The contribution of maize cropping in the Midwest USA to global warming: A regional estimate

Agricultural soils emit about 50% of the global flux of N2O attributable to human influence, mostly in response to nitrogen fertilizer use. Recent evidence that the relationship between N2O fluxes and N-fertilizer additions to cereal maize are non-linear provides an opportunity to estimate regional N2O fluxes based on estimates of N application rates rather than as a simple percentage of N inputs as used by the Intergovernmental Panel on Climate Change (IPCC). We combined a simple empirical model of N2O production with the SOCRATES soil carbon dynamics model to estimate N2O and other sources of Global Warming Potential (GWP) from cereal maize across 19,000 cropland polygons in the North Central Region (NCR) of the US over the period 1964–2005. Results indicate that the loading of greenhouse gases to the atmosphere from cereal maize production in the NCR was 1.7 Gt CO2e, with an average 268 t CO2e produced per tonne of grain. From 1970 until 2005, GHG emissions per unit product declined on average by 2.8 t CO2e ha−1 annum−1, coinciding with a stabilisation in N application rate and consistent increases in grain yield from the mid-1970’s. Nitrous oxide production from N fertilizer inputs represented 59% of these emissions, soil C decline (0–30 cm) represented 11% of total emissions, with the remaining 30% (517 Mt) from the combustion of fuel associated with farm operations. Of the 126 Mt of N fertilizer applied to cereal maize from 1964 to 2005, we estimate that 2.2 Mt N was emitted as N2O when using a non-linear response model, equivalent to 1.75% of the applied N.

Evaluation of a remote drafting system for regulating sheep access to supplement

Remote drafting technology now available for sheep makes possible targeted supplementation of individuals within a grazing flock. This system was evaluated by using 68 Merino wethers grazing dry-season, native Mitchell grass pasture (predominantly Astrebla spp.) as a group and receiving access to lupin grain through a remote drafter 0, 1, 2, 4 or 7 days/week for 8 weeks. The sole paddock watering point was separately fenced and access was via a one-way flow gate. Sheep exited the watering point through a remote drafter operated by solar power and were drafted by radio frequency identification (RFID) tag, according to treatment, either back into the paddock or into a common supplement yard where lupins were provided ad libitum in a self-feeder. Sheep were drafted into the supplement yard on only their first time through the drafter during the prescribed 24-h period and exited the supplement yard via one-way flow gates in their own time. The remote drafter operated with a high accuracy, with only 2.1% incorrect drafts recorded during the experimental period out of a total of 7027 sheep passes through the remote drafter. The actual number of accesses to supplement for each treatment group, in order, were generally less than that intended, i.e. 0.02, 0.69, 1.98, 3.35 and 6.04 days/week. Deviations from the intended number of accesses to supplement were mainly due to sheep not coming through to water on their allocated day of treatment access, although some instances were due to incorrect drafts. There was a non-linear response in growth rate to increased frequency of access to lupins with the growth rate response plateauing at similar to 3 actual accesses per week, corresponding to a growth rate of 72.5 g/head. day. This experiment has demonstrated the application of the remote drafting supplementation system for the first time under grazing conditions and with the drafter operated completely from solar power. The experiment demonstrates a growth response to increasing frequency of access to supplement and provides a starting point with which to begin to develop feeding strategies to achieve sheep weight-change targets.

Shear deformation analysis on laser-induced reverse bulging and plugging

A new kind of failure mode is observed in circular brass foils in which their peripheries are fixed and their surfaces are subjected to a long pulsed laser over a central region. The failure is classified into three stages; they are referred to as thermal bulging, localized shear deformation and perforation by plugging. A distinct feature of the failure mode is that bulging and plugging occurred in the direction opposite to the incident laser beam. To study the failure mode, we investigate the non-linear response of heated, non-homogeneous circular plates. Based on the large deflection equations of Berger [J. Appl. Mech. 22 (3), 465-472 (1965)], Ohnabe and Mizuguchi [Int. J. Non-Linear Mech. 28 (4), 365-372 (1993)] and the parabolic shear deformation theory of Bhimaraddi and Stevens [J. Appl. Mech. 51 (1), 195-198 (1984)], we have derived new coupled governing equations of shear deformation and deflection. The new equations are solved, for the plate with a clamped edge, by the Galerkin and iterative methods. The numerical results for the shear deformation distribution are in good agreement with the experimental observation.

