Tuning solid acid catalysts for glucose conversion to platform chemicals

Worldwide concern over dwindling fossil fuel reserves and impact of CO2 emissions on climate change means there is an urgent need to reduce our dependence on oil based sources of fuels and chemicals. The direct conversion of lignocellulosic derived glucose to 5-Hydroxymethylfurfural (5-HMF) is an attractive process for the production of chemicals and fuels but requires a bi-functional catalyst with acid-base or Lewis-Brönsted sites which can operate efficiently in the aqueous phase. While conventionally viewed as a superacid, the potential for tuning the acid strength in SO4/ZrO2 and potential for coupling bi-functional ZrO2-SO4/ZrO2 sites at low sulfate contents have been overlooked. Our previous work has shown effective tuning of the acid strength in SO4/ZrO2 can be used to direct selectivity in terpene isomerisation thus we rationalised control over HMF selectivity could achieved in a similar fashion. Here we report on a systematic study of the impact of acid properties of SO4/ZrO2 catalysts on the conversion of C6 sugars to 5-HMF in aqueous media and correlate the surface acid-base properties with glucose isomerisation and dehydration capabilities.

Multi-wavelength regeneration of differentially phase-encoded signals using phase sensitive amplification

We summarize the results of our recent demonstration of the first multi-channel regenerator for phase encoded signals. By developing a novel inline phase sensitive amplification scheme simultaneous suppression of deterministic phase distortion on two independent 42.66 Gbit/s DPSK modulated signal wavelengths was achieved. © 2012 SEE.

Wavelength division multiplexing at 2μm

This paper shows, for the first time, the implementation of a WDM subsystem at the 2μm wavelength window with mixed formats. Three wavelength channels were directly modulated with BPSK Fast-OFDM at 5Gbit/s per channel, with a fourth channel NRZ-OOK externally modulated at 8.5Gbit/s giving a total capacity in excess of 20 Gbit/s. © 2012 OSA.

Fiber Bragg grating Fabry-Perot structures under loading and their applications in switchable multi-wavelength lasers

Characteristics of fiber Bragg grating based Fabry-Perot (FBG-FP) structures under transversal loading are investigated. A novel switchable multi-wavelength fiber laser employing loaded FBG-FP is also demonstrated. © 2012 OSA.

Optimal duty cycle and asymmetric VSB filtering in a wavelength allocated DWDM CS-RZ transmission

Impact of duty cycle on the optimisation of ultra-narrow VSB filtering in wavelength allocated CS-RZ Nx40Gbit/s DWDM transmission is investigated. A feasibility has been confirmed of over 600 km with 0.64 bit/s/Hz spectral efficiency.

A nonreciprocal wavelength-interleaving bidirectional coherent fiber transversal filter

A bidirectional nonreciprocal wavelength-interleaving filter based on an optically coherent high birefringence fiber transversal filter structure is demonstrated. Stable, low loss operation is achieved with reconfigurable transfer characteristics for interleaved channel spacing of 0.8 nm with >30 dB isolation and ultra-low chromatic dispersion.

Actively mode-locked tunable dual-wavelength erbium-doped fibre laser

Abstract—We report an actively mode-locked tunable dual-wavelength erbium-doped fiber laser that uses parallel amplifiers in order to minimize gain cross-saturation effects. We obtain extremely stable, room-temperature dual-wavelength operation at a modulator drive frequency of 1035.38 MHz (corresponding pulsewidths of 115 and 130 ps). Furthermore, we can independently tune the power and wavelength of each lasing output signal without affecting overall output stability. In particular, we achieve a wavelength separation as narrow as 0.3 nm.

Stable dual-wavelength oscillation of an Er-doped fiber ring laser at room temperature

We propose a simple Er-doped fiber laser configuration for achieving stable dual-wavelength oscillation at room temperature, in which a high birefringence fiber Bragg grating was used as the wavelength-selective component. Stable dual-wavelength oscillation at room temperature with a wavelength spacing of 0.23 nm and mutually orthogonal polarization stages was achieved by utilizing the polarization hole-burning effect. An amplitude variation of less than 0.7 dB over an 80 s period was obtained for both wavelengths.

Stable dual-wavelength oscillation of an erbium-doped fiber ring laser at room temperature

We propose a simple Er-doped fiber laser configuration for achieving stable dual-wavelength oscillation at room temperature, in which a high birefringence fiber Bragg grating was used as the wavelength-selective component. Stable dual-wavelength oscillation at room temperature with a wavelength spacing of 0.23nm and mutually orthogonal polarisation states was achieved by utilising the polarisation hole burning effect. An amplitude variation of less than 0.7dB over 80s period was obtained for both wavelengths.

Resonant cavity time-division-multiplexed fiber Bragg grating sensor interrogator

The first resonant-cavity time-division-multiplexed (TDM) fiber Bragg grating sensor interrogation system is reported. This novel design uses a pulsed semiconductor optical amplifier in a cyclic manner to function as the optical source, amplifier, and modulator. Compatible with a range of standard wavelength detection techniques, this optically gated TDM system allows interrogation of low reflectivity "commodity" sensors spaced just 2 m apart, using a single active component. Results demonstrate an exceptional optical signal-to-noise ratio of 36 dB, a peak signal power of over +7 dBm, and no measurable crosstalk between sensors. Temperature tuning shows that the system is fully stable with a highly linear response. © 2004 IEEE.

