Organic carbon and nitrogen at DSDP Leg 58 Holes

The sediments penetrated on Leg 58 of the Deep Sea Drilling Project in the Philippine Sea represent long periods of geologic time during which depositional conditions apparently remained very constant. Organic carbon and nitrogen contents of the sediments decrease with increasing depth of burial, before leveling off at minimum values of about 0.05 to 0.10 per cent and 0.01 per cent, respectively. The depth at which the minimum values are reached varies from site to site, but ages of sediments corresponding to the minima are all about 5 m.y. We infer that slow bacterial diagenesis is responsible for the gradual depletion of organic carbon and nitrogen. It is likely that the rate of bacterial metabolism is controlled by the rate of diffusion of electron acceptors within the sediments. These results suggest that bacterial ecosystems in deep-water sediments play a much more important role in diagenesis than has previously been thought.

Chemical and isotopic compositions of water, particulates, plankton, gases, sediments, and minerals from the Kara Sea and lower Ob and Yenisei Rivers

The Kara Sea is an area uniquely suitable for studying processes in the river-sea system. This is a shallow sea, into which two great Siberian rivers, Yenisei and Ob, flow. From 1995 to 2003, the sea was studied by six international expeditions onboard the R/V Akademik Boris Petrov. This publication summarizes the results obtained, within the framework of this project, at the Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences. Various hydrogeochemical parameters, concentrations and isotopic composition of organic and carbonate carbon of the sediments, plankton, particulate organic matter, hydrocarbons, and dissolved CO2 were examined throughout the whole sea area at more than 200 sites. The d13C varies from -22 and -24 per mil where Atlantic waters enter the Kara Sea and in the north-eastern part of the water area to -27 per mil in the Yenisei and Ob estuaries. The value of d13C of the plankton is only weakly correlated with the d13C of the organic matter from the sediments and is lower by as much as 3-4 per mil. The paper presents the results obtained from a number of meridional river-sea profiles. It was determined from the relations between the isotopic compositions of plankton and particulate matter that the river waters carry material consisting of 70% detrital-humus matter and 30% planktonogenic material in the river part, and the material contained in the offshore waters consists of 30% terrigenous components, with the contribution of bioproducers amounting to 70%. The carbon isotopic composition of the plankton ranges from -29 to -35 per mil in the riverine part, from -28 to -27 per mil in the estuaries, and from -27.0 to -25 per mil in the marine part. The relative lightness of the carbon isotopic composition of plankton in Arctic waters is explained by the temperature effect, elevated CO2 concentrations, and long-distance CO2 supply to the sea with river waters. The data obtained on the isotopic composition of CO2 in the surface waters of the Kara Sea were used to map the distribution of d13C. The complex of hydrocarbon gases extracted from the waters included methane, C2-C5, and unsaturated C2=-C4= hydrocarbons, for which variations in the concentrations in the waters were studied along river-estuary-sea profiles. The geochemistry of hydrocarbon gases in surface fresh waters is characterized by comparable concentrations of methane (0.3-5 µl/l) and heavier hydrocarbons, including unsaturated ones. Microbiological methane with d13C from -105 to -90 per mil first occurs in the sediments at depths of 40-200 cm. The sediments practically everywhere display traces of methane oxidation in the form of a shift of the d13C of methane toward higher values and the occurrence of autogenic carbonate material, including ikaite, enriched in the light isotope. Ikaite (d13C from -25 to -60 per mil) was found and examined in several profiles. The redox conditions in the sediments varied from normal in the southern part of the sea to highly oxidized along the Novaya Zemlya Trough. Vertical sections through the sediments of the latter exemplify the complete suppression of the biochemical activity of microorganisms. Our data provide insight into the biogeochemistry of the Kara Sea and make it possible to specify the background values needed for ecological control during the future exploration operations and extraction of hydrocarbons in the Kara Sea.

Sulfur in bottom sediments and intersitial waters of the Gulf of California

The book is devoted to study of diagenetic changes of organic matter and mineral part of sediments and interstitial waters of the Pacific Ocean due to physical-chemical and microbiological processes. Microbiological studies deal with different groups of bacteria. Regularities of quantitative distribution and the role of microorganisms in geochemical processes are under consideration. Geochemical studies highlight redox processes of the early stages of sediment diagenesis, alterations of interstitial waters, regularities of variations in chemical composition of iron-manganese nodules.

Investigation on the ecological impact of constructing and activities of petrochemical industries of petrochemical special economic zone of Mahshahr on the abundance and diversity of macrobenthic fauna in Jafari Creek, north-west of the Persian Gulf

The impact of Petrochemical Special Economic Zone (PETZONE) activities on the health status of Jafari Creek was studied by assessing the changes in macroinvertebrate assemblages in nine sites during September 2006- January 2008. Furthermore to evaluate the ecological status of the Jafari Creek the WFD indices (i.e. AMBI, M-AMBI) were used. The relationship between spatial pattern of macro invertebrate assemblages and ambient factors (i.e. water temperature, salinity, pH, dissolved oxygen, turbidity, electrical conductivity, total dissolved solid, total hardness, total nitrogen, ammonia, total phosphorous, chemical oxygen demand, biological oxygen demand, sediment grain size distribution, sediment organic content, heavy metals contents) was measured. Background Enrichment indices, Contamination factor and Contamination degree, were used to assess the health status in the study area based on Nickel, Lead, Cadmium and Mercury contents of the sediments. The macrobenthic communities had a low diversity and were dominated by opportunistic taxa, and the AMBI and M-AMBI indices need to be calibrated before using in Persian Gulf and its coastal waters. The BIO-ENV analysis identified pH, dissolved oxygen, TDS, and the total organic content of sediments as the major environmental variables influencing the infaunal pattern. This suggests that management should attempt to ensure minimal disturbance to environmental variables underlying the spatial variation in macroinvertebrate assemblages. Background Enrichment indices showed that the health of Jafari Creek has declined over time due to the constant discharge of heavy metals to the Creek system. Furthermore WQS index shows that the quality condition of the water column in Jafari Creek, regard to the calculated number (3) is week. These indices also identified a significant degree of pollution in the study area. The decrease in the ecological potential of Jafari Creek was best highlighted by the alteration in macrobenthic assemblages.

