Avaliações térmica e reológica da matriz termoplástica PEKK utilizada em compósitos aeronáuticos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Uso do pó da palha de carnaúba em compósitos de quitosana

In this work a biodegradable composite using the carnauba straw s powder as reinforcement on chitosan matrix polymeric were manufactured. Firstly, were carried out the chemistry characterization of the carnauba straw s powder before and after treatments with NaOH and hexane. Goering and Van Soest method (1970), flotation test, moisture absorption, FTIR, TG/DTG, DSC and SEM have also being carried out. Composites were developed with variations in granulometry and in powder concentrations. They were characterized by TG/DTG, SEM and mechanicals properties. The results of chemical composition showed that the carnauba straw s powder is composed of 41% of cellulose; 28,9% of hemicellulose and 14% of lignin.The flotation test have indicated that the chemical treatment with NaOH decreased the powder s hidrophilicity.The thermal analysis showed increased of thermal stability of material after treatments. The results of FTIR and SEM revealed the removal of soluble materials from the powder (hemicelluloses and lignin), the material became rougher and clean. The composites obtained showed that the mechanicals properties of the composites were decreased in respect at chitosan films, and the composites with the powder at 150 Mesh showed less variation in the modulus values. The speed test of 10 mm/min showed the better reproducibility of the results and is in agreement to the standard ASTM D638. The SEM analysis of fracture showed the low adhesion between the fiber/matrix. The increase of volume of powder in the composite caused a decrease in values of stress and strain for the samples with untreated powder and treated with hexane. The composite with 50% of the powder s treated in NaOH didn t have significant variation in the values of stress and strain as compared with the composites with 10% of the powder, showing that the increase in the volume of fiber didn t affect the stress and strain of the composite. Thereby, it is concluded that the manufacture of polymeric composites of chitosan using carnauba straw s powder can be done, without need for pre-treatment of reinforcement, become the couple of carnauba straw s powder-chitosan a good alternative for biodegradable composites

Caracterização mecânica e térmica de compósitos de poli (cloreto de vinila) reforçados com fibras de sisal

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Influência do uso do forno de microondas ou convencional na síntese de ZrO2

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Addition of sedimentary rock to kaolinitic clays: influence on sintering process

Foram avaliadas, durante o processo de sinterização, as propriedades mecânicas de peças cerâmicas a base de argila com adição de rocha sedimentar. Foram preparados corpos de prova com 0, 20, 40, 60 e 80% em peso de rocha adicionada ao material argiloso. As peças foram sinterizadas nas temperaturas de 500, 800, 900, 1000, 1100 e 1200 °C e, posteriormente, submetidas à análise de difração de raios X e a ensaios tecnológicos Os resultados de difração de raios X mostram que a rocha sedimentar apresenta argilominerais micáceos enquanto o material argiloso possui a caulinita como fase principal. Técnicas de análises térmicas e difração de raios X das diferentes misturas mostram reações que indicam transformação (inversão do quartzo), decomposição (perda de hidróxidos) e formação de fase (mulita) durante o aquecimento das amostras. Os ensaios tecnológicos mostram que a adição da rocha sedimentar melhora algumas propriedades do material sinterizado, auxiliada pela presença de fundentes. Entretanto, a presença de quartzo na rocha dificulta a formação da fase mulita. A formação de novas fases e as transformações ocorridas no aquecimento e resfriamento das amostras ajuda explicar as propriedades tecnológicas dos materiais cerâmicos.

Preparação e caracterização de óxido de zinco nanoestruturado

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Argilominerais: influência dos aditivos (cinza de bagaço de cana-de-acúcar e rocha sedimentar) no processo de sinterização

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Propriedades estruturais de géis obtidos a partir de sono-hidrólise de TEOS e troca de fase líquida por acetona

Pós-graduação em Física - IGCE

Avaliação dos parâmetros de soldagem para compósitos de PPS/fibras contínuas com aplicações aeronáuticas

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Reação de redução de oxigênio sobre perovskitas La1-xSrxFeyCo1-yO3-δ, para células a combustível de óxido sólido (SOFC)

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Síntese, dopagem e caracterização das resinas furfurílica e fenol-furfurílica visando a otimização do processamento de carbono vítreo

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Microesferas de goma gelana e pectina como potencial estratégia para liberação controlada de fármacos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Modificação superficial de fibras de juta com descarga corona para melhora da aderência com matriz poliéster

Seeking alternatives for the total or partial substitution of synthetic fibers for natural fibers, with reinforcement in polymeric materials, this work was conducted with the objective of evaluating the treatment with corona discharge on the adherence of juta fibers with resin. The fibers were exposed to corona discharge for 1, 5, 10 and 15 minutes, as well as after treatment with hot water, molding composites fiber-reinforced with filaments treated for 10 and 15 minutes, and without the treatment. The chemical structures were evaluated by spectrometry in the region of Fourier transform infrared with attenuated total reflection (FTIR/ATR), observing the formation of a new band and the increase in the absorption of groupings with oxygen. The thermal analyses, such as thermogravimetry (TG) and differential scanning calorimetry (DSC) revealed the degradation of cellulose, hemicellulose and lignin. The microstructural characterization by scanning electron microscopy (SEM) showed changes in the surface of the fiber, such as roughness, superficial depressions, surface degradation and cavity formation. The adhesion of the fibers was evaluated by the pullout test, allowing us to verify the increase in adhesion strength after treatment with corona discharge. In conclusion, the treatment with corona discharge changes the surface of the juta fibers, resulting in better adherence with the resin.

Análise energética da madeira e do carvão de híbridos entre Corymbia citriodora (Hook.) K.D. Hill & L.A.S. Johnson e Corymbia torelliana (F. Muell.) K.D. Hill & L.A.S. Johnson

This research aimed to evaluate the wood and charcoal quality of hybrids clone of the crossing C. citriodora with C. torelliana in two different locations for charcoal production. Seven with 3,75 years old clones, planted at country of Itamarandiba – MG, and six 6,42 years old clones, planted in Dionísio – MG, were studied. For wood and charcoal quality analysis, samples were collected along the stem of the trees until the commercial height. Properties study of the wood was done by chemical analysis, basic density, superior heat power, and thermogravimetric analysis. The wood samples were carbonized in laboratory conditions with heating rate of 1.67 0 C.min -1 , starting at 100 0 C until 450 0 C and keeping on this temperature for 30 minutes. It were determined the carbonizations gravimetric yield, all in dry basis. The wood quality was evaluated based on the chemical immediate analysis, relative apparent density, and gross heating value. The experiment was installed according to the completely randomized design, with five repetitions. The collected data were submitted to analysis of variance and, when the evaluated effects were significant by “F” test, was applied the Scott-Knott test at 5% probability for multiple comparisons. For correlation analysis, Pearson correlation coefficient, tested by the "t" test at 5% probability was used. Results showed variability of wood between the genetic materials evaluated in relation to place and plant crossing. The thermal analysis of the wood showed significant variation between clones and it was possible to differentiate two stages of degradation (hemicelluloses and cellulose). The majority of the clones presented satisfactory properties for the charcoal production, while, clone 3, planted in Itamarandiba, obtained the best performance due it have the higher yield and energetic efficiency, thus, achieving the best potential for charcoal production. However, clone 9, planted in Dionísio, was the less indicated for charcoal production since it presented the lowest energetic efficiency, gravimetric yield, and densities.

Preparo e caracterização de novos compósitos de celulose bacteriana

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)