¿Estás en la onda? Aplicación de Praat a la enseñanza de la entonación

En este trabajo se pretende, por una parte, analizar cuáles son los métodos y programas existentes que se utilizan en la enseñanza de la entonación asistida por ordenador. Por otra parte, se pretende proporcionar algunas ideas para la aplicación del soporte visual en la enseñanza de la entonación

El valor de la impremta en el Grup Escolar Lluís Vives: una eina al servei de l"educació durant la II República i de la recuperació de la memòria pedagògica

Les revistes, els periòdics, els gravats i altres impresos que van sortir de les impremtes dels grups escolars del Patronat Escolar són el testimoni directe dels nens i les nenes que van viure una revolució pedagògica molt intensa en un període de temps molt reduït, ja que la guerra va estroncar el projecte educatiu. Concretament, analitzarem dues fonts documentals procedents del Grup Escolar Lluís Vives: d"una banda, el primer i únic número de la revista Vives, publicat el maig del 1936, i de l"altra, la carpeta de linogravats titulada Llibre de la natura. Ambdues publicacions permeten fer-nos una idea bastant ajustada de com era l"escola, quins eren els mètodes d"aprenentatge que se seguien i quins valors s"hi fomentaven. En definitiva, constitueixen un testimoni del dietari pedagògic de l"escola i ens permeten ratificar els idearis dels grups escolars del Patronat Escolar i de les escoles municipals de Barcelona durant la II República.

Voltametria de onda quadrada. Primeira parte: aspectos teóricos

The theoretical aspects of square wave voltammetry were discussed. Reversible, irreversible and quase-reversible electrode reactions were analyzed and the correlations between parameters like frequency, period, square wave potential and amplitude were showed. In this way, diagnostic relationships allow to characterize the electrode process. The analytical applications were discussed in base of the increment in the analytical response (current) due to the characteristics of the developed equations and the unique mode of collecting the electrode response, i.e., the direct and reverse signals. Finally, recent advances in the basic theory, as the applications to the hydrodynamic electrode and the ultramicroelectrode were also analyzed, and the multiple pulses square wave voltammetry was also introduced.

Estudo eletroanalítico do herbicida paraquat em soluções aquosas por voltametria de onda quadrada utilizando ultramicroeletrodos

The electrochemical behavior of paraquat on Pt, Au and carbon fiber ultramicroelectrodes were studied in laboratory samples by square wave voltammetry at high frequencies. The results showed two reversible peaks for paraquat reduction, in agreement to the literature data. The first peak was associated to the reduction of paraquat molecule in solution, with the further adsorption of the intermediate on the electrode surface. This adsorbed species undergoes to electroreduction in a reaction associated to the second voltammetric peak. The variation in pH and square wave parameters showed the best conditions to reduce paraquat as pH 5.0, frequency as high as 1000 s-1, scan increment of 2 mV and square wave amplitude of 50 mV. At such conditions, a variation of paraquat concentrations from 4.3 x 10-6 to 1.66 x 10-4 mol L-1 presented values for the detection limit equal to 3.9, 6.2 and 20.3 ppb on Pt, Au and carbon, respectively, at 1000 s-1. These values are quite below17 the allowed limit of paraquat in drinking water.

Dinamitzar sectors d'alt valor afegit evitarà crisis

Segons dades de Biocat, Catalunya té el 21% de les empreses del sector biotecnològic espanyol que mouen més de 15.000 milions d'euros i ocupen més de 22.000 persones. A final del 2011, en el sector hi constaven 1.156 empreses i entitats, incloent-hi centres de recerca. De les 481 empreses, un 84% són d'origen català. Una part important són d'R+D+I i d'àmbit en què les universitats i centres de recerca catalans estan més ben situats en els rànquings internacionals

Proposta de model per mesurar el valor percebut, la satisfacció i la lleialtat a les destinacions turístiques transfrontereres

L’objectiu d’aquesta treball és proposar un model de relacions causals i unes hipòtesis de treball sobre la lleialtat dels turistes a les destinacions transfrontereres en el context de la Unió Europea

Determinação voltamétrica de 4-clorofenol sobre o eletrodo de diamante dopado com boro utilizando a voltametria de onda quadrada

The anodic voltammetric behavior of 4-chlorophenol (4-CF) in aqueous solution has been studied on a Boron-doped diamond electrode using square wave voltammetry (SWV). After optimization of the experimental conditions, 4-CF was analyzed in pure and natural waters using a Britton-Robinson buffer with pH = 6.0 as the supporting electrolyte. Oxidation occurs at 0.80 V vs Ag/AgCl in a two-electron process controlled by adsorption of the species. The detection limits obtained were 6.4 µg L-1 in pure water and 21.5 µg L-1 for polluted water taken from a local creek, respectively. The combination of square wave voltammetry and diamond electrodes is an interesting and desirable alternative for analytical determinations.

