Pré-tratamento oxidativo de bagaço de cana com persulfato de sódio para sacarificação enzimática e produção de etanol celulósico

Pós-graduação em Química - IBILCE

Otimização de rotas tecnológicas de processamento e distribuição de resíduos municipais

Pós-graduação em Engenharia Mecânica - FEG

Estudo da viabilidade econômica da coleta seletiva e da compostagem dos resíduos sólidos do município de Guaratinguetá (SP)

Pós-graduação em Engenharia Civil e Ambiental - FEB

Caracterização de argilas usadas para produção de cerâmica vermelha e estudo das alterações nas suas propriedades pela adição de resíduos

Neste trabalho são apresentados os resultados de caracterização das principais argilas usadas pela indústria cerâmica vermelha regional e, também, de alguns resíduos sólidos produzidos na região de Presidente Prudente - SP. Os resultados da incorporação destes resíduos em massas cerâmicas são avaliados através do estudo de suas propriedades tecnológicas. Para a caracterização dos materiais foram utilizadas as seguintes técnicas: análise textural (concentração das frações areia, silte e argila), difratometria de raios X e análise térmica. As propriedades tecnológicas de corpos de prova cerâmicos foram avaliadas através dos seguintes parâmetros: retração linear (RL), perda de massa ao fogo (PF), massa específica aparente (MEA), porosidade aparente (PA), absorção de água (AA) e resistência mecânica à flexão (RMF). Corpos de prova, com diferentes concentrações de resíduos, foram prensados (prensa uniaxial manual) e queimados em temperaturas que variaram de 800 a 1200 oC, usando um forno tipo mufla com controle de temperatura. As argilas sedimentares foram coletadas nas margens do rio Paraná e em áreas de várzea, próximas as cerâmicas. As amostras estudadas, coletadas nos depósitos das cerâmicas, são usadas para produção de tijolos maciços, blocos furados e telhas. Quatro tipos diferentes de resíduos foram estudados: (1) lodo de estação de tratamento de água ETA, (2) torta de filtro de indústria de re-refino de óleo lubrificante, (3) pó de vidro (soda-cal) de garrafa tipo long neck descartável, e (4) cinza de bagaço de cana. Estes resíduos foram incorporados em massas cerâmicas coletadas nas indústrias... (Resumo completo, clicar acesso eletrônico abaixo)

Contaminação das águas subterrâneas por resíduos de postos de combustíveis: uma abordagem no município de Rio Claro

The contamination of underground waters is a subject of great importance, since a lot of people use this kind of source for public supply. This paperwork manages with how gas stations can contaminate these waters and what are some remediation techniques, used nowadays to solve this problem. The contamination caused by the gas stations can have its origin in the underground storage tanks when they suffer corrosion and show leaking problems. It’s a topic of great relevance, because the hydrocarbons derivated from petroleum present in the fuels can stay for a long time in the environment. Besides that, an analyses of the risk of contamination by gas stations in the city of Rio Claro was made based on three parameters: density of the gas stations, depth of the underground water and hydraulic conductivity. To achieve such goal, maps were elaborated considering those parameters individually and considering the three of them together. Analyzing those maps, it was concluded see that the spots that represent the biggest risks of contamination in Rio Claro are located southeast and center-west.

Avaliação do potencial genotóxico e mutagênico do efluente de uma refinaria de petróleo e dos rios sob sua influência, por meio de bioensaios com Oreochromis niloticus (Perciformes, Cichlidae)

