地震层析成像与天山地区的壳幔深部结构研究

The Tien Shan is the most prominent intracontinental mountain belt on the earth. The active crustal deformation and earthquake activities provide an excellent place to study the continental geodynamics of intracontinental mountain belt. The studies of deep structures in crust and upper mantle are significantly meaningful for understanding the geological evolution and geodynamics of global intracontinental mountain belts. This dissertation focuses on the deep structures and geodynamics in the crust and upper mantle in the Tien Shan mountain belt. With the arrival time data from permanent and temporal seismic stations located in the western and central Tien Shan, using seismic travel time tomographic method, we inversed the P-wave velocity and Vp/Vs structures in the crust and uppermost mantle, the Pn and Sn velocities and Pn anisotropic structures in the uppermost mantle, and the P-wave velocity structures in the crust and mantle deep to 690km depth beneath the Tien Shan. The tomographic results suggest that the deep structures and geodynamics have significant impacts not only on the deformations and earthquake activities in the crust, but also on the mountain building, collision, and dynamics of the whole Tien Shan mountain belt. With the strongly collision and deformations in the crust, the 3-D P-wave velocity and Vp/Vs ratio structures are highly complex. The Pn and Sn velocities in the uppermost mantle beneath the Tien Shan, specially beneath the central Tien Shan, are significantly lower than the seismic wavespeed beneath geological stable regions. We infer that the hot upper mantle from the small-scale convection could elevate the temperature in the lower crust and uppermost mantle, and partially melt the materials in the lower crust. The observations of low P-wave and S-wave velocities, high Vp/Vs ratios near the Moho and the absences of earthquake activities in the lower crust are consistent with this inference. Based on teleseismic tomography images of the upper mantle beneath the Tien Shan, we infer that the lithosphere beneath the Tarim basin has subducted under the Tien Shan to depths as great as 500 km. The lithosphere beneath the Kazakh shield may have subducted to similar depths in the opposite direction, but the limited resolution of this data set makes this inference less certain. These images support the plate boundary model of converge for the Tien Shan, as the lithospheres to the north and south of the range both appear to behave as plates.

中祁连花岗岩年代学、地球化学及其构造意义

The Qilian Orogenic Belts had undergone very complicated evolutional histories and play an important role in understanding the tectonic evolutions of old terrains in northwestern China, in which granitiods formed during Proterozoic-early Mesozoic are widely outcropped. Detailed studies of these granitiods can shed some light on the tectonic evolution of this region. In this thesis, we have conducted geochronological and geochemical studies on eight selected granitic plutons to unravel their emplacement ages and petrogenesis. Furthermore, their tectonic implications were also discussed based on these results. In Neo-Proterozoic, our results suggest that two stages of magmatic activities were taken place in Central Qilian Block, GroupⅠ(750-790Ma) and Group Ⅱ(845－ 930Ma). In Neo-Paleozoic, most granitic plutons were emplaced from Ordovician to Devonian, whereas granitiods with Triassic ages have also been discovered in South Qilian Belt. Inherited zircons with old ages of 1.7Ga, 2.1Ga and 2.7Ga have also been obtained in our study. Geochemical studies suggest that the Proterzoic granites were produced under high pressures and low temperatures from metamorphosed protolith rocks with compostions from basic to intermediate. This implies that some hot sources were underplated beneath lithosophere via mantle-derived magmatism. In combination with regional geological data, we propose that the Cental Qilian block was an old arc terrene during Precambrian, and two stage granitoids were formed under a back-arc extensional setting. Granitic rocks emplaced in early Paleozoic belong to strong peraluminous S-type granites, which were derived from metagreywacke having strong relationships with collisional process. Together with previous data, our results indicate that granitoids in Qilian Orogenic Belt formed during early Paleozoic have different petrogenesis and emplaced ages, which reflect that Qilian Orogenic Belt had underwent complicated multi-stage subduction-collusional processes in early Paleozoic. On the other hand, granitic rocks in South Qilian Belt with Triassic ages were formed by subduction of East Kulun during early Paleozoic-Late Mesozoic, which represent another orogenic episode in the northern margin of Tibetan Plateau.