Femtosecond optical Kerr effect study of Ge(10)AS(40)S(30)Se(20) film

The results of the femtosecond optical heterodyne detection of optical Kerr effect at 805 nm with the 80 fs ultrafast pulses in amorphous Ge10As40S30Se20 film is reported in this paper. The film shows an optical non-linear response of: 200 fs under ultrafast 80 fs-pulse excitation and the values of real and imaginary parts of non-linear susceptibility chi((3)) were 9.0 X 10(-12) and -4.0 X 10(-12) esu, respectively. The large third-order non-linearity and ultrafast response are attributed to the ultrafast distortion of the electron orbits surrounding the average positions of the nucleus of Ge, As, S and Se atoms. This Ge10As40S30Se20 chalcogenide glass would be expected as a promising material for optical switching technique. (c) 2005 Elsevier Ltd. All rights reserved.

Cinematographic OH-PLIF measurements of two interacting turbulent premixed flames with and without acoustic forcing

This paper describes an experimental investigation into the interactions that occur between two lean turbulent premixed flames stabilised on conical bluff-bodies when they are moved closer together. Cinematographic OH-PLIF measurements were acquired to investigate adjacent flame front interactions as a function of flame separation distance (S). Flame surface density (FSD) and curvature were determined to characterise the unforced flames. Acoustic forcing was then applied to explore the amplitude dependent thermo-acoustic response. Phase-averaged FSD and global heat release measurements in the form of OH * chemiluminescence were obtained for a range of forcing frequencies (f) and amplitudes (A) as a function of S. As the flames were brought closer together the adjacent annular jets were found to merge into a single jet structure. This caused adjacent flame fronts to merge above the wake region between the two flames at a location determined by the jet efflux (flame angle) and S. This region of flame-flame interaction we refer to as 'interacting region'. In the unforced flames, a trend of increasingly negative curvature for decreasing S produced a small net increase in flame surface area via cusp formation. When subjected to acoustic forcing, S-dependent regimes were found in the global heat release response as a function A. The overall trend showed that the occurrence of jet/flame merging reduces the value of A at which non-linear response occurs. In support of previous findings for flames stabilised along shear layers, the phase-averaged FSD showed that the flame dynamics that drive the thermo-acoustic response result from the roll-up of vortices which generate large-scale vortex-flame interactions. Compared with axisymmetric flames, the occurrence of jet merging alters the vortex-flame interactions resulting in an asymmetric contribution to the heat release between the wall and interacting regions. The majority of the heat release was found to occur in the interacting region through the rapid production and destruction of flame surface area. The occurrence of jet merging and large-scale interactions between adjacent flames result in different physical mechanisms that drive the thermo-acoustic response compared with single axisymmetric flames. © 2011.

A systematic approach to standard addition methods in instrumental analysis

Nine cases of standard addition methods in instrumental analysis, including linear instruments, a non-linear response, the electrochemical Nernst equation, and radiochemical techniques.

