The Cutting out of the Caroline (1838)

Two newspaper clippings from the Montreal Herald of 1838 and an essay clipped from a book, handsewn into a booklet with paper cover and handwritten title and notes. The burning of the Caroline / Susanna Moodie -- The cutting out of the Caroline : a true story / by Francis W. Rowsell -- Juvenile courage and patriotism : instanced in Canada, during the disturbances at the close of the year 1837

Modeling Metal Protein Complexes from Experimental Extended X-ray Absorption Fine Structure using Computational Intelligence

Experimental Extended X-ray Absorption Fine Structure (EXAFS) spectra carry information about the chemical structure of metal protein complexes. However, pre- dicting the structure of such complexes from EXAFS spectra is not a simple task. Currently methods such as Monte Carlo optimization or simulated annealing are used in structure refinement of EXAFS. These methods have proven somewhat successful in structure refinement but have not been successful in finding the global minima. Multiple population based algorithms, including a genetic algorithm, a restarting ge- netic algorithm, differential evolution, and particle swarm optimization, are studied for their effectiveness in structure refinement of EXAFS. The oxygen-evolving com- plex in S1 is used as a benchmark for comparing the algorithms. These algorithms were successful in finding new atomic structures that produced improved calculated EXAFS spectra over atomic structures previously found.

Photograph - Log cutting

A photograph with a male dressed in a shirt and bow-tie cutting a log and two other men in suits standing on either side of the log. They are surrounded by a large crowd.

Metal Stamp - Lion

Round stamp 2 cm in diameter. This has the image of a lion within a crown holding a flower. The inscription underneath is "sans changer" which means constant or without change. The stamp is 1 cm thick and it has a 1 cm stem protruding from it.

Metal Stamp - Woodruff Coat of Arms

Square metal stamp, 2 1/2 cm x 6 1/2 cm, with the words "P.C. Band, Toronto, Ontario" engraved on it. The bar is 1 cm thick.

Metal Stamp - Round with Amethyst

Round metal stamp which is 2 cm in diameter. The metal forms a cup above the seal which holds an amethyst piece. The amethyst is broken off and cracked.

Metal Bar - P. C. Band, Toronto, Ontario

Metal bar, 2 cm x 6 1/2 cm, with the words "P.C. Band, Toronto, Ontario" engraved on it.

Metal Button

Metal button 2 cm in diameter showing the crest of the right arm holding the honeysuckle (Woodruff crest). The button is inscribed in the inside. It has the number 50 on it and it says "N. R. Hayward, Long Acre, London, W. C."

Calculations regarding quantities needed for cutting and ditching

Calculations regarding quantities needed for cutting and ditching (1 page, handwritten), March 19, 1884.

Single-Molecule Magnets and Multifunctional Molecular Magnetic Materials Based on Polynuclear Metal Complexes

Our work on single molecule magnets and multifunctional magnetic materials is presented in four projects. In the first project we show for first time that heteroatomic-type pseudohalides, such as OCN-, can be employed as structure-directing ligands and ferromagnetic couplers in higher oxidation state metal cluster chemistry. The initial use of cyanato groups in Mn cluster chemistry has afforded structurally interesting MnII/III14 (1) and MnII/III/IV16 (2) clusters in which the end-on bridging cyanates show a preference in binding through their O-atom. The Mn14 compound shows entirely visible out-of-phase alternating currect signals below 5 K and large hysteresis loops below 2 K. Furthermore, the amalgamation of azido groups with the triethanolamine tripodal ligand in manganese carboxylate cluster chemistry has led to the isolation of a new ferromagnetic, high-nuclearity and mixed-valence MnII/III15Na2 (3) cluster with a large ground-state spin value of S = 14. In the second project we demonstrate a new synthetic route to purely inorganic-bridged, transition metal-azido clusters [CoII7 (4) and NiII7 (5)] and coordination polymers [{FeII/III2}n (6)] which exhibit strong ferromagnetic, SMM and long-range magnetic ordering behaviors. We also show that access to such a unique ferromagnetic class of inorganic, N-rich and O-free materials is feasible through the use of Me3SiN3 as the azido-ligand precursor without requiring the addition of any organic chelating/bridging ligand. In the last projects we have tried to bring together molecular magnetism and optics via the synthesis of multifunctional magnetic materials based on 3d- or 4f-metal ions. We decided to approach such challenge from two different directions: firstly, in our third project, by the deliberate replacement of non-emissive carboxylato ligands in known 3d-SMMs with their fluorescent analogues, without perturbing the metal-core structure and SMM properties (complexes 7, 8, and 9). The second route (last project) involves the use of naphthalene or pyridine-based polyalcohol bridging ligands for the synthesis of new polynuclear LnIII metal clusters (Ln = lanthanide) with novel topologies, SMM behaviors and luminescent properties arising from the increased efficiency of the “antenna” organic group. This approach has led us to the isolation of two new families of LnIII8 (complexes 10-13) and LnIII4 (complexes 14-20) clusters.

Chart of calculations regarding quarrying, cutting, transportation and cement

Chart of calculations regarding quarrying, cutting, transportation and cement, n.d.

Maquila de piezas en una industria metal mecánica y su impacto en producción, calidad y costo

Tesis (Maestría en Ciencias de la Administración con Especialidad en Producción y Calidad) UANL

Conjuntivitis en soldadores que utilizan equipo de oxiacetileno, en comparación con trabajadores no expuestos al proceso de soldadura en una empresa metal-mecánica del área metropolitana de Monterrey, Nuevo León, México

Tesis (Maestría en Salud Pública con Especialidad en Salud en el Trabajo) UANL.

Determinación de alcoholismo laboral en una empresa metal mecánica en Apodaca, N.L.

Tesis (Maestría en Salud Pública con Especialidad en Salud en el Trabajo) U.A.N.L., 2001.

Años de vida saludable perdidos por secuelas de accidentes de trabajo entre la rama metal mecánica y otras ramas de la industria en Nuevo León

Tesis (Maestría en Salud Pública con Especialidad en Salud en el Trabajo) U.A.N.L., 2001 & Bibliografía: h. 33-36.