973 resultados para C-60-GAMMA-CYCLODEXTRIN


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Wurtzite GaN films have been grown on (001) Si substrates using gamma-Al2O3 as an intermediate layer by low pressure (similar to 76 Torr) metalorganic chemical vapor deposition. Reflection high energy electron diffraction and double crystal x-ray diffraction measurements revealed that the thin gamma-Al2O3 layer of "compliant" character was an effective intermediate layer for the GaN film grown epitaxially on Si. The narrowest linewidth of the x-ray rocking curve for (0002) diffraction of the 1.3 mu m GaN sample was 54 arcmin. The orientation relationship of GaN/gamma-Al2O3/Si was (0001) GaN parallel to(001) gamma-Al2O3 parallel to(001) Si, [11-20] GaN parallel to[110] gamma-Al2O3 parallel to[110] Si. The photoluminescence measurement for GaN at room temperature exhibited a near band-edge peak of 365 nm (3.4 eV). (C) 1998 American Institute of Physics.

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MoNi/gamma-Al2O3 catalysts were prepared by the impregnation method. The catalyst samples were characterized by XRD and TPR. The effects of Mo promoter content and the catalyst reducing temperature Oil hydrotreatment activity of the catalyst were studied under 200 degrees C and 3 MPa hydrogen pressure using acetic acid as the model compound. The XRD results indicate that the addition of Mo promoter is beneficial to the uniformity of nickel species on the catalyst and decreases the Interaction between nickel species and the support Which results in the decrease the of NiAl2O4 spinel formation. The addition of Mo promoter also decreases the reducing temperature of the catalyst. After the catalyst of 0.06 MoNi/gamma-Al2O3 being reduced Under the atmosphere of H-2/N-2(5/95, V/V), nickel oxide was reduced to Ni-0. The reaction was promoted obviously upon the addition of the MoNi/gamma-Al2O3 catalyst reduced at 600 degrees C. The Mo-modified Ni/gamma-Al2O3 catalyst reduced at 600 degrees C displayed the highest activity during the reaction, the conversion of acetic acid reached the highest point of 33.2%. The products included ethyl acetate and water.

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目的构建HIV-1C亚型gp120负载人树突状细胞(dentriti ccell,DC)疫苗,并对其体外功能进行初步检测。方法利用Amaxa细胞核转染技术将pcDNA3.1-gp120质粒转染至人成熟DC,以Western blot检测gp120的表达。通过流式细胞仪检测DC表面共刺激分子的变化、混合淋巴细胞反应、CD8+T细胞表面活化分子CD25的表达及其分泌IFN-γ的变化。结果通过Western blot检测,gp120在DC中得到了正确表达。经流式细胞仪检测,DC表面分子CD80表达率由刺激前的33.34%上升至43.20%,CD86表达率由刺激前的60.08%上升至90.34%;负载gp120DC刺激淋巴细胞增殖率为86.72%;CD8+T细胞表面分子CD25表达率由刺激前的5.27%上升至74.21%,IFN-γ的表达率达37%。结论负载了HIV-1gp120的人树突状细胞能够显著刺激淋巴细胞的增殖、增强CD8+T细胞表面活化分子CD25表达以及促进CD8+T细胞分泌IFN-γ,为下一步DC治疗性疫苗的体内研究奠定基础。

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We have studied the sequential resonant tunneling of doped weakly coupled GaAs/AlAs superlattices under hydrostatic pressure up to 4.5 kbar. The pressure coefficient obtained from the experiment, 15.3 meV/kbar, provides a strong evidence for the formation of the electric field domain due to Gamma-X sequential resonant tunneling, At the same time, we have observed the transition between two kinds of sequential resonant tunneling processes within the pressure range from 0 to 4.5 kbar, where the transition pressure between Gamma-Gamma and Gamma-X sequential resonant tunneling is P-t similar to 1.6 kbar. For P < P-t, the electric field domain is formed by Gamma-Gamma sequential resonant tunneling, while for P > P-t, the electric field domain is preferably formed by Gamma-X sequential resonant tunneling. (C) 1996 American Institute of Physics.

