Caracterização de poliacrilamida parcialmente hidrolisada em regime concentrado

A partially hydrolyzed polyacrylamide (HPAM) is a copolymer composed of acrylamide and sodium acrylate. Due to its wide range of applications there are different methods for its quantification and characterization in solution systems. Evaluation of C* is important to describe the transition from dilute to semi-dilute, behavior, when the solution will have its characteristic viscosity at concentrations above C*. This dissertation describes the determination of the critical concentration of overlap C* by potentiometry of partially hydrolyzed polyacrylamide - HPAM under acidic conditions. Based on the law of mass action and the proper treatment of the constant of aggregate formation, polymer molecular weight, degree of polymerization and hydrolysis were calculated. The inflection point was determined by the intersection of the resulting equation and mathematical development, statistically satisfy the experimental points relating the number of moles of monomers (n), equilibrium constant of formation of the entanglements (K*), pH, C* and acidity constant of the polymer (Ka). The viscometric parameters of C* showed a percentage difference compared to potentiometers. The results for the determination of C*, and degree of copolymerization molar mass proved to be a simple alternative for the characterization of polymers with protonated monomers and water soluble

A dívida da vida: redes clientelistas na saúde "de favor"

The relationship between mayors and patients Who use a Casa de Apoio in Natal, RN, shows us some traditional political features anda t the same time happens in na urban and modern context, regulated by a formal institution, the State. The Oestana, as is named this Casa de Apoio, offers daily that are paid by some City Halls located in the West of Rio Grande do Norte where people go away to capital from which they have medical and hospital care. This assistance includes paid services like accommodation, food, transportation, etc., as well as services that aren´t paid as information, support and hospital material, for example. When the patients access these service, they will gain a debt with a services provider (the mayor) which its eventually paid with the vote in the municipal elections. The goal is to understand the social, the political, the symbolic and mainly the life meaning of this relationship. Our research was developed by interviews with Oestanas users and regular visits to this house that showed a political bond regulated by moral and subjection, but is reconfigured by new social categories as the affection and the logical networks.

Recursive hierarchic segmentation analysis of bone mineral density changes on digital panoramic images

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

The Hamilton-Jacobi approach to Teleparallelism

We intend to analyse the constraint structure of Teleparallelism employing the Hamilton-Jacobi formalism for singular systems. This study is conducted without using an ADM 3+1 decomposition and without fixing time gauge condition. It can be verified that the field equations constitute an integrable system.

Prediction of R plus R-2 gravity for the deflection of a photon passing close to the Sun

The cross-section for the scattering of a photon by the Sun's gravitational field, treated as an external field, is computed in the framework of R + R-2 gravity. Using this result, we found that for a photon just grazing the Sun's surface the deflection is 1.75 which is exactly the same as that given by Einstein's theory. An explanation for this pseudo-paradox is provided.

Spacetime algebraic skeleton

The cosmological constant is shown to have an algebraic meaning: it is essentially an eigenvalue of a Casimir invariant of the Lorentz group acting on the spaces tangent to every spacetime. This is found in the context of de Sitter spacetimes, for which the Einstein equation is a relation between operators. Nevertheless, the result brings, to the foreground the skeleton algebraic structure underlying the geometry of general physical spacetimes. which differ from one another by the fleshening of that structure by different tetrad fields.

Generalization of the Hamilton-Jacobi approach for higher-order singular systems

We generalize the Hamilton-Jacobi formulation for higher-order singular systems and obtain the equations of motion as total differential equations. To do this we first study the constraints structure present in such systems.

Generalized non-abelian Toda models of dyonic type

The construction of a class of non-abelian Toda models admiting dyonic type soliton solutions is reviewed.

Mass neutrino flavor evolution in spacetime with torsion

In the framework of the spacetime with torsion, we obtain the flavor evolution equation of the mass neutrino oscillation in vacuum. A comparison with the result of general relativity case shows that the flavor evolutionary equations in Riemann spacetime and Weitzenbock spacetimes are equivalent in the spherical symmetric Schwarzschild spacetime, but turn out to be different in the case of the axial symmetry.

Influência da suspensão na segurança e no conforto de um pulverizador autopropelido

Para avaliar o comportamento da suspensão do pulverizador autopropelido, foram desenvolvidos modelos físicos e matemáticos em função da excitação ocasionada pelas irregularidades do solo. Neste trabalho, estas irregularidades são representadas por obstáculos de uma pista normalizada segundo a norma ISO 5008. As equações do movimento são obtidas a partir dos modelos matemáticos de meio veículo. As simulações numéricas são executadas nos softwares Matlab® e Simulink®. A partir da entrada conhecida, podem-se determinar as características dos elementos da suspensão para obter níveis desejáveis de conforto e segurança. Foram analisadas quatro diferentes configurações do sistema, variando-se a relação de rigidez a partir de um modelo considerado padrão. Constatou-se que o aumento da relação de rigidez resulta na redução da aceleração vertical e no aumento do curso da suspensão, melhorando o conforto e diminuindo a segurança.

Varenius e o conhecimento matemático do século XVII

Neste artigo, discutimos o contexto do desenvolvimento da Geografia que, no século XVII, liberou-se do seu papel nas diferentes fés cristãs, bem como a importância da cisão dos Protestantes, em Luteranos e Calvinistas, para o processo de secularização, e o conseguinte estabelecimento da Geografia como ciência moderna. Analisamos a contribuição fundamental do luterano Bernhard Varen, cuja obra Geografia Geral apresenta o paradigma dessa nova ciência. Naquela época, a Geografia era considerada um ramo da matemática, e esta obra nos dá indícios sobre notações e conceitos matemáticos utilizados naquele século. Analisamos, particularmente, o uso da notação decimal de números não inteiros e algumas aplicações de conceitos trigonométricos, comparando a edição original com as principais reedições desta obra.

Cafeicultura científica globalizada e as montanhas capixabas: a produção de caféarábica nas regiões do Caparaó e Serrana do Espírito Santo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

A produção dos signos numa estrutura social antagônica

A partir de objeções às proposições de Mikhail BAKHTIN (ou V.N. VOLOCHINOV) sobre a produção da linguagem e do discurso literário no interior das relações sociais de produção, sugere-se a aplicação da semiótica peirceana, devidamente criticada para a análise da produção dos signos no nível da representação da consciência. Pretende-se com isto considerar o signo em toda a sua extensão, e não reduzido ao mero domínio do simbólico, e tornar mais claro o lugar e o papel das diversas formas ideológicas no interior da praxis.

BOUSSINESQ-TYPE SYSTEM OF EQUATIONS IN THE BENARD-MARANGONI SYSTEM

A system of coupled evolution equations for the bulk velocity and the surface displacement is found to govern the long-wavelength perturbations in a Benard-Marangoni system. This system of equations, involving nonlinearity, dispersion, and dissipation, is a generalization of the usual Boussinesq system.

Podolsky's higher-order electromagnetism from first principles

Podolsky's higher-order field equations are obtained by generalizing the laws of Podolsky's electrostatics, which follow from Coulomb's generalized law and superposition, to be consistent with special relativity. In addition, it is necessary to take into account the independence of the observed charge of a particle on its speed. It is also shown that the gauge-independent term concerning the Feynman propagator for Podolsky's generalized electrodynamics has a good ultraviolet behaviour at the expense of a negative metric massive ghost which, contrary to what is currently assumed in the literature, is non-tachyonic. A brief discussion on Podolsky's characteristic length is presented as well.