Microstructure, dielectric properties and optical band gap control on the photoluminescence behavior of Ba[Zr0.25Ti0.75]O-3 thin films

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Structure and optical properties of [Ba1-xY2x/3](Zr0.25Ti0.75)O-3 powders

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Structural refinement, optical and microwave dielectric properties of BaZrO3

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

An N2: CH4: H2O DC glow discharge plasma probed by optical and electric techniques: significance to the radiation chemistry of Titan's upper atmosphere in the presence of meteoritic water

This paper presents optical and electrical measurements on plasma generated by DC excited glow discharges in mixtures composed of 95% N2, 4.8% CH4 and 0.2% H2O at pressures varying from 1.064 mbar to 4.0 mbar. The discharges simulate the chemical reactions that may occur in Titan's atmosphere in the presence of meteorites and ice debris coming from Saturn's systems, assisted by cosmic rays and high energy charged particles. The results obtained from actinometric optical emission spectroscopy, combined with the results from a pulsed Langmuir probe, show that chemical species CH, CN, NH and OH are important precursors in the synthesis of the final solid products and that the chemical kinetics is essentially driven by electronic collision processes. It is shown that the presence of water is sufficient to produce complex solid products whose components are important in prebiotic compound synthesis. © 1998 Elsevier Science Ltd. All rights reserved.

Coordinate-space Faddeev-Hahn-type approach to three-body charge-transfer reactions involving exotic particles

Low-energy muon-transfer cross sections and rates in collisions of muonic atoms with hydrogen isotopes are calculated using a six-state close-coupling approximation to coordinate-space Faddeev-Hahn-type equations. In the muonic case satisfactory results are obtained for all hydrogen isotopes and the experimentaly observed strong isotopic dependence of transfer rates is also reproduced. A comparison with results of other theoretical and available experimental works is presented. The present model also leads to good transfer cross sections in the well-understood problem of antihydrogen formation in antiproton-positronium collision.

Ten years of NO2 comparisons between ground-based SAOZ and satellite instruments (GOME, SCIAMACHY, OMI)

SAOZ (Systeme d'Analyse par Observations Zenithales) is a ground-based UV-Visible zenith-sky spectrometer installed between 1988 and 1995 at a number of NDSC stations at various latitudes on the globe. The instrument is providing ozone and NO2 vertical columns at sunrise and sunset using the Differential Optical Absorption Spectroscopy (DOAS) technique in the visible spectral range. The ERS-2 GOME Ozone Monitoring Experiment (GOME) in 1995 was the first satellite mission to provide a global picture of atmospheric NO 2 with reasonable spatial and temporal resolution. It was then followed by SCanning ImAging spectroMeter for Atmospheric ChartographY (SCIAMACHY) onboard ENVISAT in 2002, and Ozone Monitoring Instrument (OMI) onboard EOS-AURA in 2004, with a similar capacity to monitor total NO 2. All these instruments are nadir viewing mapping spectrometers, applying the DOAS technique in the visible for deriving the NO2 total column. Here we present the results of NO2 long-term comparisons between GOME and SAOZ for the whole period of GOME operation since 1995 at all latitudes - tropics, mid-latitudes and polar regions - in both hemispheres. Comparisons are also shown with the most recently available SCIAMACHY and OMI data in 2004-2005. Overall, the daytime satellite measurements (around noon) are found consistent with sunrise ground-based data, with an average smaller difference at the tropics and mid-latitudes than in the polar areas in the summer. The agreement is even improved after correcting for the NO2 photochemical change between sunrise and the satellite overpass using a box model. However, some seasonal dependence of the difference between ground-based and satellite total NO2 still remains, related to the accuracy of photochemical simulations and the set of NO2 air mass factors used in the retrievals of both systems.

Intermuscular lipoma of the submandibular space

Deep lipomas, especially in the head and neck region, are uncommon. This report describes the case of a patient with a large intermuscular lipoma of the submandibular space, which had been present for 10 years and was diagnosed by computed tomography. The clinical, imaging, and histopathological features, as well as the management of the tumor, are described.

Effect of pressure-assisted thermal annealing on the optical properties of ZnO thin films

ZnO thin films were prepared by the polymeric precursor method. The films were deposited on silicon substrates using the spin-coating technique, and were annealed at 330°C for 32h under pressure-assisted thermal annealing and under ambient pressure. Their structural and optical properties were characterized, and the phases formed were identified by X-ray diffraction. No secondary phase was detected. The ZnO thin films were also characterized by field-emission scanning electron microscopy, Fourier transform infrared spectroscopy, photoluminescence and ultraviolet emission intensity measurements. The effect of pressure on these thin films modifies the active defects that cause the recombination of deep level states located inside the band gap that emit yellow-green (575nm) and orange (645nm) photoluminescence. © 2012 John Wiley & Sons, Ltd.

