Energy-Entropy-Momentum integration of discrete thermo-visco-elastic dynamics.

A novel time integration scheme is presented for the numerical solution of the dynamics of discrete systems consisting of point masses and thermo-visco-elastic springs. Even considering fully coupled constitutive laws for the elements, the obtained solutions strictly preserve the two laws of thermo dynamics and the symmetries of the continuum evolution equations. Moreover, the unconditional control over the energy and the entropy growth have the effect of stabilizing the numerical solution, allowing the use of larger time steps than those suitable for comparable implicit algorithms. Proofs for these claims are provided in the article as well as numerical examples that illustrate the performance of the method.

PV self-consumption optimization with storage and Active DSM for the residential sector

With the rising prices of the retail electricity and the decreasing cost of the PV technology, grid parity with commercial electricity will soon become a reality in Europe. This fact, together with less attractive PV feed-in-tariffs in the near future and incentives to promote self-consumption suggest, that new operation modes for the PV Distributed Generation should be explored; differently from the traditional approach which is only based on maximizing the exported electricity to the grid. The smart metering is experiencing a growth in Europe and the United States but the possibilities of its use are still uncertain, in our system we propose their use to manage the storage and to allow the user to know their electrical power and energy balances. The ADSM has many benefits studied previously but also it has important challenges, in this paper we can observe and ADSM implementation example where we propose a solution to these challenges. In this paper we study the effects of the Active Demand-Side Management (ADSM) and storage systems in the amount of consumed local electrical energy. It has been developed on a prototype of a self-sufficient solar house called “MagicBox” equipped with grid connection, PV generation, lead–acid batteries, controllable appliances and smart metering. We carried out simulations for long-time experiments (yearly studies) and real measures for short and mid-time experiments (daily and weekly studies). Results show the relationship between the electricity flows and the storage capacity, which is not linear and becomes an important design criterion.

Advanced Control for Very Fast DC-DC Converters Based on Hysteresis of the C-out Current

The bandwidth achievable by using voltage mode control or current mode control in switch-mode power supply is limited by the switching frequency. Fast transient response requires high switching frequency, although lower switching frequencies could be more suitable for higher efficiency. This paper proposes the use of hysteretic control of the output capacitor $(C_{out})$ current to improve the dynamic response of the buck converter. An external voltage loop is required to accurately regulate the output voltage. The design of the hysteretic loop and the voltage loop are presented. Besides, it is presented a non-invasive current sensor that allows measuring the current in the capacitor. This strategy has been applied for DVS (dynamic voltage scaling) on a 5 MHz buck converter. Experimental results validate the proposed control technique and show fast transient response from 1.5 V to 2.5 V in 2 $mu{rm s}$.

Improvement of the Dynamic Performance of a Multiphase Current Controlled Buck Converter using an Auxiliary Synchronous Buck Converter as an Additional Energy Path

This work is related to the output impedance improvement of a Multiphase Buck converter with Peak Current Mode Control (PCMC) by means of introducing an additional power path that virtually increases the output capacitance during transients. Various solutions that can be employed to improve the dynamic behavior of the converter system exist, but nearly all solutions are developed for a Single Phase Buck converter with Voltage Mode Control (VMC), while in the VRM applications, due to the high currents, the system is usually implemented as a Multiphase Buck Converter with Current Mode Control. The additional energy path, as presented here, is introduced with the Output Impedance Correction Circuit (OICC) based on the Controlled Current Source (CCS). The OICC is used to inject or extract a current n-1 times larger than the output capacitor current, thus virtually increasing n times the value of the output capacitance during the transients. Furthermore, this work extends the OICC concept to a Multiphase Buck Converter system while comparing proposed solution with the system that has n times bigger output capacitor. In addition, the OICC is implemented as a Synchronous Buck Converter with PCMC, thus reducing its influence on the system efficiency.

The cup anemometer, a fundamental meteorological instrument for the wind energy industry

The cup anemometer has been used widely by the wind energy industry since its early beginning, covering two fundamental aspects: wind mill performance control and wind energy production forecast. Furthermore, despite modern technological advances such as LIDAR and SODAR, the cup anemometer remains clearly the most used instrument by the wind energy industry. Together with the major advantages of this instrument (precision, robustness), some issues must be taken into account by scientists and researchers when using it. Overspeeding, interaction with stream wakes due to allocation on masts and wind- mills, loss of performance due to wear and tear, change of performance due to different climatic conditions, checking of the maintenance status and recalibration, etc. In the present work a review of the research campaigns carried out at the IDR/UPM Institute to analyze cup anemometer performance is included. Several aspects of this instrument are examined: the calibration process, the loss of performances due to aging and wear and tear, the effect of changes of air density, the rotor aerodynamics, and the harmonic terms contained in the anemometer output signal and their possible relation to the anemometer performances.