各向异性与非线性介质中弹性波场传播特征研究

The topic of this study is about the propagation features of elastic waves in the anisotropic and nonlinear media by numerical methods with high accuracy and stability. The main achievements of this paper are as followings: Firstly, basing on the third order elastic energy formula, principle of energy conservation and circumvolved matrix method, we firstly reported the equations of non-linear elastic waves with two dimensions and three components in VTI media. Secondly, several conclusions about some numerical methods have been obtained in this paper. Namely, the minimum suitable sample stepth in space is about 1/8-1/12 of the main wavelength in order to distinctly reduce the numerical dispersion resulted from the numerical mehtod, at the same time, the higher order conventional finite difference (CFD) schemes will give little contribution to avoid the numerical solutions error accumulating with time. To get the similar accuracy with the fourth order center finite difference method, the half truncation length of SFFT should be no less than 7. The FDFCT method can present with the numerical solutions without obvious dispersion when the paprameters of FCT is suitable (we think they should be in the scope from 0.0001 to 0.07). Fortunately, the NADM method not only can reported us with the higher order accuracy solutions (higher than that of the fourth order finite difference method and lower than that of the sixth order finite difference method), but also can distinctly reduce the numerical dispersion. Thirdly, basing on the numerial and theoretical analysis, we reported such nonlinear response accumulating with time as waveform aberration, harmonic generation and resonant peak shift shown by the propagation of one- and two-dimensional non-linear elasticwaves in this paper. And then, we drew the conclusion that these nonlinear responses are controlled by the product between nonlinear strength (SN) and the amplitude of the source. At last, the modified FDFCT numerical method presented by this paper is used to model the two-dimensional non-linear elastic waves propagating in VTI media. Subsequently, the wavelet analysis and polarization are adopted to investigate and understand the numerical results. And then, we found the following principles (attention: the nonlinear strength presented by this paper is weak, the thickness of the -nonlinear media is thin (200m), the initial energy of the source is weak and the anisotropy of the media is weak too): The non-linear response shown by the elastic waves in VTI media is anisotropic too; The instantaneous main frequency sections of seismic records resulted from the media with a non-linear layer have about 1/4 to 1/2 changes of the initial main frequency of source with that resulted from the media without non-linear layer; The responses shown by the elasic waves about the anisotropy and nonlinearity have obvious mutual reformation, namely, the non-linear response will be stronger in some directions because of the anisotropy and the anisotropic strength shown by the elastic waves will be stronger when the media is nonlinear.

Numerical analysis of intralaminar failure mechanisms in composite structures, Part II: Applications

A three-dimensional continuum damage mechanics-based material model was implemented in an implicit Finite Element code to simulate the progressive intralaminar degradation of fibre reinforced laminates based on ply failure mechanisms. This paper presents some structural applications of the progressive failure model implemented. The focus is on the non-linear response of the shear failure mode and its interaction with other failure modes. Structural applications of the damage model show that the proposed model is able to reproduce failure loads and patterns observed experimentally.

Application of AAO Matrix in Aligned Gold Nanorod Array Substrates for Surface-Enhanced Fluorescence and Raman Scattering

In this paper, we probed surface-enhanced Raman scattering (SERS) and surface-enhanced fluorescence (SEF) from probe molecule Rhodamine 6G (R6G) on self-standing Au nanorod array substrates made using a combination of anodization and potentiostatic electrodeposition. The initial substrates were embedded within a porous alumina template (AAO). By controlling the thickness of the AAO matrix, SEF and SERS were observed exhibiting an inverse relationship. SERS and SEF showed a non-linear response to the removal of AAO matrix due to an inhomogeneous plasmon activity across the nanorod which was supported by FDTD calculations. We showed that by optimizing the level of AAO thickness, we could obtain either maximized SERS, SEF or simultaneously observe both SERS and SEF together.

Modelling the nonlinear behaviour and fracture process of AS4/PEKK thermoplastic composite under shear loading

The accurate determination of non-linear shear behaviour and fracture toughness of continuous carbon-fibre/polymer composites remains a considerable challenge. These measurements are often necessary to generate material parameters for advanced computational damage models. In particular, there is a dearth of detailed shear fracture toughness characterisation for thermoplastic composites which are increasingly generating renewed interest within the aerospace and automotive sectors. In this work, carbon fibre (AS4)/ thermoplastic Polyetherketoneketone (PEKK) composite V-notched cross-ply specimens were manufactured to investigate their non-linear response under pure shear loading. Both monotonic and cyclic loading were applied to study the shear modulus degradation and progressive failure. For the first time in the reported literature, we use the essential work of fracture approach to measure the shear fracture toughness of continuous fibre reinforced composite laminates. Excellent geometric similarity in the load-displacement curves was observed for ligament-scaled specimens. The laminate fracture toughness was determined by linear regression, of the specific work of fracture values, to zero ligament thickness, and verified with computational models. The matrix intralaminar fracture toughness (ply level fracture toughness), associated with shear loading was determined by the area method. This paper also details the numerical implementation of a new three-dimensional phenomenological model for carbon fibre thermoplastic composites using the measured values, which is able to accurately represent the full non-linear mechanical response and fracture process. The constitutive model includes a new non-linear shear profile, shear modulus degradation and load reversal. It is combined with a smeared crack model for representing ply-level damage initiation and propagation. The model is shown to accurately predict the constitutive response in terms of permanent plastic strain, degraded modulus as well as load reversal. Predictions are also shown to compare favourably with the evolution of damage leading to final fracture.

