Residual effect of natural and synthetic zinc chelates on zinc in a soil solution of a waterlogged acidic soil. Evolution of the pH and redox potential.

Zinc chelates have been widely used to correct deficiencies in this micronutrient in different soil types and under different moisture conditions. The aging of the metal in soil could cause a change in its availability. Over time the most labile forms of Zn could decrease in activity and extractability and change to more stable forms. Various soil parameters, such as redox conditions, time, soil type and moisture conditions, affect the aging process and modify the solubility of the metal. In general, redox conditions influence pH and also the chemical forms dissolved in the soil solution. Soil pH also affects Zn solubility; at high pH values, most of the Zn is present in forms that are not bioavailable to plants. The objective of this study was to determine the changes in Zn over time in a soil solution in a waterlogged acidic soil to which synthetic and natural chelates were applied

Forest Hydrology, Soil Conservation and Green Barriers in Canary Islands

In volcanic islands, the rainfall regime and its torrential nature, together with the steep slopes and the soil types present are considered to be some of the main factors affecting forest hydrology and soil conservation. In such environments, rain regime is generally irregular and characterized by short and intense rainfalls, which could cause destructive flows at times, followed by long periods of rain absence. The volcanic nature of these islands have as a direct resultant steep slopes which influences the runoff volume and speed, as well as the amount of topsoil susceptible to be detached and transported downstream. The soil type also affects the susceptibility to erosion processes. Andisols are the most typical soil on volcanic islands. Their particularities derive their mineral constituents, called short-range-order products, which provide these soils with an increased structural stability, which in turn reduces their susceptibility to erosion. However, the land use changes and the environmental factors such as rain regime and steep slopes may be determinant factor in destabilizing these soils and ultimately a cause for soil erosion and runoffs, which become a threat to the population downstream. Green barriers have been traditionally used to prevent or reduce these processes, also to enhance the dew effect and the fog water collection, and as a firebreak which acts as a barrier to slow or stop the progress of a wildfire. Wooded species present and subsequently their performance have a major influence on their effectiveness. The use of this natural erosion and fire control methods on volcanic islands is discussed in this paper.

Diseño basado en técnicas de fiabilidad del tratamiento de mejora del terreno mediante columnas de grava