Temperaturas de confort e implicaciones energéticas en viviendas climatizadas mecánicamente. Estudio en clima cálido y húmedo

Este trabajo presenta un estudio de campo sobre confort térmico basado en la concepción adaptativa, para la determinación de las temperaturas y rangos de confort térmico de sujetos habituados a espacios enfriados mecánicamente en viviendas con aire acondicionado (AA) en el clima cálido y húmedo de la ciudad de Maracaibo (Venezuela) y las consecuentes implicaciones energéticas que tiene la satisfacción de esa demanda de confortabilidad en el sector residencial de la ciudad. Para la estimación de la temperatura de confort (Tc) y el rango de temperaturas de confort se aplican diferentes metodologías de análisis estadístico, las cuales son comparadas con las respectivas calculadas con el índice PMV; se analizan también otros aspectos asociados a la confortabilidad térmica, tales como las respuestas en las diferentes escalas de valoración de la confortabilidad, las preferencias, experiencias y expectativas térmicas de los sujetos. Las implicaciones energéticas se determinan en base al consumo de la energía eléctrica residencial debido exclusivamente a la variación de la Tc, entre la obtenida inicialmente en espacios naturalmente ventilados (NV) en Maracaibo (Bravo y Gonzalez 2001a) y la determinada ahora en espacios con AA. Para ello, se utiliza una metodología que es el resultado de la modificación parcial de la propuesta por Yamtraipat et al (2006). Entre los resultados y conclusiones derivadas de este estudio se encuentra que el 57 % de las personas prefieren las mismas condiciones confortables experimentadas en los ambientes con AA y solamente un 30 % prefieren experimentar ambientes ligeramente fríos y ligeramente calientes. Mientras tanto, las estimaciones de la Tc, y el respectivo rango, varían de acuerdo a la metodología empleada. Con la convencional metodología adaptativa, la Tc se estima en 25 °C en un amplio rango de 6 °C, entre 22 °C y 28 °C; mientras que con la metodología denominada “método de los promedios de los intervalos de las sensaciones térmicas” (Gómez-Azpeitia et al, 2007), la misma Tc se estima en 24 °C, en un rango estrecho de 22,5 °C a 25,5 °C y en un rango ampliado de 21 °C a 27 °C (amplitud 6 °C), donde se encuentran las tres cuartas partes de las personas del estudio. Ambas Tc son muy próximas a la temperatura operativa optima de 24,5 °C (rango de 23 °C a 26 °C) establecida por las normas internacionales ISO 7730:1994 y ASHRAE 55:1992 para el verano en climas templados. Sin embargo, la Tc estimada con los valores de PMV resulta ser superior en 1 °C y 2 °C a la Tc estimada con la metodología adaptativa (25 °C) y con el metodo de los promedios de los intervalos (24 °C), respectivamente. Con la metodología aplicada y la muestra del estudio se estima que de haberse registrado una Tbsint igual o próxima a 28 C (equivalente a la Tc en espacios NV en Maracaibo) en todos los espacios medidos (con Tbsint entre 19 C y 29 C), el ahorro total de la energía anual seria de 1.648,1 GWh en un ano respecto al consumo de AA en el año 2007 (2.522,3 GWh en un ano), mientras que el ahorro de energía asumiendo Tbsint de 24 C y de 25 C, resultan en 651,9 GWh en un ano y 425,7 GWh en un ano, respectivamente. Esto significa respectivos consumos adiciones de energía eléctrica equivalentes al 60,4 % y 74,2 %. Finalmente, los hábitos o conductas adoptadas por las personas de este estudio, sumado a las predominantes manifestaciones de confortabilidad en ambientes enfriados mecánicamente, redundan en mayores adaptaciones a condiciones de frio y exigencias de temperaturas de confort más bajas, con su consecuente consumo energético para proveerlas. ABSTRACT This investigation presents a study on thermal comfort following the adaptive approach for the determination of the thermal comfort temperatures and ranges of subjects accustomed to mechanically refrigerated spaces in dwellings with air conditioning (AA) systems in the hot and humid weather of the city of Maracaibo (Venezuela) and the ensuing energy use implications it has on the satisfaction of such demand of comfortability in the residential sector of the city. For the estimation of the comfort temperature (Tc) and the range of comfort temperatures different statistical analysis methodologies were used, which are then compared to the respective values calculated with the PMV index, also discusses other aspects related with thermal comfortability were analyzed, such as the responses on the different scales of perception of thermal comfortability, preferences, experiences and expectations of the analyzed subjects. The energetic implications are determined through the residential energy consumption related exclusively with the variation of the Tc between the originally calculated for naturally ventilated (NV) spaces in Maracaibo (Bravo y Gonzalez 2001a) and the one calculated on the present study with AA. For this, a new methodology was developed by partially modifying the Yamtraipat et al (2006) proposal. Among the results and conclusions of this study are that 57 % of the studied subjects prefer the same comfortable conditions experienced on AA environments and only a 30 % prefer to experience slightly cooler or warmer environments. Also, estimations of the Tc and its respective range vary according to the used methodology. With the conventional adaptive methodology, the Tc is estimated in 25 °C with a wide range of 6 °C, between 22 °C and 28 °C, while using the “thermal sensation intervals averages method” (Gomez-Azpeitia et al, 2007) the Tc is estimated in 24 °C on a narrow range between 22.5 °C and 25.5 °C and a widened range of 21 °C to 27 °C (6 °C in amplitude), a range where . of the studied subjects are located. Both Tc are very close to the optimum operation temperature of 24.5 °C (with a range between 23 °C and 26 °C) established on the ISO 7730:1994 and ASHRAE 55:1992 international norms for the summer on warm climates. However, the estimated Tc with the PMV indexes results to be 1 °C and 2 °C above the Tc estimated with the adaptive methodology (25 °C) and the thermal sensation intervals averages method (24 °C), respectively. With the applied methodology and this study sample, its estimated that if a Tbsint equal or close to 28 °C (equivalent to the Tc in NV spaces in Maracaibo) was registered in all measured spaces (with Tbsint between 19 °C and 29 °C) the total yearly energy savings would be of 1.648,1 GWh in a year with respect to the AA consumption in the year 2007 (2.522.3 GWh in a year), while the energy savings assuming a Tbinst of 24 °C and 25 °C result in 651.9 GWh and 425.7 Gwh in a year, respectively. This means that the respective additional electrical energy consumption amount to 60.4 % and 74.2 %, respectively. Finally, the habits or behaviors adopted by the subjects analyzed on this study, added to the predominant manifestations of comfortability in mechanically refrigerated environments result in greater adaptations to colder conditions and lower thermal comfort temperature demands, with the consequential increase in power consumption to meet them.

