Influência do sistema de cimentação e do modo de ativação na resistência ao push-out de pinos de fibra de vidro

O objetivo deste estudo foi avaliar a influência do tipo de sistema de cimentação (condicionamento ácido total ou autoadesivo), do modo de ativação (autoativado ou dual), do terço do conduto radicular (cervical, médio ou apical) e da espessura do filme de cimento sobre a resistência de união de pinos de fibra de vidro cimentados em dentes humanos. Quarenta raízes foram incluídas em resina epóxi, submetidas a tratamento endodôntico e obturadas com guta percha e cimento endodôntico sem eugenol. Decorridos sete dias, os condutos foram preparados a uma profundidade de 10mm com brocas padronizadas do sistema dos pinos de fibra (WhitePost DC #2) e aleatoriamente divididos em 4 grupos, conforme o sistema de cimentação e o modo de ativação: (G1) RelyX ARC/Adper Scotchbond Multi-Purpose Plus (condicionamento ácido total), ativação dual, (G2) RelyX ARC/Adper Scotchbond Multi-Purpose Plus, autoativado, (G3) RelyX U100 (autoadesivo), dual e (G4) RelyX U100, autoativado. Após uma semana, cada raiz foi seccionada em máquina de corte, originando 6 fatias de 1 mm de espessura (n=60). Antes do ensaio de push-out cada fatia foi fotografada em ambas as faces, para determinação do raio dos pinos e da espessura do filme de cimento. Após o ensaio mecânico, novas imagens foram capturadas para determinação do modo de falha. Para automatizar a determinação da espessura de cimento, foi desenvolvida uma macro no software KS 400. Os dados foram estatisticamente analisados com ANOVA 3 fatores (resistência de união) e teste de Kruskall-Wallis (espessura do cimento). Comparações múltiplas foram realizadas com o teste Student-Newman-Keuls. Análise de regressão, modelo linear, foi empregada para verificar a correlação entre espessura do cimento e resistência de união. Todos os testes foram aplicados com α = 0,05. O fator cimento exerceu influência significativa para a resistência de união (p = 0,0402): o RelyX U100 apresentou a maior média. A ativação dual elevou os valores de resistência de união em comparação ao modo quimicamente ativado (p < 0,0001). Houve diferenças significantes entre os grupos, sendo G1 (22,4 4,0 MPa) > G3 (20,4 3,6 MPa) > G4 (17,8 5,2 MPa) > G2 (13,5 4,3 MPa). O terço do conduto não exerceu influência significativa sobre a resistência adesiva (p = 0,4749). As espessuras dos filmes de cimento foram estatisticamente diferentes nos diferentes terços: cervical (102 45 m) > médio (75 29 m) > apical (52 28m). Não foi observada forte correlação entre os valores de espessura e os de resistência ao push-out (r = - 0,2016, p = 0,0033). O tipo de falha predominante foi a mista, exceto para o G2, que apresentou 74% das falhas na interface cimento-pino. Dessa forma, o cimento autoadesivo apresentou melhor desempenho que o convencional, e ambos os sistemas duais, sobretudo o RelyX ARC, apresentaram dependência da fotoativação para atingirem maiores valores de resistência de união.

Application of diatom analysis for the study of the history of the lakes of north-west USSR. [Translation from: Istoriya Ozer; Trudy Vses.Simp.Vilnius p1-7. Vilnius, 1970.]

During late - and post-glacial times lakes played a leading role in the development of the landscape of the North-west European part of USSR. A variety of geographic circumstances created great variegation of natural conditions in lakes and determined the composition of their diatoms. The basic stages of the development of the diatom flora of lakes are linked with general climatic changes. The deepwater regions of large periglacial lakes of the North-west USSR are inhabited by plankton diatoms of the genera Melosira and Cyclotella. Diatom analysis is further applied for the study of the history of the lakes of north-west USSR.

Observations on the influence of external factors on the duration of the embryonic development and on the molting rhythm of Cyclops vicinus. [Translation from: Oecologia 7, 342-355, 1971.]