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The gamma-Al2O3 films were grown on Si (100) substrates using the sources of TMA (Al (CH3)(3)) and O-2 by very low-pressure chemical vapor deposition (VLP-CVD). It has been found that the gamma-Al2O3 film has a mirror-like surface and the RMS was about 2.5nm. And the orientation relationship was gamma-Al2O3(100)/Si(100). The thickness uniformity of gamma-Al2O3 films for 2-inch epi-wafer was less than 5%. The X-ray diffraction (XRD) and reflection high-energy electron diffraction (RHEED) results show that the crystalline quality of the film was improved after the film was annealed at 1000degreesC in O-2 atmosphere. The high-frequency C-V and leakage current of Al/gamma-Al2O3/Si capacitor were also measured to verify the annealing effect of the film. The results show that the dielectric constant increased from 4 to 7 and the breakdown voltage for 65-nm-thick gamma-Al2O3 film on silicon increases from 17V to 53V.

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工业革命以来,由于人口的快速增加和人类活动的强烈干扰(主要包括煤炭、石油等石化燃料的燃烧、化肥生产和使用)导致土地利用/覆被变化、大气CO2浓度升高、N沉降等一系列全球环境变化问题。有关陆地生态系统生物地球化学循环,尤其是陆地生态系统C、N循环及其耦合过程方面的研究成为全球变化科学研究领域的重要内容。 干旱/半干旱地区占地球陆地总面积的1/3。与湿润地区相比较,干旱/半干旱地区生态系统稳定性比较差,往往属于生态脆弱区。因此,全球变化对干旱/半干旱地区生态系统影响更加敏感。科尔沁沙地位于我国北方干旱/半干旱地区,是我国典型的农牧交错区和生态脆弱区。科尔沁沙地是世界上人口密度最高的干旱/半干旱地区之一,人类活动对其影响剧烈。然而,有关科尔沁沙地生态系统C、N元素生物地球化学循环过程对土地利用/覆被变化、N沉降等全球变化响应及其反馈机制的研究非常缺乏。因此,本文以科尔沁沙地退化沙质草地、农田、不同年龄樟子松和杨树人工林等生态系统为对象,开展了造林、模拟N沉降和凋落物管理对生态系统C、N元素循环过程影响的研究。 在科尔沁沙地东南缘,以退化沙质草地、樟子松(Pinus sylvestris var. mongolica)人工林(15、24和30年生)、杨树(Poplus xiaozhuanica)人工林(7、11和15年生)为对象,研究草地转变为林地对生态系统C、N储量影响;以退化草地、榆树疏林草地和32年生樟子松人工林为对象,比较草地造林对土壤C、N循环过程及其土壤微生物性状的影响;以农田和5、10、15年生杨树人工林为对象,研究退耕还林对生态系统C、N储量和循环过程影响;以35年生樟子松人工林为对象,模拟研究N沉降和凋落物管理对生态系统C、N循环过程影响。通过上述研究,得到以下主要结果: (1)草地生态系统总C储量为34.38 Mg ha-1,15、24和30年生樟子松人工林生态系统总C储量分别为43.56、60.45和66.59 Mg ha-1,7、11和15年生杨树人工林生态系统总C储量分别为34.54、48.26和78.77 Mg ha-1;与农田相比,退耕5年的杨树人工林生态系统总C库储量下降13%,而10年和15年杨树人工林分别增加了176%和5倍;随着人工林年龄的增加,地上植被生物量C库储量占生态系统总C库储量的比例逐渐增加,并主要分配在树干。草地生态系统总N库储量为2.54 Mg ha-1,15、24和30年生樟子松人工林生态系统总N库储量分别为1.96、2.10和2.19 Mg ha-1,7、11和15年生杨树人工林生态系统总N库储量分别为2.27、1.84和2.60 Mg ha-1;与农田相比,退耕5年的杨树人工林生态系统总N库储量下降32%,而10年和15年杨树人工林分别增加了47%和76%;农田和草地造林后生态系统N储量依然主要分配在土壤中。 (2)草地和农田造林后土壤C、N库储量的变化受多因子的影响,例如林龄、树种种类以及立地条件等。农田和草地造林初期,土壤C、N库储量表现出下降趋势,随着林龄的增加,土壤C、N储量逐渐恢复。草地营造樟子松人工林30年后,0–60 cm深度土壤C、N储量依然显著低于草地;与草地相比,15年生杨树人工林土壤C、N储量差异不显著。在立地条件较好的情况下,10年杨树人工林土壤C、N储量已显著高于农田;然而,在立地条件相对较差的情况下,15年杨树人工林土壤C、N储量仍然与农田相比差异不显著。 (3)土地利用变化能够强烈地改变土壤C、N循环过程。与草地或疏林草地相比,32年生樟子松人工林土壤C、N、P含量显著降低;土壤C、N矿化过程发生显著变化,并且受季节变化的影响;在不同季节,土壤微生物量碳含量、代谢熵(qCO2)、微生物熵(MBC/TOC)以及土壤酶活性等在不同土地利用条件下表现出规律不一致。同样,农田退耕杨树人工林能够显著影响土壤C、N矿化过程,土壤无机氮(铵态氮+硝态氮)含量,土壤微生物量碳含量以及土壤微生物活性。草地造林在一定程度上导致土壤质量下降。而农田造林有利于土壤质量改善,尤其在在立地条件较好情况下。 (4)N添加增加对沙地樟子松人工林地上和地下C、N元素含量影响不大;N添加1年后,仅林下植被C、N含量显著增加,高氮处理(N15)凋落物N含量显著增加。N添加抑制了沙地樟子松人工林凋落物的早期分解和N、P元素释放。5、6、8和9月份土壤无机N含量均随着N输入增加表现出一定程度的增加,然而,7月份N添加导致土壤无机N含量降低。N添加对土壤潜在N矿化速率影响不显著。7和8月份N添加影响土壤C矿化速率,而其它月份影响不显著。低氮处理(N5)有利于增加土壤微生物量碳含量,而高氮处理(N15)在一定程度上降低土壤微生物量碳含量。 (5)凋落物输入变化(凋落物添加和凋落物移出)在一定程度上改变了35年生沙地樟子松人工林生态系统C、N循环过程。凋落物移出(C0)增加了林下植被C含量,降低了树木叶片N含量。凋落物移出抑制了凋落物分解和P元素的释放,而增加了C元素的早期释放速率,对N元素释放过程影响不显著。凋落物输入变化对不同月份土壤无机N含量和土壤N矿化过程影响均不显著。仅在6月份凋落物移出显著抑制了土壤C矿化速率,其它月份差异均不显著。凋落物管理对土壤微生物量碳含量影响不显著。 以上研究结果表明,土地利用变化、N沉降和凋落物输入改变等能够影响半干旱地区沙地生态系统C、N储量和循环过程。尤其是土地利用变化强烈改变沙地生态系统C、N储量、分配格局和循环过程,并且受到多因子的影响。科尔沁沙地樟子松人工林生态系统C、N元素生物地球化学循环存在密切的耦合关系。今后有必要进一步结合3S技术、同位素技术、模型模拟以及分子生物学技术等,从微观-宏观不同尺度上,研究半干旱地区沙地生态系统C、N循环过程对全球变化的响应及其反馈机制。