Biaxial seismic behaviour of reinforced concrete columns

A análise dos efeitos dos sismos mostra que a investigação em engenharia sísmica deve dar especial atenção à avaliação da vulnerabilidade das construções existentes, frequentemente desprovidas de adequada resistência sísmica tal como acontece em edifícios de betão armado (BA) de muitas cidades em países do sul da Europa, entre os quais Portugal. Sendo os pilares elementos estruturais fundamentais na resistência sísmica dos edifícios, deve ser dada especial atenção à sua resposta sob ações cíclicas. Acresce que o sismo é um tipo de ação cujos efeitos nos edifícios exige a consideração de duas componentes horizontais, o que tem exigências mais severas nos pilares comparativamente à ação unidirecional. Assim, esta tese centra-se na avaliação da resposta estrutural de pilares de betão armado sujeitos a ações cíclicas horizontais biaxiais, em três linhas principais. Em primeiro lugar desenvolveu-se uma campanha de ensaios para o estudo do comportamento cíclico uniaxial e biaxial de pilares de betão armado com esforço axial constante. Para tal foram construídas quatro séries de pilares retangulares de betão armado (24 no total) com diferentes características geométricas e quantidades de armadura longitudinal, tendo os pilares sido ensaiados para diferentes histórias de carga. Os resultados experimentais obtidos são analisados e discutidos dando particular atenção à evolução do dano, à degradação de rigidez e resistência com o aumento das exigências de deformação, à energia dissipada, ao amortecimento viscoso equivalente; por fim é proposto um índice de dano para pilares solicitados biaxialmente. De seguida foram aplicadas diferentes estratégias de modelação não-linear para a representação do comportamento biaxial dos pilares ensaiados, considerando não-linearidade distribuída ao longo dos elementos ou concentrada nas extremidades dos mesmos. Os resultados obtidos com as várias estratégias de modelação demonstraram representar adequadamente a resposta em termos das curvas envolventes força-deslocamento, mas foram encontradas algumas dificuldades na representação da degradação de resistência e na evolução da energia dissipada. Por fim, é proposto um modelo global para a representação do comportamento não-linear em flexão de elementos de betão armado sujeitos a ações biaxiais cíclicas. Este modelo tem por base um modelo uniaxial conhecido, combinado com uma função de interação desenvolvida com base no modelo de Bouc- Wen. Esta função de interação foi calibrada com recurso a técnicas de otimização e usando resultados de uma série de análises numéricas com um modelo refinado. É ainda demonstrada a capacidade do modelo simplificado em reproduzir os resultados experimentais de ensaios biaxiais de pilares.

Indoor and outdoor atmospheric fungal spores in the So Paulo metropolitan area (Brazil): species and numeric concentrations

The aim of this study was to estimate the indoor and outdoor concentrations of fungal spores in the Metropolitan Area of Sao Paulo (MASP), collected at different sites in winter/spring and summer seasons. The techniques adopted included cultivation (samples collected with impactors) and microscopic enumeration (samples collected with impingers). The overall results showed total concentrations of fungal spores as high as 36,000 per cubic meter, with a large proportion of non culturable spores (around 91% of the total). Penicillium sp. and Aspergillus sp. were the dominant species both indoors and outdoors, in all seasons tested, occurring in more than 30% of homes at very high concentrations of culturable airborne fungi [colony forming units(CFU) m(-3)]. There was no significant difference between indoor and outdoor concentrations. The total fungal spore concentration found in winter was 19% higher than that in summer. Heat and humidity were the main factors affecting fungal growth; however, a non-linear response to these factors was found. Thus, temperatures below 16A degrees C and above 25A degrees C caused a reduction in the concentration (CFU m(-3)) of airborne fungi, which fits with MASP climatalogy. The same pattern was observed for humidity, although not as clearly as with temperature given the usual high relative humidity (above 70%) in the study area. These results are relevant for public health interventions that aim to reduce respiratory morbidity among susceptible populations.

