Performance and emissions of a gas turbine engine using ox tallow ethyl-ester blended with kerosene

The performance and emissions behavior of a Rover 1S/60 turboshaft engine when operated with several blends of aviation kerosene and ox tallow ethyl-ester are shown in this article. The tests were performed with a compressor shaft coupled to an hydraulic dynamometer where data of power and mass fuel flow were collected to determine the brake specific fuel consumption. A flue gas analyzer was positioned at the exhaust duct to collect oxygen, carbon dioxide, carbon monoxide and nitrous oxides. An increase in the specific fuel consumption was observed due to the lesser lower heating value of the most oxygenated blends. However, reductions of CO, CO2 and NO (x) have been observed and no-significant ill effects have occurred in the turbine operation.

Efeitos da poluição atmosférica no sistema respiratório de indivíduos praticantes de exercício físico aeróbio em ambiente aberto e fechado

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Cardiovascular Responses Induced by Catalase Inhibitior into the Fourth Cerebral Ventricle is Changed in Wistar Rats Exposed to Sidestream Cigarette Smoke

Objectives: This experimental study aimed to evaluate the effects of central catalase inhibition on cardiovascular responses in rats exposed to sidestream cigarette smoke (SSCS) for 3 weeks. Methodology: A total of 20 males Wistar rats (320–370g) were implanted with a stainless steel guide cannula into the fourth cerebral ventricle (4thV). Femoral artery and vein were cannulated for mean arterial pressure (MAP) and heart rate (HR) measurement and drug infusion, respectively. Rats were exposed to SSCS for three weeks, 180 minutes per day, 5 days/week [carbon monoxide (CO): 100–300 ppm)]. Baroreflex was tested with one pressor dose of phenylephrine (PHE, 8 μg/kg, bolus) and one depressor dose of sodium nitroprusside (SNP, 50 μg/kg, bolus). Cardiovascular responses were evaluated before and 15 minutes after 3-amino-1, 2, 4-triazole (ATZ, catalase inhibitor, 0.001g/100μL) injection into the 4th V. Results: Vehicle treatment into the 4th V did not change cardiovascular responses. Central catalase inhibition increased tachycardic peak, attenuated bradycardic peak and reduced HR range at 15 minutes, increased MAP at 5, 15 and 30 min and increased HR at 5 and 15 min. In rats exposed to SSCS, central ATZ increased basal MAP after 5 min and increased HR at 5, 15 and 30 minutes, respectively, and attenuated bradycardic peak at 15 minutes. Conclusion: This study suggests that brain oxidative stress caused by SSCS influences autonomic regulation of the cardiovascular system.

Controle de dissociação caótica de moléculas diatômicas

In this work we investigate the dissociation of heteronuclear diatomic molecules subjected to laser pulses. This phenomenon can be modeled by the classical forced Morse oscillator. This system presents a chaotic dynamics associated with the anharmonicity of the internuclear potential and with the coupling of permanent dipole of molecule with the electric field of laser. We want to verify how the dissociation probability evolves while we change the intensity and frequency of laser. We study the phase space of molecules to have a better understanding of system dynamics. We make the calculations changing two parameters of laser (intensity and frequency) and checking how this parameters influences on molecule dissociation. We compare the results of HF molecule (Fluoride acid) and CO molecule (Carbon monoxide) to check how the dipole moment of each molecule can influence on laser interaction

Estudo da adsorção e oxidação do monóxido de carbono sobre as fases intermetálicas ordenadas AuIn, AuSb2, AuSn, PdSb e PdSn

Aiming to reduce the cost of electrocatalysts and a greater resistance to CO poisoning this work was to study the adsorption and oxidation of carbon monoxide on ordered intermetallic phases AuIn, AuSb2, AuSn, PdSb and PdSn using voltammetric techniques in alkaline electrolyte solution. The results suggest that the AuSn and PdSn intermetallics has some form of resistance to CO poisoning. It is assumed that this behavior is a result of electronic effect and the effect of the third body has been achieved by adding a second metal to Au and Pd. However, further studies should be conducted to confirm this hypothesis as to test these materials as electrocatalysts in the reaction of oxidation of fuels

Poluição atmosférica e paisagem urbana no município de São Paulo

This paper proposes an analysis of two major polluting elements of the atmosphere of São Paulo city, carbon monoxide (CO) and sulfur dioxide (SO2). This study was performed through analysis of data on the quality of air, by means of published reports and records obtained by experiment using measuring rate monitor for CO2. Atmospheric data were collected and sorted. From this work it was possible to identify the concentration of carbon dioxide in the center of São Paulo on September 14, 2012 using the infrared gas analyzer (IRGA). From the ratios of carbon monoxide and sulfur dioxide spatially analyzed could identify major emitters by comparing records of pollutants and their origin. The analysis makes it possible to map the intensity of air pollution in urban areas, identifying the polluting elements, their issuers and thereby contributes to the current understanding of atmospheric features, bringing a geographical spatial analysis of air pollutants in São Paulo, contributing to awareness of vulnerabilities, enabling a useful tool for planning and maintenance of the urban environment related public policies

