WeSenseNET - Plataforma de Visualização, Gestão Remota e Agregação Múltipla de Dados

Nos últimos anos, o avanço da tecnologia e a miniaturização de diversos componentes de electrónica associados a novos conceitos têm permitido nascer novas ideias e projectos, que até há alguns anos não passariam de ficção científica. Talvez o exemplo mais acabado seja actualmente o smartphone, um pequeno bloco de hardware e software, com capacidade de processamento que ultrapassa várias vezes o dos computadores com uma dúzia de anos. Estas capacidades têm sido utilizadas em comunicações, blocos de notas, agendas e até entretenimento. No entanto, podem ser reutilizadas para ajudar a resolver algumas limitações/constrangimentos da actualidade. Dentro destes destacam-se a gestão de recursos escassos. Com efeito, o consumo de energia eléctrica tem aumentado como consequência directa do desenvolvimento global e aumento do número de aparelhos eléctricos. Uma percentagem significativa de energia eléctrica tem sido produzida através de recursos não-renováveis de energia. No entanto, a dependência energética, associada à subida de preços e a redução das emissões de gases do efeito estufa, estimula o desenvolvimento de novas soluções que permitam lidar com esta situação. O desempenho energético por sua vez depende não só das características da estrutura, mas também do comportamento do utilizador. O desempenho energético dos edifícios é muito importante, uma vez que os respectivos consumos são responsáveis por mais de metade do total da energia produzida. Desta forma, a fim de alcançar um melhor desempenho é importante não só considerar o desempenho de estrutura, mas também monitorizar o comportamento do utilizador. Esta última questão coloca várias limitações, uma vez que depende muito do tipo de utilizador. Um dos conceitos actuais emergentes são as chamadas redes de sensores sem fio. Com esta tecnologia, pequenos módulos podem ser desenvolvidos com muitas possibilidades de conectividade, com elevado poder de processamento e com grande autonomia, sem serem excessivamente caros. Isto proporciona os meios para implementar vários dispositivos em toda a instalação, para recolher uma variedade de dados, sendo posteriormente armazenados num servidor. Os blocos fundamentais da infra-estrutura de sensores do projecto foram concebidos na Evoleo Technologies em simultâneo com o decorrer do estágio. Estes blocos recolhem dados específicos na instalação, e periodicamente enviam para o servidor central os valores recolhidos, onde são armazenados e colocados à disposição do utilizador. Os dados recolhidos podem então ser apresentados ao utilizador, proporcionando um registo de consumo de energia associado a um dado período de tempo. Uma vez que todos os dados são armazenados no servidor, podem ser efectuados estudos para determinar o uso típico, possíveis problemas em aparelhos, a qualidade da energia eléctrica, etc., permitindo determinar onde a energia está a ser eventualmente desperdiçada e fornecendo dados ao utilizador para que este possa proceder a alterações, tendo por base dados recolhidos num dado período. O objectivo principal deste trabalho passa por estabelecer a ligação entre o nível máquina e o nível de utilizador, isto é, uma plataforma de interacção entre dispositivos e administrador da instalação. Fornecer os dados de uma forma fácil e sem necessidade de instalação de software específico em cada dispositivo que se pretenda utilizar para monitorizar foi uma das principais preocupações das fases de concepção do projecto.

Development of bioplastics from agro-wastes

Poster

North Sea Oil and Genuine Saving in the Scottish Economy

The World Bank has published estimates of sustainability of consumption paths by adjusting saving rates to take account of the depletion of non-renewable resources. During the period of North Sea oil production Scotland has been in a fiscal union with the rest of the UK. The present paper adjusts the World Bank data to produce separate genuine saving estimates for Scotland and the rest of the UK for 1970-2009, based on a ‘derivation’ principle for oil revenues. The calculations indicate that Scotland has had a negative genuine saving rate for most of the period of exploitation of North Sea oil resources, with genuine saving being positive in the rest of the UK during this period.

North Sea Oil and Genuine Saving in the Scottish Economy

The World Bank has published estimates of sustainability of consumption paths by adjusting saving rates to take account of the depletion of non-renewable resources. During the period of North Sea oil production Scotland has been in a fiscal union with the rest of the UK. The present paper adjusts the World Bank data to produce separate genuine saving estimates for Scotland and the rest of the UK for 1970-2009, based on a ‘derivation’ principle for oil revenues. The calculations indicate that Scotland has had a negative genuine saving rate for most of the period of exploitation of North Sea oil resources, with genuine saving being positive in the rest of the UK during this period.

