Influence of a Counterion on the Ion Atmosphere of an Anion: A Molecular Dynamics Study of LiX and CsX (X = F-, Cl-, I-) in Methanol

We report molecular dynamics (MD) simulations to explore the influence of a counterion on the structure and dynamics of cationic and anionic solvation shells for various ions in methanol at 298 K. We show that the variation in ionic size of either the cation or the anion in an ion pair influences the solvation structure of the other ion as well as the diffusivity in an electrolyte solution of methanol. The extent of ionic association between the cation and its counteranion of different ionic sizes has been investigated by analyzing the radial distribution functions (RDFs) and the orientation of methanol molecules in the first solvation shell (FSS) of ions. It is shown that the methanol in the FSS of the anion as well the cation exhibit quite different radial and orientational structures as compared to methanol which lie in the FSS of either the anion or the cation but not both. We find that the coordination number (CN) of F-, Cr-, and I- ions decreases with increasing size of the anion which is contrary to the trend reported for the anions in H2O. The mean residence time (MRT) of methanol molecules in the FSS of ions has been calculated using the stable states picture (SSP) approach. It is seen that the ion-counterion interaction has a considerable influence on the MRT of methanol molecules in the FSS of ions. We also discuss the stability order of the ion-counterion using the potentials of mean force (PMFs) for ion pairs with ions of different sizes. The PMF plots reveal that the Li+-F- pair (small-small) is highly stable and the Li+-I- pair is least stable (small-large) in electrolyte solutions.

Impact of the commercial fishery on the population of bait shrimp (Penaeus spp.) in Biscayne Bay, 1986

Monthly population size of bait shrimp in the Bay was estimated from December 1984 to July 1985. Growth rates for male and female P. duorarum showed that pink shrimp exhibit a mean residence time in the nursery area (Biscayne Bay) of approximately 21 weeks. Monthly mortality rates were determined for each sex of pink shrimp. It was estimated that 23% and 26% of the male and female monthly population size, respectively, was absorbed by both the fishery and ecosystem monthly. Monthly proportion of the standing stock expected to die exclusively through fishing was 6.5% and 6.0% for males and females respectively. Estimates of emigration rates showed that approximately 4.0% of the population was lost from the Bay system each month. This surplus production was about 50% of the average monthly catch by the fleet. Fishing mortality represents only 8 - 9% of the losses to the shrimp population. The biggest source of loss is emigration, suggesting that most shrimp beyond the size at recruitment (to the fishery) are not utilized for food while in the Bay. Thus, it appears that the direct impact of the fishery on the bait shrimp population is relatively small. (PDF contains 46 pages)

Some aspects of the temperature, oxygen and nutrient distributions in Monterey Bay, California. Annual Report, Part 1, 1973

Seasonal variations in temperature, dissolved oxygen, and nutrients in the nearshore areas and in the canyon area of Monterey Bay, California during 1971-1972 were similar~ During upwelling periods, however, water in the nearshore areas was higher in temperature and oxygen and lower in nutrients than water in the canyon area~ This was caused by upwelled water moving north and south of the canyon into counterclockwise and clockwise flow in the northern and southern ends of the bay respectively. The water was heated by insolation and depleted of its nutrients by photosynthesis during this movement. The residence time of water in the nearshore northern and southern bay during upwelling is estimated to be 3 to 8 days, and this fits well into the above circulation pattern and average measured current velocities of 10 to 15 cm/sec~ There is sorne evidence that this circulation pattern and the estimated residence time may be also valid for on-upwelling periods. Upwelling apparently occurred in Monterey Submarine Canyon at rates of 0.4 to 2.9 m/day and was stronger in 1971 than 1972. (PDF contains 107 pages)

In Vitro and In Vivo Evaluation of a Folate-Targeted Copolymeric Submicrohydrogel Based on N-Isopropylacrylamide as 5-Fluorouracil Delivery System

