(Table 1) Variation in chemical composition of Black Sea ctenophores depending on size

Data of chemical analysis of Black Sea ctenophore Mnemiopsis leidyi indicates that their body contains on average 5.28% carbon, 3.48% nitrogen, 0.11% phosphorus, and 0.03% silicon on dry weight. Mean ratios of the main biogenic elements in ctenophores is C:N=1.4, N:P=10.9, and C:P=32.2. Comparing concentration of the main biogenic elements in the surface layer with their concentrations in ctenophores it is concluded that mass development of M. leidyi has negative effect on the hydrochemical structure of the Black Sea.

(Table 3) Contents of phosphorus, iron, and manganese in various zones of Fe-Mn nodules from the Pacific radiolarian belt

Phosphorus content in the surface layer of bottom sediments varies from 0.07% to 0.73%. Clayey radiolarian and radiolarian clayey oozes contain 0.12% P, miopelagic clays 0.21% P, and sediments with high iron and manganese concentrations 0.46% P (average contents). Phosphorus content of iron-manganese nodules varies from 0.14% to 0.39%, average 0.19%. Correlation between phosphorus contents in nodules and surrounding sediments is indicated indirectly by P/Fe ratio. Phosphorus is non-uniformly distributed in some nodules and sometimes correlates with iron. Accumulation of phosphorus in iron-manganese nodules is governed by a degree of manganese predominance in ore components.

Hydrography and water chemistry of the open Mediterranean Sea

On a cruise from the eastern into western Mediterranean Sea in November/December 1978 a total of 126 samples were collected from 8 vertical profiles and 7 coastal stations for trace metal analysis. The sampling, processing and analysis was performed under strict "clean room" conditions. The concentration of the open-sea samples are close to oceanic results gathered under similar conditions. The grand averages from all profiles (± st. dev. of the individual samples) of 0.40 ± 0.16 µg/l Zn, 17.4 ± 7.4 ng/l Cd, 0.21 ± 0.07 µg/l Cu, 0.21 ± 0.13 µg/l Mn and 0.25 ± 0.09 µg/l Fe indicate that a "metal problem" does not exist in the open Mediterranean. A biologically mediated deplition in surface waters or correlation with nutrients have not been observed under the conditions established on this cruise. This is probably due top low primary production and seasonal advection processes prevailing in this sea. The data for manganese show generally higher values in the surface layer (0-75 m) than in deep waters. This could evidently proved in the nearshore profile indicating a terrigenous source for manganese.

Rare earth elements in bottom sediments and Fe-Mn nodules of the Black Sea

Distributions of rare earth element contents in surface layer bottom sediments, in vertical sediment section, and in Fe-Mn nodules of the Black Sea have been studied. An inverse relationship of rare earth element contents and CaCO3 contents has been found in the studied sediments. Fe-Mn nodules of the Black Sea do not concentrate rare earth elements, and their rare earth element composition differs from one of host sediments. It is concluded that rare earth elements are bound with clay minerals of bottom sediments.

Speciation of metals in bottom sediments from the south Kara Sea and Ob and Yenisei estuarine zones

Speciation of Fe, Mn, Zn, Cu, Co, Ni, Cr, Pb, and Cd was studied in 52 samples of bottom sediments collected during Cruise 49 of the R/V "Dmitry Mendeleev" to the estuaries of the Ob and Yenisei rivers and to the southwest Kara Sea. Immediately after sampling the samples were subjected to on-board consecutive extraction to separate metal species according to their modes of occurrence in the sediments: (1) adsorbed, (2) amorphous Fe-Mn hydroxides and related metals, (3) organic + sulfide, and (4) residual, or lithogenic. Atomic absorption spectroscopy of the extracts was carried out at a stationary laboratory. Distribution of Fe, Zn, Cu, Co, Ni, Cr, Pb, and Cd species is characterized by predominance of lithogenic or geochemically inert modes (70-95% of bulk contents), in which the metals are bound in terrigenous and clastic mineral particles and organic detritus. About half of total Mn amount and 15-30% of Zn and Cu are contained in geochemically mobile modes. Spatiotemporal variations in proportions of the metal species in the surface layer of sediments along sub-meridional sections and through vertical sections of bottom sediment cores testify that Mn and, to a lesser extent, Cu are the most sensitive to changes in sedimentation environment. The role of their geochemically mobile species notably increases under reducing conditions.

