A dedicated setup for the measurement of the electron transport parameters in gases at large electric fields

Electron transport parameters are important in several areas ranging from particle detectors to plasma-assisted processing reactors. Nevertheless, especially at high fields strengths and for complex gases, relatively few data are published. A dedicated setup has been developed to measure the electron drift velocity and the first Townsend coefficient in parallel plate geometry. An RPC-like cell has been adopted to reach high field strengths without the risk of destructive sparks. The validation data obtained with pure Nitrogen will be presented and compared to a selection of the available literature and to calculations performed with Magboltz 2 version 8.6. The new data collected in pure Isobutane will then be discussed. This is the first time the electron drift velocity in pure Isobutane is measured well into the saturation region. Good agreement is found with expectations from Magboltz. (C) 2009 Elsevier B.V. All rights reserved.

Dynamical self-stabilization of the Mott insulator: Time evolution of the density and entanglement entropy of out-of-equilibrium cold fermion gases

The time evolution of the out-of-equilibrium Mott insulator is investigated numerically through calculations of space-time-resolved density and entropy profiles resulting from the release of a gas of ultracold fermionic atoms from an optical trap. For adiabatic, moderate and sudden switching-off of the trapping potential, the out-of-equilibrium dynamics of the Mott insulator is found to differ profoundly from that of the band insulator and the metallic phase, displaying a self-induced stability that is robust within a wide range of densities, system sizes and interaction strengths. The connection between the entanglement entropy and changes of phase, known for equilibrium situations, is found to extend to the out-of-equilibrium regime. Finally, the relation between the system`s long time behavior and the thermalization limit is analyzed. Copyright (C) EPLA, 2011

Influence of nitriding gases on the growth of boron nitride nanotubes

Boron nitride (BN) nanotubes of different sizes and tubular structures exhibit very different mechanical and chemical properties, as well as different applications. BN nanotubes of different sizes and nanostructures have been produced in different nitriding gases in a milling and annealing process, in which elemental boron powder was first milled in NH₃ for 150 h and subsequently annealed at 1,200 °C for 6 h. The influence of nitriding gases was investigated by using N₂, NH₃, N₂–H₂ mixture gases. A relatively slow nitriding reaction in NH₃ gas leaded to a 2D growth of BN (002) basal planes and the formation of thin BN nanotubes without the help of metal catalysts. Fast nitriding reactions occurred in N₂ or N₂–H₂ mixture gases, catalyzed by metal particles, resulted in 3D crystal growth and the formation of many large cylindrical and bamboo tubes.

Inverse opal gas sensors : Zn(II)-doped tin dioxide systems for low temperature detection of pollutant gases

Focusing here on the effects of zinc doping in a nanocrystalline matrix of tin dioxide, inverse opal prototype sensors are presented and extensively studied as superior candidates for gas sensing applications. Courtesy of factors including controlled porosity, enhanced surface to volume ratio and homogeneous dispersion of species in the crystalline lattice assured by the sol–gel technique, prototype sensors were prepared with high dopant ratios in a range of new compositions. Exploiting their high sensitivities to low-gas concentrations at low working temperatures, and thanks to the presented templated sol–gel approach, the prepared sensors open up new frontiers in compositional control over the sensing oxide materials, consequently widening the possibilities available in on-demand gas sensor synthesis.

Exposure to fumes and gases during welding operations

The exposure to fumes and gases is one of the hazards associated with welding operations. Apart from research conducted on the mechanism of fume and gas formation and the relationship between fume formation rates and common welding parameters, little is known about the exposure process during welding. This research project aimed to identify the factors that influence exposure, develop an understanding of their role in the exposure process and through this understanding formulate strategies for the effective control of exposure during welding. To address these aims a literature review and an experimental program was conducted The literature review surveyed epidemiological, toxicological and exposure data. The experimental program involved three approaches, the first, an evaluation of the factors that influence exposure by assessing a metal inert gas/mild steel welding process in a workshop setting. The second approach involved the study of exposure in a controlled environment provided by a wind tunnel and simulated welding process. The final approach was to investigate workplace conditions through an assessment of exposure and control strategies in industry. The exposure to fumes and gases during welding is highly variable and frequently in excess of the health based exposure standards. Exposure is influenced by a number of a factors including the welding process, base material, arc time, electrode, arc current, arc voltage, arc length, electrode polarity, shield gas, wire-to-metal-work distance (metal inert gas), metal transfer mode, intensity of the UV radiation (ozone), the frequency of arc ignitions (ozone), thermal buoyancy generated by the arc process, ventilation (natural and mechanical), the welding environment, the position of the welder, the welders stance, helmet type, and helmet position. Exposure occurs as a result of three processes: the formation of contaminants at or around the arc region; their transport from the arc region, as influenced by the entry and thermal expansion of shield gases, the vigorous production of contaminants, thermal air currents produced by the heat of the arc process, and ventilation; and finally the entry of contaminants into the breathing zone of the welder, as influenced by the position of the welder, the welders stance, helmet type, and the helmet position. The control of exposure during welding can be achieved by several means: through the selection of welding parameters that generate low contaminant formation rates; through the limitation of arc time; and by isolating the breathing zone of the welder from the contaminant plume through the use of ventilation, welder position or the welding helmet as a physical barrier. Effective control is achieved by careful examination of the workplace, the selection of the most appropriate control option, and motivation of the workforce.