Construction of perfect space-time codes

In this work, we propose an innovative methodology to extend the construction of minimum and non-minimum delay perfect codes as a subset of cyclic division algebras over ℚ(ζ3), where the signal constellations are isomorphic to the hexagonal An 2 -rotated lattice, for any channel of any dimension n such that gcd{n, 3) = 1.

Modelo conceitual de geoinformação: proposta para o município de Feira de Santana - Bahia

Pós-graduação em Geografia - IGCE

Processos comunicacionais em Cajazeirinha: estudo exploratório em Ilhas do Lago da Usina Hidrelétrica de Tucuruí

Esta pesquisa aborda processos comunicacionais em uma comunidade amazônica, denominada Cajazeirinha, situada no Lago da Usina Hidrelétrica de Tucuruí, no estado do Pará. O objetivo central da investigação foi identificar e analisar os processos comunicacionais das crianças no cotidiano da Cajazeirinha. Esta comunidade tem a especificidade de localizar-se a poucos metros da usina hidrelétrica e, contraditoriamente, não ter acesso ao fornecimento de energia elétrica, o que faz com que a população busque fontes alternativas de eletricidade (bateria de carro, placa solar ou gerador) para, entre outras coisas, utilizar meios de comunicação, como a televisão, o rádio e o celular. Inicialmente, partiu-se do pressuposto de que, para se analisar a comunicação de uma comunidade ou grupo de pessoas é necessário compreender o seu campo de ação e sua constituição, e então observar a realidade de maneira contextualizada, não dissociada no tempo e no espaço. Assim, procurou-se compreender os processos comunicacionais da comunidade, baseando-se nos conceitos teóricos de processos comunicativos de Vera França, processos comunicacionais de José Luiz Braga, no conceito de mediações de Jesús Martín-Barbero e nas bases teóricas dos Estudos de Recepção Latino Americano, a partir das autoras Ana Carolina Escosteguy e Nilda Jacks, além da noção de interação social, de John Thompson. O caminho metodológico trilhado tem como perspectiva a pesquisa exploratória com análise de dados qualitativos, a partir de pesquisas bibliográficas, de entrevistas em profundidade (com crianças, mães e formadores de opinião), da observação não participante sistemática e do diário de campo. O intuito foi identificar e analisar os processos comunicacionais da comunidade Cajazeirinha e mapear os meios de comunicação massivos existentes em Tucuruí e nas ilhas dessa comunidade. Nessa pesquisa, verificou-se que na Cajazeirinha os processos comunicacionais são constituídos a partir de mediações socioculturais, com destaque para a família, a igreja e a escola. Também foram observadas as interações comunicacionais que ocorrem em momentos de lazer e a presença dos meios de comunicação no cotidiano da comunidade, principalmente no que concerne a conteúdos como telenovelas, telejornais e desenhos animados. Por fim, verificou-se que os modos de recepção na Cajazeirinha são permeados por características espaço-temporais locais, por conta do ritmo do rio que determina a vida da comunidade.

Structural refinement, optical and ferroelectric properties of microcrystalline Ba(Zr0.05Ti0.95)O-3 perovskite

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Wide vector solitons in systems with time- and space-modulated nonlinearities

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Characterizing background heterogeneity in visual communication

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Continental degassing of He-4 by surficial discharge of deep groundwater

Radiogenic He-4 is produced by the decay of uranium and thorium in the Earths mantle and crust. From here, it is degassed to the atmosphere(1-5) and eventually escapes to space(1,5,6). Assuming that all of the He-4 produced is degassed, about 70% of the total He-4 degassed from Earth comes from the continental crust(2,-5,7). However, the outgoing flux of crustal He-4 has not been directly measured at the Earths surface(2) and the migration pathways are poorly understood(2-4,7,8). Here we present measurements of helium isotopes and the long-lived cosmogenic radio-isotope Kr-81 in the deep, continental-scale Guarani aquifer in Brazil and show that crustal He-4 reaches the atmosphere primarily by the surficial discharge of deep groundwater. We estimate that He-4 in Guarani groundwater discharge accounts for about 20% of the assumed global flux from continental crust, and that other large aquifers may account for about 33%. Old groundwater ages suggest that He-4 in the Guarani aquifer accumulates over half- to one-million-year timescales. We conclude that He-4 degassing from the continents is regulated by groundwater discharge, rather than episodic tectonic events, and suggest that the assumed steady state between crustal production and degassing of He-4, and its resulting atmospheric residence time, should be re-examined.