(Appendix) Range chart of calcareous nannofossils in ODP Hole 129-802A

Only Site 802 has recorded appreciable Cenozoic carbonate sediments during Ocean Drilling Program Leg 129 in the central Mariana Basin of the western Pacific Ocean. Calcareous nannofossils provide the best biostratigraphic information for the 360-m Tertiary section, which consists primarily of volcaniclastic turbidites interbedded with calcareous claystone and chalk. Many samples contain significant amounts of nannofossils reworked from older sediments. An unconformity appears to be present between Cores 129-802A-32R and -33R, with upper Oligocene-lower Miocene sediments above and lower Eocene-upper Paleocene sediments below the unconformity. The sediments below the unconformity contain abundant reworked Cretaceous nannofossils. Only one sample from Site 801 yielded nannofossils, and those consist of a mixture of Campanian-Maastrichtian and Paleogene forms.

Calcareous nannofossil stratigraphy and key biohorizons of ODP Leg 173 sites

Six sites were drilled on the southern Iberia Abyssal Plain during Ocean Drilling Program (ODP) Leg 173. Three holes (1067A, 1068A, and 1069A) recovered Eocene sediments consisting of thinly bedded turbidite deposits with interbedded hemipelagic sediments (Bouma sequence Te) deposited near the calcite compensation depth. The hemipelagic sediments are barren of nannofossils, necessitating the use of the turbidite deposits to erect an Eocene biostratigraphy for these holes. Moderately preserved, diverse assemblages of nannofossils were recovered from silty clays (Bouma sequence Td) and poorly preserved, less diverse assemblages were recovered from sandy/silty clays (Bouma sequence Tc). Hole 1067A has a continuous record of sedimentation (Subzones CP9a-CP14a) and Holes 1068A and 1069A have similar continuous records (Subzones CP9a-CP12a), although all holes contain barren intervals. Holes 1067A, 1068A, 1069A, 900A (ODP Leg 149), and 398D (Deep Sea Drilling Project Leg 47B) display a similar increase in mass accumulation rates in the lowermost middle Eocene. A reliable Eocene biostratigraphy has been erected using nannofossil data from turbidite sequences, allowing for correlation between Iberia Abyssal Plain sites.

(Table 1) Main constituents of coccolith size fractions expressed as carbonate contribution at Bass River during the PETM

Coccoliths, calcite plates produced by the marine phytoplankton coccolithophores, have previously shown a large array of carbon and oxygen stable isotope fractionations (termed "vital effects"), correlated to cell size and hypothesized to reflect the varying importance of active carbon acquisition strategies. Culture studies show a reduced range of vital effects between large and small coccolithophores under high CO2, consistent with previous observations of a smaller range of interspecific vital effects in Paleocene coccoliths. We present new fossil data examining coccolithophore vital effects over three key Cenozoic intervals reflecting changing climate and atmospheric partial pressure of CO2 (pCO2). Oxygen and carbon stable isotopes of size-separated coccolith fractions dominated by different species from well preserved Paleocene-Eocene thermal maximum (PETM, ~56 Ma) samples show reduced interspecific differences within the greenhouse boundary conditions of the PETM. Conversely, isotope data from the Plio-Pleistocene transition (PPT; 3.5-2 Ma) and the last glacial maximum (LGM; ~22 ka) show persistent vital effects of ~2 per mil. PPT and LGM data show a clear positive trend between coccolith (cell) size and isotopic enrichment in coccolith carbonate, as seen in laboratory cultures. On geological timescales, the degree of expression of vital effects in coccoliths appears to be insensitive topCO2 changes over the range ~350 ppm (Pliocene) to ~180 ppm (LGM). The modern array of coccolith vital effects arose after the PETM but before the late Pliocene and may reflect the operation of more diverse carbon acquisition strategies in coccolithophores in response to decreasing Cenozoic pCO2.