Simulación, construcción y medida de un sistema de telealimentación eficiente

Los sistemas de telealimentación han tomado gran importancia en diferentes campos, incluido el de las telecomunicaciones, algunos ejemplos pueden ser: En la red conmutada telefónica junto con la señal de información y llamada existe una alimentación de 48v que se transmite a través de toda la línea de transmisión hasta los terminales. En algunos ferrocarriles eléctricos, se aprovecha la producción de energía eléctrica cuando un tren baja una cuesta y el motor funciona como generador, devolviendo la energía excedente a la propia catenaria por medio de superposición, y siendo esta recuperada en otro lugar y aprovechada por ejemplo por otro tren que requiere energía. Otro uso en ferrocarriles de la telealimentación es la llamada "tecnología del transpondedor magnético", en la que el tren transmite a las balizas una señal en 27MHz además de otras de información propias, que se convierte en energía útil para estas balizas. En este proyecto pretendemos implementar un pequeño ejemplo de sistema de telealimentación trabajando en 5 MHz (RF). Este sistema transforma una señal de CC en una señal de potencia de CA que podría ser, por ejemplo, transmitida a lo largo de una línea de transmisión o radiada por medio de una antena. Después, en el extremo receptor, esta señal RF se transforma finalmente en DC. El objetivo es lograr el mejor rendimiento de conversión de energía, DC a AC y AC a DC. El sistema se divide en dos partes: El inversor, que es la cadena de conversión DC-AC y el rectificador, que es la cadena de conversión AC-DC. Cada parte va a ser calculada, simulada, implementada físicamente y medida aparte. Finalmente el sistema de telealimentación completo se va a medir mediante la interconexión de cada parte por medio de un adaptador o una línea de transmisión. Por último, se mostrarán los resultados obtenidos. ABSTRACT. Remote powering systems have become very important in different fields, including telecommunications, some examples include: In the switched telephone network with the information signal and call there is a 48v supply that is transmitted across the transmission line to the terminals. In some electric railways, the production of electrical energy is used when a train is coming down a hill and the motor acts as a generator, returning the surplus energy to the catenary itself by overlapping, and this being recovered elsewhere and used by other train. Home TV amplifiers that are located in places (storage, remote locations ..) where there is no outlet, remote power allows to carry information and power signal by the same physical medium, for instance a coax. The AC power signal is transformed into DC at the end to feed the amplifier. In medicine, photovoltaic converters and fiber optics can be used as means for feeding devices implanted in patients. Another use of the remote powering systems on railways is the "magnetic transponder technology", in which the station transmits a beacon signal at 27MHz own as well as other information, which is converted into useful energy to these beacons. In this Project we are pretending to implement a little example of remote powering system working in 5 MHz (RF). This system transform DC into an AC-RF power signal which could be, for instance, transmitted throughout a transmission line or radiated by means of an aerial. At the receiving end, this RF signal is then transformed to DC. The objective is to achieve the best power conversion performance, DC to AC and AC to DC. The system is divided in two parts: The inverter, that is the DC-AC conversion chain and the rectifier that is the AC-DC conversion chain. Each part is going to be calculated, simulated, implemented physically and measured apart. Then the complete remote-powering system is to be measured by interconnecting each part by means of a interconnector or a transmission line. Finally, obtained results will be shown.

Contribución al diseño de lazos de realimentación electrónica para microsistemas electromecánicos (MEMS) resonantes: ruido de fase generado en lazos osciladores por sus realimentaciones