Estimativa das emissões de monóxido de carbono por veículos automotivos na cidade de Campinas/SP utilizando o modelo CAL3QHCR

Air pollution is an environmental issue worldwide and frequently cause negative effects on population health and ecosystems on cities. The relationship between climate and atmospheric pollution can be used as a surrogate to the intensity of air pollution. The present and quantity of some gases can be used as indicators to air quality: particulate matter (PM), sulfur dioxide (SO2), carbon monoxide (CO), ozone (O3), and nitrogen dioxide (NO2). Among those gases, CO has its major source within the cities, where automobiles are the main emitter. But measure pollutant concentration are challenging, sometimes because the lack of good equipments due to high costs and of the large variability of models that varies in precision, way of measure and distribution of sellers. Modeling are useful when there are an intend to evaluate air pollution, its sources and evaluate scenarios. This work aims to use CAL3QHCR model developed by the U.S Environmental Protection Agency (EPA) to generate predictive surfaces of CO concentration distribution on a site within Campinas city, located in São Paulo state, Brazil. CAL3QHCR model use data urban automobile circulation to generate spatial results for CO distribution. We observed that the pollution concentration was lower on our modeling than the concentrations measured by Companhia Ambiental do Estado de São Paulo (CETESB), the main environmental company on the São Paulo state. Also the correlation between average estimates of our model and the measure by CETESB was weak, indicating that the model used on this study need to be or better parameterized, or the scale we measured of CO emissions need to be rescaled. Although the model failed to correlate to CETESB data, maybe one that explore the estimated emissions distributed within the sites to understand spatial distributions of CO on the regions. Also, the generated information can also be used to other studies, and come to be useful to explain heat island

Efeitos do tabagismo passivo no tranporte mucociliar e sistema nervoso autônomo de adultos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Caracterização de estruturas de óxido de estanho modificado como sensores de gases

Pós-graduação em Química - IQ

Associação entre Síndrome de burnout, uso prejudicial de álcool e tabagismo em profissionais de enfermagem nas unidades de teripa intensiva do Hospital das Clínicas de Botucatu-UNESP

Pós-graduação em Saúde Coletiva - FMB

Avaliação da eficácia do tratamento da cessação do tabagismo iniciado durante internação hospitalar em pacientes com doença cardiológica ou respiratória agudizada

Pós-graduação em Fisiopatologia em Clínica Médica - FMB

Operational and environmental assessment on the use of charcoal in iron ore sinter production

A study was carried out into the use of charcoal as a supplementary fuel in the iron-ore sintering process. The primary fuel was coke breeze and anthracite with 0, 10, 25, 50 and 100% replacement of the energy input with charcoal to produce sinter. This was achieved by considering the carbon content of each fuel and its corresponding participation on fuel blending, in order to have the same carbon input in each test run. An extensive analysis of the environmental impact was carried out regarding the atmospheric pollutants characterization (dust, sulphur dioxide, nitrogen oxides, carbon monoxide, carbon dioxide, methane, total hydrocarbons, and dioxins and furans). Experimental results indicate that fuel blending where 50% of the heat input was provided by charcoal may be comparable with those using 100% coke, under normal sintering conditions, and may result in a 50% reduction on greenhouse gas emission. It was also observed that while dust, methane and hydrocarbons emissions increased, the total dioxins and furans, expressed as polychlorinated dibenzodioxins/furans, decreased approximately 50% when compared with operation with 100% coke.

Utilização de dados fornecidos por satélites para determinação de riscos ambientais

Pós-graduação em Engenharia Mecânica - FEG

Produção do monóxido de titânio em estrelas variáveis

Mira are pulsating variable stars in advanced stages of evolution. Their atmospheres are sources of intense absorption bands attributed to molecular titanium monoxide (TiO). It has been suggested that the abundance of TiO reaches its maximum value near the minimum light. In this sense, the study of the processes of formation and destruction of TiO in circumstellar envelopes of Mira stars, not only allows us to understand the physical and chemical processes that occur in these environments, as it allows to verify the correlation between the abundance of TiO and its light curve. However, the main mechanisms of formation and destruction of TiO are poorly known and, consequently, the possible correlation between the abundance of this species and the light curve. In these sense, we studied the main processes of formation and destruction of titanium monoxide in molecular layers of Mira atmospheres and determined its temporal variation as function of the stellar radius. The TiO profile along the radius was expected for the different stellar phase, however its abundance is not enough to explain the light curve. The reasons behind it are discussed in details

Radiative association of Ti and O atoms

Rate coefficients for the radiative association of titanium and oxygen atoms to form the titanium monoxide (TiO) molecule are estimated. The radiative association of Ti(F-3) and O(P-3) atoms is dominated by an approach along the C-3 Delta potential energy curve, accompanied by spontaneous emission into the X-3 Delta ground state of TiO. For temperatures ranging from 300-14 000 K, the total rate coefficients are found to vary from 4.76 x 10(-17) to 9.96 x 10(-17) cm(3) s(-1), respectively.