内蒙古白云鄂博地区元古宙构造-岩浆演化史与超大型REE-Nb-Fe矿床成因

Bayan Obo giant REE-Nb-Fe deposit in the northen margin of the North China Craton (NCC) is well known in the world for its abundant rare earth element resources. There is nearly one hundred year of studying history in substance component, chronology and geochemistry of the ore deposit, since the main ore body was found in 1927. However, there still exist remarkable divergences in genesis, mineralized age and material origin. Especially the REE enrichment mechanism leaves us a secret. Recent research shows that the Bayan Obo ore deposit likely resulted from the carbonatite magma activity, which is a favorable factor for REE accumulation. Based on the analysis of tectonic evolution history of north margin of NCC this thesis mainly discussed the formation background of cratonic margined rifts in Bayan Obo, and presented the analytical results of formation environment, intrusion age and deep origin of Proterozoic carbonatite magma. These research results can provide evidence for ore genesis. LA ICP-MS U-Pb dating on zircon shows that the Neoarchean basement was mainly composed of calc-alkaline TTG gneisses (2588±16Ma). The collision orogeny movement of the northen margin of the NCC between 2.0 Ga to 1.9 Ga brought the swarm of diorite-granodiotite magma (2023±16Ma) and intense regional metamorphism event (1906.3±7.7 Ma to 1892.7±6.7 Ma). In the sequent super continent break up background, intense metamorphic and deformed basement complex was uplifted to the surface suffered denudation, forming Mesoproterozoic Bayan Obo group in the contemporary continental margin rifts. The uplift of basement complex and formation of continental rifts were likely related with mantle plume activity. Evidence from petrological and geochemical data suggests that abundant alkaline-basic magma resulted from enhancement of continental breakup activity, that separated into carbonatite veins and mafic dykes by melt immiscibility mechanism, intruded in Bayan Obo margin rifts at the late stage of extension movement. Carbonatite veins can be divided into three main types by mineral composition: dolomite carbonatite, dolomite-calcite coexistent carbonatite and calcite carbonatite. Intrusion relationship between different types of carbonatite veins show that the calcite carbonatite veins were formed latter than the dolomite type as well as the coexistent type. Moreover, geochemical data also reveals successive and evolutive character between them. The content of REE increases together with the calcite minerals component. That is to say that REE gradually accumulated as the evolution of carbonatite magma. High precision Sm-Nd isochron data shows that the intrusion age of carbonatite veins was at 1319±48Ma. Moreover, the REE mineralization age in calcite carbonatite veins was around 1275±87Ma that is consistent with the intrusion age in error range. According to these data the abundant REE already existed in the carbonatite magma before intrusion and result in the earlier ore mineralization. The average age of mineralized dolomite was at 1353±100Ma, and the mineralization age of apatite in coarse grain dolomite was around 1329±150Ma. These data is consistent with carbonatite. Considering the coincident rare, trace element and isochron composition between them, it is presumed that mineralized dolomite was also the carbonatite intrusion and was the mainly factor for huge REE enrichment.

青藏高原东部长周期大地电磁测深研究

As a complement to conventional MT, Long-period Magnetotellurics (LMT) has been developed at low frequency for soundings of deep electric structures. Eastern Himalayan Syntaxis (EHS) and surrounding area is a key place for the study of dynamics of the uplift of Tibetan plateau. Experiments in the pioneer studies for EHS3D project showed that the study area shares an unusual low resistive crust and upper mantle. Conventional MT could not provide sufficient information about the deep structures of the study area that requested long period MT measurement to be complemented. This thesis presents the LMT studies in eastern Tibet along the EHS3D-3 Profile from Xiachayu to Yushu including data acquisition, processing, inversion and interpretation. The effective period of the measured LMT signals extend from 10s up to 30000s for the duration more than one week measurement. The resulting model shows that the LMT sounding coincides with the MT data in overlapped periods. Especially the induction arrows and tippers derived from LMT data provide more information about the base of the conductors beneath the plateau with higher resolution. Anomalous induction coefficients and 2-D model suggest extensive conductive bodies beneath Lhasa block and Qiangtang terrain which would be a possible evidence for partial melt and fluids at depth.

青藏高原东部电性结构特征及其构造意义

Eastern Himalayan Syntaxis (EHS) and its surroundings (eastern margin of Tibet) is one of the most complicated tectonic areas in the world. As the exhaust opening of the balanced materials of the Tibetan Plateau during the collision of Indan and Eurasian plates, the deep structure beneath EHS surrounding region is referred to as the key to the study of the dynamics of the plateau. EHS3D project, sponsored by NSFC, has been proposed to explore the deep electric features of the area. During the first stage of EHS3D(2006-2008), MT+LMT measurements have been conducted along two lines from Chayu to Qingshuihe (EHS3D-3) and Chayu to Ruoergai (EHS3D-2). This paper will discuss the MT models of EHS3D-3 line. By the data procrssing, including distortion analysis, Robust estimation and strike decomposition, rotated apparent resitivities and phases have been obtained for each station. Then conventional 2-D inversion algorithms (NLCG and RRI) were employed to produce 2-D models. The final preferred 2-D model suggests that the upper crust consists of resistive blocks while in mid-lower crust there are two extensive conductive bodies beneath Lhasa block and Qiangtang terrain respectively. Jinshajiang suture is a gradient belt and Bangong-Nujiang suture appear a conductive belt dipping to the north. . We concluded that the formation of the two conductive bodies attributed to the partial melt and fluids in the lower crust. The regional electric strike derived from decomposition analysis indicates that the crust and upper mantle move in different manners. The upper crust moves like slips of rigid blocks along major slip faults while the lower crust creeps as a flow in the conductive channels.

华北及周边地区层析成像研究

Our study deals with the high resolution body wave tomography in North china and adjacent areas(30°N-43°N，100°E-130°E), where earthquakes occurred many times in history and has a very complicated geological structure. 6870 events recorded at 273 digital seismic stations from CDSN during 1996－2002 and stations settled by Seislab of IGCAS in Bohai Bay area, including 1382 local earthquakes and 5488 teleseismic earthquakes are used in this study. In the data we used, the average number of received stations is greater than 5, the error of picking up direct arrival time is 0.1－0.5s. Before the inversion, we use Checkerboard method to confirm the reliability of result of Local events; use Restoring Resolution Test to confirm the reliability of result of teleseismic events. We also analyzed the effect of different parameters in the inversion. Based the analysis above, the model used in this paper is divided into small blocks with a dimension of 0.33°in the latitude and longitude directions and 5km、15km、30km in depth, and initial velocity model. Using pseudobending method to calculate the ray traveling path, LSQR algorithm to inverse, finally, we got the body velocity images below 25km and above 480km in this area using Joint- inversion with local events and teleseismic events. We made the conclusion at last: (1)at top zone of the south of Sichuan Basin , there exits low velocity anomalies, below 40km is the high velocity zone extend to 300km; (2) Above the 40km of Ordos block exits low velocity zone, while below 40km until 240km, the high velocity anomalies are interlaced by low velocity anomalies. Below 300km, the anomalies are unclear any more; (3) On the whole, the velocity structure below 400km on the mantle transition zone of Eastern China area shows its changes from low velocity to high velocity.