En 1966, D. B. Leeson publicó el artículo titulado “A simple model of feedback oscillator noise spectrum” en el que, mediante una ecuación obtenida de forma heurística y basada en parámetros conocidos de los osciladores, proponía un modelo para estimar el espectro de potencia que cuantifica el Ruido de Fase de estos osciladores. Este Ruido de Fase pone de manifiesto las fluctuaciones aleatorias que se producen en la fase de la señal de salida de cualquier oscilador de frecuencia f_0. Desde entonces, los adelantos tecnológicos han permitido grandes progresos en cuanto a la medida del Ruido de Fase, llegando a encontrar una estrecha “zona plana”, alrededor de f_0, conocida con el nombre de Ensanchamiento de Línea (EL) que Leeson no llegó a observar y que su modelo empírico no recogía. Paralelamente han ido surgiendo teorías que han tratado de explicar el Ruido de Fase con mayor o menor éxito. En esta Tesis se propone una nueva teoría para explicar el espectro de potencia del Ruido de Fase de un oscilador realimentado y basado en resonador L-C (Inductancia-Capacidad). Al igual que otras teorías, la nuestra también relaciona el Ruido de Fase del oscilador con el ruido térmico del circuito que lo implementa pero, a diferencia de aquellas, nuestra teoría se basa en un Modelo Complejo de ruido eléctrico que considera tanto las Fluctuaciones de energía eléctrica asociadas a la susceptancia capacitiva del resonador como las Disipaciones de energía eléctrica asociadas a su inevitable conductancia G=1⁄R, que dan cuenta del contacto térmico entre el resonador y el entorno térmico que le rodea. En concreto, la nueva teoría que proponemos explica tanto la parte del espectro del Ruido de Fase centrada alrededor de la frecuencia portadora f_0 que hemos llamado EL y su posterior caída proporcional a 〖∆f〗^(-2) al alejarnos de f_0, como la zona plana o pedestal que aparece en el espectro de Ruido de Fase lejos de esa f_0. Además, al saber cuantificar el EL y su origen, podemos explicar con facilidad la aparición de zonas del espectro de Ruido de Fase con caída 〖∆f〗^(-3) cercanas a la portadora y que provienen del denominado “exceso de ruido 1⁄f” de dispositivos de Estado Sólido y del ruido “flicker” de espectro 1⁄f^β (0,8≤β≤1,2) que aparece en dispositivos de vacío como las válvulas termoiónicas. Habiendo mostrado que una parte del Ruido de Fase de osciladores L-C realimentados que hemos denominado Ruido de Fase Térmico, se debe al ruido eléctrico de origen térmico de la electrónica que forma ese oscilador, proponemos en esta Tesis una nueva fuente de Ruido de Fase que hemos llamado Ruido de Fase Técnico, que se añadirá al Térmico y que aparecerá cuando el desfase del lazo a la frecuencia de resonancia f_0 del resonador no sea 0° o múltiplo entero de 360° (Condición Barkhausen de Fase, CBF). En estos casos, la modulación aleatoria de ganancia de lazo que realiza el Control Automático de Amplitud en su lucha contra ruidos que traten de variar la amplitud de la señal oscilante del lazo, producirá a su vez una modulación aleatoria de la frecuencia de tal señal que se observará como más Ruido de Fase añadido al Térmico. Para dar una prueba empírica sobre la existencia de esta nueva fuente de Ruido de Fase, se diseñó y construyó un oscilador en torno a un resonador mecánico “grande” para tener un Ruido de Fase Térmico despreciable a efectos prácticos. En este oscilador se midió su Ruido de Fase Técnico tanto en función del valor del desfase añadido al lazo de realimentación para apartarlo de su CBF, como en función de la perturbación de amplitud inyectada para mostrar sin ambigüedad la aparición de este Ruido de Fase Técnico cuando el lazo tiene este fallo técnico: que no cumple la Condición Barkhausen de Fase a la frecuencia de resonancia f_0 del resonador, por lo que oscila a otra frecuencia. ABSTRACT In 1966, D. B. Leeson published the article titled “A simple model of feedback oscillator noise spectrum” in which, by means of an equation obtained heuristically and based on known parameters of the oscillators, a model was proposed to estimate the power spectrum that quantifies the Phase Noise of these oscillators. This Phase Noise reveals the random fluctuations that are produced in the phase of the output signal from any oscillator of frequencyf_0. Since then, technological advances have allowed significant progress regarding the measurement of Phase Noise. This way, the narrow flat region that has been found around f_(0 ), is known as Line Widening (LW). This region that Leeson could not detect at that time does not appear in his empirical model. After Leeson’s work, different theories have appeared trying to explain the Phase Noise of oscillators. This Thesis proposes a new theory that explains the Phase Noise power spectrum of a feedback oscillator around a resonator L-C (Inductance-Capacity). Like other theories, ours also relates the oscillator Phase Noise to the thermal noise of the feedback circuitry, but departing from them, our theory uses a new, Complex Model for electrical noise that considers both Fluctuations of electrical energy associated with the capacitive susceptance of the resonator and Dissipations of electrical energy associated with its unavoidable conductance G=1/R, which accounts for the thermal contact between the resonator and its surrounding environment (thermal bath). More specifically, the new theory we propose explains both the Phase Noise region of the spectrum centered at the carrier frequency f_0 that we have called LW and shows a region falling as 〖∆f〗^(-2) as we depart from f_0, and the flat zone or pedestal that appears in the Phase Noise spectrum far from f_0. Being able to quantify the LW and its origin, we can easily explain the appearance of Phase Noise spectrum zones with 〖∆f〗^(-3) slope near the carrier that come from the so called “1/f excess noise” in Solid-State devices and “flicker noise” with 1⁄f^β (0,8≤β≤1,2) spectrum that appears in vacuum devices such as thermoionic valves. Having shown that the part of the Phase Noise of L-C oscillators that we have called Thermal Phase Noise is due to the electrical noise of the electronics used in the oscillator, this Thesis can propose a new source of Phase Noise that we have called Technical Phase Noise, which will appear when the loop phase shift to the resonance frequency f_0 is not 0° or an integer multiple of 360° (Barkhausen Phase Condition, BPC). This Phase Noise that will add to the Thermal one, comes from the random modulation of the loop gain carried out by the Amplitude Automatic Control fighting against noises trying to change the amplitude of the oscillating signal in the loop. In this case, the BPC failure gives rise to a random modulation of the frequency of the output signal that will be observed as more Phase Noise added to the Thermal one. To give an empirical proof on the existence of this new source of Phase Noise, an oscillator was designed and constructed around a “big” mechanical resonator whose Thermal Phase Noise is negligible for practical effects. The Technical Phase Noise of this oscillator has been measured with regard to the phase lag added to the feedback loop to separate it from its BPC, and with regard to the amplitude disturbance injected to show without ambiguity the appearance of this Technical Phase Noise that appears when the loop has this technical failure: that it does not fulfill the Barkhausen Phase Condition at f_0, the resonance frequency of the resonator and therefore it is oscillating at a frequency other than f_0.