Folate-targeted poly[(p-nitrophenyl acrylate)-co-(N-isopropylacrylamide)] nanohydrogel (F-SubMG) was loaded with 5-fluorouracil (5-FU) to obtain low (16.3 +/- 1.9 mu g 5-FU/mg F-SubMG) and high (46.8 +/- 3.8 mu g 5-FU/mg F-SubMG) load 5-FU-loaded F-SubMGs. The complete in vitro drug release took place in 8 h. The cytotoxicity of unloaded F-SubMGs in MCF7 and HeLa cells was low; although it increased for high F-SubMG concentration. The administration of 10 mu M 5-FU by 5-FU-loaded F-SubMGs was effective on both cellular types. Cell uptake of F-SubMGs took place in both cell types, but it was higher in HeLa cells because they are folate receptor positive. After subcutaneous administration (28 mg 5-FU/kg b.w.) in Wistar rats, F-SubMGs were detected at the site of injection under the skin. Histological studies indicated that the F-SubMGs were surrounded by connective tissue, without any signs of rejections, even 60 days after injection. Pharmacokinetic study showed an increase in MRT (mean residence time) of 5-FU when the drug was administered by drug-loaded F-SubMGs.

Cheese consumption and prevalence of overweight and obesity in a Basque adult population: a crosssectional study

[EN] Studies have reported a negative association between dairy product consumption and weight status. However, not as much research has focused on cheese; therefore, the aim of this study was to study the association between cheese intake and overweight and obesity in a representative Basque adult population. A food frequency questionnaire (FFQ) was obtained from a random sample of 1081 adults (530 males and 551 females, 17–96 years old). Cheese consumption data were expressed as g/1000 kcal/day. The prevalence of overweight/obesity was higher in men (55.1%) than in women (35.4%) (p50.001). Participants with low or moderate intake of fresh and processed cheese demonstrated a higher prevalence of excess weight, compared with those with higher consumption. The confounding variables selected in multivariate analysis were occupational status and age in both genders; and place of residence in men. In conclusion, negative associations were found between consumption of some types of cheese and overweight and obesity in this population.

Oxidation of Volatile Organic Compounds in Aqueous Solution and at the Air-water Interface of Aqueous Microdroplets

Isoprene (ISO),the most abundant non-methane VOC, is the major contributor to secondary organic aerosols (SOA) formation. The mechanisms involved in such transformation, however, are not fully understood. Current mechanisms, which are based on the oxidation of ISO in the gas-phase, underestimate SOA yields. The heightened awareness that ISO is only partially processed in the gas-phase has turned attention to heterogeneous processes as alternative pathways toward SOA.

During my research project, I investigated the photochemical oxidation of isoprene in bulk water. Below, I will report on the λ > 305 nm photolysis of H₂O₂ in dilute ISO solutions. This process yields C₁₀H₁₅OH species as primary products, whose formation both requires and is inhibited by O₂. Several isomers of C₁₀H₁₅OH were resolved by reverse-phase high-performance liquid chromatography and detected as MH⁺ (m/z = 153) and MH⁺-18 (m/z = 135) signals by electrospray ionization mass spectrometry. This finding is consistent with the addition of ·OH to ISO, followed by HO-ISO· reactions with ISO (in competition with O₂) leading to second generation HO(ISO)₂· radicals that terminate as C₁₀H₁₅OH via β-H abstraction by O₂.

It is not generally realized that chemistry on the surface of water cannot be deduced, extrapolated or translated to those in bulk gas and liquid phases. The water density drops a thousand-fold within a few Angstroms through the gas-liquid interfacial region and therefore hydrophobic VOCs such as ISO will likely remain in these relatively 'dry' interfacial water layers rather than proceed into bulk water. In previous experiments from our laboratory, it was found that gas-phase olefins can be protonated on the surface of pH < 4 water. This phenomenon increases the residence time of gases at the interface, an event that makes them increasingly susceptible to interaction with gaseous atmospheric oxidants such as ozone and hydroxyl radicals.

In order to test this hypothesis, I carried out experiments in which ISO(g) collides with the surface of aqueous microdroplets of various compositions. Herein I report that ISO(g) is oxidized into soluble species via Fenton chemistry on the surface of aqueous Fe(II)Cl₂ solutions simultaneously exposed to H₂O₂(g). Monomer and oligomeric species (ISO)1-8H⁺ were detected via online electrospray ionization mass spectrometry (ESI-MS) on the surface of pH ~ 2 water, and were then oxidized into a suite of products whose combined yields exceed ~ 5% of (ISO)1-8H⁺. MS/MS analysis revealed that products mainly consisted of alcohols, ketones, epoxides and acids. Our experiments demonstrated that olefins in ambient air may be oxidized upon impact on the surface of Fe-containing aqueous acidic media, such as those of typical to tropospheric aerosols.

