983 resultados para pH-zone-refining counter-current chromatography
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Tese de doutoramento, Sociologia (Sociologia da Família, Juventude e das Relações do Género), Universidade de Lisboa, Instituto de Ciências Sociais, 2016
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Russian gas industry: The current condition of the gas industry is one of the most crucial factors influencing the Russian state·s functioning, internal situation and international position. Not only is gas the principal energy resource in Russia, it also subsidises other sectors of the economy. Status of the main European gas exporter strengthens also Russia's importance in the international arena. New regional in-security: Ten years have passed since the Central Asian states declared their independence, but their relationship with Russia still remains close, and the latter treats them as its exclusive zone of influence. A crucial reason for keeping Central Asia within the orbit of Moscow·s influence is the fact that Russia exercises control over the most important transport routes out of the region of raw materials for the power industry, on which the economic development of Asia depends on. But this is the only manifestation of Central Asia·s economic dependence on Russia. Moscow lacks solid economic instruments (i.e. investment input or power industry dependence) to shape the situation in the region. Caspian oil and gas: Caspian stocks of energy resources are not, and most probably will not be, of any great significance on the world scale. Nevertheless it is the Caspian region which will have the opportunity to become an oil exporter which will reduce the dependence of the European countries on Arabian oil, and which will guarantee Russia the quantities of gas which are indispensable both for meeting its internal demands and for maintaining its current level of export. For Azerbaijan, Kazakhstan and Turkmenistan, the confirmation of the existence of successive oil strata is not only an opportunity to increase income, but also an additional bargaining chip in the game for the future of the whole region. The stake in this game is the opportunity to limit the economic, and by extension the political influences of Russia in the region.
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This paper examines the main EU-level initiatives that have been put forward in the weeks following the attacks in Paris in January 2015, which will be discussed in the informal European Council meeting of 12 February 2015. It argues that a majority of these proposals predated the Paris shootings and had until that point proved contentious as regards their efficacy, legitimacy and lawfulness. The paper finds that EU counterterrorism responses raise two fundamental challenges: A first challenge is posed to the freedom of movement, Schengen and EU citizenship. Priority is being given to the expanded use of large-scale surveillance and systematic monitoring of all travellers including EU citizens, which stands in contravention of Schengen and the free movement principle. A second challenge concerns EU democratic rule of law. Current pressures calling for the adoption of measures such as the EU Passenger Name Record challenge the scrutiny roles held by the European Parliament and the Court of Justice of the EU on counterterrorism measures in a post-Lisbon Treaty setting. The paper proposes that the EU adopts a new European Agenda on Security and Liberty based on an EU security (criminal justice-led) cooperation model that is firmly anchored in current EU legal principles and rule of law standards. This model would call for ‘less is more’ concerning the use, processing and retention of data by police and intelligence communities. Instead, it would pursue better and more accurate use of data meeting the quality standards of evidence in criminal judicial proceedings.
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This paper examines the EU’s counter-terrorism policies responding to the Paris attacks of 13 November 2015. It argues that these events call for a re-think of the current information-sharing and preventive-justice model guiding the EU’s counter-terrorism tools, along with security agencies such as Europol and Eurojust. Priority should be given to independently evaluating ‘what has worked’ and ‘what has not’ when it comes to police and criminal justice cooperation in the Union. Current EU counter-terrorism policies face two challenges: one is related to their efficiency and other concerns their legality. ‘More data’ without the necessary human resources, more effective cross-border operational cooperation and more trust between the law enforcement authorities of EU member states is not an efficient policy response. Large-scale surveillance and preventive justice techniques are also incompatible with the legal and judicial standards developed by the Court of Justice of the EU. The EU can bring further added value first, by boosting traditional policing and criminal justice cooperation to fight terrorism; second, by re-directing EU agencies’ competences towards more coordination and support in cross-border operational cooperation and joint investigations, subject to greater accountability checks (Europol and Eurojust +); and third, by improving the use of policy measures following a criminal justice-led cooperation model focused on improving cross-border joint investigations and the use of information that meets the quality standards of ‘evidence’ in criminal judicial proceedings. Any EU and national counter-terrorism policies must not undermine democratic rule of law, fundamental rights or the EU’s founding constitutional principles, such as the free movement of persons and the Schengen system. Otherwise, these policies will defeat their purpose by generating more insecurity, instability, mistrust and legal uncertainty for all.
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We present sedimentary geochemical data and in situ benthic flux measurements of dissolved inorganic nitrogen (DIN: NO3-, NO2-, NH4+) and oxygen (O2) from 7 sites with variable sand content along 18°N offshore Mauritania (NW Africa). Bottom water O2 concentrations at the shallowest station were hypoxic (42 µM) and increased to 125 µM at the deepest site (1113 m). Total oxygen uptake rates were highest on the shelf (-10.3 mmol O2 /m2 d) and decreased quasi-exponentially with water depth to -3.2 mmol O2 /m2 d. Average denitrification rates estimated from a flux balance decreased with water depth from 2.2 to 0.2 mmol N /m2 d. Overall, the sediments acted as net sink for DIN. Observed increases in delta 15NNO3 and delta 18ONO3 in the benthic chamber deployed on the shelf, characterized by muddy sand, were used to calculate apparent benthic nitrate fractionation factors of 8.0 pro mille (15epsilon app) and 14.1 pro mille (18epsilon app). Measurements of delta 15NNO2 further demonstrated that the sediments acted as a source of 15N depleted NO2-. These observations were analyzed using an isotope box model that considered denitrification and nitrification of NH4+ and NO2-. The principal findings were that (i) net benthic 14N/15N fractionation (epsilon DEN) was 12.9 ± 1.7pro mille, (ii) inverse fractionation during nitrite oxidation leads to an efflux of isotopically light NO2- (-22 ± 1.9 pro mille), and (iii) direct coupling between nitrification and denitrification in the sediment is negligible. Previously reported epsilon DEN for fine-grained sediments are much lower (4-8 pro mille). We speculate that high benthic nitrate fractionation is driven by a combination of enhanced porewater-seawater exchange in permeable sediments and the hypoxic, high productivity environment. Although not without uncertainties, the results presented could have important implications for understanding the current state of the marine N cycle.