基于三重震相波形模拟研究亚洲东北部上地幔过渡带速度结构

Both the global and regional P wave tomographic studies have revealed significant deep structural heterogeneities in subduction zone regions. In particular, low-velocity anomalies have been observed beneath the descending high-velocity slabs in a number of subduction zones. The limited resolution at large depths and possible trade-off between the high and low velocities, however, make it difficult to substantiate this feature and evaluate the vertical extent of the low-velocity structure. From broadband waveform modeling of triplicated phases near the 660-km discontinuity for three deep events, we constrained both the P and SH wave velocity structures around the base of the upper mantle in northeast Asia. For the two events beneath the southern Kurile, the rays traveled through the lowermost transition zone and uppermost lower mantle under the descending Pacific slab. Our preferred models consistently suggest normal-to-lower P and significantly low SH velocities above and below the 660-km discontinuity extending to about 760-km depth compared with the global IASP91 model, corroborating previous observations for a slow structure underneath the slab. In contrast, both high P and SH velocity anomalies are shown in our preferred models for the Japan subduction zone region, likely reflecting the structural feature of a slab stagnant above the 660-km discontinuity. The velocity jumps across the 660-km discontinuity were found to be on average 4.5% and 7% for P and S waves under the south Kurile, and 3% and 6% under the Japan subduction zone. The respective velocity contrasts in the two regions are consistent with mineralogical models for colder slab interior and hotter under-slab areas. Based on mineral physics data, the depth-averaged ~1.5% P and ~2.5% SH velocity differences in the depth range of 560-760 km between the two regions could be primarily explained by a 350~450K temperature variation, although the presence of about 0.5wt%~1wt% water might also contribute to the subtle velocity variations near the base of the transition zone in the southern Kurile. From our modeling results, we speculate that the slow structure in the southern Kurile may be correlated to the low velocity zone observed previously around the 410-km discontinuity under Northern Honshu. Both are probably associated with a thermal anomaly rooted in the lower mantle beneath the subduction zone in northeast Asia.

山东莒南地区韧性剪切带的变形特征与形成演化

Ju Nan of Shandong province is located at southwest of Sulu UHP (ultrahigh-pressure) metamorphic terrane. It is composed of gneiss, paragneiss, eclogites, ultramafic rocks, marble and quartzite. A large ductile shear zone extends east-west has been found at the Zhubian, The south of Junan county. The Zhubian ductile shear zone is composed of high srain rock and mylonites. The mylonites fall into 3 types: Initial gneiss mylonite, mylonite and altramylonit.obvious lineation of penetration,foliation,S-Cfabrics,porphyroclasts,folds,irregularundulatory,extinction,subgrain boundary, dynamic recrystallization microstructure, core-mantle structure and are common in the ductile shear zone. Based on field work and microstructural analyse, a conclution is arrived: The ductile shear zone is an approximately SE trending faults. The Zhubian ductile shear zone formed at Ep ―Hb facies conditions which could be proved by deformaed and metamorphosed mineral aggregates, Deformation behavior, Ternary-feldspar geothermometry and so on. Zircon MC―ICP―MS U-Pb analysis is performed on the mylonite and have an average age ―835.9±13.9Ma, it’s the primary rocks formed age. The Zhubian ductile shear zone maybe formed at 224-242Ma.

内蒙古克什克腾旗小东沟斑岩型钼矿床的成矿作用

In this paper, the Xiaodonggou porphyry molybdenum deposit located in the Xarmoron molybdenum metallogenic belt is chose as the research area. We have analyzed the petrology of the Xiaodonggou pluton in detail and made chemical analysis of the major and trace elements, Rb-Sr and Sm-Nd isotope, common lead isotope and SHRIMP zircon U-Pb dating et al; in the other hand, we use the molybdenite to make common lead analysis and Re-Os isotopic dating. The Xiaodonggou pluton is rich in silicon, potass, zirconium, and low in REE. In addition, it has no minus Eu abnormity and show a isotopic composition high in εNd(t) and low in Sri, indicating its magma origining from the melting of juvenile thicken lower crust. In the meanwhile, it contained the features of high temperature, quick melting, quick segregation and quick emplacement. The common lead analysis of the pluton orthoclase and molybdenite show that the former transfer from orogen to mantle and the latter come from mantle, which is consistent to the molybdenite sulfur isotopic and quartz oxygen isotopic composition, demonstrating that the rock and ore-forming materials of deposit having different sources, magma from the lower crust mixing with mantle fluid. In plus, we use the physical experiments results of the water-magma reaction to explain the interaction of magma and mantle fluid. In the deep crust, these two systems uplifted in a immiscible state; when they reached low depth, the stream film between fluid-magma collapsed, and the magma was broken into small agglomerates by the fluid, then they mixed thoroughly. The SHRIMP zircon U-Pb dating gave a result of 142±2Ma and the molybdenite Re-Os dating result is 138.1±2.8Ma, corresponding to the big tectonic transition period of 140Ma, when the major stress field changing from south and north to west and east. At this time, the Da Hinggan ling ranges area was under an extensive background, underplating proceeded and mantle materials could add into the magmas forming in the lower crust. So, from the above analysis, we propose the following model for the Xiaodonggou porphyry molybdenum deposit: in the early Cretaceous period, the Da Hinggan ling ranges area was under a extensive background, the adding of mantle fluid containing ore materials into heated lower crust made it melting to produce magmas. Following more mantle fluid got into the magma room and urged the magma to segregate from the source quickly. The fluid and magma uplifted together, when they arrived at shallow depth, the fluid-magma became unstable and the latter was broken into many small agglomerates with fluid connecting them in the interspaces. Because of the H+, K+ and various elements existing in the fluid, it would reacted with the magma and the rock through alteration and ore minerals crystallized out, forming the Xiaodonggou porphyry deposit with disseminated mineralization phenomenon.

