consolidación de preimpregnados a través de la aplicación simultánea de altas presiones y temperatura. Las elevadas presiones empleadas en autoclave reducen la porosidad de los componentes garantizando unas buenas propiedades mecánicas. Sin embargo, este sistema de fabricación conlleva tiempos de producción largos y grandes inversiones en equipamiento lo que restringe su aplicación a otros sectores alejados del sector aeronáutico. Este hecho ha generado una creciente demanda de sistemas de fabricación alternativos al autoclave. Aunque estos sistemas son capaces de reducir los tiempos de producción y el gasto energético, por lo general, dan lugar a materiales con menores prestaciones mecánicas debido a que se reduce la compactación del material al aplicar presiones mas bajas y, por tanto, la fracción volumétrica de fibras, y disminuye el control de la porosidad durante el proceso. Los modelos numéricos existentes permiten conocer los fundamentos de los mecanismos de crecimiento de poros durante la fabricación de materiales compuestos de matriz polimérica mediante autoclave. Dichos modelos analizan el comportamiento de pequeños poros esféricos embebidos en una resina viscosa. Su validez no ha sido probada, sin embargo, para la morfología típica observada en materiales compuestos fabricados fuera de autoclave, consistente en poros cilíndricos y alargados embebidos en resina y rodeados de fibras continuas. Por otro lado, aunque existe una clara evidencia experimental del efecto pernicioso de la porosidad en las prestaciones mecánicas de los materiales compuestos, no existe información detallada sobre la influencia de las condiciones de procesado en la forma, fracción volumétrica y distribución espacial de los poros en los materiales compuestos. Las técnicas de análisis convencionales para la caracterización microestructural de los materiales compuestos proporcionan información en dos dimensiones (2D) (microscopía óptica y electrónica, radiografía de rayos X, ultrasonidos, emisión acústica) y sólo algunas son adecuadas para el análisis de la porosidad. En esta tesis, se ha analizado el efecto de ciclo de curado en el desarrollo de los poros durante la consolidación de preimpregnados Hexply AS4/8552 a bajas presiones mediante moldeo por compresión, en paneles unidireccionales y multiaxiales utilizando tres ciclos de curado diferentes. Dichos ciclos fueron cuidadosamente diseñados de acuerdo a la caracterización térmica y reológica de los preimpregnados. La fracción volumétrica de poros, su forma y distribución espacial se analizaron en detalle mediante tomografía de rayos X. Esta técnica no destructiva ha demostrado su capacidad para analizar la microestructura de materiales compuestos. Se observó, que la porosidad depende en gran medida de la evolución de la viscosidad dinámica a lo largo del ciclo y que la mayoría de la porosidad inicial procedía del aire atrapado durante el apilamiento de las láminas de preimpregnado. En el caso de los laminados multiaxiales, la porosidad también se vio afectada por la secuencia de apilamiento. En general, los poros tenían forma cilíndrica y se estaban orientados en la dirección de las fibras. Además, la proyección de la población de poros a lo largo de la dirección de la fibra reveló la existencia de una estructura celular de un diámetro aproximado de 1 mm. Las paredes de las celdas correspondían con regiones con mayor densidad de fibra mientras que los poros se concentraban en el interior de las celdas. Esta distribución de la porosidad es el resultado de una consolidación no homogenea. Toda esta información es crítica a la hora de optimizar las condiciones de procesado y proporcionar datos de partida para desarrollar herramientas de simulación de los procesos de fabricación de materiales compuestos fuera de autoclave. Adicionalmente, se determinaron ciertas propiedades mecánicas dependientes de la matriz termoestable con objeto de establecer la relación entre condiciones de procesado y las prestaciones mecánicas. En el caso de los laminados unidireccionales, la resistencia interlaminar depende de la porosidad para fracciones volumétricas de poros superiores 1%. Las mismas tendencias se observaron en el caso de GIIc mientras GIc no se vio afectada por la porosidad. En el caso de los laminados multiaxiales se evaluó la influencia de la porosidad en la resistencia a compresión, la resistencia a impacto a baja velocidad y la resistencia a copresión después de impacto. La resistencia a compresión se redujo con el contenido en poros, pero éste no influyó significativamente en la resistencia a compresión despues de impacto ya que quedó enmascarada por otros factores como la secuencia de apilamiento o la magnitud del daño generado tras el impacto. Finalmente, el efecto de las condiciones de fabricación en el proceso de compactación mediante moldeo por compresión en laminados unidireccionales fue simulado mediante el método de los elementos finitos en una primera aproximación para simular la fabricación de materiales compuestos fuera de autoclave. Los parámetros del modelo se