MF_2:Eu,Ce(M=Ca,Sr,Ba)中稀土离子的价态变化

我们已经实验证明并报道了Eu-Tb之间、Ce-Yb之间的电荷转移.本文首次实验证实了Ce~(3+)离子和Eu~(3+)离子之间电荷转移现象的存在,进一步阐述了稀土价态与其电子组态共轭特征的相关性.1 实验部分1.1 试剂CaF_2,SrF_2,BaF_2,NH_4HF_2、氢氟酸、盐酸均为分析纯,EuF_3和CeF_3分别由高纯Eu_2O_3(99.95%)及CeO_2(99.99%)自制.1.2 MF_2:Eu,Ce体系的合成按化学计量比(MF_2:X%CeF_2,y%EuF_3;X=1,y=0,0.1,0.3,0.5,1;X=0,0.05,0.1,0.3,0.5,y=1)准确称取原料,放人玛瑙研钵中充分研混后装入刚玉柑涡中,置于管状炉内(用氢气

钐原子激发态自然辐射寿命的测量

稀土元素钐(Sm)的基组态是4f~66s~2,其4f壳层未添满,s电子及f电子都有可能被激发,产生复杂的光谱性质。早在1969年,Handrich等人就采用能级交叉的方法测量了钐原子的4个低激发态的寿命。之后,由于寿命测量技术的发展,人们采用各种不同的方法与技

Studies on synthesis, structure and biological activities of novel triazole compounds containing thioamide

Four novel triazole compounds containing thioamide group were designed and synthesized by using triazole, phenyl isothiocyanate and aryl ethyl ketone as raw material. Their structures were conformed by elemental analysis, H-1 NMR, IR and MS spectra. The crystal structure of 1-[1-anilinothiocarbonyl-1-(4-fluorobenzoyl)methyl]-1,2,4-trizole has been determined by X-ray diffraction analysis. The preliminary bioassays have shown that the title compounds exhibit certain antifungal activity.

人工栽培抱茎獐牙菜矿物质元素含量的研究

采集种子采收前和采收后的抱茎獐牙莱全植株，分别分析测试其钾、钠、钙、镁等矿物质元素的含量。结果表明：青海西宁廿里铺种植抱茎獐牙菜矿物质元素主要分布于植株的茎杆部位，矿物质元素含量在成熟种子采收前后具有动态性变化的特征。

糖茶藨种子脂肪酸含量分析

用超临界萃取技术对产于青藏高原上的糖茶藨种子中脂肪酸进行萃取，其萃取率为12％。用毛细管气相色谱对萃取的脂肪酸进行了分离和分析。结果表明不饱和脂肪酸的质量分数在90％以上。其中α-亚麻酸（α-linolenic acid）为27.4％，У-亚麻酸（У-linolenic acia）为2．70％。亚油酸（1inoleic acid）40．0%，油酸（oleic acid）21．0％。[著者文摘]

DEDS理论在CIMS中应用研究回顾与展望

离散事件动态系统ＤＥＤＳ理论为制造系统分析设计提供了支持工具，制造技术的发展又为ＤＥＤＳ理论提供了实际应用背景．本文综述离散事件动态系统ＤＥＤＳ理论的发展及其在计算机集成制造系统ＣＩＭＳ中的应用研究．分析了各种ＤＥＤＳ方法的特点和探讨了相应ＤＥＤＳ模型的描述范围．扼要叙述了ＣＩＭＳ的发展状况．阐述了ＣＩＭＳ新阶段对未来ＤＥＤＳ理论研究的要求。

太阳变化驱动气候变化研究进展

从５个方面综述了近２０年来太阳变化驱动气候变化研究的进展，重点在机制方面，即对全球变暖原因看法的分歧、太阳总辐射量的卫星测量结果、树轮＾１４Ｃ记录与太阳变化代用指标、太阳变化影响的模拟研究，以及太阳－宇宙射线－云量的关系，强调这是一个有重大经济和科学意义的前沿课题。