The petrochemical industry represents a sector of intense activity, in constant expansion and great economic importance for Brazil. In order to be used in various human activities petroleum needs to suffer a refinement process that, besides requiring large amounts of water, produces large amounts of wastes, which are discharged in hydric resources. Petroleum is a complex mixture mainly comprised by hydrocarbons, many of them are recognized as toxic chemicals, which are able to induce a considerable environmental pollution. Since water is an important resource for the maintenance of ecosystems and is also the final receiver of effluent discharges of the petroleum industry, there is an imminent need to monitor, constantly, the hydric resources that are influenced by this industrial activity, so that it can be ensured the environmental health. This study aimed, mainly, to analyze the quality of water samples derived from refinement process performed of the largest petroleum refinery in Brazil (REPLAN), in distinct steps of the industry treatment, and waters of rivers associated to its activity. Micronuclei and Nuclear Abnormalities tests were performed in erythrocytes of the fish species Oreochromis niloticus exposed to water samples derived from refinery use and to rivers under the influence of their effluents, in order to evaluate its possible toxic, genotoxic and mutagenic effects. The results obtained show that the treatment carried out by the refinery, during the evaluated periods, was effective, since the substances present in the water samples did not induce significant genotoxic and/or mutagenic alterations in the genetic material of the test organisms. On the other hand, when the substances present in the refinery effluent mix with the ones derived from other industrial activities developed upstream of this industry, the resultant compound, in some periods, presented genotoxic potencial, characterized by a rise of erythrocytic...

Gerenciamento dos resíduos de serviços de saúde da Unidade de Terapia Intensiva do Pronto Socorro do Hospital das Clínicas da Faculdade de Medicina de Botucatu – UNESP

Health care waste (HCW) is the type of waste that results from activities performed in health care services during care provision to humans or animals. Presently, according to RDC 306/04, issued in 2004 by Anvisa, and Resolution no. 358/05, by CONAMA, waste groups have the following classification: Group A (biological waste), Group B (chemical waste), Group C (waste containing radionucleotides), Group D (common waste) and Group E (piercing and cutting waste). In Brazil, 149 tons of wastes are collected every day, and HCW corresponds to approximately 1% to 3 % of that total. An efficient way to adequately manage HCW is through the Health Care Waste Management Plan (HCWMP), and it is possible to reduce the risk posed by certain materials in addition to ensuring disposal in an ecologically correct and economical fashion. According to the Pan-American Health Organization (PAHO), the management process enables health care establishments to adequately manage waste. Hence, there is greater control and reduction in the health risks caused by infectious or special waste, in addition to facilitated recycling, treatment, storage, transport and final disposal of solid hospital waste in an environmentally safe fashion. To evaluate the management of HCW of Groups A and D from the Intensive Care Unit of the University Emergency Hospital - FMB - UNESP in the city of Botucatu according to the guidelines presently in force. The waste flow was followed up, and during four random days in the month of September 2011, waste was quantified by estimating daily and monthly values, according to its classification. : In 2011, the University hospital has produced an average of 57,676.8 kg/month of biological and common waste. By adding Groups A and D, during the four days, approximately 209.8 Kg of waste (202.2 Kg of Group A and 7.6 Kg of Group D) were produced in the establishment under study, which... (Complete abstract click electronic access below)

Micro-fungos de interesse para o setor de petróleo, gás e biocombustíveis

Oil is a hydrocarbon mixture of various sizes, including saturated and aromatic compounds. Natural gas is a mixture of gaseous hydrocarbons and its main component is methane. In our society, the great demand for these fuels requires fast extraction, transportation and refining, increasing the number of accidents that compromise the environment. Oil is a finite resource and it is necessary to reduce the problems related to the question concerning environmental pollution which has encouraged the search for alternative fuel sources in our country. So today we have two major biofuels: ethanol and biodiesel. Concurrently, many studies have been done directed toward the isolation of microorganisms capable of degrading petrochemical industrial wastes, most of them using as a source of isolation soil and water collected in a contaminated environment. Isolation from alternative substrates has emerged as a new strategy that has provided satisfactory results. In this work, we present the leaf-cutter ants of the Attini tribe as a source for the isolation of micro-fungi with the potential for hydrocarbon degradation. These insects have a social way of life and a highly specialized system of intra and interspecific communication, which is based on the recognition of individuals through volatile chemical compounds, the majority hydrocarbons, stored in their exoskeleton. The micro-environment exoskeleton of Attini ants (genus Atta) used in this work proved to be a rich source of microbial biodiversity, as other studies have found. The flotation isolation technique applied here allowed the achievement of 214 micro-fungi, 118 representatives of the dematiaceous fungi group and 96 hyaline filamentous fungi. They were submitted to toluene degradation tests and at least one strain of each genus presented good results, namely Teratosphaeria, Exophiala, Cladosporium, Penicillium, Aspergillus... (Complete abstract click electronic access below)