obtuvieron mediante experimentos térmicos y reológicos del preimpregnado Hexply AS4/8552. Los resultados obtenidos en la predicción de la reducción de espesor durante el proceso de consolidación concordaron razonablemente con los resultados experimentales. Manufacturing of high performance polymer-matrix composites is normally carried out by means of autoclave using prepreg tapes stacked and consolidated under the simultaneous application of pressure and temperature. High autoclave pressures reduce the porosity in the laminate and ensure excellent mechanical properties. However, this manufacturing route is expensive in terms of capital investment and processing time, hindering its application in many industrial sectors. This fact has driven the demand of alternative out-of-autoclave processing routes. These techniques claim to produce composite parts faster and at lower cost but the mechanical performance is also reduced due to the lower fiber content and to the higher porosity. Corrient numerical models are able to simulate the mechanisms of void growth in polymer-matrix composites processed in autoclave. However these models are restricted to small spherical voids surrounded by a viscous resin. Their validity is not proved for long cylindrical voids in a viscous matrix surrounded by aligned fibers, the standard morphology observed in out-of-autoclave composites. In addition, there is an experimental evidence of the detrimental effect of voids on the mechanical performance of composites but, there is detailed information regarding the influence of curing conditions on the actual volume fraction, shape and spatial distribution of voids within the laminate. The standard techniques of microstructural characterization of composites (optical or electron microscopy, X-ray radiography, ultrasonics) provide information in two dimensions and are not always suitable to determine the porosity or void population. Moreover, they can not provide 3D information. The effect of curing cycle on the development of voids during consolidation of AS4/8552 prepregs at low pressure by compression molding was studied in unidirectional and multiaxial panels. They were manufactured using three different curing cycles carefully designed following the rheological and thermal analysis of the raw prepregs. The void volume fraction, shape and spatial distribution were analyzed in detail by means of X-ray computed microtomography, which has demonstrated its potential for analyzing the microstructural features of composites. It was demonstrated that the final void volume fraction depended on the evolution of the dynamic viscosity throughout the cycle. Most of the initial voids were the result of air entrapment and wrinkles created during lay-up. Differences in the final void volume fraction depended on the processing conditions for unidirectional and multiaxial panels. Voids were rod-like shaped and were oriented parallel to the fibers and concentrated in channels along the fiber orientation. X-ray computer tomography analysis of voids along the fiber direction showed a cellular structure with an approximate cell diameter of 1 mm. The cell walls were fiber-rich regions and porosity was localized at the center of the cells. This porosity distribution within the laminate was the result of inhomogeneous consolidation. This information is critical to optimize processing parameters and to provide inputs for virtual testing and virtual processing tools. In addition, the matrix-controlled mechanical properties of the panels were measured in order to establish the relationship between processing conditions and mechanical performance. The interlaminar shear strength (ILSS) and the interlaminar toughness (GIc and GIIc) were selected to evaluate the effect of porosity on the mechanical performance of unidirectional panels. The ILSS was strongly affected by the porosity when the void contents was higher than 1%. The same trends were observed in the case of GIIc while GIc was insensitive to the void volume fraction. Additionally, the mechanical performance of multiaxial panels in compression, low velocity impact and compression after impact (CAI) was measured to address the effect of processing conditions. The compressive strength decreased with porosity and ply-clustering. However, the porosity did not influence the impact resistance and the coompression after impact strength because the effect of porosity was masked by other factors as the damage due to impact or the laminate lay-up. Finally, the effect of the processing conditions on the compaction behavior of unidirectional AS4/8552 panels manufactured by compression moulding was simulated using the finite element method, as a first approximation to more complex and accurate models for out-of autoclave curing and consolidation of composite laminates. The model parameters were obtained from rheological and thermo-mechanical experiments carried out in raw prepreg samples. The predictions of the thickness change during consolidation were in reasonable agreement with the experimental results.