Uso da restrição alimentar quantitativa para diminuir a mortalidade de frangos de corte machos

The effect of feed restriction (0, 10, 20, 30, 40 and 50%) from 8 until 14 days post-hatching on performance, total mortality incidence and sudden death syndrome (SDS) rate was studied in male broilers during winter and summer.Ad libitum fed broilers had a better performance, but a higher total mortality rate (13.00% in winter, 3.67% in summer) and SDS (3.67% in winter, 0.67% in summer). All restricted groups had a lower mortality level in winter than the control group with a non linear response influenced by feed restriction. Birds submitted to 40% feed restriction showed the lowest mortality incidence (2.67%) followed by groups submitted to 30% (4.67%), 50% (5.33%) and 10% and 20% (7.67%) feed restriction. Birds fed ad libitum had the highest SDS incidence (3.67%, against .33, 1.00, .67, 1.33 and 1.33% at 10, 20, 30, 40, 50% feed restriction, respectively), but differences were not significant. In summer, incidences of total mortality and due to SDS were low and not influenced by feed restriction, either during the restrictive period itself (8 to 14 days) or during the total period of raising (1 to 49 days). In both seasons, the feed restricted birds showed compensatory gain only until three weeks post-restriction period. At 49 days, body weight and weight-gain were lower in feed restricted birds, but feed :gain ratio rate was improved. This resulted in better productivity index in winter, but not in summer. The feed restriction at 30 to 40% for seven days during the second week may decrease mortality in male broilers raised in winter without lowering productivity if the restriction is followed by at least three weeks of full feeding.

Geotechnical and structural behavior of the railroad track in large-scale apparatus

This paper analyses the static and dynamic behavior of the railroad track model in laboratory. Measurements of stresses and strains on a large-scale railroad track apparatus were studied. The model includes: compacted soil, representing the final layers of platform, ballast layer, and ties (steel, wooden, and pre-stressed concrete). The soil and soil ballast interface were instrumented with pneumatic stress gauge. Settlement measurement device were positioned at the same levels as the load cells. Loads were applied by hydraulic actuators, statically and dynamically. After the prescribed number of load cycles, in pre-determined intervals, stresses and strains were measured. Observations indicate that stress and strain distributions, transmitted by wooden or steel ties, behave similarly. A more favorable behavior was observed with pre-stressed concrete mono block ties. Non-linear response was observed after a threshold numbers of cycles were surpassed, showing that the strain modulus increases with the numbers of cycles. © 2009 IOS Press.

Nonlinear effects generation in suspended core chalcogenide fibre

In this work we report our achievements in the elaboration and optical characterizations of low-losses suspended core optical fibers elaborated from As2S3 glass. For preforms elaboration, alternatively to other processes like the stack and draw or extrusion, we use a process based on mechanical drilling. The drawing of these drilled performs into fibers allows reaching a suspended core geometry, in which a 2 μm diameter core is linked to the fiber clad region by three supporting struts. The different fibers that have been drawn show losses close to 0.9 dB/m at 1.55 μm. The suspended core waveguide geometry has also an efficient influence on the chromatic dispersion and allows its management. Indeed, the zero dispersion wavelength, which is around 5 μm in the bulk glass, is calculated to be shifted towards around 2μm in our suspended core fibers. In order to qualify their nonlinearity we have pumped them at 1.995 μm with the help of a fibered ns source. We have observed a strong non linear response with evidence of spontaneous Raman scattering and strong spectral broadening. © 2011 SPIE.