Subsurface time series of chlorophyll a at the PhytoCly station, Bay of Calvi, Corsica, Mediterranean Sea

The development of the winter-spring phytoplankton bloom was investigated in the Bay of Calvi (Corsica, Ligurian Sea, northwestern Mediterranean) in 1979, 1986, 1988, 1997 and 1998. A drastic reduction of phytoplankton biomass was evidenced over the last 2 decades, in relation to long-term changes in climatic and environmental conditions. Between 1979 and 1998, the monthly averaged chlorophyll a concentrations at 1 m decreased by about 80% during February, March and April. Simultaneously, major changes to hydrodynamic conditions include warmer water, overall decrease of salinity at 10 m depth, longer periods of bright sunshine and lower wind stress. The changes in environmental conditions were large enough to affect the vertical stability of the water column during the winter-spring period and to reduce nutrient replenishment of the surface layer prior to the usual period of phytoplankton growth. Until 1986, the main factor driving nutrient replenishment was the winter upward mixing of nutrient-rich deep waters, while the progressive reduction of mixing from 1988 induced nutrient limitation of surface waters in the last decade. The following hypotheses on changes in the development of the winter-spring phytoplankton bloom are made: (1) Until 1986, phytoplankton peaks took place in relatively high-nutrient waters and were diatom-dominated. (2) Between 1986 and 1988, decreasing Si availability led to Si limitation which caused a reduction in diatom abundance. This resulted in the disappearance of the diatom-dominated pulses and in lower phytoplankton biomass and was accompanied by a shift toward non-siliceous phytoplankton. (3) In 1988, 1997 and 1998, decreasing nitrate availability led to nitrate limitation, thus explaining the progressive reduction in non-siliceous phytoplankton biomass. Other, associated changes in benthos assemblages and ichthyofauna are documented. The conclusions from the Bay of Calvi are extended to the whole western Corsican coast. This confirms that the Mediterranean reacts rapidly to external perturbations, which are driven by climate change in that particular area.

(Table 1) Results of measurements of productive characteristics of phytoplankton and environmental parameters in the Barents Sea in September-October 1997

The described studies were carried out in the eastern part of the sea during the end of the summer seasonal succession from September 1 to October 12, 1997. Concentration of chlorophyll a in the surface layer varied from 0.09 to 1.24 mg/m**3; it tended to increase in the southern regions (<74°N). Primary production in the water column (P_p) varied from 24 to 214 mg C/m**2/day and was on average 91 mg C/m**2/day. The low level of P_p seems to result from combination of physical and chemical environmental factors unfavorable for photosynthesis (e.g. deficiency of nutrients and low values of insolation and temperature) and intensive grazing of phytoplankton by zooplankton. The lower boundary of the photosynthetic layer in open waters was located at depth 60-75 m; irradiance there was 0.1-0.5% of incident irradiance. In deep-water regions (>200 m) the subsurface maximum of chlorophyll occurred in the layer at 20-40 m; usually this maximum resulted in formation of additional maxima of primary production.

Part of the global DOC versus AOU (dissolved organic carbon/apparent oxygen utilization) data compilation, Azores-I

Temperate, transitional and subtropical waters of the remote Azores Front region east of Azores (24-40°N, 22-32°W) were sampled during three cruises conducted under increasing stratification conditions (April 1999, May 1997 and August 1998). Despite the temporal increase of surface temperature (by 5 °C) and stratification (by 2.1 1/min**2), as well as the thermocline shoaling (by ~15 m), dissolved organic carbon (DOC) and nitrogen (DON) in the surface layer were not significantly different for the early spring, late spring and summer periods, with average concentrations of 69±2 µM-C and 5.2±0.4 µM-N, respectively. The surface excess of semi-labile DOC, compared with the baseline DOC concentration in the deep ocean (47±2 µM-C), represents 33% of the bulk DOC concentration and as much as 85% of the TOC (=POC+DOC) excess. When compared with the winter baseline (56±2 µM-C), the seasonal surface DOC excess is 20% of the bulk DOC concentration and 87% of the seasonal TOC excess. These results confirm the major role played by DOC in the carbon cycle of surface waters of the Azores Front region. The total amount of bioreactive DOC transported from the temperate to the subtropical North Atlantic by the Ekman flux between March and December represents only ~15% of the average annual primary production, and ~15% and ~30% of the measured sinking POC flux+vertical DOC eddy diffusion during early spring and summer, respectively. Vertical eddy diffusion is 35% and 2% of the spring and summer sinking POC flux, respectively. On the other hand, DOC only contributes 13% to the local oxidation of organic matter in subsurface waters (between the pycnocline and 500 m) of the study region.

(Table 1) Permanent currents in the Campeche Bank area based on data of 24-hour stations

Data of twenty buoy stations were used to compile a new chart of permanent currents in the surface layer (10 m depth) for the region of the Yucatan shelf (Campeche Bank). It was found that vertical variations in direction of the currents are insignificant within the shallow plateau of the banks.