One-watt fiber-based power-by-light system for satellite applications

In this work, a fiber-based optical powering (or power-by-light) system capable of providing more than 1 W is developed. The prototype was used in order to power a shunt regulator for controlling the activation and deactivation of solar panels in satellites. The work involves the manufacture of a light receiver (a GaAs multiple photovoltaic converter (MPC)), a power conditioning block, and a regulator and the implementation and characterization of the whole system. The MPC, with an active area of just 3.1 mm2, was able to supply 1 W at 5 V with an efficiency of 30%. The maximum measured device efficiency was over 40% at an input power (Pin) of 0.5 W. Open circuit voltage over 7 V was measured for Pin over 0.5 W. A system optoelectronic efficiency (including the optical fiber, connectors, and MPC) of 27% was measured at an output power (Pout) of 1 W. At Pout = 0.2 W, the efficiency was as high as 36%. The power conditioning block and the regulator were successfully powered with the system. The maximum supplied power in steady state was 0.2 W, whereas in transient state, it reached 0.44 W. The paper also describes the characterization of the system within the temperature range going from -70 to +100?°C.

Digital chaos synchronization in optical networks

A new method to obtain digital chaos synchronization between two systems is reported. It is based on the use of Optically Programmable Logic Cells as chaos generators. When these cells are feedbacked, periodic and chaotic behaviours are obtained. They depend on the ratio between internal and external delay times. Chaos synchronization is obtained if a common driving signal feeds both systems. A control to impose the same boundary conditions to both systems is added to the emitter. New techniques to analyse digital chaos are presented. The main application of these structures is to obtain secure communications in optical networks.

Spectral behavior of a low-cost all-fiber component based on untapered multifiber unions

Untapered multifiber unions are reported to show a spectral behavior similar to the tapered ones. Their oscillatory behavior does not depend on the biconical regions. This suggests a novel way to make low-cost all-fiber devices with applications as passive components such as optical filters and wavelength multiplexers/demultiplexers. Two types of multimode fibers have been studied and information about the index profile influence has been obtained. Polarization insensitivity and temperature stability have been observed.

Optical regeneration based on noise generated in bistable devices: going from 2R to 3R

In this paper we propose to employ an instability that occurs in bistable devices as a control signal at the reception stage to generate the clock signal. One of the adopted configurations is composed of two semiconductor optical amplifiers arranged in a cascaded structure. This configuration has an output equivalent to that obtained from Self-Electrooptic Effect Devices (SEEDs), and it can implement the main Boolean functions of two binary inputs. These outputs, obtained from the addition of two binary signals, show a short spike in the transition from "1" to "2" in the internal processing. A similar result is obtained for a simple semiconductor amplifier with bistable behavior. The paper will show how these structures may help recover clock signals in any optical transmission system

Strange attractor in optical logic cells

Optical logic cells, employed in several tasks as optical computing or optically controlled switches for photonic switching, offer a very particular behavior when the working conditions are slightly modified. One of the more striking changes occurs when some delayed feedback is applied between one of the possible output gates and a control input. Some of these new phenomena have been studied by us and reported in previous papers. A chaotic behavior is one of the more characteristic results and its possible applications range from communications to cryptography. But the main problem related with this behavior is the binary character of the resulting signal. Most of the nowadays-employed techniques to analyze chaotic signals concern to analogue signals where algebraic equations are possible to obtain. There are no specific tools to study digital chaotic signals. Some methods have been proposed. One of the more used is equivalent to the phase diagram in analogue chaos. The binary signal is converted to hexadecimal and then analyzed. We represented the fractal characteristics of the signal. It has the characteristics of a strange attractor and gives more information than the obtained from previous methods. A phase diagram, as the one obtained by previous techniques, may fully cover its surface with the trajectories and almost no information may be obtained from it. Now, this new method offers the evolution around just a certain area being this lines the strange attractor.

Transmission of digital chaotic and information-bearing signals in optical communication systems

A new proposal to have secure communications in a system is reported. The basis is the use of a synchronized digital chaotic systems, sending the information signal added to an initial chaos. The received signal is analyzed by another chaos generator located at the receiver and, by a logic boolean function of the chaotic and the received signals, the original information is recovered. One of the most important facts of this system is that the bandwidth needed by the system remain the same with and without chaos.