Nutritional composition, fatty acid and tocopherol contents of buriti (Mauritia flexuosa) and patawa (Oenocarpus bataua) fruit pulp from the amazon region

O buriti e o patauá são duas palmeiras endêmicas da região Amazônica. As polpas destes frutos são tradicionalmente consumidas pela população local, mas ainda não ganharam os mercados nacional e internacional. A composição nutricional em ácidos graxos e tocoferol foi determinada com metodologias analíticas modernas de cromatografia gasosa (CG) e cromatografia líquida de alta eficiência (CLAE) baseadas nos padrões da AOCS (AMERICAN..., 2002) e AOAC (ASSOCIATION..., 1997), respectivamente. As duas polpas se mostraram bastante energéticas, com uma alta concentração em ácidos graxos, respectivamente 38,4% e 29,1% em massa seca (MS), em proteínas, 7,8% e 7,4% MS e em fibras dietéticas, 46% e 44,7%. A polpa de buriti pode ser considerada uma ótima fonte de vitamina E devido ao seu alto teor de tocoferol (1169 µg.g^-1 MS). O perfil de ácidos graxos encontrados para a polpa de patauá foi muito semelhante ao de azeite de oliva.

(Table 1) Composition of stomach and gut content of the amphipod Onisimus litoralis, and algal availability near Barrow, Alaska

Sea ice algae have been widely discussed as a potential food source for pelagic and benthic animals in ice-covered waters, specifically in the light of current substantial changes in the Arctic ice regime. Stomach and gut contents of the Arctic nearshore lysianassid amphipod Onisimus litoralis sampled from February to May 2003 indicate that Arctic ice algae were dominant food no earlier than the onset of ice melt. Crustaceans, common prey in a previous study, were absent in stomachs and guts during the survey period. Our data support the concept that sea ice-derived organic carbon is of specific relevance for Arctic plankton and benthos during the period of ice melt.

(Table 1) Dissolved organic carbon and dissolved sugar of interstitial water of DSDP Holes 96-618, 96-619 and 96-623

Preliminary data on dissolved organic carbon (DOC) and dissolved sugars in interstitial water samples collected at Sites 618, 619, and 623 of Deep Sea Drilling Project Leg 96 are presented. At Site 618 in Orca Basin, the DOC content of the interstitial water peaks in the hypersaline sulfate reduction zone. The sugar content reaches a maximum and the DOC content begins to decrease at the depth of methane gas generation. Below that depth, the sugar and DOC contents are about constant. At Site 619 in Pigmy Basin, the DOC content increases slightly with depth in the sulfate reduction and the methane fermentation zones. The sugar content is lower in the sulfate reduction zone than in the methane fermentation zone; sugar concentration increases and fluctuates with methane gas percentages within the methane fermentation zone. At Site 623 in the lower fan region of the Mississippi Fan, there is no sulfate reduction zone. The DOC and sugar contents of the interstitial water are almost constant with depth.

Characterization of the sediments overlying the Floridan aquifer system in Alachua County, Florida

The primary purpose of this project is to attempt to improve the existing hydrogeologic information through lithologic and hydrogeologic characterizations of the sediments overlying the Floridan aquifer system in Alachua County. These sediments locally comprise both the intermediate aquifer system and associated confining beds and the surficial aquifer system. (PDF has 119 pages.)

Electrical conductivity and mineral composition of the imbibition solution of bean seeds during storage

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Palynological analyses of the sediments around the Miocene/Pliocene boundary in ODP Hole 151-911A

The late Neogene evolution of the Arctic to Subarctic region is poorly understood due to few available records and poor age control. At the margin of the Arctic Ocean, Yermak Plateau Ocean Drilling Program (ODP) Hole 911A is strategically located for establishing a stratigraphic framework for the Arctic. Here we present dinoflagellate cyst and acritarch data from 24 stratigraphic levels in the lower part (474.26-505.64 metres below the seafloor (mbsf)) of ODP Hole 911A. The marine palynomorphs indicate a latest Miocene to earliest Pliocene age (between 5.8 and 5.0 Ma) for the base of the hole based on the co-occurrence of the dinoflagellate cyst Barssidinium evangelineae and acritarch Lavradosphaera crista. Our age estimate for the sediments can possibly be further refined to 5.0-5.33 Ma based on the presence of Achomosphaera andalousiensis suttonensis, which apparently has a range restricted to the Pliocene. An age close to the Miocene/Pliocene boundary agrees with the planktonic foraminifer data. Together with recently available magnetostratigraphic data, the base of the hole is likely to be placed at ~5.2 Ma. This new chronostratigraphy is a first step towards a better understanding of the late Neogene palaeoenvironment for the Yermak Plateau and also for the wider Arctic to Subarctic region. The terrestrial and fresh water palynomorphs were most likely redistributed and/or displaced from the shelf towards deeper parts of the basin during contourite deposition under the influence of the West Spitsbergen Current. The in situ marine dinoflagellate cyst assemblage contains a mixture of cool water and thermophilic taxa, indicating sea-ice free, cool-temperate, warmer than present conditions at the Yermak Plateau. Rivers were likely the source for the freshwater influence.