El proyecto geotécnico de columnas de grava tiene todas las incertidumbres asociadas a un proyecto geotécnico y además hay que considerar las incertidumbres inherentes a la compleja interacción entre el terreno y la columna, la puesta en obra de los materiales y el producto final conseguido. Este hecho es común a otros tratamientos del terreno cuyo objetivo sea, en general, la mejora “profunda”. Como los métodos de fiabilidad (v.gr., FORM, SORM, Monte Carlo, Simulación Direccional) dan respuesta a la incertidumbre de forma mucho más consistente y racional que el coeficiente de seguridad tradicional, ha surgido un interés reciente en la aplicación de técnicas de fiabilidad a la ingeniería geotécnica. Si bien la aplicación concreta al proyecto de técnicas de mejora del terreno no es tan extensa. En esta Tesis se han aplicado las técnicas de fiabilidad a algunos aspectos del proyecto de columnas de grava (estimación de asientos, tiempos de consolidación y aumento de la capacidad portante) con el objetivo de efectuar un análisis racional del proceso de diseño, considerando los efectos que tienen la incertidumbre y la variabilidad en la seguridad del proyecto, es decir, en la probabilidad de fallo. Para alcanzar este objetivo se ha utilizado un método analítico avanzado debido a Castro y Sagaseta (2009), que mejora notablemente la predicción de las variables involucradas en el diseño del tratamiento y su evolución temporal (consolidación). Se ha estudiado el problema del asiento (valor y tiempo de consolidación) en el contexto de la incertidumbre, analizando dos modos de fallo: i) el primer modo representa la situación en la que es posible finalizar la consolidación primaria, parcial o totalmente, del terreno mejorado antes de la ejecución de la estructura final, bien sea por un precarga o porque la carga se pueda aplicar gradualmente sin afectar a la estructura o instalación; y ii) por otra parte, el segundo modo de fallo implica que el terreno mejorado se carga desde el instante inicial con la estructura definitiva o instalación y se comprueba que el asiento final (transcurrida la consolidación primaria) sea lo suficientemente pequeño para que pueda considerarse admisible. Para trabajar con valores realistas de los parámetros geotécnicos, los datos se han obtenido de un terreno real mejorado con columnas de grava, consiguiendo, de esta forma, un análisis de fiabilidad más riguroso. La conclusión más importante, obtenida del análisis de este caso particular, es la necesidad de precargar el terreno mejorado con columnas de grava para conseguir que el asiento ocurra de forma anticipada antes de la aplicación de la carga correspondiente a la estructura definitiva. De otra forma la probabilidad de fallo es muy alta, incluso cuando el margen de seguridad determinista pudiera ser suficiente. En lo que respecta a la capacidad portante de las columnas, existen un buen número de métodos de cálculo y de ensayos de carga (tanto de campo como de laboratorio) que dan predicciones dispares del valor de la capacidad última de las columnas de grava. En las mallas indefinidas de columnas, los resultados del análisis de fiabilidad han confirmado las consideraciones teóricas y experimentales existentes relativas a que no se produce fallo por estabilidad, obteniéndose una probabilidad de fallo prácticamente nula para este modo de fallo. Sin embargo, cuando se analiza, en el contexto de la incertidumbre, la capacidad portante de pequeños grupos de columnas bajo zapatas se ha obtenido, para un caso con unos parámetros geotécnicos típicos, que la probabilidad de fallo es bastante alta, por encima de los umbrales normalmente admitidos para Estados Límite Últimos. Por último, el trabajo de recopilación sobre los métodos de cálculo y de ensayos de carga sobre la columna aislada ha permitido generar una base de datos suficientemente amplia como para abordar una actualización bayesiana de los métodos de cálculo de la columna de grava aislada. El marco bayesiano de actualización ha resultado de utilidad en la mejora de las predicciones de la capacidad última de carga de la columna, permitiendo “actualizar” los parámetros del modelo de cálculo a medida que se dispongan de ensayos de carga adicionales para un proyecto específico. Constituye una herramienta valiosa para la toma de decisiones en condiciones de incertidumbre ya que permite comparar el coste de los ensayos adicionales con el coste de una posible rotura y , en consecuencia, decidir si es procedente efectuar dichos ensayos. The geotechnical design of stone columns has all the uncertainties associated with a geotechnical project and those inherent to the complex interaction between the soil and the column, the installation of the materials and the characteristics of the final (as built) column must be considered. This is common to other soil treatments aimed, in general, to “deep” soil improvement. Since reliability methods (eg, FORM, SORM, Monte Carlo, Directional Simulation) deals with uncertainty in a much more consistent and rational way than the traditional safety factor, recent interest has arisen in the application of reliability techniques to geotechnical engineering. But the specific application of these techniques to soil improvement projects is not as extensive. In this thesis reliability techniques have been applied to some aspects of stone columns design (estimated settlements, consolidation times and increased bearing capacity) to make a rational analysis of the design process, considering the effects of uncertainty and variability on the safety of the project, i.e., on the probability of failure. To achieve this goal an advanced analytical method due to Castro and Sagaseta (2009), that significantly improves the prediction of the variables involved in the design of treatment and its temporal evolution (consolidation), has been employed. This thesis studies the problem of stone column settlement (amount and speed) in the context of uncertainty, analyzing two failure modes: i) the first mode represents the situation in which it is possible to cause primary consolidation, partial or total, of the improved ground prior to implementation of the final structure, either by a pre-load or because the load can be applied gradually or programmed without affecting the structure or installation; and ii) on the other hand, the second mode implies that the improved ground is loaded from the initial instant with the final structure or installation, expecting that the final settlement (elapsed primary consolidation) is small enough to be allowable. To work with realistic values of geotechnical parameters, data were obtained from a real soil improved with stone columns, hence producing a more rigorous reliability analysis. The most important conclusion obtained from the analysis of this particular case is the need to preload the stone columns-improved soil to make the settlement to occur before the application of the load corresponding to the final structure. Otherwise the probability of failure is very high, even when the deterministic safety margin would be sufficient. With respect to the bearing capacity of the columns, there are numerous methods of calculation and load tests (both for the field and the laboratory) giving different predictions of the ultimate capacity of stone columns. For indefinite columns grids, the results of reliability analysis confirmed the existing theoretical and experimental considerations that no failure occurs due to the stability failure mode, therefore resulting in a negligible probability of failure. However, when analyzed in the context of uncertainty (for a case with typical geotechnical parameters), results show that the probability of failure due to the bearing capacity failure mode of a group of columns is quite high, above thresholds usually admitted for Ultimate Limit States. Finally, the review of calculation methods and load tests results for isolated columns, has generated a large enough database, that allowed a subsequent Bayesian updating of the methods for calculating the bearing capacity of isolated stone columns. The Bayesian updating framework has been useful to improve the predictions of the ultimate load capacity of the column, allowing to "update" the parameters of the calculation model as additional load tests become available for a specific project. Moreover, it is a valuable tool for decision making under uncertainty since it is possible to compare the cost of further testing to the cost of a possible failure and therefore to decide whether it is appropriate to perform such tests.

