North-West elevation, C House, Coorparoo, Brisbane

Upper level of North-West elevation, kitchen skylight on left.

Outdoor room, C House, Coorparoo, Brisbane

As seen from upper level of house.

View from Sunshine Beach House, Sunshine Coast

View to ocean from upper level viewing deck.

View from Sunshine Beach House, Sunshine Coast

View to ocean for upper level viewing deck.

View from Sunshine Beach House, Sunshine Coast

View to ocean as seen from upper level viewing deck.

Sunshine Beach House, Sunshine Coast

View down upper level hallway.

View from Sunshine Beach House, Sunshine Coast

View to ocean for upper level viewing deck.

Viewing Deck, Sunshine Beach House, Sunshine Coast

View through doors to upper level viewing deck.

Three-bedroom townhouse, Air Niugini Staff Housing, Papua New Guinea

Side elevation, showing upper level bedroom windows.

Interior of tower, Carpenter Hall house, Wilston, Brisbane

View to landscape beyond through windows of upper level of tower.

Interior of tower, Carpenter Hall house, Wilston, Brisbane

View to landscape beyond through windows of upper level of tower (shown open).

Timber cross-bracing, Mooloomba House, Point Lookout, North Stradbroke Island

Detail view of timber cross-bracing with polycarbonate sheeting behind as seen from upper level dining studio.

Timber cross-bracing, Mooloomba House, Point Lookout, North Stradbroke Island

Detail view of timber cross-bracing with polycarbonate sheeting behind as seen from upper level dining studio.

Cladding detail, Mooloomba House, Point Lookout, North Stradbroke Island

Detail view of cladding to upper level dining studio.

Coupling of a Jahn-Teller pseudorotation with a hindered internal rotation in an isolated molecule: 9-hydroxytriptycene

The irregular vibronic structure in the S-1<--S-0 resonant two-photon ionization (R2PI) spectrum of supersonically cooled triptycene is a result of a classic Exe Jahn-Teller effect [A. Furlan et al., J. Chem. Phys. 96, 7306 (1992)]. This is well characterized and can be used as an effective probe of intramolecular perturbations. Here we examine the S-1<--S-0 R2PI spectrum of 9-hydroxytriptycene and the fluorescence from various excited state vibronic levels. In this system the pseudorotation of the Jahn-Teller vibration is strongly coupled to the torsional motion of the bridgehead hydroxy group. This torsional motion results in a tunneling splitting in both the ground and excited states. The population of the upper level in the ground electronic state results in additional vibronic transitions becoming symmetry allowed in the R2PI spectrum that are forbidden in the bare triptycene molecule. The assignment of the R2PI and fluorescence spectra allows the potential energy surfaces of these vibrational modes to be accurately quantified. The full C-3v vibronic point group must be used to interpret the spectra. The time scale of the internal rotation of the-OH group and the butterfly flapping of the Jahn-Teller pseudorotation are of similar magnitude. The tunneling between the nine minima on the three dimensional potential energy surface is such that the Jahn-Teller pseudorotation occurs in concert with the-OH internal rotation. The Berry phase that is acquired during this motion is discussed. The simple physical picture emerges of the angle between two of the three benzene moieties opening in three equivalent ways in the S-1 electronic state. This geometry follows the position of the hydroxy group, which preferentially orients itself to point between these two rings. (C) 1998 American Institute of Physics. [S0021-9606(98)02348-4].