Improved WDM performance of a fibre optical parametric amplifier using Raman-assisted pumping

We experimentally demonstrate a Raman-Assisted Fibre Optical Parametric Amplifier (RA-FOPA) with 20dB net gain using wavelength division multiplexed signals. We report amplification of 10×58Gb/s 100GHz-spaced QPSK signals and show that by appropriate tuning of the parametric pump power and frequency, gain improvement of up to 5dB can be achieved for the RA-FOPA compared with combined individual contributions from the parametric and Raman pumps. We compare the RAFOPA with an equivalent-gain conventional FOPA and find that four-wave mixing crosstalk is substantially reduced by up to 5.8 ± 0.4dB using the RA-FOPA. Worst-case performance penalty of the RA-FOPA is found to be only 1.0 ± 0.2dB over all measured OSNRs, frequencies and input powers, making it an attractive proposal for future communications systems.

Switchable dual-wavelength Q-switched and mode-locked fiber lasers using a large-angle tilted fiber grating

We proposed and demonstrated pulsed fiber lasers Q-switched and mode-locked by using a large-angle tilted fiber grating, for the first time to our best knowledge. Owing to the unique polarization properties of the large-angle tilted fiber grating (LA-TFG), i.e. polarization-dependent loss and polarization-mode splitting, switchable dual-wavelength Q-switched and mode-locked pulses have been achieved with short and long cavities, respectively. For the mode-locking case, the laser was under the operation of nanosecond rectangular pulses, due to the peak-power clamping effect. With the increasing pump power, the durations of both single-and dual-wavelength rectangular pulses increase. It was also found that each filtered wavelength of the dual-wavelength rectangular pulse corresponds to an individual nanosecond rectangular pulse by employing a tunable bandpass filter.

Colour management of InGaN/GaN based monolithic two-wavelength LEDs

The recent advancement in the growth technology of InGaN/GaN has decently positioned InGaN based white LEDs to leap into the area of general or daily lighting. Monolithic white LEDs with multiple QWs were previously demonstrated by Damilano et al. [1] in 2001. However, there are several challenges yet to be overcome for InGaN based monolithic white LEDs to establish themselves as an alternative to other day-to-day lighting sources [2,3]. Alongside the key characteristics of luminous efficacy and EQE, colour rendering index (CRI) and correlated colour temperature (CCT) are important characteristics for these structures [2,4]. Investigated monolithic white structures were similar to that described in [5] and contained blue and green InGaN multiple QWs without short-period superlattice between them and emitting at 440 nm and 530 nm, respectively. The electroluminescence (EL) measurements were done in the CW and pulse current modes. An integration sphere (Labsphere “CDS 600” spectrometer) and a pulse generator (Agilent 8114A) were used to perform the measurements. The CCT and Green/Blue radiant flux ratio were investigated at extended operation currents from 100mA to 2A using current pulses from 100ns to 100μs with a duty cycle varying from 1% to 95%. The strong dependence of the CCT on the duty cycle value, with the CCT value decreasing by more than three times at high duty cycle values (shown at the 300 mA pulse operation current) was demonstrated (Fig. 1). The pulse width variation seems to have a negligible effect on the CCT (Fig. 1). To account for the joule heating, a duty cycle more than 1% was considered as an overheated mode. For the 1% duty cycle it was demonstrated that the CCT was tuneable in three times by modulating input current and pulse width (Fig. 2). It has also been demonstrated that there is a possibility of keeping luminous flux independent of pulse width variation for a constant value of current pulse (Fig. 3).

Wide wavelength selectable all-fiber thulium doped fiber laser between 1925 nm and 2200 nm

We demonstrate an all-fiber Tm3+-doped silica fiber laser operating at a wide selectable wavelength range by using different fiber Bragg gratings (FBGs) as wavelength selection elements. With a specifically designed high reflective (HR) FBG and the fiber end as an output coupler, the lasing in the range from 1975 nm to 2150 nm with slope efficiency of >30% can be achieved. By employing a low reflective (LR) FBG as the output coupler, the obtainable wavelengths were extended to the range between 1925 nm and 2200 nm which is the reported longest wavelength from the Tm3+-doped silica fiber lasers. Furthermore, by employing a FBG array in the laser cavity and inducing bend loss between adjacent FBGs in the array, six switchable lasing wavelengths were achieved. © 2014 Optical Society of America.

Single polarization, dual wavelength fiber laser based on a 3-stage all fiber lyot filter

We have demonstrated a switchable dual wavelength fiber ring laser with a high degree of polarization output by using an intracavity 3-stage all fiber Lyot filter. The filter is formed by concatenating four 45° tilted fiber gratings separated by polarization maintaining fibers with a length ratio of 1:2:4 (20, 40, and 80 cm), giving a compact integrated configuration with reduced bandwidth. Switchable dual wavelength or single wavelength output at 1533.5 and 1563.3 nm has been achieved. The output lasing is considerably stable owing to the in-phase mode-selecting function of the multistage Lyot filter, and has a very high degree of polarization higher than 99.9%. © 1989-2012 IEEE.