GUINEA-BISSAU: The Role of Local and International NGOs in Environmental Preservation and Sustainability of the Bijagos Archipelago

Bijagos Archipelago in Guinea-Bissau is at present subject to numerous external impacts that affect its centuries old balance. Since 1975 Guinean society has been using its natural resources in an uncontrolled way over the territory and especially in the coastal area. The archipelago has been increasingly raising interest, most of which is incompatible with the guarantee for a long-term sustainable development. It has also displayed a general impoverishment as far as resource preservation is concerned, due to internal demographic pressure of a population that has doubled since 1981 and to external pressure related to neighboring migrations and consequent depletion of non-renewable resources. This article aims to analyze the actions of local and international NGOs in the preservation and sustainability of the Bijagos Archipelago. We seek through an interdisciplinary approach to analyze the phenomena that are configured within the strategies of NGOs, on the assumption that these issues are articulated in the field of geography and sociology, as well as in politics and international cooperation. It is proposed new challenges to environmental issues, especially in a current situation shaken by constant instability internal and external policies.

Simulation of the energy performance of maize production integrated to pig farming

The study evaluated the energy performance of pig farming integrated with maize production in mechanized no-tillage system. In this proposed conception of integration, the swine excrement is used as fertilizers in the maize crop. The system was designed involving the activities associated to the pig management and maize production (soil management, cultivation and harvest). A one-year period of analysis was considered, enabling the production of three batches of pigs and two crops of maize. To evaluate the energy performance, three indicators were created: energy efficiency, use of non-renewable resources efficiency and cost of non-renewable energy to produce protein. The energy inputs are composed by the inputs and infrastructure used by the breeding of pigs and maize production, as well as the solar energy incident on the agroecosystem. The energy outputs are represented by the products (finished pigs and maize). The results obtained in the simulation indicates that the integration improves the energy performance of pig farms, with an increase in the energy efficiency (186%) as well as in the use of the non-renewable energy resources efficiency (352%), while reducing the cost of non-renewable energy to produce protein (‑58%).

Puuperäiset polymeerit synteettisten sideaineiden korvaajina

Tämän kandidaatintyön aiheena oli löytää biojalostamon näkökulmasta käyttökelpoisia tuotantoreittejä puuperäisistä materiaaleista bioperäisiin kemikaaleihin, joilla olisi mahdollista korvata synteettisiä sideaineita. Tällä hetkellä suurin osa sideaineista ja päällystemateriaaleista tuotetaan uusiutumattomista luonnonvaroista, kuten maakaasusta ja öljystä. Lopputuotteiden kierrätettävyyden ja vihreyden ohella yksi metsäteollisuuden tulevaisuuden trendejä on pyrkiä irti öljy- ja maakaasuriippuvuudesta. Muutoksella voidaan säästää sekä ympäristöä, että rahaa. Biopohjaisilla drop-in kemikaaleilla ja muilla biopohjaisilla vaihtoehdoilla tämä on mahdollista Tässä työssä tutkittiin ja havainnollistettiin mahdollisin tuotantoreitein useiden tällä hetkellä käytössä olevien sideaineiden korvaamista biopohjaisilla versioilla. Työ tehtiin kirjallisuustutkielmana, eikä siihen kuulunut laboratoriokokeita. Työn ensimmäisessä osassa painopiste on biojalostamossa ja dispersiopäällystyksessä. Toisessa osassa esitellään tällä hetkellä käytettyjä sideaineita ja niiden mahdollisia biopohjaisia korvaajia tuotantoreitteineen. Työn toissijainen tarkoitus oli selvittää lyhyesti mitä muita puuperäisiä komponentteja voidaan käyttää suoraan paperin ja kartongin päällystämiseen. Viimeiseksi on esitelty vielä lyhyesti kaupallisesti käytössä olevia biomuoveja ja päällysteitä.

Simulation of the energy performance of maize production integrated to pig farming

Foi avaliado o desempenho energético da suinocultura integrada à produção de milho em grão em sistema de plantio direto mecanizado. Nesta concepção de integração proposta, os dejetos suínos são utilizados como fertilizantes na produção de milho. O sistema foi delimitado envolvendo as atividades associadas ao manejo dos suínos e de produção do milho (manejo do solo, cultivo e colheita). O período de análise considerado foi de um ano, o que possibilita a produção de três lotes de suínos e duas safras de milho. Para avaliar o desempenho energético, foram criados três indicadores: eficiência energética, eficiência de uso de fontes não renováveis e o custo de energia não renovável para a produção de proteína. As entradas energéticas são compostas pelos insumos e pela infraestrutura, utilizados na criação dos suínos e na produção de milho, e pela radiação solar incidente no agrossistema. Já as saídas são representadas pelos seus produtos (suínos terminados e o milho). Os resultados obtidos nas simulações apontam que a integração melhora o desempenho energético das granjas suinícolas, aumentando a eficiência energética (186%) e a eficiência não renovável (352%), além de reduzir o custo de energia não renovável para a produção de proteína (‑58%).

