519 resultados para voltametria cíclica
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Pós-graduação em Química - IQ
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Pós-graduação em Química - IQ
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This paper aimed to study the treatability of rainwater collected in Rio Claro, SP, using natural coagulant tannin based. The tannin was compared with other too primary coagulants, namely ferric chloride and corn starch. Assays were performed in laboratory scale using equipment known as Jarteste and aimed to study the conditions most suitable dosage and coagulation pH. First tests were conducted to compare the coagulating and determination of the conditions to be used in the following tests, taking as a criterion the greatest efficiency for water treatment. Also performed were performed tests to construct the tannin coagulation diagram, using the optimal concentration found in the previous phase, by varying the dosage of coagulant and the pH of clotting in order to determine the isoefficiency regions for apparent color and turbidity. Finally, tests were performed cyclically filtration with filter paper. Preliminary tests indicated that the vegetable tannin concentration 3% (m/m) from the commercial solution was presented the best set of results (84.3% removal of apparent color and 82.51% removal of turbidity) compared to ferric chloride (66.25% removal efficiency and apparent color of turbidity 67.82%) and starch (73.68% removal efficiency apparent color and turbidity to 67.19%). The coagulation diagrams indicate that the best region to work with vegetable tannin 3% is where the coagulant dosage ranges from 15 mg/L to about 37.5 mg/L and coagulation pH ranging from about 6.5 to 7.5. The cyclic filtration showed to be not efficient for the best dosage of coagulant, due to the process of clogging of the filter paper, but proved to be efficient for other dosages. Thus, for the waters studied, the results indicate that the natural coagulant based tannin is an alternative to conventional coagulants, possessing benefits of technical and environmental
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Pós-graduação em Cirurgia Veterinária - FCAV
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Many structures and mechanical equipment requires a union member, and the screw is one of the most used, the cost is low, it is versatile and easy to find on the market. The resulting pre-load assembly torque associated with the cyclical external load has great influence, so it will be studied carefully. This study analyzed some of these factors, as the format of nuts, and the washer material when they are incompatible with the bolt material can cause a reduction in life of the joint fatigue
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Pós-graduação em Engenharia Mecânica - FEG
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Métodos comparativos foram desenvolvidos para detectar e quantificar o corante solvente azul 14 (SA-14) em amostras de combustíveis. O método eletroanalítico foi baseado na técnica de voltametria de onda quadrada (VOQ) com detecção em +0,60 V vs. Ag/AgCl sobre o eletrodo de carbono vítreo, usando tampão Britton-Robinson e N, N-dimetilformamida (1:1, v/v) como eletrólito suporte. Para metodologia, envolvendo a cromatografia líquida de alta performance (CLAE) foi empregada uma fase móvel composta de acetonitrila e cloreto de lítio (85:15, v/v) e a detecção eletroquímica foi realizada em um potencial de oxidação em +0,65 V vs. Ag/AgCl. Sob as melhores condições de trabalho curvas de calibração foram obtidas, para ambos os métodos, as quais foram lineares na faixa de concentração de 5,0×10 -7 a 6,0×10 -6 mol L-1 (VOQ) e 8,0×10 -8 a 3,0×10 -6 mol L-1 (CLAE). Os métodos foram aplicados para quantificar o corante em amostras de álcool e querosene após um simples processo de extração em fase sólida com resultados de recuperação satisfatórios.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Pós-graduação em Química - IQ
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Pós-graduação em Ciência dos Materiais - FEIS
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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The framework of this study was to comprehend the specific conditions surrounding the incorporation and political-economical consolidation of the state of Mato Grosso Sul to the national scenario, during the cyclic evolution of the capitalistic system as well as the role of Campo Grande in this process. The origin and evolution of Campo Grande were analyzed in the context of possible relations between urbanization, regional development and the integration of the state in the national scope. In this approach, several theoretical compatible formulations were considered as to systemic view of reality, from the complex and dynamic point of view. This implies a multi scale reasoning, associating spatial dimension to the historical one, in a theoretical- methodological effort of comprehend the logic between the general and the specific. It was possible to verity peculiarities attributed to Mato Grosso do Sul in the general laws of the capitalistic system, and instances capable of explaning the local effects of the intervention of industrial economy in the dynamic of the process analysed since colonial times, as well as the role of Campo Grande in this process, especially in relation to the economical integration of the state territory to the rest of the nation.
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Pós-graduação em Química - IBILCE