喜马拉雅西构造结区岩石圈演化三维有限元动力学数值模拟

The past three decades have seen numerous attempts to numerically model stress and strain patterns in the lithosphere of the Earth on both global and regional scales. This efforts have been indispensable in identifying the features we need to include in our endeavour to develop better models of our planet’s lithosphere and they have also raised our awareness for the many unresolved issue in the deep geodynamical issues that need to be addressed in the future. Nonetheless, in most models, the lithosphere is treated as a single layer with depth-averaged properties, and as the same distribution in the stress and strain fields, and as deforming under plane strain. All these above make a great hander for its reality and degree of recognition. As the beginning in this paper, some principal numerical models and results on the evolution of Tibetan plateau are reviewed and analyzed. Then, the geological and geophysical expedition on the Western Himalayan Syntaxis is briefly reviewed. Furthermore, we analysis the feature in deep geophysical field studies in this area and adjacent regions. Because, for most continents, stress models driven by plate boundary forces have successfully reproduced the main characteristics of the stress and strain field, we present a set of three-dimensional models of lithosphere system for a simplified geometry of the Western Himalayan Syntaxis area and its adjacent regions, where we try to match the first-order characteristics of the stress and strain fields of lithosphere since 10 Ma, and deformation and geodynamical evolution process in former 2Ma. Of course, the kinematic boundary conditions of the stress models driven by plate boundary forces were applied. The rheology plays a significant role in the lithospheric tectonics, which lead to different rheological parameters were used in different works although the have the same constitutive equations in models. So, in this paper we do not aim to produce all characteristics of the Western Himalayan Syntaxis areas’ stress and strain fields by the choices of various parameters, but rather the dynamic response between various rheological parameters and stress and strain fields. We have chosen to concentrate on the importance of rheology and lateral strength variations for lithospheric stress and strain patterns and use our findings to build a model of the Western Himalayan Syntaxis areas. In doing so, we want to go beyond purely elastic models or purely viscoelastic models. Compared the results of the crust viscosity in the Western Himalayan Syntaxis areas, we believed that, when various viscoelastic models are adopted, the selection of the coefficient of viscosity in the Western Syntaxis area has important influence on the its uplifts and evolutions. A wider uplift ranges and gently elevation was observed at the same time when a lower viscosity was used in our models, and vice versa. Data of stress magnitudes are not available, but it is clear that the stress levels must be at or below the failure threshold of rock under compression. Under these criteria, the calculation results show that the viscosity in the Western Syntaxis area should be smaller than 1023Pa.s When elastic model is adopted in relatively rigid Tarim basin, obvious changes are induced to the stress and strain fields of the whole Western Syntaxis area. We found that rigid block of lithosphere reduced stress levels within its interior and that, at the edges of such regions, stress orientation can change. Furthermore there is no evidence that such rigid regions act as stress barriers in that they shield areas in opposite sides of the structure from the influence of one another. In our models, the upper crustal material of the Western Syntaxis area does not turns to move westward. Whereas, because of the stress and strain fields have been decoupling at the interior of the lithosphere, we can get the results that the deep material must not move westward.