Related experiments involving the reaction of ISO(g) with ·OH radicals from the photolysis of dissolved H₂O₂ were also carried out to test the surface oxidation of ISO(g) by photolyzing H₂O₂(aq) at 266 nm at various pH. The products were analyzed via online electrospray ionization mass spectrometry. Similar to our Fenton experiments, we detected (ISO)1-7H⁺ at pH < 4, and new m/z⁺ = 271 and m/z^- = 76 products at pH > 5.

Changes in social inequalities in disability-free life expectancy in Southern Europe: the case of the Basque Country

Background: Health expectancy is a useful tool to monitor health inequalities. The evidence about the recent changes in social inequalities in healthy expectancy is relatively scarce and inconclusive, and most studies have focused on Anglo-Saxon and central or northern European countries. The objective of this study was to analyse the changes in socioeconomic inequalities in disability-free life expectancy in a Southern European population, the Basque Country, during the first decade of the 21st century. Methods: This was an ecological cross-sectional study of temporal trends on the Basque population in 1999-2003 and 2004-2008. All-cause mortality rate, life expectancy, prevalence of disability and disability free-life expectancy were calculated for each period according to the deprivation level of the area of residence. The slope index of inequality and the relative index of inequality were calculated to summarize and compare the inequalities in the two periods. Results: Disability free-life expectancy decreased as area deprivation increased both in men and in women. The difference between the most extreme groups in 2004-2008 was 6.7 years in men and 3.7 in women. Between 1999-2003 and 2004-2008, socioeconomic inequalities in life expectancy decreased, and inequalities in disability-free expectancy increased in men and decreased in women. Conclusions: This study found important socioeconomic inequalities in health expectancy in the Basque Country. These inequalities increased in men and decreased in women in the first decade of the 21st century, during which the Basque Country saw considerable economic growth.

Creating dangerously: literature as an instrument of resistance in the works of Edwidge Danticat

O objetivo desta dissertação é discutir o lugar que o fazer literário ocupa no processo de resistência à poderes hegemônicos. Como fontes primárias centrais, foram escolhidos o romance histórico The Farming of Bones (1998) e a narrativa autobiográfica Brother, Im Dying (2007), ambos escritos pela autora haitiana-americana Edwidge Danticat. Em The Farming of Bones, Danticat reconstrói ficcionalmente o trágico e obscuro episódio ocorrido em 1937 quando o então ditador da República Dominicana, Rafael Trujillo, ordenou o extermínio de todos os haitianos que residiam e trabalhavam em cidades dominicanas próximas à fronteira com o Haiti. O silêncio por parte dos governos de ambos os países em torno do massacre ainda perdura. A publicação do romance histórico de Danticat 61 anos após tal ato de terrorismo de Estado se torna, desta forma, exemplo de como o fazer literário e o fazer histórico podem fundir-se. Em Brother, Im Dying, Danticat narra a história da vida e da morte de suas duas figuras paternas, seu pai Andre (Mira) Dantica e seu tio Joseph Dantica (que a criou dos 4 aos 12 anos, no Haiti). Joseph, sobrevivente de um câncer de laringe, foi pastor batista e fundador de uma igreja e uma escola no Haiti. Morreu dois dias depois de pedir asilo político nos EUA e ser detido na prisão Krome, em Miami. Mira, que migrara no início da ditadura de François Duvalier para os EUA, onde trabalhou como taxista, morreu vítima de fibrose pulmonar poucos meses depois de seu irmão mais velho. Edwidge Danticat recebeu a notícia de que o quadro de seu pai era irreversível no mesmo dia em que descobriu que está grávida de sua primeira filha. Com uma escrita que abrange tanto a narrativa de si quanto a narrativa do outro, além das esferas públicas e privadas, Danticat cria em Brother, Im Dying um locus de fazer auto/biográfico que dialoga com questões de diáspora, identidade cultural e memória. Os ensaios publicados em Create Dangerously (2010) e as várias entrevistas concedidas por Danticat também reforçam meu argumento que Edwidge Danticat exerce seu papel de artista engajada através de seu fazer principalmente, mas não exclusivamente literário. Desta forma, a autora constrói uma possibilidade de resistência ao discurso hegemônico que opera tanto em seu país de origem quanto em seu país de residência.