Comparative study of the life cycle assessment of particleboards made of residues from sugarcane bagasse (Saccharum spp.) and pine wood shavings (Pinus elliottii)

This paper presents a research on the environmental impacts of particleboards produced from wastes, based on a comparative Life Cycle Assessment study. The particleboards were manufactured in laboratorial scale from the following residues: sugarcane bagasse (Saccharum spp.) and pine wood shavings (Pinus elliottii). The study was developed following the methodological guidelines of ISO 14040. The functional unit adopted was the m2 of the particleboards produced and the impacts were evaluated by the Environmental Development of Industrial Products method. The results indicated that pine particleboard present the highest environmental impact potential. Our findings suggested that the factors that mostly aggravated the environmental impacts were: the distance between the raw materials and the production site, and formaldehyde emissions (FE). The first is related to the combustion of fossil fuel during the acquisition of raw material, which achieved the values of 2185.94 g/m2 for consumption of non-renewable resources for pine particleboard and 893.53 g/m2 for bagasse particleboard. The second is related to the use of urea-formaldehyde resin, responsible for the FE into the air during production. The FE is accountable for the contamination of approximately 7,800,000.00 m3 of air per m2 of particleboard produced, and was the factor with the greatest impact in human toxicity potential. © 2013 Elsevier Ltd. All rights reserved.

The economics of climate change in Latin America and the Caribbean: Paradoxes and challenges of sustainable development

The robust growth of Latin American and Caribbean economies in recent years has led to an improvement in economic and social conditions in the region. It has also had collateral negative effects, however, such as more air pollution in urban areas and a serious deterioration of various natural assets, including non-renewable resources, water resources and forests. There are economies and societies within the region that are highly vulnerable to all sorts of adverse impacts of climate change, and whose production structures and consumption patterns still tend to leave a large carbon footprint. This situation has reached the point of undermining the foundations of the region’s economic buoyancy. Latin America and the Caribbean therefore needs to make the transition in the years to come towards a sustainable form of development that will preserve its economic, social and natural assets for future generations and leave them with a legacy of a more equal, more socially inclusive, low-carbon form of economic growth. Viewed from this standpoint, the climate change challenge is also a sustainable development challenge, and if it is to be addressed successfully, a global consensus that recognizes the asymmetries and paradoxes of the problem will have to be reached..

Análise econômica do uso de célula a combustível para acionamento de ônibus urbano

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Emergy assessment of tilapia cage farming in a hydroelectric reservoir

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Zoneamento geoambiental como instrumento de planejamento e gestão de recursos do pólo cerâmico de Santa Gertrudes

The disorded and unnplaned occupation is not recent in out territory but it concerns to a historical territorial invasion that roots the time of our country discovery. However, they have started to cause issues nowadays, as in the case of urban conurbations. Somehow these unorganized urban, industrial and agricultural occupations did not have any sort of information or indication of the appropriate situation at that time. Because of that there has been researches by several groups to induce the users of the several renewable and non renewable resources to explore them according to their natural potential capacity.The Ceramic Pole of Santa Gertrudes, the national largest producer of ceramic tile, faces this problem of disorder occupation. Among other themes, the reorganization of the physical environment, proposed by several groups of researchers and scholars of this subject, is gaining attention now.The method of Geoenvironmental Zoning results in a way of prevention from this issue. Crossing information of the physical environment and generating maps whose areas and subdivisions have similar characteristics, it is possible to manage studies and handle these areas according to their potentiality.

Use of solvents and environmental friendly materials for applications in Green Chemistry