Comportamiento térmico y mecánico del yeso con adiciones de aerogel de sílice granulado

La presente tesis doctoral aborda el estudio de un nuevo material mineral, compuesto principalmente por una matriz de yeso (proveniente de un conglomerante industrial basado en sulfato de calcio multifase) y partículas de aerogel de sílice hidrófugo mesoporoso, compatibilizadas mediante un surfactante polimérico, debido a su alto carácter hidrófugo. La investigación se centra en conocer los factores que influyen en las propiedades mecánicas y conductividad térmica del material compuesto generado. Este estudio pretende contribuir al conocimiento sobre el desarrollo de nuevos morteros de elevado aislamiento térmico que puedan ser utilizados en la rehabilitación energética de edificios de viviendas existentes, debido a que estos representan gran parte del consumo energético del parque de viviendas de España, aunque también a nivel internacional. De los materiales utilizados para desarrollar los morteros estudiados, el yeso, además de ser un material muy abundante, especialmente en España, requiere una menor cantidad de energía para la fabricación de un conglomerante (debido a una menor temperatura de fabricación), en comparación con el cemento o la cal, por lo que presenta una menor huella de carbono que estos últimos. Por otro lado, el aerogel de sílice hidrófugo mesoporoso es, de acuerdo con la documentación disponible, el material que posee actualmente la mayor capacidad de aislamiento térmico en el mercado. El desarrollo de nuevos morteros minerales con una capacidad de aislamiento térmico mayor que los materiales aislantes utilizados tradicionalmente, tiene una aplicación relevante en los casos de rehabilitación energética de edificios históricos y patrimoniales, en los que se requiere la aplicación del aislamiento por el interior de la fachada, ya que este tipo de soluciones tienen el inconveniente de reducir el espacio habitable de las áreas involucradas, especialmente en zonas climáticas en las que el aislamiento térmico puede suponer un espesor considerable, por lo que es ideal utilizar materiales de altas prestaciones de aislamiento térmico capaces de aportar el mismo nivel de aislamiento (o incluso mayor), pero en un espesor considerablemente menor. La investigación se desarrolla en tres etapas: bibliográfica, experimental y de simulación. La primera etapa, parte del estudio de la bibliografía existente, relacionada con materiales aislantes, incluyendo soluciones basadas, tanto en morteros aislantes, como en paneles de aislamiento térmico. La segunda, de carácter experimental, se centra en estudiar la influencia de la microestrucrura y macroestructura, del nuevo material mineral, en las propiedades físicas elementales, mecánicas y conductividad térmica del compuesto. La tercera etapa, mediante una simulación del consumo energético, consiste en cuantificar teóricamente el potencial ahorro energético que puede aportar este material en un caso de rehabilitación energética en particular. La investigación experimental se centró principalmente en conocer los factores principales que influyen en las propiedades mecánicas y conductividad térmica de los materiales compuestos minerales desarrollados en esta tesis. Para ello, se llevó a cabo una caracterización de los materiales de estudio, así como el desarrollo de distintas muestras de ensayo, de tal forma que se pudo estudiar, tanto la hidratación del yeso en los compuestos, como su posterior microestructura y macroestructura, aspectos fundamentales para el entendimiento de las propiedades mecánicas y conductividad térmica del compuesto aislante. De este modo, se pudieron conocer y cuantificar, los factores que influyen en las propiedades estudiadas, aportando una base de conocimiento y entendimiento de este tipo de compuestos minerales con aerogel de sílice hidrófugo, no existiendo estudios publicados hasta el momento de finalización de esta tesis, con la aproximación al material propuesta en este estudio, ni con yeso (basado en sulfato de calcio multifase), ni con otro tipo de conglomerantes. Particularmente, se determinó la influencia que tiene la incorporación de partículas de aerogel de sílice hidrófugo, en grandes proporciones en volumen, en un compuesto mineral basado en distintas fases de sulfato de calcio. No obstante, para llevar a cabo las mezclas, fue necesario utilizar un surfactante para compatibilizar este tipo de partículas, con el conglomerante basado en agua. El uso de este tipo de aditivos tiene una influencia, no solo en el aerogel, sino en las propiedades del compuesto en general, dependiendo de su concentración, por lo que se establecieron dos porcentajes de adición: la primera, determinada a partir de la cantidad mínima necesaria para compatibilizar las mezclas (0,1% del agua de amasado), y la segunda, como límite superior, la concentración utilizada habitualmente a nivel industrial para estabilizar burbujas de aire en hormigones espumados (5%). El surfactante utilizado mostró la capacidad de modificar la superficie del aerogel, cambiando el comportamiento de las partículas frente al agua, permitiendo una invasión parcial de su estructura porosa, por parte del agua de amasado. Este comportamiento supone un aumento muy importante en la relación agua/yeso, afectando el hábito cristalino e influenciando negativamente las propiedades mecánicas de la matriz de yeso, presentando un efecto aún notable a mayor concentración de surfactante (5%). En cuanto a las propiedades finales alcanzadas, fue posible lograr un compuesto mineral ultraligero (200 kg/m3), con alrededor de un 60% de aerogel en volumen y de alta capacidad aislante (0,028 W/m•K), presentando una conductividad térmica notablemente menor que los morteros aislantes del mercado, e incluso también menor que la de los aislantes tradicionales basado en las lanas minerales o EPS; no obstante, con la limitante de presentar bajas propiedades mecánicas, condicionando su posible aplicación futura. Entre los factores principales relacionados con las propiedades mecánicas, se encontró que estas dependen exponencialmente del volumen de yeso en el compuesto; no obstante, factores de segundo orden, como el grado de hidratación, o una mejor distribución del conglomerante entre las partículas de aerogel, debido al aumento de la superficie específica del polvo mineral, pueden aumentar las propiedades mecánicas entre el doble y el triple, dependiendo del volumen de aerogel en cuestión. Además, se encontró que el aerogel, en conjunto con el surfactante, es capaz de introducir una gran cantidad de aire (0,70 m3 por cada m3 de aerogel), que unido al agua evaporada (no consumida por el conglomerante durante la hidratación), el volumen de aire total alcanza, generalmente, un 40%, independientemente de la cantidad de aerogel en la mezcla. De este modo, el aire introducido en la matriz desplaza las proporciones en volumen del aerogel y del yeso, disminuyendo, tanto las propiedades mecánicas, como la capacidad aislante de compuesto mineral. Por otro lado, la conductividad térmica mostró tener una dependencia directa de la contribución de las tres fases principales en el compuesto: yeso, aerogel y aire ocluido. De este modo, se pudo desarrollar un modelo matemático, adaptado de uno existente, capaz de calcular, con bastante precisión, la relación de los tres componentes mencionados, en la conductividad térmica de los compuestos, para el rango de volúmenes y materiales utilizados en esta tesis. Finalmente, la simulación del consumo energético realizada a una vivienda típica de España, de los años 1900 a 1959 (basada en muros de ladrillo macizo), para las zonas climáticas estudiadas (A, D y E), permitió observar el potencial ahorro energético que puede aportar este material, dependiendo de su espesor, como aislamiento interior de los muros de