The influence of inert impurities on the catalyst lifetime and properties of nanofibrous carbon produced by utilization of diluted hydrocarbon gases

Experimental studies were focused on the feasibility of utilization of hydrocarbons diluted with inert gases (such as associated oil gases) during the synthesis of nanofibrous carbon. The carbon yield and catalyst lifetime were studied regarding the initial reaction mixture parameters. Varying the composition of the initial gas mixture, it is possible to control textural characteristics of the resulting carbon product.

Study of radio frequency plasma treatment of PVDF film using Ar, O2 and Ar + O2 gases for improved polypyrrole adhesion

Improvement of the binding of polypyrrole with PVDF (polyvinylidene fluoride) thin film using low pressure plasma was studied. The effects of various plasma gases i.e., Ar, O2 and Ar + O2 gases on surface roughness, surface chemistry and hydrophilicity were noted. The topographical change of the PVDF film was observed by means of scanning electron microscopy and chemical changes by X-ray photoelectron spectroscopy, with adhesion of polypyrrole (PPy) by abrasion tests and sheet resistance measurements. Results showed that the increase in roughness and surface functionalization by oxygen functional groups contributed to improved adhesion and Ar + O2 plasma gave better adhesion.

Fusões e aquisições como fator estratégico nas empresas de logística especializadas no transporte de cargas terrestres do Estado de São Paulo

Dissertação apresentada ao Programa de Mestrado em Administração da Universidade Municipal de São Caetano do Sul - USCS

A integração de sistema transporte público de passageiros na região do Grande ABC: oportunidades e obstáculos

FERRARO, Clovis José Ramos. A integração de sistema transporte público de passageiros na região do Grande ABC: oportunidades e obstáculos. 2011. 145f. Dissertação (Mestrado em Administração) - Universidade Municipal de São Caetano do Sul, São Caetano do Sul, 2012.

Atratividade setorial no transporte aéreo de passageiros no Brasil

Dissertação apresentada ao Programa de Pós- Graduação em Administração - Mestrado como requisito para a obtenção do título de Mestre em Administração

Influência da educação corporativa sobre a relação entre aprendizagem e carreira: estudo em uma empresa de transporte de cargas

Esse estudo se propõe analisar se a participação dos indivíduos em programas pertencentes à Educação Corporativa apresenta efeitos sobre a carreira e sobre o desenvolvimento pessoal dos colaboradores. Trata-se de uma pesquisa qualitativa, de cunho, exploratório, em uma organização do segmento de transportes de cargas. Participaram do estudo líderes departamentais, sendo que para obtenção de dados foi utilizada uma entrevista baseada em roteiro semiestruturado. Como resultados, identificaram-se os caminhos da educação corporativa e desenvolvimento da carreira. Desta forma, foi possível caracterizar um modelo e exemplo prático de educação corporativa às empresas de transportes de cargas, contribuindo para a formação de uma cultura organizacional. Conclui-se que se têm efeitos sobre a participação dos colaboradores nos programas de Educação Corporativa.

Empregado, autônomo e empresário : a tomada de decisão no setor de transporte rodoviário de cargas em São Marcos, RS

São Marcos, no Rio Grande do Sul, caracteriza-se por sua participação no setor do transporte rodoviário de cargas, sendo o município brasileiro com maior número de veículos pesados por habitante. Este trabalho busca identificar os fatores que influenciam a tomada de decisão dentro desse ramo de negócios. Assim, são estudados quatro casos de profissionais da área. Esses indivíduos iniciaram sua trajetória na condição de empregados, passando em seguida para a fase de autônomos. No entanto, apenas dois deles prosperaram, tornando-se empresários; os outros dois retornaram à condição de empregados. O estudo também possibilitou identificar o nível de insatisfação dos empregados do setor na busca de um progresso dentro do mesmo, assim como observar o perfil de competência daqueles que chegam a implantar suas próprias organizações. Dessa forma, é possível formar um paralelo entre as experiências bem-sucedidas e as tentativas frustradas. Os dados foram levantados a partir de uma série de fontes de evidências como entrevistas, registros de arquivos e documentos dos personagens referidos. A análise desses dados leva à interpretação de dois fatores como fundamentais na tomada de decisões dos indivíduos que trabalham no transporte rodoviário de cargas: a intuição e a influência de outras pessoas que cercam os tomadores de decisão. Esses fatores reforçam a idéia da subjetividade dentro do processo administrativo. O trabalho possibilita a formação de um quadro de dados gerais a respeito do setor. Além disso, serve de referencial às atitudes de organizações públicas e privadas, de pessoas ligadas ao ramo e de jovens que pretendem entrar nesse universo de trabalho.