Subsídios para o gerenciamento de resíduos de serviços de saúde em municípios de médio porte: estudo de caso de Araraquara - SP

The Health Care Wastes (HCW) present serious risks to health and to the environment, if incorrectly managed, because in addition to the presence of pathogenic agents, the may pollute the soil and the water. Thus, a study was performed aiming at diagnosing the HCW management in Araraquara (SP), identifying the difficulties of the agents (municipal gestors and managers of institutions which generate this wastes) in implanting the HCW management Plan (HCWMP) proposed by ANVISA, in order to subside the HCWMP implantation. The methodology was based on question applications in health centers selected to be the samples, and on quantitative data related to the phases of Treatment and Final Disposal, provided by DAAE. As a result, it was observed that a great part of the interviewed centers managed these wastes according to norm RDC no 306/ 2004 of ANVISA. However, only 24% of the interviewed centers knew about this norm, and only 22% of them had the HCWMP. The difficulties in managing the HCW concentrated in the correct segregation of theses wastes in the generation source. The large number of people involved in this phase suggests the causes of the difficulties.

Uso de sistemas construídos de áreas alagadas (Constructed Wetland System - CWS) tipo ascendente/descendente, para tratamento de efluentes avícolas

Human development and population growth during the twentieth century increased the water demand, tripling its consumption between 1950 and 1990. As the water streams were polluted; and as water is the source of minerals and also regulates vital functions, it becomes the vehicle of transmission and consequently spreads many diseases. Probably, the industries are the major responsible for this pollution when they dump untreated effluents to water streams, saturating the already insufficient net of sanitation facilities polluting water and soil. An effective treatment has been established with low cost in Europe and the United States, through constructed systems on wetlands Constructed Wetland Systems - CWSs, gradually used in other countries in the last three decades. Lately, we observe a continuous growth in Brazilian poultry business, and poultry industry showed greatest dynamism in the country, following the global market. Pondering this information and the efficiency of such treatment, this work aimed to study prototypes, in a laboratory scale, simulating ascending and descending types of CWSs, vegetated with aquatic macrophytes Eichhornia crassipes and the uses of aggregates and soil, to treat industrial wastewater from slaughterhouses and aviary. We conducted the initial characterization of the effluent to have an idea of its constituents and to scale the system and the continuous flow. Furthermore, we characterized the soil to be used in this system. The collects are periodically made in the refrigeration industry FRICOCK FRIGORIFICAÇÃO AVICULTURA INDÚSTRIA E COMÉRCIO LTDA. for local treatment simulation. The effluent that was treated with 12 prototypes of CWSs are analyzed with some frequency. The results of these reviews were compared to the effluent coming from the industry... (Complete abstract click electronic access below)

Determinação de metais em água produzida de petróleo

In order to enable the reuse of the large surplus volume of petroleum produced water for irrigation of crops inedible, the quality evaluation of this water is very important. This work aimed to evaluate the effectiveness of the diffusive gradient in thin films technique (DGT) for the determination of labile Cu (II), Mn (II) and Zn (II) in petroleum produced water destined to reuse in agriculture. Samples were collected at the exit of the wastewater treatment plant (WWTP) (after separation oil/water and flotation) of a Petrobrás onshore production region. Basically, the laboratory experiments with DGT devices involved the evaluation of the behavior of the main variables of the technique for determination of analytes in the samples (diffusion coefficients, immersion time, fractionation of organic and inorganic species, and performance of diffusion gels with different porosities, among others). Also, experiments were conducted based on the solid phase extraction (SPE) protocol with Chelex- 100 resin using previously established protocols to support the study. During the project the possibility of in situ immersions in water treatment plants was evaluated. The DGT technique presented satisfactory results for determination of Mn in produced water, and can be used for in situ determinations. However, the results obtained for Cu and Zn show the need of additional studies

Gestão de resíduos de demolição e da construção civil no município de Guaratinguetá-SP

