Composition of bottom sediments from the anoxic Mogil'noe Lake, Kil'din Island (Barents Sea)

In summer 2006 integrated geological, geochemical, hydrological, and hydrochemical studies were carried out in the relict anoxic Mogil'noe Lake (down to 16 m depths) located in the Kil'din Island in the Barents Sea. Chemical and grain size compositions of bottom sediments from the lake (permanently anoxic basin) and from the Baltic Sea deeps (periodically anoxic basins) were compared. Vertical location of the hydrogen sulfide layer boundary in the lake (9-11 m depths) was practically the same from 1974 up to now. Concentrations of suspended matter in the lake in June and July 2006 appeared to be close to its summer concentrations in seawater of the open Baltic Sea. Muds from the Mogil'noe Lake compared to those of the Baltic Sea deeps are characterized by fluid and flake consistency and by pronounced admixtures of sandy and silty fractions (probably of eolic origin). Lacustrine mud contains much plant remains; iron sulfides and vivianite were also found. Concentrations of 22 elements determined in lacustrine bottom sediments were of the same levels as those found here 33 years ago. Concentrations also appeared to be close to those in corresponding grain size types of bottom sediments in the Baltic Sea. Low C_org/N values (aver. 5.0) in muds of the Mogil'noe Lake compared to ones for muds of the Baltic Sea deeps (aver. 10) evidence considerable planktogenic component in organic matter composition of the lacustrine muds. No indications were reveled for anthropogenic contaminations of the lacustrine bottom sediments with toxic metals.

(Table 1) Age of sediments with anomalously high Hg concentrations in core BDP-98, Lake Baikal

Mercury distribution was examined in the sediments of Lake Baikal that were sampled within the scope of the Baikal Drilling International Project in 1996-1999. The Hg concentrations in the ancient sediments are close to those in the modern sediments with the exception of a few peak values, whose ages coincide with those of active volcanism in adjacent areas. Mercury was demonstrated to be contained in the sediments in the adsorbed Hg0 mode, predominantly in relation with organic matter. When the organic matter of the bottom sediments is decomposed in the course of lithification, Hg is retained in the sediments adsorbed on the residual organic matter, and the concentration of this element corresponds to its initial content in the bottom sediments during their accumulation. Mercury concentrations in lithologically distinct bottom sediments of Lake Baikal and its sediments as a whole depend on the climate. Sediments that were formed during warm periods of time contain more Hg than those produced during cold periods or glaciation. Periodical variations in the Hg concentrations in the bottom sediments of Lake Baikal reflect the variations in the contents of this element in the Earth's atmosphere in the Late Cenozoic, which were, in turn, controlled by the climatic variations on the planet and, thus, can be used for detailed reconstructions of variations in the average global temperature near the planet's surface.

Pollen record and age determiation of sediments from the Labaz Lake area

Pollen records from perennially frozen sequences provide vegetation and climate reconstruction for the last 48,000 14C years in the central part of Taymyr Peninsula. Open larch forest with Alnus fruticosa and Betula nana grew during the Kargin (Middle Weichselian) Interstade, ca. 48,000-25,000 14C yr B.P. The climate was generally warmer and wetter than today. Open steppe-like communities with Artemisia, Poaceae, Asteraceae, and herb tundralike communities with dwarf Betula and Salix dominated during the Sartan (Late Weichselian) Stade, ca. 24,000-10,300 14C yr B.P. The statistical information method used for climate reconstruction shows that the coldest climate was ca. 20,000-17,000 14C yr B.P. A warming (Allerød Interstade?) with mean July temperature ca. 1.5°C warmer than today occurred ca. 12,000 14C yr B.P. The following cooling with temperatures about 3°-4°C cooler than present and precipitation about 100 mm lower corresponds well with the Younger Dryas Stade. Tundra-steppe vegetation changed to Betula nana-Alnus fruticosa shrub tundra ca. 10,000 14C yr B.P. Larch appeared in the area ca. 9400 14C yr B.P. and disappeared after 2900 14C yr B.P. Cooling events ca. 10,500, 9600, and 8200 14C yr B.P. characterized the first half of the Holocene. A significant warming occurred ca. 8500 14C yr B.P., but the Holocene temperature maximum was at about 6000-4500 14C yr B.P. The vegetation cover approximated modern conditions ca. 2800 14C yr B.P. Late Holocene warming events occurred at ca. 3500, 2000, and 1000 14C yr B.P. A cooling (Little Ice Age?) took place between 500 and 200 14C yr ago.

