Phase-separation suppression in GaN-rich side of GaNP alloys grown by metal-organic chemical vapor deposition

The GaN-rich side of GaNP ternary alloys has been successfully synthesized by light-radiation heating and low-pressure metal-organic chemical vapor deposition. X-ray diffraction (XRD) rocking curves show that the ( 0002) peak of GaNP shifts to a smaller angle with increasing P content. From the GaNP photoluminescence (PL) spectra, the red shifts from the band-edge emission of GaN are determined to be 73, 78 and 100 meV, respectively, in the GaNP alloys with the P contents of 1.5%, 5.5% and 7.5%. No PL peak or XRD peak related to GaP is observed, indicating that phase separation induced by the short-range distribution of GaP-rich regions in the GaNP layer has been effectively suppressed. The phase-separation suppression in the GaNP layer is associated with the high growth rate and the quick cooling rate under the given growth conditions, which can efficiently restrain the accumulation of P atoms in the GaNP layer.

A Si-based tunable narrow-band flat-top filter with multiple-step-type Fabry-Perot cavity structure

In the optical network, the quick and accurate alignment with wavelength is an important issue during the channel detection. At this point, a filter having flat-top response characteristic is an effective solution. Based on multiple-step-type Fabry-Perot cavity structure, a novel all-Si-based thermooptical tunable flat-top filter with narrow-band has been fabricated, using our patent silicon-on-reflector bonding technology. The device demonstrated a 1-dB flat-top width of 1 nm, 3-dB band of 3 nm, free spectra range of 8 nm, and the tuning range of 4.6 nm was obtained under the applied voltage of 4 V.

Measurement of threading dislocation densities in GaN by wet chemical etching

We demonstrate a technique based on wet chemical etching that enables quick and accurate evaluation of edge- and screw/mixed-type threading dislocations (TDs) in GaN. Large and small etch pits are formed by phosphoric acid on the etched surfaces. The large etch pits are attributed to screw/mixed TDs and the small ones to edge TDs, according to their locations on the surface and Burgers vectors of TDs. Additionally, the origin of small etch pits is confirmed by a transmission electron microscopy. The difference in the size of etch pits is discussed in view of their origin and merging. Overetching at elevated temperatures or for a long time may result in merging of individual etch pits and underestimating of the density of TDs. Wet chemical etching has also been proved efficient in revealing the distribution of TDs in epitaxial lateral overgrowth GaN.

Temperature quenching mechanisms for photoluminescence of MBE-grown chlorine-doped ZnSe epilayers

We report on a detailed investigation on the temperature-dependent behavior of photoluminescence from molecular beam epitaxy (MBE)-grown chlorine-doped ZnSe epilayers. The overwhelming neutral donor bound exciton ((ClX)-X-0) emission at 2.797 eV near the band edge with a full-width at half-maximum (FWHM) of similar to 13 meV reveals the high crystalline quality of the samples used. In our experiments, the quick quenching of the (ClX)-X-0 line above 200 K is mainly due to the presence of a nonradiative center with a thermal activation energy of similar to 90 meV, The same activation energy and similar quenching tendency of the (ClX)-X-0 line and the I-3 line at 2.713 eV indicate that they originate from the same physical mechanism. We demonstrate for the first time that the dominant decrease of the integrated intensity of the I, line is due to the thermal excitation of the "I-3 center"-bound excitons to its free exciton states, leaving the "I-3 centers" as efficient nonradiative centers. The optical performance of ZnSe materials is expected to be greatly improved if the density of the "I-3 center" can be controlled. The decrease in the luminescence intensity at moderately low temperature (30-200 K) of the (ClX)-X-0 line is due to the thermal activation of neutral-donor-bound excitons ((ClX)-X-0) to free excitons. (C) 2000 Published by Elsevier Science B.V.