Improving simulation of soil water balance using lysimeter observations in a semiarid climate.

Water balance simulation in cropping systems is a very useful tool to study how water can be used efficiently. However this requires that models simulate an accurate water balance. Comparing model results with field observations will provide information on the performance of the models. The objective of this study was to test the performance of DSSAT model in simulating the water balance by comparing the simulations with observed measurements. The soil water balance in DSSAT uses a one dimensional ?tipping bucket? soil water balance approach where available soil water is determined by the drained upper limit (DUL), lower limit (LL) and saturated water content (SAT). A continuous weighing lysimeter was used to get the observed values of drainage and evapotranspiration (ET). An automated agrometeorological weather station close to the lisymeter was also used to record the climatic data. The model simulated accurately the soil water content after the optimization of the soil parameters. However it was found the inability of the model to capture small changes in daily drainage and ET. For that reason simulated cumulative values had larger errors as the time passed by. These results suggested the need to compare outputs of DSSAT and some hydrological model that simulates soil water movement with a more mechanistic approach. The comparison of the two models will allow us to find which mechanism can be modified or incorporated in DSSAT model to improve the simulations.

Geochemistry, fatty acid content and phylogenetic affiliation of soil samples from Livingston Island, South Shetland Archipelago, Antarctica

Microorganisms inhabit very different soil habitats in the ice-free areas of Antarctica, playing a major role in nutrient cycling in cold environments. We studied the soil characteristics and the dominant bacterial composition from nine different soil profiles located on Livingston Island (maritime Antarctica). The total carbon (TC) and total nitrogen (TN) values were high for the vegetated soils, decreasing with depth, whereas the values for the mineral soils were generally low. Soil pH was more acidic for moss-covered soils and neutral to alkaline for mineral soils. Numbers of culturable heterotrophic bacteria were higher at vegetated sites, but significant numbers were also detectable in carbon-depleted soils. Patterns of denaturing gradient gel electrophoresis (DGGE) revealed a highly heterogeneous picture throughout the soil profiles. Subsequent sequencing of DGGE bands revealed in total 252 sequences that could be assigned to 114 operational taxonomic units, showing the dominance of members of the Bacteroidetes and Acidobacteria. The results of phospholipid fatty acid analysis showed a lack of unsaturated fatty acids for most of the samples. Samples with a prevalence of unsaturated over saturated fatty acids were restricted to several surface samples. Statistical analysis showed that the dominant soil bacterial community composition is most affected by TC and TN contents and soil physical factors such as grain size and moisture, but not pH. Keywords

Selected soil properties and bacterial abundance in the glacier forefields 'Black Valley Transect' and 'Glacier Transect' on Larsemann Hills, East Antarctica

Antarctic glacier forefields are extreme environments and pioneer sites for ecological succession. Increasing temperatures due to global warming lead to enhanced deglaciation processes in cold-affected habitats, and new terrain is becoming exposed to soil formation and microbial colonization. However, only little is known about the impact of environmental changes on microbial communities and how they develop in connection to shifting habitat characteristics. In this study, using a combination of molecular and geochemical analysis, we determine the structure and development of bacterial communities depending on soil parameters in two different glacier forefields on Larsemann Hills, East Antarctica. Our results demonstrate that deglaciation-dependent habitat formation, resulting in a gradient in soil moisture, pH and conductivity, leads to an orderly bacterial succession for some groups, for example Cyanobacteria, Bacteroidetes and Deltaproteobacteria in a transect representing 'classical' glacier forefields. A variable bacterial distribution and different composed communities were revealed according to soil heterogeneity in a slightly 'matured' glacier forefield transect, where Gemmatimonadetes, Flavobacteria, Gamma- and Deltaproteobacteria occur depending on water availability and soil depth. Actinobacteria are dominant in both sites with dominance connected to certain trace elements in the glacier forefields.

1-Furoyl-3-methyl-3-phenylthiourea

The title compound, C13H12N2O2S, crystallizes with two independent molecules in the asymmetric unit. The two molecules differ in the conformation of the thiocarbonyl and carbonyl groups, and show the typical geometric parameters of substituted thiourea derivatives. The crystal structure is mainly stabilized by intermolecular N-H center dot center dot center dot O hydrogen bonding.