Fiber penetration and copper access regulation

Research question, methodology and messages to take home - Impact of copper (legacy networks)regulation(LLU and bitstream)on NGN adoption - Methodology: fixed effects regression and forecasting with s- curves(logistic) - Key message:(excessive) copper regulation discourages NGN adoption (deployment, investments), in particular an increase ofunbundling access charges and/or a decrease of wholesale access would increase penetration of fibre and cable modem.

QKD in dense WDM passive optical networks

Quantum cryptography in communications networks

Multiplexing QKD systems in Conventional Optical Networks

Current QKD designs try to keep the quantum channel as error free as possible by using a separate physical medium for this purpose. In the most common case, this means the exclusive use of an optical fiber for the quantum channel, precluding its use for any other purpose. In current optical networks, the fiber is the single most expensive element and this poses a major problem from a cost and availability point of view. Sharing the fiber is thus mandatory for the widespread adoption of QKD. The objective of this communication is to propose a general scheme and present some preliminary measurements of a metropolitan area network (MAN) designed to multiplex of the order of 64 addressable quantum channels and the associated QKD classical service signals on a single dark fibre. It uses as much existing components and infraestructure as possible in an attempt to simultaneously lower most of the practical barriers for the adoption of QKD.

Deploying QKD in Standard Optical Networks

In order to deploy QKD in a cost effective and scalable way, its integration with already installed optical networks is a logical step. If, for the sake of security, we require that no intermediate trusted nodes would be needed, the maximum distance/absorptions allowed by QKD systems limit ourselves to metropolitan area networks. Current metro networks are mostly all optical and passive, hence a transparent link can be established among any two points and this link can be used to transport the quantum channel. In this poster we report on our findings studying the problems arising when integrating QKD systems in standard telecommunications networks.

Mach-Zehnder interferometer based on all-fiber multimode interference device for DPSK signal demodulation

Differential Phase Shift Keying (DPSK) modulation format has been shown as a robust solution for next-generation optical transmission systems. One key device enabling such systems is the delay interferometer, converting the signal phase information into intensity modulation to be detected by the photodiodes. Usually, Mach-Zehnder interferometer (MZI) is used for demodulating DPSK signals. In this paper, we developed an MZI which is based on all-fiber Multimode Interference (MI) structure: a multimode fiber (MMF) located between two single-mode fibers (SMF) without any transition zones. The standard MZI is not very stable since the two beams go through two different paths before they recombine. In our design the two arms of the MZI are in the same fiber, which will make it less temperature-sensitive than the standard MZI. Performance of such MZI will be analyzed from transmission spectrum. Finally such all-fiber MI-based MZI (MI-MZI) is used to demodulate 10 Gbps DPSK signals. The demodulated signals are analyzed from eye diagram and bit error rate (BER).

Infiltration of a photonic crystal fiber with cholesteric liquid crystal and blue phase

Photonic crystal fibers (PCF) have been selectively filled with a cholesteric liquid crystal (ChLC) with special interest in the blue phase (BP) of the liquid crystal. It has been observed thermal tuning of the guided light in the visible region. A dramatically enhance appears when the phase of the liquid crystal changes from cholesteric to blue phase I (BPI). When a thermal range of the blue phase I is achieved, no changes are observed while increasing temperature from BPI through BPII and to the isotropic phase.

Optimization and evaluation in space conditions of multi-GHz optical modulators

Among the different optical modulator technologies available such as polymer, III-V semiconductors, Silicon, the well-known Lithium Niobate (LN) offers the best trade-off in terms of performances, ease of use, and power handling capability [1-9]. The LN technology is still widely deployed within the current high data rate fibre optic communications networks. This technology is also the most mature and guarantees the reliability which is required for space applications [9].In or der to fulfil the target specifications of opto-microwave payloads, an optimization of the design of a Mach-Zehnder (MZ) modulator working at the 1500nm telecom wavelength was performed in the frame of the ESA-ARTES "Multi GigaHertz Optical Modulator" (MGOM) project in order to reach ultra-low optical insertion loss and low effective driving voltage in the Ka band. The selected modulator configuration was the X-cut crystal orientation, associated to high stability Titanium in-diffusion process for the optical waveguide. Starting from an initial modulator configuration exhibiting 9 V drive voltage @ 30 GHz, a complete redesign of the coplanar microwave electrodes was carried out in order to reach a 6 V drive voltage @ 30GHz version. This redesign was associated to an optimization of the interaction between the optical waveguide and the electrodes. Following the optimisation steps, an evaluation program was applied on a lot of 8 identical modulators. A full characterisation was carried out to compare performances, showing small variations between the initial and final functional characteristics. In parallel, two similar modulators were submitted to both gamma (10-100 krad) and proton irradiation (10.109 p/cm²) with minor performance degradation.