班公湖带多不杂超大型富金斑岩铜矿床的成岩成矿年代学、岩石学及高氧化岩浆¬流体-成矿作用

Duobuza copper deposit, newly discovered typical gold-rich porphyry copper deposit with superlarge potential, is located in the Tiegelong Mesozoic tectonic -magmatic arc of the southern edge of Qiangtang block and the northern margin of Bangonghu-Nujiang suture. Quartz diorite porphyrite and grandiorite porphyry, occurred in stock, are the main ore-bearing porphyries. As the emplacement of porphyry stock, a wide range of hydrothermal alteration has developed. Within the framework of the ore district, abundant hydrothermal magnetite developed, and the relationship between precipitation of copper and gold and hydrothermal magnetite seems much close. Correspondingly, a series of veinlets and network veinlets occurred in all alteration zones. Therefore, systematic research on such a superlarge high-grade Duobuza gold-rich porphyry copper deposit can fully revealed the metallogenic characteristics of gold-rich porphyry copper deposits in this region, establish metallogenetic model and prospecting criteria, and has important practical significance on the promotion of regional exploration. In addition, this research on it can enrich metallogenic theory of strong oxidation magma-fluid to gold-rich porphyry copper deposit, and will be helpful to understand the metallogenic characteristics in early of subduction of Gangdese arc stages and its entire evolution history of the Qinghai-Tibet Plateau, the temporal and spatial distribution of ore deposits and their geodynamics settings. Northern ore body of Duobuza copper deposit have been controlled with width (north-south) about 100 ~ 400 m, length (east-west) about 1400 m, dip of 200 °, angle of dip 65 °~ 80 °. And controlled resource amount is of 2.7 million tons Cu with grade 0.94% and 13 tons Au with 0.21g/tAu. Overall features of ore body are large scale, higher grade copper, gold-rich. Ore occurred in the body of granodiotite porphyry and quartz diorite porphyrite and its contact zone with wall rock. Through the detailed mapping and field work studies, some typies of alteration are identificated as follows: albitization, biotititation, sericitization, silication, epidotization, chloritization, carbonatization, illitization, kaolinization and so on. The range of alteration is more than 10km2. Wall alteration zone can be divided into potassic alteration, moderate argillization alteration, argillization, illite-hydromuscovite or propylitization from ore-bearing porphyry center outwards, but phyllic alteration has not well developed and only sericite-quartz veins occurred in local area. Moreover, micro-fracture is development in ore district , and correspondingly a series of veinlets are development as follows: biotite vein (EB type), K-feldspar-biotite-chalcopyrite-quartz vein, magnetite-antinolite-K-feldspar vein, quartz-chalcopyrite-magnetite veins (A-type), quartz-magnetite-biotite-K-feldspar vein, chalcopyrite veinlets in potassic alteration zone; (2) chalcopyrite occurring in the center vein–quartz vein (B type), chalcopyrite veinlets, chalcopyrite-gypsum vein in intermediate argillization alteration; (3) chalcopyrite- pyrite-quartz vein, pyrite-quartz vein, chalcopyrite-gypsum veins, quartz-gypsum- molybdenite-chalcopyrite vein in argillization alteration; (4) gypsum veins, quartz-(molybdenite)-chalcopyrite vein, quartz-pyrite vein, gypsum- chalcopyrite vein, potassium feldspar veinlets, Carbonate veins, quartz-magnetite veins in the wall rock. In short, various veins are very abundant within the framework of the ore district. The results of electronic probe microscopy analysis (EMPA) indicate that Albite (Ab 91.5~99.7%) occurred along the rim of plagioclase phenocryst and fracture, and respresents the earliest stages of alteration. K-feldspar (Or 75.1~96.9%) altered plagioclase phenocryst and matrix or formed secondary potassium feldspar veinlets. Secondary biotite occurred mainly in phenocryst, matrix and veinlets, belong to magnesium-rich biotite formed under the conditions of high-oxidation magma- hydrothermal. Chloritization developed in all alteration zones and alterd iron- magnesium minerals such as biotite and hornblende and then formed chlorite veinlets. As the temperature rises, Si in the tetrahedral site of chlorite decreased, and chlorite component evolved from diabantite to ripiolite. The consistent 280℃~360℃ of formation temperature hinted that chlorite formed on the same temperature range in all alteration zones. However, formation temperature range of chlorite from the gypsum-carbonate-chlorite vein was 190℃~220℃, and it may be the product of the latest stage of hydrothermal activity. The closely relationship between biotite and rutile indicate that most of rutiles are precipitated in the process of biotite alteration and recrystallization. In addition, the V2O3 concentration of rutile from ore body in Duobuza gold-rich porphyry copper deposit is >0.4％, indicate that V concentration in rutile has important significance on marking main ore body of porphyry copper deposit. Apatites from Duobuza deposit all are F-rich. And apatite in the wall rock contained low MnO content and relatively high FeO content, which may due to the basaltic composition of the wall rocks. The MnO in apatite from altered porphyry show a strong positive correlation with FeO. In addition, Cl/F ratio of apatite from wall rock was highest, followed by the potassic alteration zone and potassic alteration zone overprinted by moderate argillization alteration was the lowest. SO2 in Apatite are in the scope of 0 to 0.66%, biotite in the apatite has the highest SO2, followed by the potassic alteration zone, potassic alteration zone overprinted by moderate argillization alteration, and the lowest in the