赣中变质岩带变泥砂质岩石地球化学特征及其地质意义

赣中变质岩带主要由变泥砂质岩石和少量斜长角闪岩组成。30个变泥砂质岩石样品分析表明，稀土元素分布模式显示明显富集轻稀土元素及Eu负异常[∑REE=129～296μg／g，δEu=0．51～0．86，(La／Yb)N=3．95～12．91，其小相容元素比值高(Th／Sc=0．57～3．59、La／Sc=1．46～12．4、La／Yb=5．84～19．0、La／Sm=4．69～6．87、Th／U=3．40～6．42)，大离子亲石元素富集，Zr、Hf、Sc、Ti、Y、HREE和Sr含量较低，其原岩应为一套砂泥质岩石，沉积于远离陆地的克拉通大陆架浅海环境；δBa=0．10～0．93，Nd同位素亏损地幔模式年龄tDM=1597～2525Ma，εNd(0)=-9．9～-15．8，其源区物质主体由占元占代富铝富钾的花岗质岩石和(或)碎屑沉积岩构成，经历了较强的化学风化作用。

贵州区域农业生态环境综合评价

科学地评价贵州的农业生态环境, 可以为西部大开发中的区域发展战略提供理论依据。本文应用模糊综合评价方法, 通过对贵州各个区域的自然、社会、经济环境的系统研究, 对贵州各区域农业生态环境进行了客观评价, 从定量角度对各区农业生态环境加以探讨; 并对西部大开发中贵州农业生态环境保护提出了合理建议。

Memorias políticas y militares, para servir de continuacion a los Comentarios del Marques de San Felipe : desde el año de MDCCXXV, en que concluyó este autor su obra, hasta el presente, con los Tratados de Paz Y Alianzas de España correspondientes

Signaturas: [ ]1, A-Z4, 2A-2R4, 2S1.

Comentarios de la Guerra de España, e historia de su rey Phelipe V el Animoso, desde el principio de su reynado, hasta la Paz General del año de 1725 : dividido en dos tomos

[Vá esta impression cotejada con el original del Autor, y corregida de los innumerables errores que padecen las otras].

A Linearization of the Lambda-Calculus and Consequences

If every lambda-abstraction in a lambda-term M binds at most one variable occurrence, then M is said to be "linear". Many questions about linear lambda-terms are relatively easy to answer, e.g. they all are beta-strongly normalizing and all are simply-typable. We extend the syntax of the standard lambda-calculus L to a non-standard lambda-calculus L^ satisfying a linearity condition generalizing the notion in the standard case. Specifically, in L^ a subterm Q of a term M can be applied to several subterms R1,...,Rk in parallel, which we write as (Q. R1 \wedge ... \wedge Rk). The appropriate notion of beta-reduction beta^ for the calculus L^ is such that, if Q is the lambda-abstraction (\lambda x.P) with m\geq 0 bound occurrences of x, the reduction can be carried out provided k = max(m,1). Every M in L^ is thus beta^-SN. We relate standard beta-reduction and non-standard beta^-reduction in several different ways, and draw several consequences, e.g. a new simple proof for the fact that a standard term M is beta-SN iff M can be assigned a so-called "intersection" type ("top" type disallowed).

A Self-initializing Eyebrow Tracker for Binary Switch Emulation

We designed the Eyebrow-Clicker, a camera-based human computer interface system that implements a new form of binary switch. When the user raises his or her eyebrows, the binary switch is activated and a selection command is issued. The Eyebrow-Clicker thus replaces the "click" functionality of a mouse. The system initializes itself by detecting the user's eyes and eyebrows, tracks these features at frame rate, and recovers in the event of errors. The initialization uses the natural blinking of the human eye to select suitable templates for tracking. Once execution has begun, a user therefore never has to restart the program or even touch the computer. In our experiments with human-computer interaction software, the system successfully determined 93% of the time when a user raised his eyebrows.