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189W activities were produced via the 192Os(n, α) reaction using irradiation of isotopically enriched 192Os metallic powder of ~100 mg/cm2 with 14 MeV neutrons. The X-γ and γ-γ coincidence measurements were made so as to obtain γ rays from 189W decay and its coincidence relations. A new simple decay scheme of 189W including three γ rays of 210.2, 229.6 and 260.2 keV is proposed. Two new levels of 189Re at 470.4 and 489.8 keV are assigned.

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C60 在与重离子作用下的激发机制与入射离子能量、质量及电荷态有关。核阻止主要出现在低能重离子与C60 的碰撞中 ;而高能轻离子作用下 ,电子阻止迅速增强 ,成为主要的激发方式。本文中直接观察到由弹性碰撞引起的C+ 峰 ,及其丰度依赖于入射离子的质量。同时我们还发现电子阻止随入射离子能量 (7~ 2 0keV)增大相应增加 ,这与绝热量子分子动力学计算的结果一致。

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The newly developed multi-quasiparticle triaxial projected shell model approach is employed to study the high-spin band structures in neutron-deficient even-even Ce- and Nd-isotopes. It is observed that gamma-bands are built on each intrinsic configuration of the triaxial mean-field deformation. Due to the fact that a triaxial configuration is a superposition of several K-states, the projection from these states results in several low-lying bands originating from the same intrinsic configuration. This generalizes the well-known concept of the surface gamma-oscillation in deformed nuclei based on the ground-state to gamma-bands built on multi-quasiparticle configurations. This new feature provides an alternative explanation on the observation of two I = 10 aligning states in Ce-134 and both exhibiting a neutron character. (C) 2009 Elsevier B.V. All rights reserved.