surrounding rocks, which may be caused by the decrease of oxygen fugacity of hydrothermal fluid and S exhaust by sulfide precipitation in potassic alteration. Magnetite in the wall rock have higher Cr2O3 and lower Al2O3 features compared with altered porphyry, this may be due to basalt wall rock generally has high Cr content. And magnetites have higher TiO2 content in potassic alteration than moderate argillization alteration overprinted by potassic alteration, argillization and wall rock, suggested that its formation temperature in potassic alteration was the highest among them. The ore minerals mainly are chalcopyrite and bornite, and Au contents of chalcopyrite, bornite, and pyrite are similar with chalcopyrite slightly higher. The Eu* negative anomaly of disseminated chalcopyrite was relatively lower than chalcopyrite in veinlets. Within a drill hole, the Eu* negative anomaly of disseminated chalcopyrite was gradually larger from bottom to top. Magnetite has the same distribution model, with obvious negative Eu* abnormal, and ΣREE in great changes. The gypsum has the highest ΣREE content and the obvious negative anomaly, and biotite obviously has the Eu* abnormal. Based on the petrographic and geochemical characteristics, five series of magmatic rocks can be broadly classified; they are volcanic rocks of the normal island arc, high-Nb basaltic rocks, adakites, altered porphyry and diorite. The Sr, Nd, Hf isotopes and geochemistry of various series of magmatic rock show that they may be the result of mixing between basic magma and various degrees of acid magma coming from lower crust melted by high temperature basic underplating from partial melting of the subduction sediment melt metasomatic mantle wedge. Furthermore S isotope and Pb isotope of the sulfide, ore-bearing porphyries and volcanic rocks indicated ore-forming source is the mantle wedge metasomatied by subduction sediment melt. Oxygen fugacity of magma estimated by Fe2O3/FeO of whole rock and zircon Ce4+/Ce3+ indicated that the oxidation of basalt-andesitic rocks is higher than ore-forming porphyry, and might imply high-oxidation characteristics of underplated basic magma. Its high oxidative mechanism is likely mantle sources metasomatied by subduction sediment magma, including water and Fe3+. And such high oxidation of basaltic magma is conducive to the mantle of sulfides in the effective access to melt. And the An component of dark part within plagioclase phenocryst zoning belong to bytownite (An 74%), and its may be a result of magma composition changes refreshment by basaltic magma injection. SHRIMP zircon U-Pb and LA-ICP-MS zircon U-Pb geochronology study showed that the intrusions and volcanic rocks from Duobuza porphyry copper deposit belong to early Cretaceous magma series (126~105Ma). The magma evolution series are as follows: the earliest diorite and diorite porphyrite → ore-bearing porphyry and barren grandiorite porphyry →basaltic andesite → diorite porphyrite → andesite → basaltic andesite, and magma component shows a evolution trend from intermediate to intermediate-acid to basic. Based on the field evidences, the formation age of high-Nb basalt may be the latest. The Ar-Ar geochronology of altered secondary biotite, K-feldspar and sericite shows that the main mineralization lasting a interval of about 4 Ma, the duration limit of whole magma-hydrothermal evolution of about 6 Ma, and possibly such a long duration limit may result in the formation of Duobuza super-large copper deposit. Moreover, tectonic diagram and trace element geochemistry of volcanic rocks and diorite from Duobuza porphyry copper deposit confirm that it formed in a continental margin arc environment. Zircon U-Pb age of volcanic rocks and porphyry fall in the range of 105~121Ma, and Duobuza porphyry copper deposit locating in the north of the Bangonghu- Nujiang suture zone, suggested that Neo-Tethys ocean still subducted northward at least early Cretaceous, and its closure time should be later than 105 Ma. Three major inclusion types and ten subtypes are distinguished from quartz phenocrysts and various quartz veins. Vapor generally coexisting with brine inclusions, suggest that fluid boiling may be the main ore-forming mechanism. Raman spectrums of fluid inclusions display that the content of vapor and liquid inclusion mainly contain water, and vapor occasionally contain a little CO2. In addition, the component of liquid inclusions mainly include Cl-, SO42-, Na+, K+, a small amount of Ca2+, F-; and Cl- and Na+ show good correlation. Vapor mainly contains water, a small amount of CO2, CH4 and C2H6 and so on. The daughter minerals identified by Laman spectroscopy and SEM include gypsum, chalcopyrite, halite, sylvite, rutile, potassium feldspar, Fe-Mn-chloride and other minerals, and ore-forming fluid belong to a complex hydrothermal system containing H2O-NaCl-KClFeCl2CaCl2. H and O isotopic analysis of quartz phenocryst, vein quartz, magnetite, chlorite and gypsum from all alteration zones show that the ore-forming fluid of Duobuza gold-rich porphyry copper deposit consisted mainly of magmatic water, without addition of meteric water. Duobuza gold-rich porphyry copper deposit formed by the primary magmatic fluid (600-950C), which has high oxidation, ultra-high salinity and metallogenic element-rich, exsolution direct from the magma, and it is representative of the typical orthomagmatic end member of the porphyry continuum. Moreover, the fluid evolution model of Duobuza gold-rich porphyry copper deposit has been established. Furthermore, two key factors for formation of large Au-rich porphyry copper deposit have been summed up, which are ore-forming fluids earlier separated from magma and high oxidation magma-mineralization fluid system.