fachada. Particularmente, para la zona A, se determinó un espesor óptimo de 1 cm, mientras que para la zona D y E, 3,5 y 3,9 cm respectivamente. En este sentido, el nuevo material estudiado es capaz de disminuir, entre un 35% y un 80%, el espesor de la capa aislante, en comparación con paneles de lana de roca o los morteros minerales de mayor capacidad aislante del mercado español respectivamente. ABSTRACT The present doctoral thesis studies a new mineral-based composite material, composed by a gypsum matrix (based on an industrial multiphase gypsum binder) and mesoporous hydrophobic silica aerogel particles, compatibilized with a polymeric surfactant due to the high hydrophobic character of the insulating particles. This study pretends to contribute to the development of new composite insulating materials that could be used in energy renovation of existing dwellings, in order to reduce their high energy consumption, as they represent a great part of the total energy consumed in Spain, but also internationally. Between the materials used to develop de studied insulating mortars, gypsum, besides being an abundant material, especially in Spain, requires less energy for the manufacture of a mineral binder (due to lower manufacturing temperatures), compared to lime or cement, thus presenting lower carbon footprint. In other hand, the hydrophobic mesoporous silica aerogel, is, according to the existing references, the material with the highest know insulating capacity in the market. The development of new mineral mortars with higher thermal insulation capacity than traditional insulating materials, presents a relevant application in energy retrofitting of historic and cultural heritage buildings, in which implies that the insulating material should be installed as an internal layer, rather than as an external insulating system. This type of solution involves a reduced internal useful area, especially in climatic zones where the demand for thermal insulation is higher, and so the insulating layer thickness, being idealistic to use materials with very high insulating properties, in order to reach same insulating level (or higher), but in lower thickness than the provided by traditional insulating materials. This research is developed in three main stages: bibliographic, experimental and simulation. The first stage starts by studying the existing references regarding thermally insulating materials, including existing insulating mortars and insulating panels. The second stage, mainly experimental, is centered in the study of the the influence of the microstructure and macrostructure in the physical and mechanical properties, and also in the thermal conductivity of the new mineral-based material. The thirds stage, through energy simulation, consists in theoretically quantifying the energy savings potential that can provide this type of insulating material, in a particular energy retrofitting case study. The experimental research is mainly focused in the study of the factors that influence the mechanical properties and the thermal conductivity of the thermal insulating mineral composites developed in this thesis. For this, the characterization of the studied materials has been performed, as well as the development of several experimental samples, in order to study the hydration of the mineral binder within the composites, but also the final microstructure and macrostructure, fundamental aspects for the understanding of the composite’s mechanical and insulating properties. Thus, is was possible to determine and quantify the factors that influence the studied material properties, providing a knowledge base and understanding of mineral composites that comprises mesoporous hydrophobic silica aerogel particles, being the first study up to date regarding the specific approach of the present study, regarding not just multiphase calcium sulfate plaster, but also other mineral binders. Particularly, the influence of the incorporation of hydrophobic silica aerogel particles, in high volume ratios into a mineral compound, based on different phases of calcium sulfate has been determined. However, to perform mixing, it is necessary to use a surfactant in order to compatibilize these particles with the water-based mineral binder. The use of such additives has an influence, not only in the aerogel, but the overall properties of the compound, so two different surfactant concentration has been studied: the first, the minimum amount of surfactant (used in this thesis) in order to develop the slurries (0.1% concentration of the mixing water), and the second, as the upper limit, the concentration usually used industrially to stabilize air bubbles in foamed concrete (5%). One of the side effects of using such additive, was the modification of the aerogel particles, by changing their behavior in respect to water, generating a partial invasion of the aerogel’s porous structure, by the mixing water. This behavior produces a very important increase in water/binder ratios, affecting the crystal habit and negatively influencing the mechanical properties of the gypsum matrix. This effect further increased when a higher concentration of surfactant (5%) is used. Regarding final materials properties, it was possible to achieve an ultra-lightweight mineral composite (200 kg/m3), with around 60% by volume of aerogel, presenting a very high insulating capacity (0.028 W/m•K), a noticeable lower thermal conductivity compared to the insulating mortars and traditional thermal insulating panels on the market, such as mineral wool or EPS; however, the limiting factor for future’s material application in buildings, is related to the very low mechanical properties achieved. Among the main factors related to the mechanical properties, it has been found an exponential correlation to the volume of gypsum in the composite. However, second-order factors such as the degree of hydration, or a better distribution of the binder between the aerogel particles, due to the increased surface area of the mineral powder, can increase the mechanical properties between two to three times, depending aerogel volume involved. In addition, it was found that the aerogel, together with the surfactant, is able to entrain a large amount of air volume (around 0.70 m3 per m3 of aerogel), which together with the evaporated water (not consumed by the binder during hydration), can reach generally around 40% of entrained air within the gypsum matrix, regardless of the amount of aerogel in the mixture. Thus, the entrained air into the matrix displaces the volume proportions of the aerogel and gypsum, reducing both mechanical and insulating properties of the mineral composite. On the other hand, it has been observed a direct contribution of three main phases into the thermal conductivity of the composite: gypsum, aerogel and entrained air. Thus, it was possible to develop a mathematical model (adapted from an existing one), capable of calculating quite accurate the thermal conductivity of such mineral composites, from the ratio these three components and for the range of volumes and materials used in this thesis. Finally, the energy simulation performed to a typical Spanish dwelling, from the years 1900 to 1959 (mainly constructed with massive clay bricks), within three climatic zones of Spain (A, D and E), showed the energy savings potential that can provide this type of insulating material, depending on the thickness of the applied layer. Particularly, for the climatic A zone, it has been found an optimal layer thickness of 1 cm, while for zone D and E, 3.5 and 3.9 cm respectively. In this manner, the new studied materials is capable of decreasing the thickness of the insulating layer by 35% and 80%, compared with rock wool panels or mineral mortars with the highest insulating performance of the Spanish market respectively.