The present Thesis studies three alternative solvent groups as sustainable replacement of traditional organic solvents. Some aspects of fluorinated solvents, supercritical fluids and ionic liquids, have been analysed with a critical approach and their effective “greenness” has been evaluated from the points of view of the synthesis, the properties and the applications. In particular, the attention has been put on the environmental and human health issues, evaluating the eco-toxicity, the toxicity and the persistence, to underline that applicability and sustainability are subjects with equal importance. The “green” features of fluorous solvents and supercritical fluids are almost well-established; in particular supercritical carbon dioxide (scCO2) is probably the “greenest” solvent among the alternative solvent systems developed in the last years, enabling to combine numerous advantages both from the point of view of industrial/technological applications and eco-compatibility. In the Thesis the analysis of these two classes of alternative solvents has been mainly focused on their applicability, rather than the evaluation of their environmental impact. Specifically they have been evaluated as alternative media for non-aqueous biocatalysis. For this purpose, the hydrophobic ion pairing (HIP), which allows solubilising enzymes in apolar solvents by an ion pairing between the protein and a surfactant, has been investigated as effective enzymatic derivatisation technique to improve the catalytic activity under homogeneous conditions in non conventional media. The results showed that the complex enzyme-surfactant was much more active both in fluorous solvents and in supercritical carbon dioxide than the native form of the enzyme. Ionic liquids, especially imidazolium salts, have been proposed some years ago as “fully green” alternative solvents; however this epithet does not take into account several “brown” aspects such as their synthesis from petro-chemical starting materials, their considerable eco-toxicity, toxicity and resistance to biodegradation, and the difficulty of clearly outline applications in which ionic liquids are really more advantageous than traditional solvents. For all of these reasons in this Thesis a critical analysis of ionic liquids has been focused on three main topics: i) alternative synthesis by introducing structural moieties which could reduce the toxicity of the most known liquid salts, and by using starting materials from renewable resources; ii) on the evaluation of their environmental impact through eco-toxicological tests (Daphnia magna and Vibrio fischeri acute toxicity tests, and algal growth inhibition), toxicity tests (MTT test, AChE inhibition and LDH release tests) and fate and rate of aerobic biodegradation in soil and water; iii) and on the demonstration of their effectiveness as reaction media in organo-catalysis and as extractive solvents in the recovery of vegetable oil from terrestrial and aquatic biomass. The results about eco-toxicity tests with Daphnia magna, Vibrio fischeri and algae, and toxicity assay using cultured cell lines, clearly indicate that the difference in toxicity between alkyl and oxygenated cations relies in differences of polarity, according to the general trend of decreasing toxicity by decreasing the lipophilicity. Independently by the biological approach in fact, all the results are in agreement, showing a lower toxicity for compounds with oxygenated lateral chains than for those having purely alkyl lateral chains. These findings indicate that an appropriate choice of cation and anion structures is important not only to design the IL with improved and suitable chemico-physical properties but also to obtain safer and eco-friendly ILs. Moreover there is a clear indication that the composition of the abiotic environment has to be taken into account when the toxicity of ILs in various biological test systems is analysed, because, for example, the data reported in the Thesis indicate a significant influence of salinity variations on algal toxicity. Aerobic biodegradation of four imidazolium ionic liquids, two alkylated and two oxygenated, in soil was evaluated for the first time. Alkyl ionic liquids were shown to be biodegradable over the 6 months test period, and in contrast no significant mineralisation was observed with oxygenated derivatives. A different result was observed in the aerobic biodegradation of alkylated and oxygenated pyridinium ionic liquids in water because all the ionic liquids were almost completely degraded after 10 days, independently by the number of oxygen in the lateral chain of the cation. The synthesis of new ionic liquids by using renewable feedstock as starting materials, has been developed through the synthesis of furan-based ion pairs from furfural. The new ammonium salts were synthesised in very good yields, good purity of the products and wide versatility, combining low melting points with high decomposition temperatures and reduced viscosities. Regarding the possible applications as surfactants and biocides, furan-based salts could be a valuable alternative to benzyltributylammonium salts and benzalkonium chloride that are produced from non-renewable resources. A new procedure for the allylation of ketones and aldehydes with tetraallyltin in ionic liquids was developed. The reaction afforded high yields both in sulfonate-containing ILs and in ILs without sulfonate upon addition of a small amount of sulfonic acid. The checked reaction resulted in peculiar chemoselectivity favouring aliphatic substrates towards aromatic ketones and good stereoselectivity in the allylation of levoglucosenone. Finally ILs-based systems could be easily and successfully recycled, making the described procedure environmentally benign. The potential role of switchable polarity solvents as a green technology for the extraction of vegetable oil from terrestrial and aquatic biomass has been investigated. The extraction efficiency of terrestrial biomass rich in triacylglycerols, as soy bean flakes and sunflower seeds, was comparable to those of traditional organic solvents, being the yield of vegetable oils recovery very similar. Switchable polarity solvents as been also exploited for the first time in the extraction of hydrocarbons from the microalga Botryococcus braunii, demonstrating the efficiency of the process for the extraction of both dried microalgal biomass and directly of the aqueous growth medium. The switchable polarity solvents exhibited better extraction efficiency than conventional solvents, both with dried and liquid samples. This is an important issue considering that the harvest and the dewatering of algal biomass have a large impact on overall costs and energy balance.