Age and isotopes in bottom sediments from Core VER-99-1-St2, Baikal Lake

A simple, reliable, and efficient method has been elaborated for direct determination of isotopic composition of authigenic uranium in siliceous lacustrine sediments. The method is based on studying kinetics of selective extraction of authigenic uranium from sediments by weak solutions of ammonium hydrocarbonate followed by ICP-MS analysis of nuclides. To estimate contamination of authigenic uranium by terrigenous one contents of 232Th and some other clastogenic elements in the extracts were measured simultaneously. Selectivity of extraction of authigenic uranium from the sediments treated with 1% NH4HCO3 solution appeared to be no worse than 99%. The method was applied to analysis of isotopic composition of authigenic uranium at several key horizons of the earlier dated core from the Baikal Lake. Measurements directly show that 234U/238U values in Baikal water varied depending on climate, which contradicts existing hypotheses. Measured 234U/238U ratios in water of the paleo-Baikal match corresponding values reconstructed from isotopic data for total uranium in the sediments on supposition that U/Th ratio is constant in terrigenous fraction of the sediments. Direct experimental determination of total and authigenic nuclides in sediments enhances potentiality of the method for 234U-230Th dating of non-carbonate lacustrine sediments including those from the Baikal Lake within intervals corresponding to periods of glaciation, when sediments were rich in terrigenous components. Portions of terrigenous and authigenic uranium are well separated and we can study variability of sources of terrigenous matter and refine the earlier model for reconstructing climate humidity in the East Siberia.

(Table 2) Age determination of sediments from lake basins near Polyarny, Russia

A relative sea-level curve for the Holocene is constructed for Polyarny on the Kola Peninsula, northwest Russia. The curve is based on 18 radiocarbon dates of isolation contacts, identified from lithological and diatomological criteria, in nine lake basins situated between 12 and 57 m a.s.l. Most of the lakes show a conformable, regressive I-II-III (marine-transitional-freshwater) facies succession, indicating a postglacial history comprising an early (10,000-9000 radiocarbon years BP) phase of rapid, glacio-isostatically induced emergence (~5 cm/year) and a later phase (after 7000 years BP,) having a moderate rate of emergence (<0.5 cm/year). Three lakes together record a phase of very low rate of emergence or slight sea-level rise at a level of ~27 m a.s.l., between 8500 and 7000 years BP, which correlates with the regional Tapes transgression. Pollen stratigraphy in the highest lake shows that the area was deglaciated before the Younger Dryas and that previously reconstructed Younger Dryas glacier margins along the north Kola coast lie too far north

Carbonates and selected geochemistry composition for sediments from Lake Iznik for the past 31 ka cal BP

This study examines the forcing mechanisms driving long-term carbonate accumulation and preservation in lacustrine sediments in Lake Iznik (northwestern Turkey) since the last glacial. Currently, carbonates precipitate during summer from the alkaline water column, and the sediments preserve aragonite and calcite. Based on X-ray diffraction data, carbonate accumulation has changed significantly and striking reversals in the abundance of the two carbonate polymorphs have occurred on a decadal time scale, during the last 31 ka cal BP. Different lines of evidence, such as grain size, organic matter and redox sensitive elements, indicate that reversals in carbonate polymorph abundance arise due to physical changes in the lacustrine setting, for example, water column depth and lake mixing. The aragonite concentrations are remarkably sensitive to climate, and exhibit millennial-scale oscillations. Extending observations from modern lakes, the Iznik record shows that the aerobic decomposition of organic matter and sulphate reduction are also substantial factors in carbonate preservation over long time periods. Lower lake levels favour aragonite precipitation from supersaturated waters. Prolonged periods of stratification and consequently enhanced sulphate reduction favour aragonite preservation. In contrast, prolonged or repeated exposure of the sediment-water interface to oxygen results in in situ aerobic organic matter decomposition, eventually leading to carbonate dissolution. Notably, the Iznik sediment profile raises the hypothesis that different states of lacustrine mixing lead to selective preservation of different carbonate polymorphs. Thus, a change in the entire lake water chemistry is not strictly necessary to favour the preservation of one polymorph over another.