面向协同的服装供应链快速反应机制研究

我国服装企业存在库存高和客户满足率低的矛盾,解决这对矛盾的一个有效方法是建立面向协同的供应链快速反应机制。通过分析这对矛盾的根本原因,提出了面向协同的服装供应链快速反应机制的解决方案,并对其中主要相关的服装设计开发、物流分销和信息化等策略与方法进行了阐述。

生物质循环流化床气化炉的数学模型研究

以试验为基础，根据有关化学动力学、快速流态化模型等资料，结合原料的宽筛分特性，建立了生物质循环流化床气化炉（CFBG）的数学模型，并用Quick－Basic语言编制程序。利用模型对循环流化床木粉气化炉的运行参数进行模拟计算，模拟结果与试验数据符合良好，在一定程度上证明了模型的有效性和可靠性。利用该模型不仅能选择气化炉的最佳运行工况，而且可为同类反应器设计提供理论指导。

Effect of Ru addition to CO/SiO2/HZSM-5 catalysts on Fischer-Tropsch synthesis of gasoline-range hydrocarbons

Microporous HZSM-5 zeolite and mesoporous SiO2 supported Ru-Co catalysts of various Ru adding amounts were prepared and evaluated for Fischer-Tropsch synthesis (FTS) of gasoline-range hydrocarbons (C-5-C-12). The tailor-made Ru-Co/SiO2/HZSM-5 catalysts possessed both micro- and mesopores, which accelerated hydrocracking/hydroisomerization of long-chain products and provided quick mass transfer channels respectively during FTS. In the same time. Ru increased Cor reduction degree by hydrogen spillover, thus CO conversion of 62.8% and gasoline-range hydrocarbon selectivity of 47%, including more than 14% isoparaffins, were achieved simultaneously when Ru content was optimized at 1 wt% in Ru-Co/SiO2/HZSM-5 catalyst.

Gasoline-range hydrocarbon synthesis over cobalt-based Fischer-Tropsch catalysts supported onSiO2/HZSM-5

Two types of SiO2 with different mesopore size and HZSM-5 zeolite were used to prepare hybrid supported cobalt-based catalysts. The textual and structural properties of the catalysts were studied using N-2 physisorption, X-ray diffraction (XRD), and H-2 temperature-programmed reduction (TPR) techniques. Fischer-Tropsch synthesis (FTS) performances of the catalysts were carried out in a fixed-bed reactor. The combination effects of the meso- and micropores of the supports as well as the interaction between supports and cobalt particles on FTS activity are discussed. The results indicate that the catalyst supported on the tailor-made SiO2 and HZSM-5 hybrid maintained both meso- and micropore pores during the preparation process without HZSM-5 particles agglomerating. The mesopores provided quick mass transfer channels, while the micropores contributed to high metal dispersion and accelerated hydrocracking/hydroisomerization reaction rate. High CO conversion of 83.9% and selectivity to gasoline-range hydrocarbons (C-5-C-12) of 55%, including more than 10% isoparaffins, were achieved simultaneously on this type of catalyst.

乔木蒸腾耗水量研究方法述评与展望

参阅了大量国内外有关乔木蒸腾研究方法文献,认为乔木蒸腾量研究方法主要有二大类,即组织器官测定、单木测定;分类对典型研究方法(快速称重法、气孔计法、整株容器称重法、同位素示踪法、热脉冲法、树干热平衡法、热扩散探针法)进行了述评,对比分析了各种方法间的优缺点及其适用范围;展望了乔木蒸腾耗水作用研究方法的应用前景,认为热技术法是未来几年内的主要测定方法。

硼磷酸盐及相关基质中稀土离子的UV－VUV光谱和XAFS

采用高温固相反应合成了稀土离子激活的碱土硼磷酸盐MBPO_5:RE（M=Ca, Sr, Ba；RE＝Sm, Eu, Tb, Dy), Ba_3BPO_7:RE和Ba_3BP_O_(12):RE、稀土硼磷酸盐Ln_7BP_2P_(17):RE (Ln=La, Gd)、碱土（稀土）磷酸盐M_3(PO_4)_2:RE (M=Sr, Ba),ABLa(PP_4)_2:Ce,Tb (A=K, Na;B＝Mg, Zn）、碱土（稀土）硼酸盐SrB_4O_7:RE（Re＝Sm, Eu），BaB_8O_(13):Eu，SrB_6O_(10):Sm, M_3Gd_2(BO_3）_4:RE (M＝Ca, Sr)，B_3O6:Eu(RE=La, Gd)和稀土硼钨酸盐Cd_3BWO_9:Eu。通过XRD、IR光谱和Raman光谱等表征了其结构。测定了上述19个基质的数十个发光体的UV佩VUV光谱和RE-L_3（RE=Sm,Eu, Gd)边的XANES和EXAFS。碱土硼磷酸盐Ba_3BPO_7和Ba_3BP_3O_(12)、稀土硼磷酸盐Ln_7BP_2O_(17) (Ln=La, Gd)和稀土钨硼酸盐Gd3Bwo9等6个基质中稀土离子的UV-VUV光谱和除个别基质（REB_3O_6等）外的VUV光谱均属首次报道。发现土稀土离子激活的这些发光体在VUV范围有丰富的基质吸收带。认为基质中阴离子的结构和基质的晶体结构可能是影响基质的吸收带位置的重要因素。通过XANEs和UV-VUV光谱的联系，结合经验公式首次确证了一些复合氧化物基质中一些RE~(3＋)在vuv范围的f-d跃迁位置。根据VUV光谱测定结果推测了一些基质中RE~(3+)的CTB位置。首次应用RE-L_3边的XANES和UV-VUV光谱两种方法分析比较了RE~(3＋)(RE=Eu, Sm)离子在空气条件下在碱土硼磷酸盐、硼酸盐和磷酸盐基质中的还原。首次应用高分辨发射光谱和RE-L_3边的EXAFS研究了在一些基质中发光中心的配位数、键长和格位对称性等结构因素。