A novel multicomponent regulatory system mediates H2 sensing in Alcaligenes eutrophus

Oxidation of molecular hydrogen catalyzed by [NiFe] hydrogenases is a widespread mechanism of energy generation among prokaryotes. Biosynthesis of the H2-oxidizing enzymes is a complex process subject to positive control by H2 and negative control by organic energy sources. In this report we describe a novel signal transduction system regulating hydrogenase gene (hox) expression in the proteobacterium Alcaligenes eutrophus. This multicomponent system consists of the proteins HoxB, HoxC, HoxJ*, and HoxA. HoxB and HoxC share characteristic features of dimeric [NiFe] hydrogenases and form the putative H2 receptor that interacts directly or indirectly with the histidine protein kinase HoxJ*. A single amino acid substitution (HoxJ*G422S) in a conserved C-terminal glycine-rich motif of HoxJ* resulted in a loss of H2-dependent signal transduction and a concomitant block in autophosphorylating activity, suggesting that autokinase activity is essential for the response to H2. Whereas deletions in hoxB or hoxC abolished hydrogenase synthesis almost completely, the autokinase-deficient strain maintained high-level hox gene expression, indicating that the active sensor kinase exerts a negative effect on hox gene expression in the absence of H2. Substitutions of the conserved phosphoryl acceptor residue Asp55 in the response regulator HoxA (HoxAD55E and HoxAD55N) disrupted the H2 signal-transduction chain. Unlike other NtrC-like regulators, the altered HoxA proteins still allowed high-level transcriptional activation. The data presented here suggest a model in which the nonphosphorylated form of HoxA stimulates transcription in concert with a yet unknown global energy-responsive factor.

Potential effects of gas hydrate on human welfare

For almost 30 years. serious interest has been directed toward natural gas hydrate, a crystalline solid composed of water and methane, as a potential (i) energy resource, (ii) factor in global climate change, and (iii) submarine geohazard. Although each of these issues can affect human welfare, only (iii) is considered to be of immediate importance. Assessments of gas hydrate as an energy resource have often been overly optimistic, based in part on its very high methane content and on its worldwide occurrence in continental margins. Although these attributes are attractive, geologic settings, reservoir properties, and phase-equilibria considerations diminish the energy resource potential of natural gas hydrate. The possible role of gas hydrate in global climate change has been often overstated. Although methane is a “greenhouse” gas in the atmosphere, much methane from dissociated gas hydrate may never reach the atmosphere, but rather may be converted to carbon dioxide and sequestered by the hydrosphere/biosphere before reaching the atmosphere. Thus, methane from gas hydrate may have little opportunity to affect global climate change. However, submarine geohazards (such as sediment instabilities and slope failures on local and regional scales, leading to debris flows, slumps, slides, and possible tsunamis) caused by gas-hydrate dissociation are of immediate and increasing importance as humankind moves to exploit seabed resources in ever-deepening waters of coastal oceans. The vulnerability of gas hydrate to temperature and sea level changes enhances the instability of deep-water oceanic sediments, and thus human activities and installations in this setting can be affected.