Geochemical mass-balance and oxygen-isotope constrains on silcrete formation and its paleoclimatic implications in Southern Australia

Two geographically distinct silcrete associations are present in southern Australia, inland and eastern; these were sampled in central South Australia and central Victoria, respectively, At each site, both silicified and immediately adjacent unsilicified parent material were collected. Analytical data from these pairs were used to construct isocons, assuming Zr immobility, and to calculate the volume change and amount of silica introduced during silicification, These results, together with whole-rock oxygen isotope compositions, were used to determine the delta(18)O of th, introduced silica, The results show that the eastern silcretes in central Victoria are probably linked genetically to the associated basalts, weathering of which supplied the introduced silica, This conclusion is based on the close spatial connection between the two, as well as the substantial amount of introduced silica in the silcretes (greater than in the inland silcretes), resulting in volume increases in some eastern silcretes, Oxygen isotopic calculations for the silcretes indicate that the silica precipitated from groundwaters at temperatures slightly higher than present conditions. Silcrete formation apparently occurred during the Miocene and Pliocene (basalts in Victoria younger than Pliocene lack associated silcrete) and may reflect the much wetter climate in southeastern Australia at that time. The inland silcretes of central South Australia can be divided into pedogenic (the most common) and groundwater varieties. The pedogenic silcretes, which show typical soil features like columnar and nodular textures, contain moderate amounts of introduced silica that precipitated by evaporation from saline groundwaters, For the groundwater silcretes, which have massive textures and formed at or close to the water table, insufficient data are available to determine the mode of formation. The inland pedogenic silcretes have probably been farming from the Eocene-Miocene to the present, implying that conditions of seasonally high evaporation have occurred in central Australia during this time period. Thus silcrete formation depends on a complex interplay between climate and silica supply, and it is impossible to generalize that the presence of silcrete is indicative of a particular climate. Likewise, the elemental composition of silcretes, particularly Ti content, is not necessarily of climatic significance, Nevertheless, detailed geochemical and oxygen isotopic studies of a silcrete and its parent material can elucidate the mechanisms of silcrete formation, and if evaporation is indicated as a major factor in silcrete formation, then the climate at the time was likely to have been at least seasonally arid.

Water wave-driven seepage in marine sediments

The action of water waves moving over a porous seabed drives a seepage flux into and out of the marine sediments. The volume of fluid exchange per wave cycle may affect the rate of contaminant transport in the sediments. In this paper, the dynamic response of the seabed to ocean waves is treated analytically on the basis of pore-elastic theory applied to a porous seabed. The seabed is modelled as a semi-infinite, isotropic, homogeneous material. Most previous investigations on the wave-seabed interaction problem have assumed quasi-static conditions within the seabed, although dynamic behaviour often occurs in natural environments. Furthermore, wave pressures used in the previous approaches were obtained from conventional ocean wave theories: which are based on the assumption of an impermeable rigid seabed. By introducing a complex wave number, we derive a new wave dispersion equation, which includes the seabed characteristics (such as soil permeability, shear modulus, etc.). Based on the new closed-form analytical solution, the relative differences of the wave-induced seabed response under dynamic and quasi-static conditions are examined. The effects of wave and soil parameters on the seepage flux per wave cycle are also discussed in detail. (C) 2000 Elsevier Science Ltd. All rights reserved.

Quantum phase-space analysis of the pendular cavity

We perform a quantum-mechanical analysis of the pendular cavity, using the positive-P representation, showing that the quantum state of the moving mirror, a macroscopic object, has noticeable effects on the dynamics. This system has previously been proposed as a candidate for the quantum-limited measurement of small displacements of the mirror due to radiation pressure, for the production of states with entanglement between the mirror and the field, and even for superposition states of the mirror. However, when we treat the oscillating mirror quantum mechanically, we find that it always oscillates, has no stationary steady state, and exhibits uncertainties in position and momentum which are typically larger than the mean values. This means that previous linearized fluctuation analyses which have been used to predict these highly quantum states are of limited use. We find that the achievable accuracy in measurement is fat, worse than the standard quantum limit due to thermal noise, which, for typical experimental parameters, is overwhelming even at 2 mK

Avaliação e correlação de parâmetros físicos e mecânicos de um solo residual granítico

Os solos residuais mostram divergências em relação aos solos transportados modelados pelas teorias da Mecânica dos Solos. Estas divergências são em grande parte devido a uma estrutura de cimentação herdada da rocha mãe. Este estudo foi baseado nos resultados obtidos em sondagens mecânicas e ensaios de penetração dinâmica, estática e laboratoriais e consistiu na avaliação e correlação dos parâmetros que determinam o comportamento geomecânico do terreno, como a resistência e a deformabilidade.