Investigations on the control of the embryonic and post-embryonic development of arthropods have formed an intensively studied field of zoological research for a long time, Here in especially favourable cases the causal chain from the operation of external factors on the influence of physiological mechanisms, eg. of the hormone variety, is known right through to its primary influences. A comparative approach to the relevant questions was in the main only made in the case of the insects. For crustacea , investigations are available almost exclusively only for the malacostraca. This study examines the influence of the factors of temperature and photoperiod on the entire development of Cyclops vicinus. Tests were made on whether the light-darkness change serves as a regulator for a possible existing molting rhythm - a question which for the entire arthropods has been settled only very rarely. The basic material for the cultures that were examined originates from Lake Constance.

Fundamental aspects of the feeding of the amphipod Gammarus (R.) balcanicus (Crustacea, Amphipoda). [Translation from: Nauchn.Dokl.vyssh.Shkoly (Biol.Nauk) 1970(7) 12-16, 1970]

The amphipods are major food items for many commercial fishes, and they are used as protein food for agricultural animals. In the present paper are presented the results of four-year observations on the feeding of Gammarus balcanicus in nature and in an aquarium. Among the studied aspects were the dependence of daily food ration on sex and physiological state (with and without eggs) and feeding on different kinds of plant food. The study concludes that Gammarus balcanicus willingly feed on soft half-decayed plant residues; into their ration also enters food of animal origin. In contrast to other amphipods, G. balcanicus eats representatives of its own species very rarely, and only dead or immobile ones.

Diurnal periodicity of activity in the spawning perch P. fluviatilis L. [Translation from: Kalamies 1972(7) 3, 1972]

Diurnal periodicity of spawning in the perch so far are rather meagre and found to be partly contrary to experiences of perch anglers. Therefore a study was made on the spawning during a 5-day period in the spring of 1971 in the Kuusamo area. Observations were made during the main spawning season, between 4- 9 June 1971. The perch were often measured, weighed and then released back into the water. The differences between spawning and non-spawning perch were studied as well as the time of roe discharge in a 24 hour period. Activity and environmental factors such as light intensity were also taken into consideration.

Cultivation methods for Lemnaceae [Translation from: Wiadomosci Botaniczne 7(2) 153-164, 1963]

Representatives from the family of Lemnaceae (duckweed) make ideal experimental material for research into a succession of phytophysiological processes with regard to growth rate and vegetative reproduction. They are also easy to maintain in sterile cultures. Lemnaceae belong to the higher flowering plants (flowers are rarely produced), however they are distinguished by a much simplified morphological and anatomical structure. As water plants they possess the advantage, that they can be cultivated in synthetic media under laboratory conditions controlled by the application of both a known light intensity and temperature. This paper describes experimental research of growth of Lemnaceae in different conditions. Some of the variables were mineral media, illumination and aeration.

Biology of the amphipod Gammarus pulex L. in water-bodies of the Leningrad district, and its piscicultural importance [Translation from: Trudy Vsesoyuznogo Gidrobiologicheskogo Obshchestva 7 99-122, 1956]

Observations and laboratory experiments are summarised that examine the widely discussed issue of what Gammarus pulex feeds on. On the basis of the observations of the authors and data from the literature it can be noted that G. pulex belongs to the omnivorous organisms, but, depending on the conditions of subsistence, in its rations either plant or animal food can predominate.

Electromagnetic decay of the 1.7- and 2.43-MeV levels in ^9Be

The 1.7- and 2.43-MeV levels in ⁹Be were populated with the reaction ¹¹B(d, α)⁹Be* by bombarding thin boron on carbon foils with 1.7-MeV deuterons. The alpha particles were analyzed in energy with a surface-barrier counter set at the unique kinematically determined angle and the recoiling ⁹Be nuclei at 90^o were analyzed in rigidity with a magnetic spectrometer, in energy by a surface-barrier counter at the spectrometer focus, and in velocity by the time delay between an alpha and a ⁹Be count. When a pulse from the spectrometer counter was in the appropriate delayed coincidence with a pulse from the alpha counter, the two pulses were recorded in a two-dimensional pulse height analyzer. Most of the ⁹Be* decay by particle breakup. Only those that gamma decay are detected by the spectrometer counter. Thus the experiment provides a direct measurement of Γ_rad/Γ. Analysis of 384 observed events gives Γ_rad/Γ = (1.16 ± 0.14) X 10^-4 for the 2.43-MeV level. Combining this ratio with the value of Γ_rad = 0.122 ± 0.015 eV found from inelastic electron scattering gives Γ = (1.05 ± 0.18) keV. For the 1.7-MeV level, an upper limit, Γ_rad/Γ ≤ 2.4 = 10^-5, was determined.