Unifying theory of hypoxia tolerance: molecular/metabolic defense and rescue mechanisms for surviving oxygen lack.

We develop a unifying theory of hypoxia tolerance based on information from two cell level models (brain cortical cells and isolated hepatocytes) from the highly anoxia tolerant aquatic turtle and from other more hypoxia sensitive systems. We propose that the response of hypoxia tolerant systems to oxygen lack occurs in two phases (defense and rescue). The first lines of defense against hypoxia include a balanced suppression of ATP-demand and ATP-supply pathways; this regulation stabilizes (adenylates) at new steady-state levels even while ATP turnover rates greatly decline. The ATP demands of ion pumping are down-regulated by generalized "channel" arrest in hepatocytes and by "spike" arrest in neurons. Hypoxic ATP demands of protein synthesis are down-regulated probably by translational arrest. In hypoxia sensitive cells this translational arrest seems irreversible, but hypoxia-tolerant systems activate "rescue" mechanisms if the period of oxygen lack is extended by preferentially regulating the expression of several proteins. In these cells, a cascade of processes underpinning hypoxia rescue and defense begins with an oxygen sensor (a heme protein) and a signal-transduction pathway, which leads to significant gene-based metabolic reprogramming-the rescue process-with maintained down-regulation of energy-demand and energy-supply pathways in metabolism throughout the hypoxic period. This recent work begins to clarify how normoxic maintenance ATP turnover rates can be drastically (10-fold) down-regulated to a new hypometabolic steady state, which is prerequisite for surviving prolonged hypoxia or anoxia. The implications of these developments are extensive in biology and medicine.

Procedimento de avaliação de integridade estrutural de juntas soldadas circunferenciais em tubulações submarinas rígidas submetidas à flexão.

A demanda crescente por energia tem motivado a procura por petróleo e gás natural em ambientes com condições extremas, como operações em águas profundas e o transporte de fluídos corrosivos. Avanços tecnológicos recentes favorecem o uso de tubos de aço contendo uma camada interna resistente a corrosão (comumente chamados de Lined ou Clad Pipes) para o transporte de tais fluidos agressivos. Além disso, as tubulações submarinas são sujeitas a condições de instalação muito severas e, um caso de interesse, é o procedimento de reeling que permite com que a fabricação e inspeção da tubulação seja feita em terra. Apesar de possuir vantagens econômicas, a avaliação da integridade estrutural e especificação dos tamanhos toleráveis de trinca em juntas soldadas, nestas condições, torna-se uma tarefa complexa, devido a natureza dissimilar dos materiais e ao grande nível de deformação plástica no processo. Dessa maneira, este trabalho tem por objetivo o desenvolvimento de um procedimento de avaliação de forças motrizes elasto-plásticas em tubos contendo juntas soldadas circunferenciais sujeitos a flexão, para uma extensa gama de configurações geométricas. Dois métodos distintos foram desenvolvidos e analisados: a metodologia EPRI e o procedimento que utiliza a curva de tensão vs. deformação equivalente. As análises numéricas 3D fornecem os parâmetros de fratura necessários para a resolução do problema e a acurácia dos procedimentos é verificada a partir de estudos de casos e análises paramétricas.

Fermi-edge singularities in linear and nonlinear ultrafast spectroscopy

We discuss Fermi-edge singularity effects on the linear and nonlinear transient response of an electron gas in a doped semiconductor. We use a bosonization scheme to describe the low-energy excitations, which allows us to compute the time and temperature dependence of the response functions. Coherent control of the energy absorption at resonance is analyzed in the linear regime. It is shown that a phase shift appears in the coherent control oscillations, which is not present in the excitonic case. The nonlinear response is calculated analytically and used to predict that four wave-mixing experiments would present a Fermi-edge singularity when the exciting energy is varied. A new dephasing mechanism is predicted in doped samples that depends linearly on temperature and is produced by the low-energy bosonic excitations in the conduction band.

Between energy security and energy market integration. Guidelines for the future development of the EU’s external energy policy in Europe’s neighbourhood. OSW Report, June 2011

For many years the European Union has been improving the efficient use of energy resources and yet the demand for energy in the EU continues to increase. When Europe belonged to one of the world’s key energy markets with relatively easy access to energy resources, growing energy needs were not seen as a source of concern. Today, however, as the competition for energy resources is intensifying and the global position of the EU energy market is being challenged by growing economies in the developing countries, above all China and India, the EU needs to adopt bold policies to guarantee the sustainable supply of energy. This report argues the EU needs to develop a fully-fledged external energy policy; i.e. a common, coherent, strategic approach that build bridges between the interests and needs of the EU integrated energy market on the one hand and supplier countries on the other. The EU’s external energy policy has two main objectives. The first one is to ensure a sustainable, stable and cost-effective energy supply. The second is to promote energy market integration and regulatory convergence with neighbouring countries (often but not always this supports the achievement of the first objective). However, in order to improve its effectiveness, the EU’s external energy policy needs to be seen in a broader economic and political context. Any progress in energy cooperation with third countries is contingent upon the EU’s general stance and offer to those countries.