基于QuickBird卫星影像的沈阳城市绿地景观格局研究

城市绿地是城市景观的重要组成部分，起着调节城市生态环境、美化城市景观、提供休闲游憩场所的重要作用，在城市发展中扮演着关键角色。沈阳市近年来将城市绿地建设作为城市建设的重要方面，取得了显著成效。因此，本文利用2006年Quick Bird高分辨率卫星影像对沈阳市三环内的城市绿地景观格局进行了研究，具体结论如下： (1) 沈阳三环内绿地斑块18261个，绿地面积 173.71km2，斑块数目主要以中型斑块为主(62.25%)；在面积上以大型斑块为主(85.59%)；绿地总体呈现斑块分布不均衡。 (2) 居住绿地、单位附属绿地与道路绿地破碎化程度高，分布分散，斑块形状复杂。城市绿地廊道连通性较高，道路绿地平均分维数最大。 (3) 公园绿地亚类中，综合型公园与带状公园面积较大，破碎化程度低；社区公园与街头绿地面积较小，破碎化程度高，分布分散。 (4) 绿地景观整体上，绿地斑块密度较大，破碎化程度高，景观多样性指数为1.6，斑块类型丰富，均匀度指数为0.73，蔓延度指数为0.83，存在着少数类型控制整个景观的现象。 (5) 绿地系统梯度分析表明:类型水平上,不同的绿地类型沿景观格局梯度表现出明显的空间特征；景观水平上,不同景观指数沿样带梯度也表现出差异性,表明城市化导致景观的破碎化程度增大,景观异质性增高。城乡边缘区绿地类型最为丰富，多样性指数较高，其格局有利于绿地生态环境维护功能的发挥。

波浪作用下悬移质泥沙运动的两相流数值模型

该文采用基于水沙两相紊流的数值模型对波浪作用下的悬移质泥沙运动进行研究. 基本方程中将水相和颗粒相通过相间作用力进行耦合, 合理地考虑了相间相对运动的影响. 数值计算方法为有限体积法, 对流项处理利用了三阶精度的QUICK格式, 离散方程组求解采用的是TDMA迭代方法. 计算得到的悬移质泥沙垂线时均计算值与不同尺度的水槽实验数据吻合很好, 表明数学模型及其计算方法对于低浓度水沙两相问题是合理的. 该研究还探讨了悬沙浓度、泥沙沉降速度以及各种相间作用力随时间的分布规律

Interface delamination of the thermal barrier coating subjected to local heating

To investigate the possible failure modes of the thermal barrier coating (TBC) used to protect the scramjet combustion chamber, the local heating via laser beam irradiation was utilized to simulate the service condition of high thermal flux and high temperature gradient. Firstly, the experimental method and process were described and the typical fracture morphology of the TBC under test were provided. Then, the theoretical and finite element modeling were carried out to study the temperature, deformation and stresses of the specimen when the top ceramic coat was subjected to local heating, and to demonstrate the mechanism on the failure of the TBC. It is revealed that the interface delamination shall appear and ultimately lead to the failure of the TBC under such thermal loading of local quick heating. According to the outcome of this study, the driving force of the interface delamination is influenced greatly by the key structural parameters and performance matching. Moreover, by utilizing the rules of the effects of these parameters on the fracture driving force, there is some possibility for the designer to optimize the performances of the TBC.