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The effect of volcanic activity on submarine hydrothermal systems has been well documented along fast- and intermediate-spreading centers but not from slow-spreading ridges. Indeed, volcanic eruptions are expected to be rare on slow-spreading axes. Here we report the presence of hydrothermal venting associated with extremely fresh lava flows at an elevated, apparently magmatically robust segment center on the slow-spreading southern Mid-Atlantic Ridge near 5°S. Three high-temperature vent fields have been recognized so far over a strike length of less than 2 km with two fields venting phase-separated, vapor-type fluids. Exit temperatures at one of the fields reach up to 407°C, at conditions of the critical point of seawater, the highest temperatures ever recorded from the seafloor. Fluid and vent field characteristics show a large variability between the vent fields, a variation that is not expected within such a limited area. We conclude from mineralogical investigations of hydrothermal precipitates that vent-fluid compositions have evolved recently from relatively oxidizing to more reducing conditions, a shift that could also be related to renewed magmatic activity in the area. Current high exit temperatures, reducing conditions, low silica contents, and high hydrogen contents in the fluids of two vent sites are consistent with a shallow magmatic source, probably related to a young volcanic eruption event nearby, in which basaltic magma is actively crystallizing. This is the first reported evidence for direct magmatic-hydrothermal interaction on a slow-spreading mid-ocean ridge.
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Estimates of summer sea surface temperatures (SSSTs) derived from planktic foraminiferal associations using the Modern Analog Technique and combined with isotopic analyses and determination of ice-rafted debris, mirror the Pleistocene evolution of the planktic Subantarctic surface waters in the Atlantic Ocean. The SSSTs indicate that the isotherms that define the modern polar front zone and Subantarctic front, were located at more northerly latitudes (up to 7°) during most of the investigated period, which covers the past 550 kyr. Exceptions are during climatic optima in the early Holocene, at marine isotope stages (MIS) 5.5, 7.1, 7.5, 9.3, and presumably during MIS 11.3 when SSSTs exceeded modern values by 1 -5°C. The close similarity between the SSST and the Vostok temperature indicates strong regional temperature correlation. Both records show that MIS 9.3 was the warmest period during the last 420 kyr whereas SSSTs obtained for MIS 11.3 are overestimated due to strong carbonate dissolution. Spectral analysis corroborates that the initiation of warming in southern high latitudes heralds the start of deglaciation on the Northern Hemisphere.
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Soil degradation threatens agricultural production and food security in Sub-Saharan Africa. In the coming decades, soil degradation, in particular soil erosion, will become worse through the expansion of agriculture into savannah and forest and changes in climate. This study aims to improve the understanding of how land use and climate change affect the hydrological cycle and soil erosion rates at the catchment scale. We used the semi-distributed, time-continuous erosion model SWAT (Soil Water Assessment Tool) to quantify runoff processes and sheet and rill erosion in the Upper Ouémé River catchment (14500 km**2, Central Benin) for the period 1998-2005. We could then evaluate a range of land use and climate change scenarios with the SWAT model for the period 2001-2050 using spatial data from the land use model CLUE-S and the regional climate model REMO. Field investigations were performed to parameterise a soil map, to measure suspended sediment concentrations for model calibration and validation and to characterise erosion forms, degraded agricultural fields and soil conservation practices. Modelling results reveal current "hotspots" of soil erosion in the north-western, eastern and north-eastern parts of the Upper Ouémé catchment. As a consequence of rapid expansion of agricultural areas triggered by high population growth (partially caused by migration) and resulting increases in surface runoff and topsoil erosion, the mean sediment yield in the Upper Ouémé River outlet is expected to increase by 42 to 95% by 2025, depending on the land use scenario. In contrast, changes in climate variables led to decreases in sediment yield of 5 to 14% in 2001-2025 and 17 to 24% in 2026-2050. Combined scenarios showed the dominance of land use change leading to changes in mean sediment yield of -2 to +31% in 2001-2025. Scenario results vary considerably within the catchment. Current "hotspots" of soil erosion will aggravate, and a new "hotspot" will appear in the southern part of the catchment. Although only small parts of the Upper Ouémé catchment belong to the most degraded zones in the country, sustainable soil and plant management practices should be promoted in the entire catchment. The results of this study can support planning of soil conservation activities in Benin.
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Thesis t.-p. attached to the cover of the issue reprinted from the Physical review, n.s., vol. xii, no. 4, October 1918.
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Reprinted from the Bulletin of the Bureau of standards, vol. 7, no. 3, 1911.
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"27 December 1985."
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"March 1970."
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"April 1954."
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"January 1966."