I. The 3.7 Å crystal structure of horse heart ferricytochrome C. II. The application of the Karle-Hauptman tangent formula to protein phasing

I. The 3.7 Å Crystal Structure of Horse Heart Ferricytochrome C.

The crystal structure of horse heart ferricytochrome c has been determined to a resolution of 3.7 Å using the multiple isomorphous replacement technique. Two isomorphous derivatives were used in the analysis, leading to a map with a mean figure of merit of 0.458. The quality of the resulting map was extremely high, even though the derivative data did not appear to be of high quality.

Although it was impossible to fit the known amino acid sequence to the calculated structure in an unambiguous way, many important features of the molecule could still be determined from the 3.7 Å electron density map. Among these was the fact that cytochrome c contains little or no α-helix. The polypeptide chain appears to be wound about the heme group in such a way as to form a loosely packed hydrophobic core in the molecule.

The heme group is located in a cleft on the molecule with one edge exposed to the solvent. The fifth coordinating ligand is His 18 and the sixth coordinating ligand is probably neither His 26 nor His 33.

The high resolution analysis of cytochrome c is now in progress and should be completed within the next year.

II. The Application of the Karle-Hauptman Tangent Formula to Protein Phasing.

The Karle-Hauptman tangent formula has been shown to be applicable to the refinement of previously determined protein phases. Tests were made with both the cytochrome c data from Part I and a theoretical structure based on the myoglobin molecule. The refinement process was found to be highly dependent upon the manner in which the tangent formula was applied. Iterative procedures did not work well, at least at low resolution.

The tangent formula worked very well in selecting the true phase from the two possible phase choices resulting from a single isomorphous replacement phase analysis. The only restriction on this application is that the heavy atoms form a non-centric cluster in the unit cell.

Pages 156 through 284 in this Thesis consist of previously published papers relating to the above two sections. References to these papers can be found on page 155.

Final report on the updating service on environmental chemicals in freshwater for the period 9.1.89 to 9.7.89

This report presents five batches of data which have been despatched to the Joint Research Centre, Ispra. The data as been allocated to various ECDIN (Environmental Chemicals Data and Information Network) files. The data comprises environmental chemicals in the freshwater environment, taking in paricular consideration: aquatic toxicity, bioaccumulation, metabolism and elimination biodegradation.

Synthesis and structural characterisation of [Cu2[(PDC)2(bpa)(H2O)2]•nH2O•mDMF (n=3 and m=1 for 1, n=7 and m=0 for 2, PDC=2,5-pyrindinedicarboxylate and bpa= 1,2-di(4-pyridil)ethane))

[EN] Combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce solid coordination frameworks (SCF) which are crystalline materials based on connections between metal ions through organic ligands. In this sense, combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce extended structures. In this context, this work is focused on two novel CuII-based SCFs exhibiting PDC (2,5-pyridinedicarboxylate) and bpa (1,2-di(4-pyridyl)ethane), being the first structures reported in literature containing both ligands. Chemical formula are [Cu2[(PDC)2(bpa)(H2O)2]•3H2O•DMF (1), and [Cu2(PDC)2(bpa)(H2O)2]•7H2O (2), where DMF is dimethylformamide. Compounds 1 and 2 have been characterized by means of XRD, IR, TG/DTG, and DTA analysis.

5th European Conference on Energy Efficiency and Sustainability in Architecture and Planning : Donostia-San Sebastián, 7-9 Julio 2014

XXXIII Cursos de Verano de la UPV/EHU