Voltametria de onda quadrada. Segunda parte: aplicações

The aim of this work is to discuss some selected applications of square wave voltammetry published in the last five years. The applications focused here cover several electroanalytical fields such as: determination of pesticides; molecules with biological activity; metals and other environmental pollutants. Special attention is given to the work developed in the Grupo de Materiais Eletroquímicos e Métodos Eletroanalíticos - IQSC - USP concerning the utilization of square wave voltammetry, with different kinds of electrodes, for the determination of pesticides in natural waters and active principles in pharmaceutical formulations. The new methodology is simple, fast and sensitive when compared with the traditional ones such as chromatography and spectrophotometry. The satisfactory results obtained provide alternative procedures for the quality control of drugs and the monitoring of pesticides in natural environments.

Quantificação do pesticida diclorvos por voltametria de onda quadrada em águas puras e naturais

This work reports the use of square wave voltammetry (SWV) to analyse the electrochemical reduction of dichlorvos (2, 2-dichlorovinyl-dimethylphosphate) in spiked pure and natural waters. SWV measurements were carried out in 0.5 mol L-1 Na2SO4 aqueous solutions at pH 5, prepared with water originated from three different sources, namely, one sample of purified water and others from two urban creeks in São Carlos County. In all cases, two reduction peaks were observed, at potentials of -0.15 and -1.05 V vs Ag/AgCl, with both current and potential being dependent on pesticide concentration. This allowed the calculation of the following detection limits: 1.0, 2.5 and 3.0x10-8 mol L-1 for purified, Gregorio creek and Monjolinho creek waters, respectively, in a working range between 2.0x10-7 and 1.4x10-6 mol L-1. Recovery measurements found values higher than 80% in all cases, for an added concentration of 4.0 x 10-7 mol L-1 of dichlorvos in each solution. All analytical experiments were performed in triplicate and showed a standard deviation always less than 3%.

Determinação de manganês em material particulado atmosférico de ambientes de trabalho utilizando eletrodo de diamante dopado com boro e voltametria de onda quadrada com redissolução catódica

A boron-doped diamond electrode is used for determination of Mn(II) in atmospheric particulate matter by square wave cathodic stripping voltammetry. The analytical curve was linear for Mn(II) concentrations between 5.0 and 37.5 µg L-1, with quantification limit of 3.6 µg L-1. The precision was evaluated by the relative standard deviation, with values between 5.1% and 9.3%. The electrode is free of adsorption, minimizing memory effects. Samples collected in the workplace atmosphere of a foundry had Mn(II) concentrations between 0.4 and 4 µg m-3. No significant differences were observed between the proposed method and inductively coupled plasma optical emission spectroscopy.

Calidad de onda en el servicio eléctrico: causas y efectos de las perturbaciones que afectan la calidad de la electricidad

La qualitat d'ona en el servei elèctric

Monitorización y diagnostico de la calidad de onda : estrategias para la identificación y localización de faltas en sistemas de distribución eléctrica

Control de la qualitat de la Xarxa elèctrixa

Creando valor a través de las TIC: nuevos intermediarios

Este trabajo analiza cómo se puede crear valor a través del uso de las TIC. Para ello se utiliza el Modelo de creación de valor en e-business desarrollado por Amit y Zott (2001) y se aplica a una tipología de nuevos intermediarios que opera en el sector de los contenidos digitales: gregadores de noticias. Para lograr este objetivo, se ha realizado un estudio exploratorio y un estudio de casos a través de entrevistas personales con informadores estratégicos y un análisis del contenido de las páginas web de 56 empresas relacionadas con el sector y cuestionarios, principalmenteSe han analizado empresas de EEUU, Canadá, España, Francia, Alemania, Reino Unido y Suiza