荣成基底片麻岩原岩岩石成因及其构造意义

Extensive high to ultrahigh pressure metamorphic rocks are outcropped in the the Dabie-Sulu UHP orogenic belt. Disputes still exist about for protolith nature of metamorphic rocks, petrogenesis, tectonic setting, and influence on upper mantle during the Triassic deep subduction. In this study, a combined study of petrology, geochemistry, isotope geochemistry and zircon chronology was accomplished for high-grade gneisses in the basement of the ultrahigh-pressure metamorphic Rongcheng terrane to reveal protolith nature and petrogenesis of the gneisses and to disucss the magmatic succession along the northern margin of the Yangtze block in Neoproterozoic. Gneisses in the Rongcheng terrane are characterized by negative Nb, Ta, P and Ti anomalies, relatively low Sr/Y ratios and relatively high Ba/La, Ba/Nb and Ba/Zr ratios, mostly displaying geochemical affinity to Phanerozoic volcanic arc. Neoproterozoic protolith ages (0.7 ~ 0.8 Ga) and Paleoproterozoic average crustal residence time (1.92 ~ 2.21 Ga) favour a Yangtze affinity. The gneisses mostly display characteristics of enrichment of LREE, flat heavy rare earth elements (REE) patterns, moderately fractionation between LREE and HREE and slight negative or positive Eu anomalies, probably reflecting that melting took place in the middle to low crust (26 ~ 33 km), where amphibole fractionated from the melts and/or inherited from source material as major mineral phases in the source area. Sr-Nd isotopic composition of the gneisses supports this conclusion. According to εNd(t) and εHf(t) values, the gneisses can be divided into three groups. Gneisses of group I have the highest εNd(t) and εHf(t) values, corresponding to the range of -6 ~ -3 and -2.9 ~ 13.4, respectively. This suggests obvious influx of depleted mantle or juvenile crust in the formation of protoliths. Gneisses of group II have medium εNd(t) (-9 ~ -7) and εHf(t) values (-15.8 ~ -1.4), corresponding to relatively high TDM2(Nd) (1.99 ~ 2.31 Ga) and TDM2(Hf) (1.76 ~ 2.67 Ga) , respectively. This suggests these gneisses were formed by partial melting of Paleoproterozoic crust. Gneisses of group III have the lowest εNd(t) (-15 ~ -10) and εHf(t) values (-15.8 ~ -1.4), corresponding to the largest TDM2(Nd) (1.99 ~ 2.31 Ga) and TDM2(Hf) ( 1.76 ~ 2.67 Ga), respectively. This indicates that gneisses of group III were formed by remelting of Archean crustal material and further demonstrates existence of an Archean basement probably of the Yangtze affinity beneath the Rongcheng terrane. Gneisses of three groups have also certain different geochemical characteristics. Contents of REEs and trace elements reduce gradually from group I to group III. Zirconium saturation temperatures also show similar tendency. Compared to gneisses of group II and group III, gneisses of group I display geochemical feature similar to extensional tectonic setting, having relatively little influence by the source area. Therefore, geochemical characteristics for gneisses of group I can indictate that the protoliths of the Rongcheng gneisses formed in an extensional rifting tectonic setting. This conclusion is supported by the results of eclogites and gabbros previously reported in the Dabie-Sulu orogenic belt. Statistical results of the protolith ages of the Rongcheng gneisses show two age peaks around ~728 Ma and ~783 Ma with an about 50 Ma gap. Extensive magatism in abou 750 Ma along the northern margin of the Yangtze block can hardly be observed in the Rongcheng terrane. This phenomenon likely suggests discontinuous Neoproterozoic magmatism along the northern margin of the Yangtze block.

北山及邻区古生代-早中生代增生与碰撞大地构造格局

The Beishan orogenic collage locates at the triple-joint among Xinjiang, Gansu, and Inner Mongolia Provinces, at which the Siberian, Tarim and North China plates join together. It also occupies the central segment of the southern Central Asian Orogenic Belt (CAOB). The main study area in the present suty focused on the southwest part of the Beishan Mountain, which can be subdivided into four units southernward, the Mazhongshan continental block, Huaniushan Arc, Liuyuan suture zone and Shibanshan-Daqishan Arc. 1. The Huaniushan Arc was formed by northernward dipping subduction from the Orcovician to Permian, in which volcanic rocks ranging from basic to acidic with island arc affinity were widely developed. The granitiod intrusions become smaller and younger southward, whichs indicates a southward rollback of slab. The granitiod intrusions are mainly composed of I type granites, and their geochemical compositions suggest that they have affinities of island arc settings. In the early Paleozoic（440Ma-390Ma）. The Shibanshan-Daqishan Arc, however, were produced in the southernward dipping subduction system from Carboniferous to Permian. Volcanic rocks from basic to acidic rocks are typical calcic-alkaline rocks. The granitiod intrusions become smaller and younger northernward, indicating subdution with a northernward rollback. The granitiod intrusions mainly consist of I-type granites, of which geochemical data support they belong to island arc granite. 2. Two series of adakite intrusions and eruptive rocks have been discovered in the southern margin of the Huaniushan Island Arc. The older series formed during Silurian (441.7±2.5Ma) are gneiss granitoid. These adakite granites intruded the early Paleozoic Liuyuan accretionary complex, and have the same age as most of the granite intrusions in the Huanniushan Arc. Their geochemical compostions demonstrate that they were derived from partial melting of the subudcted oceanic slab. These characteristics indicate a young oceanic crust subduction in the early Paleozoic. The late stage adakites with compositons of dacites associate with Nb-enriched basalts, and island arc basalts and dacites. Their geochemistries demonstrate that the adakites are the products of subducted slab melts, whereas the Nb-enriched basalt is products of the mantle wedge which have metasomatized by adakite melts. Such a association indicates the existences of a young ocean slab subduction. 3. The Liuyuan suture zone is composed of late Paleozoic ophiolites and two series of accretionary complexes with age of early Paleozoic. The early Paleozoic accretionary complex extensively intruded by early Palozioc granites is composed of metamorphic clastics, marble, flysch, various metamorphic igneous rocks (ultramafic, mafic and dacite), and eclogite blocks, which are connected by faults. The original compositions of the rocks in this complex are highly varied, including MORB, E-MORB, arc rocks. Geochronological study indicates that they were formed during the Silurian (420.9±2.5Ma and 421.1±4.3Ma). Large-scale granitiods intruded in the accretionary complex suggest a fast growth effect at the south margin of the Huaniushan arc. During late Paleozoic, island arc were developed on this accretionary complex. The late Paleozoic ophiolite has an age of early Permian (285.7±2.2Ma), in which the rock assemblage includes ultra-mafic, gabbros, gabbros veins, massive basalts, pillow basalt, basaltic clastic breccias, and thin layer tuff, with chert on the top.These igneous rocks have both arc and MORB affinities, indicating their belonging to SSZ type ophiolite. Therefore, oceanic basins area were still existed in the Liuyuan area in the early Permian. 4. The mafic-ultramafic complexes are distributed along major faults, and composed of zoned cumulate rocks, in which peridotites are surrounded by pyroxenite, hornblendites, gabbros norite and diorite outward. They have island-arc affinities and are consistent with typical Alaska-type mafic-ultramafic complexes. The geochronological results indicate that they were formed in the early Permian. 5. The Liuyuan A-type granite were formed under post-collisional settings during the late Triassic (230.9±2.5Ma), indicating the persistence of orogenic process till the late Triassic in the study area. Geochronological results suggested that A-type granites become younger southward from the Wulungu A-type granite belt to Liuyuan A-type granite belt, which is in good agreement with the accretionary direction of the CAOB in this area, which indicate that the Liuyuan suture is the final sture of the Paleo-Asin Ocean. 6. Structural geological evidence demonstrate the W-E spreading of main tectonic terrenes. These terrenes had mainly underwent through S-N direction contraction and NE strike-faulting. The study area had experienced a S-N direction compression after the Permian, indicating a collisional event after the Permian. Based on the evidene from sedimentary geology, paleontology, and geomagnetism, our studies indicate that the orogenic process can be subdivided into five stages: (1) the pre-orogenic stage occurred before the Ordovicain; (2) the subduction orogenic stage occurred from the Orcovician to the Permian; (3) the collisional orogenic stage occurred from the late Permian to the late Triassic; (4) the post-collision stage occurred after the Triassic. The Liuyuan areas have a long and complex tectonic evolutional history, and the Liuyuan suture zone is one of the most important sutures. It is the finally suture zone of the paleo-Asian ocean in the Beishan area.