AMO: Ateliê Móvel Oficial

Este texto é uma fabulação que cumpre papel de revelar um processo de trabalho em arte ao longo de dois anos. Trata-se de um percurso teórico-poético percorrido a partir da descoberta/invenção de um ateliê de criação em meio a minha residência. Um quadrado de 2x2 metros demarcado por sobreposição = fita amarela. Instaurado em divergentes contextos paisagísticos = casa, quarto de hotel, estúdio de dança, galeria de arte, palco, cidade. Trata de habitar os mesmos friccionando esfera de vivência pessoal e sítio específico de acontecimento. No texto, tem lugar reflexões pessoais a partir do trabalho, articulada a outros artistas (como Lygia Clark, Angel e Klauss Vianna, Antonin Artaud, Yves Klein, Min Tanaka, Tadashi Endo) e teóricos (dentre eles Hannah Arendt e Michel Foucault), compondo diferentes tons de fala produzidos ao longo desse período de trabalho

Movement patterns of winter flounder (Pseudopleuronectes americanus) in the southern Gulf of Maine: observations with the use of passive acoustic telemetry

Despite its recreational and commercial importance, the movement patterns and spawning habitats of winter flounder (Pseudopleuronectes americanus) in the Gulf of Maine are poorly understood. To address these uncertainties, 72 adult winter flounder (27–48 cm) were fitted with acoustic transmitters and tracked by passive telemetry in the southern Gulf of Maine between 2007 and 2009. Two sympatric contingents of adult winter flounder were observed, which exhibited divergent spawning migrations. One contingent remained in coastal waters during the spawning season, while a smaller contingent of winter flounder was observed migrating to estuarine habitats. Estuarine residence times were highly variable, and ranged from 2 to 91 days (mean=28 days). Flounder were nearly absent from the estuary during the fall and winter months and were most abundant in the estuary from late spring to early summer. The observed seasonal movements appeared to be strongly related to water temperature. This is the first study to investigate the seasonal distribution, migration, and spawning behavior of adult winter flounder in the Gulf of Maine by using passive acoustic telemetry. This approach offered valuable insight into the life history of this species in nearshore and estuarine habitats and improved the information available for the conservation and management of this species.

Early marine growth in relation to marine-stage survival rates for Alaska sockeye salmon (Oncorhynchus nerka)

We tested the hypothesis that larger juvenile sockeye salmon (Oncorhynchus nerka) in Bristol Bay, Alaska, have higher marine-stage survival rates than smaller juvenile salmon. We used scales from returning adults (33 years of data) and trawl samples of juveniles (n= 3572) collected along the eastern Bering Sea shelf during August through September 2000−02. The size of juvenile sockeye salmon mirrored indices of their marine-stage survival rate (e.g., smaller fish had lower indices of marine-stage survival rate). However, there was no relationship between the size of sockeye salmon after their first year at sea, as estimated from archived scales, and brood-year survival size was relatively uniform over the time series, possibly indicating size-selective mortality on smaller individuals during their marine residence. Variation in size, relative abundance, and marine-stage survival rate of juvenile sockeye salmon is likely related to ocean conditions affecting their early marine migratory pathways along the eastern Bering Sea shelf.

Socioeconomic status, parental support, motivation and self-confidence in youth competitive sport

World Conference on Psychology and Sociology 2012

Migratory and within-estuary behaviors of adult Summer Flounder (Paralichthys dentatus) in a lagoon system of the southern mid-Atlantic Bight

We monitored the movements of 45 adult Summer Flounder (Paralichthys dentatus) between June 2007 and July 2008 through the use of passive acoustic telemetry to elucidate migratory and within-estuary behaviors in a lagoon system of the southern mid-Atlantic Bight. Between 8 June and 10 October 2007, fish resided primarily in the deeper (>3 m) regions of the system and exhibited low levels of large-scale (100s of meters) activity. Mean residence time within this estuarine lagoon system was conservatively estimated to be 130 days (range: 18–223 days), which is 1.5 times longer than the residence time previously reported for Summer Flounder in a similar estuarine habitat ~250 km to the north. The majority of fish remained within the lagoon system until mid-October, although some fish dispersed earlier and some of them appeared to disperse temporarily (i.e., exited the system for at least 14 consecutive days before returning). Larger fish were more likely to disperse before mid-October than smaller fish and may have moved to other estuaries or the inner continental shelf. Fish that dispersed after mid-October were more likely to return to the lagoon system the following spring than were fish that dispersed before mid-October. In 2008, fish returned to the system between 7 February and 7 April. Dispersals and returns most closely followed seasonal changes in mean water temperature, but photoperiod and other factors also may have played a role in large-scale movements of Summer Flounder.