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Within a chiral constituent quark model approach, η-meson production on the proton via electromagnetic and hadron probes is studied. With few parameters, the differential cross section and polarized beam asymmetry for γp → ηp and differential cross section for π − p → ηn processes are calculated and successfully compared with the data in the center-of-mass energy range from threshold up to 2 GeV. The five known resonances S11(1535), S11(1650), P13(1720),D13(1520), and F15(1680) are found to be dominant in the reaction mechanisms in both channels. Possible roles played by new resonances are also investigated; and in the photoproduction channel, significant contribution from S11 and D15 resonances, with masses around 1715 and 2090 MeV, respectively, are deduced. For the so-called missing resonances, no evidence is found within the investigated reactions. The helicity amplitudes and decay widths of N ∗ → πN, ηN are also presented and found to be consistent with the Particle Data Group values.

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Objective The purpose of this study is to investigate the effect of subdinical-dose C-12(6+)-beam irradiation on cell cycle and cell apoptosis in hepatocarcinoma cells. Materials and methods The HepG(2) cells were exposed to 0-2.0 Gy of either the C-12(6+) beam or a gamma-ray. Cell survival was detected by clonogenic assay. Cell cycle was determined by flow-cytometry analysis. The apoptosis was monitored by fluorescence microscope with DAPI staining. p53 and p21 expression were detected by Western blot. Results The G(0)/G(1) cells in the irradiated groups were significantly more than those in the control (P<0.05). The C-12(6+)-ion irradiation had a greater effect on the cell cycle of HepG(2) cells (including promoting G(1)-phase and G(2)-phase arrest) than gamma-ray irradiation. The apoptotic cells induced by C-12(6+) beam were significantly more numerous than those induced by gamma-ray (P<0.05). The carbon ions had a stronger effect on p53 and p21 expression than the gamma-ray irradiation. The survival fractions for cells irradiated by C-12(6+) beam were significantly smaller than those irradiated by gamma-ray (P<0.05).

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Recent experimental advances have made it possible to study excited structure in superheavy nuclei. The observed states have often been interpreted as quasiparticle excitations. We show that in superheavy nuclei collective vibrations systematically appear as low-energy excitation modes. By using the microscopic Triaxial Projected Shell Model, we make a detailed prediction on gamma-vibrational states and their E2 transition probabilities to the ground state band in fermium and nobelium isotopes where active structure research is going on, and in (270)Ds, the heaviest isotope where decay data have been obtained for the ground-state and for an isomeric state.

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We have investigated the performance of a EXOGAM-Segmented-Clover with 16 segments as a Compton polarimeter to measure the linear polarization of gamma rays. The polarization sensitivity of the Clover detector has been measured at the energy of 1332keV through the coincidence measurements of cascade gamma-rays from Co-60. Experimental values were in good accord with our expectation.We have investigated the performance of a EXOGAM-Segmented-Clover with 16 segments as a Compton polarimeter to measure the linear polarization of gamma rays. The polarization sensitivity of the Clover detector has been measured at the energy of 1332keV through the coincidence measurements of cascade gamma-rays from Co-60. Experimental values were in good accord with our expectation.

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Hepatoma and melanoma cells were exposed to C-12(6+) beams generated by HIRFL facility and gamma-rays and the cell response was studied by colony assays as well as the analysis of RBE of carbon ions was evolved. The survival curves of cells irradiated by heavy ions were different from those of cells irradiated by gamma-rays. And two kinds of cell showed the obvious discrepancy in response to the photon and ion irradiation. The results showed that heavy ions have special physical properties and mighty potency to kill cell in both single and fractional irradiation meanwhile it can kill tumor cells with high radioresistance more efficiently. When involved in clinical therapy, heavy ions will enhance the therapy efficiency and decrease the suffering of patients because it can impair the repair for sublethal damage of cells which can lead to fewer irradiation fractions.

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The neutron-rich target-like isotope Th-236 has been produced in the U-238-2p multinucleon transfer reaction between a 60 MeV/u O-18 beam and natural U-238 targets. The activities of thorium were determined after radiochemical separation of Th from the mixture of uranium and reaction products. The Th-236 isotope was identified by the characteristic gamma-rays of 642.2, 687.6 and 229.6 keV. The production cross section of Th-236 was determined to be 250 +/- 50 mu b.