高温实验中重金属钼在硅酸盐熔体中的含量研究

This dissertation discusses current status of high temperature and high pressure and focuses on analyzing systematically the solubility of heavy metals in the silicate magma in HTHP experiments. The high temperature study on the content of heavy metal molybdenum in the silicate melts in this dissertation, which is granted, based on the geology mineralization model and the theory of HTHP experiments and combined with mineralization grade and geochemical nature of Mo, discusses the difference of mineralization between mantle plume and aqueous fluids and comes to the conclusions, which are as follows: (1) The content of Mo in the silicate melts is much greater than Mo mineralization grade. The molybdenum ore has the exploitation value when the industrial grade is higher than 0.06%. Mo content in different silicate melts varies because of the concentration of SiO2, that is, Mo content in the granodiorite is greater. (2) The content of Mo, which varies with reaction time, arises first and drops down in the alkali basalt melts, while variation is not too obvious in the granodiorite melts on the whole. (3) According to the picture of sample, the conclusion is not reached very well on some issues, such as the volatility and characteristic of molybdenum oxide and dependence on the geology environment.

东准噶尔和尔赛斑岩铜矿特征及其形成的构造背景

Hersai porphyry copper deposit(PCD) of eastern junggar, newly discovered copper deposit, is located at the eastern segment of the Xiemisitai-Kulankazigan-Zhifang-Qiongheba Paleozoic island arc, Eastern Junggar. The Hersai PCD is developed in a intrusive complex, characterized by intensive and multiform hydrothermal alteration, including potassic alteration, silification, chloritization，sericitization，kaolinitization and carbonatization. Granodiorite, grandiorite porphyry, granite and concealed explosion breccia are hosts of the ore bodies containing veinlet and disseminated ore. Ore-bearing granite (ZK107-1-9), granodiorite (ZK107-1-9) and Ore-barren granodiorite (HES2-1) are selected to date zircon U-Pb age by SHRIMP method, and have an age of 429.4±6.4Ma ,413.0±3.4Ma and 411.1±4.8Ma, respectively, showing that they were emplaced from Late Silurian to Early Devonian. In addition, sample ZK107-1-9 has some hydrothermal zircons with a weighted mean 206Pb/238U age of 404.9±3.7Ma which is interpreted to be related to the granodiorite porphyry. Re-Os dating of five molybdenite samples yielded a weighted average model age of 408.0±2.9Ma, indicating the metallogenic epoch of the Hersai PCD. The ore-forming age is close to the petrogenic time of garnodiorite (411-413Ma), this suggests the ore-forming porphyry is most possiblely granodiorite porphyry. Systematic major - trace elements and Rb-Sr-Sm-Nd-Pb-Hf isotopic characteristics were studied. Analysis results show that these intrusives have some interesting and special characteristics, as following:1) containing both calc-alkaline rocks and high potassium calc-alkaline rocks ; 2) have some characteristics of adakite, but not totally, such as much lower La/Yb ratios and no Eu anomaly or just faint Eu anomaly; 3) have an initial 87Sr/86Sr ratios(0.703852-0.704565) similar to that of BSE, positive εNd(t) values between 6.1 and 7.4, the initial 206Pb/204Pb values (17.576-17.912), 207Pb/204Pb values (15.400-15.453) , 208Pb/204Pb values (37.252-37.466) , and high εHf(t) values (10.2-15.4) close to the value of depleted mantle. These geochemical features suggest that these igneous rocks in the Hersai area not only have some characteristics of island arc, but also some characteristics that only appear in the continental margin arc. It is suggested that Hersai PCD is formed in the subduction setting by the partial melting of young crust. These works and advancements mentioned in the paper are helpful to understand the deposit geology, geochemistry and metallogenesis of Hersai PCD. It is also significant to understand mineralization and tectonic setting in the Qiongheba area.