998 resultados para Theoretische Chemie, Coupled-Cluster-Theorie


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A mathematical model for coupled multiphase fluid flow and sedimentation deformation is developed based on fluid-solid interaction mechanism. A finite difference-finite element numerical approach is presented. The results of an example show that the fluid-solid coupled effect has great influence on multiphase fluid flow and reservoir recovery performances, and the coupled model has practical significance for oilfield development.

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The present paper describes a systematic study of argon plasmas in a bell-jar inductively coupled plasma (ICP) source over the range of pressure 5-20 mtorr and power input 0.2-0.5 kW, Experimental measurements as well as results of numerical simulations are presented. The models used in the study include the well-known global balance model (or the global model) as well as a detailed two-dimensional (2-D) fluid model of the system, The global model is able to provide reasonably accurate values for the global electron temperature and plasma density, The 2-D model provides spatial distributions of various plasma parameters that make it possible to compare with data measured in the experiments, The experimental measurements were obtained using a tuned Langmuir double-probe technique to reduce the RF interference and obtain the light versus current (I-V) characteristics of the probe. Time-averaged electron temperature and plasma density were measured for various combinations of pressure and applied RF power, The predictions of the 2-D model were found to be in good qualitative agreement with measured data, It was found that the electron temperature distribution T-e was more or less uniform in the chamber, It was also seen that the electron temperature depends primarily on pressure, but is almost independent of the power input, except in the very low-pressure regime. The plasma density goes up almost linearly with the power input.

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We investigate the existence of wavelike solution for the logistic coupled map lattices for which the spatiotemporal periodic patterns can be predicted by a simple two-dimensional mapping. The existence of such wavelike solutions is proved by the implicit function theorem with constraints. We also examine the stabilities of these wave solutions under perturbations of uniform small deformation type. We show that in some specific cases these perturbations are completely general. The technique used in this paper is also applicable to investigate other space-time regular patterns.

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In the present paper, argon (Ar) plasmas in a bell jar inductively coupled plasma (ICP) source are systematically studied over pressures from 5 to 20 mtorr and power inputs from 0.2 to 0.5 kW. In this study, both a two-dimensional (2-D) fluid model simulation and global model calculation are compared, The 2-D fluid model simulation with a self-consistent power deposition is developed to describe the Ar plasma behavior as well as predict the plasma parameter distributions, Finally, a quantitative comparison between the global model and the fluid model is made to test their validity.