Temporal and spatial aspects of bottlenose dolphin occurrence in coastal and estuarine waters near Charleston, South Carolina

The spatial and temporal occurrence of Atlantic bottlenose dolphins (Tursiops truncatus) in the coastal and estuarine waters near Charleston, SC were evaluated. Sighting and photographic data from photo-identification (ID), remote biopsy, capture-release and radio-tracking studies, conducted from 1994 through 2003, were analyzed in order to further delineate residence patterns of Charleston area bottlenose dolphins. Data from 250 photo-ID, 106 remote biopsy, 15 capture-release and 83 radio-tracking surveys were collected in the Stono River Estuary (n = 247), Charleston Harbor (n = 86), North Edisto River (n = 54), Intracoastal Waterway (n = 26) and the coastal waters north and south of Charleston Harbor (n = 41). Coverage for all survey types was spatially and temporally variable, and in the case of biopsy, capture-release and radio-tracking surveys, data analyzed in this report were collected incidental to other research. Eight-hundred and thirty-nine individuals were photographically identified during the study period. One-hundred and fifteen (13.7%) of the 839 photographically identified individuals were sighted between 11-40 times, evidence of consistent occurrence in the Charleston area (i.e., site fidelity). Adjusted sighting proportions (ASP), which reflect an individual’s sighting frequency in a subarea relative to other subareas after adjusting for survey effort, were analyzed in order to evaluate dolphin spatial occurrence. Forty-three percent (n = 139) of dolphins that qualified for ASP analyses exhibited a strong subarea affiliation while the remaining 57% (n = 187) showed no strong subarea preference. Group size data were derived from field estimates of 2,342 dolphin groups encountered in the five Charleston subareas. Group size appeared positively correlated with degree of “openness” of the body of water where dolphins were encountered; and for sightings along the coast, group size was larger during summer months. This study provides valuable information on the complex nature of bottlenose dolphin spatial and temporal occurrence near Charleston, SC. In addition, it helps us to better understand the stock structure of dolphins along the Atlantic seaboard.

The distribution of larval fishes of the Charleston Gyre Region off the southeastern United States in winter shaped by mesoscale, cyclonic eddies

Serial, cyclonic, mesoscale eddies arise just north of the Charleston Bump, a topographical rise on the continental slope and Blake Plateau, and characterize the U.S. outer shelf and upper slope in the region of the Charleston Gyre. This region was transected during the winters of 2000, 2001, and 2002, and hydrographic data and larval fishes were collected. The hydrodynamics of the cyclonic eddies of the Charleston Gyre shape the distribution of larval fishes by mixing larvae from the outer continental shelf and the Gulf Stream and entraining them into the eddy circulation at the peripheral margins, the wrap-around filaments. Over all years and transects (those that intercepted eddies and those that did not), chlorophyll a concentrations, zooplankton displacement volumes, and larval fish concentrations were positively correlated. Chlorophyll a concentrations were highest in filaments that wrapped around eddies, and zooplankton displacement volumes were highest in the continental shelf–Gulf Stream–frontal mix. Overall, the concentration of all larval fishes declined from inshore to offshore with highest concentrations occurring over the outer shelf. Collections produced larvae from 91 fish families representing continental shelf and oceanic species. The larvae of shelf-spawned fishes—Atlantic Menhaden Brevoortia tyrannus, Round Herring Etrumeus teres, Spot Leiostomus xanthurus, and Atlantic Croaker Micropogonias undulatus—were most concentrated over the outer shelf and in the continental shelf–Gulf Stream–frontal mix. The larvae of ocean-spawned fishes—lanternfishes, bristlemouths, and lightfishes—were more evenly dispersed in low concentrations across the outer shelf and upper slope, the highest typically in the Gulf Stream and Sargasso Sea, except for lightfishes that were highest in the continental shelf–Gulf Stream–frontal mix. Detrended correspondence analysis rendered groups of larval fishes that corresponded with a gradient between the continental shelf and Gulf Stream and Sargasso Sea. Eddies propagate northeastward with a residence time on the outer shelf and upper slope of ∼1 month, the same duration as the larval period of most fishes. The pelagic habitat afforded by eddies and fronts of the Charleston Gyre region can be exploited as nursery areas for feeding and growth of larval fishes within the southeastern Atlantic continental shelf ecosystem of the U.S. Eddies, and the nursery habitat they provide, translocate larvae northeastward.