Planificación de una red 4G

La intensa evolución tecnológica que está experimentando nuestra sociedad en las últimas décadas hace que se estén desarrollando continuamente nuevas tecnologías que proporcionan mejoras tanto en la calidad como en la seguridad del servicio, este es el caso del 4G. A día de hoy, en España, la cuarta generación de comunicaciones móviles se ve encabezada por LTE, mientras que LTE-Advanced sólo se está implantando en las principales ciudades de nuestro país durante los últimos meses. Por este motivo, se ha creído interesante realizar una planificación sobre una zona que, hasta el momento, no está cubierta por cobertura LTE-Advanced. Además hay que tener en cuenta la naturaleza del terreno en el que trabajaremos, ya que se aleja del suelo urbano que encontramos en las principales ciudades con LTE-Advanced, como Madrid, Barcelona o Valencia. El estudio de esta zona semirural es de gran interés ya que uno de los objetivos de la cuarta generación es hacer llegar conexión a internet de calidad a lugares en los que no puede llegar la fibra óptica, como por ejemplo estas zonas semirurales. Para añadir aún más interés en el estudio, se ha decidido utilizar la banda de 800 MHz para el despliegue de la red. Esta banda que anteriormente era utilizada para la transmisión TDT, recientemente ha quedado liberada, en el conocido como Dividendo Digital para su uso en comunicaciones móviles. La tecnología LTE-Advanced se está empezando a desplegar en esta banda aunque realmente hasta Noviembre del año 2015 no tendremos un uso real de la misma, por lo que en estos momentos las redes 4G están utilizando la banda de 2.6 GHz. La utilización de la banda de 800 MHz conllevará mejoras tanto al usuario como a las operadoras, las cuales iremos viendo a lo largo del desarrollo del proyecto. La planificación pasará por distintas fases de optimización y expansión en las que se analizaran tanto la parte radioeléctrica como su capacidad. Se analizaran señales del tipo RSRP, RSSI o RSRQ y para el análisis de capacidad se definirá un conjunto de usuarios, distribuidos adecuadamente por toda la zona, que permitirá estudiar en detalle la capacidad de nuestra red. Para finalizar, se realizarán varias pruebas que demostrarán lo importante que es la tecnología MIMO tanto en LTE como en LTE-Advanced. ABSTRACT. Nowadays, our society is experiencing an intense pace of technological evolution which causes the constant development of new technologies. In the network planning area, these new technologies are focused on improving both quality and safety of service, with the recent deployment of 4G technologies in our networks. This project focuses on Spain, where the fourth generation of mobile communications is led by LTE, because LTE-Advanced has only been deployed in the largest cities, so far. The goal of this project is to plan, deploy and simulate LTE-Advanced network, of an area that hasn´t yet been covered. Furthermore, it will be taken into account the nature of the terrain where the network will be developed, as it moves away from urban areas in the major cities with LTE-Advanced, including Madrid, Barcelona and Valencia. The study of these semi-rural areas is extremely important because one of the main objectives of the fourth generation technologies is to get high-speed internet access to places that can be reached through other technologies, such as optical fiber. In order to adjust to the actual needs, the project was developed for the 800 MHz band. Those frequencies used to be assigned for digital terrestrial TV, but they have recently been released through the Digital Dividend in 2015 to use with mobile communications. That is the reason why, the LTE-Advanced technology in Spain is starting to be deployed in those frequencies. Despite the freeing of the 800 MHz band, it is not allowed to use it until November 2015, so 4G networks are currently using the 2.6 GHz band. The use of the 800 MHz band will led to advantages and improvements to users and operators, which will be detailed over the project. Each step of the planning of the 4G network is detailed. It is analyzed the optimization and expansion of the network, based on the radio and capacity premises. RSRP, RSSI or RSRQ signals were analyzed and an analysis of the network capacity was carried out. Finally, several tests are developed to show the importance of MIMO in LTE and LTE-Advanced.