The large volume of waste generated by construction and demolition has become increasingly a matter of concern to society. The handling and disposal of RCD's to gain prominence as over the years intensified the requirements for a sustainable world. This paper presents the positive and negative factors that the management of construction and demolition waste can bring in the municipality of Guaratinguetá-SP. This study examines the methods used in waste management since he was not done any treatment to the present day. Presents comparative tables on the feasibility of installing a central crushing of inert waste and implementation of an inert waste landfill in the municipality of Guaratinguetá and Cachoeira Paulista. And yet the work being done by the city of Guaratinguetá reuse the material in class A in paving roads

Recuperação de resíduos plásticos provenientes dos processos de injeção

The competitiveness among global markets, the constant need for reducing manufacturing costs and also the growing environmental commitments are fueling the development of techniques for recovery residual parts generated by industrial processes. Among the various areas of a company, we highlight those that involve the processing of raw materials derived from oil, such as polymers (resins), which may take centuries to decompose in the environment and also present as a economic and environmentally strategic point. Thus, this study would examine the recovery of waste polypropylene, from the injection process of a major multinational in the field of home appliances through the recycling by a process comprising the milling, extrusion and chipping of waste material. Easy to deploy, this proposal aims to reduce levels negligible disposal (scrap) of these residues as well as the reintegration of the production process into pieces no visual and no structural importance, aimed at cutting costs and reducing environmental impacts caused. After the survey data in kilograms of waste material generated in a given period of time, and the study of changes in material properties, it would enable the reuse steadily in the injection process

Diagnóstico dos resíduos sólidos domiciliares no município de Ribeirão Pires/SP

O progresso econômico-social e o desenvolvimento industrial aumentaram as quantidades de resíduos gerados pela humanidade; para se obter um equilíbrio ambiental é preciso que estes sejam reintroduzidos no ciclo de produção, sob a forma de matéria-prima. O meio ambiente vem nos dando sinais da sua incapacidade de armazenar todos os resíduos gerados e ainda as reservas de matéria-prima não são inesgotáveis. Desta forma as políticas de gerenciamento dos resíduos sólidos tornam-se fundamentais para o melhoramento da qualidade de vida da população e promover o crescimento sustentável das cidades no Brasil e no mundo. O município de Ribeirão Pires localiza-se na região do Grande ABC, a sudoeste do Estado de São Paulo, tendo a totalidade do seu pequeno território – 99 km2 – em área de mananciais, apresentando uma população de 107.046 habitantes, segundo dados oficiais. O objetivo do presente trabalho consistiu em realizar um diagnóstico da geração, coleta e destinação final dos resíduos sólidos domiciliares no município de Ribeirão Pires, além de verificar quais são as políticas e projetos da Prefeitura para essa área de atuação, e avaliar o sistema atual de coleta seletiva e triagem da cidade. Inicialmente, realizou-se uma revisão de bibliografia específica, consulta a trabalhos de pesquisa realizados por órgãos federais, estaduais e municipais, levantamento de dados e informações junto aos órgãos responsáveis pela administração dos resíduos sólidos, aplicação de entrevistas e questionários à parte técnica dos órgãos públicos relacionados diretamente com as atividades de coleta, tratamento e destinação final de resíduos sólidos domiciliares, além da visita à cooperativa de reciclagem. Após estas atividades, o material e os dados coletados foram analisados e sistematizados para gerar informações e conhecimento que contribuem... (Resumo completo, clicar acesso eletrônico abaixo)

Aproveitamento energético de resíduos de esgotamento sanitário

This paper presents alternatives for waste energy recovery from the sewage of cities. Through a review of the literature it is observed that the technologies studied are usually turbines, microturbines, and engines adapted to the use of biogas. For project design analyzes the technologies found in some sewage treatment plants in Brazil and the world, compared with those found in the literature. With this study it can be concluded that the most used technologies are microturbines and motor generator sets, which are already implemented in some locations in the USA, Europe and even Brazil. It can also be concluded that the energy recovery of waste from sewage can enable design of wastewater treatment plants thereby contributing to improved quality of life