Evolução da região de Santana do Araguaia (PA) com base na geologia e geocronologia Pb-Pb em zircão de granitoides

A região de Santana do Araguaia, foco deste trabalho, localiza-se no sudeste do Estado do Pará, que, por sua vez, fica no sudeste do Cráton Amazônico. Sob o ponto de vista tectônico, posiciona-se no Domínio Santana do Araguaia, interpretado como um terreno arqueano afetado pelo Ciclo Transamazônico. Um estudo petrográfico e geocronológico, com suporte de dados de campo, foi empreendido em granitoides da região com o intuito de desvendar a evolução desse domínio. Em termos modais, as rochas estudadas compõem-se de biotita monzogranito, biotita metagranodiorito, hornblenda-biotita granodiorito, hornblenda-biotita metatonalito e enderbito. Essas rochas apresentam-se não deformadas a moderadamente deformadas, com algumas particularidades: o biotita metagranodiorito apresenta foliação seguindo um trend E-W; o hornblenda-biotita metatonalito possui uma foliação seguindo a direção NW-SE, com mergulhos normalmente altos a subverticais; o biotita monzogranito é isotrópico e os litotipos hornblenda-biotita granodiorito e enderbito apresentam apenas uma leve orientação de seus cristais, perceptível principalmente em lâmina delgada. Esses litotipos foram analisados pelo método de evaporação de Pb de zircão, tendo sido obtidas as seguintes idades: biotita metagranodiorito, 3066 ± 3 Ma e 2829 ± 13 Ma, hornblenda-biotita metatonalito, 2852 ± 2 Ma; biotita monzogranito (ML-08), 2678 a 2342 Ma; hornblenda-biotita granodiorito, 1990 ± 7 Ma; e enderbito, 1988 ± 4 Ma. Os dados geocronológicos indicam que as rochas cristalizaram tanto no Arqueano quanto no Paleoproterozoico, contudo, não foram detectadas evidências que comprovem a ação do Ciclo Transamazônico na região.

Radioatividade e hidroquímica em águas subterrâneas do município de Botucatu (SP)

The main objective of this study is to determine the activity of Po-210, Pb-210 and gross alpha/beta radioactivity in groundwater collected in Botucatu, municipality of the São Paulo state, Brazil. Samples were collected in wells to perform the radiochemical analysis. Most wells are registered in DAEE, Sabesp or CPRM. The activity of polonium was obtained by the method of alpha spectrometry, held in LABIDRO at UNESP, Rio Claro. All samples showed radioactivity values below the maximum allowed by WHO, that are: gross alpha radioactivity = 0,5 Bq/L, gross beta radioactivity = 1,0 Bq/L, Po210 = 0,2 Bq/L and Pb210 = 0,1 Bq/L. The results of hydrochemical analysis were compared with the 1469 Ordinance of the Health Ministry, and all values are bellow the maximum allowed. The data also allowed obtain the samples classification using the Piper diagram. The samples AAB, Quinta do Manacás, Faz. Quatro Irmãs, Sesi, Sitio São José and ITE are classified as calcic bicarbonate; the samples Staroup and Caio are potassic; the samples Banespa and BTC are bicarbonate and mixed interms of dissolved cations; Sitio das Palmeiras sample is sodium bicarbonate; the sample Faz. São Paulo is chlorinated calcic; the sample Sítio Btu-Pardinho chlorinated and mixed interms of dissolved cations

High-resolution summer temperature reconstruction from Lake Silvaplana based on in-situ reflectance spectroscopy

Annually laminated (varved) sediments of proglacial Lake Silvaplana (46 ̊27’N, 9 ̊48’E, 1791 m a.s.l., Engadine, eastern Swiss Alps) provide an excellent archive for quantitative high-resolution (seasonal – annual) reconstruction of high- and lowfrequency climate signals back to AD 1580. The chronology of the core is based on varve counting, Cs-137, Pb-210 and event stratigraphy. In this study we present a reconstruction based on in-situ reflectance spectroscopy. In situ reflectance spectroscopy is known as a cost- and time-effective non destructtive method for semi-quantitative analysis of pigments (e.g., chlorines and carotenoids) and of lithoclastic sediment fractions. Reflectance-dependent absorption (RDA) was measured with a Gretac Macbeth spectrolino at 2 mm resolution. The spectral coverage ranges from 380 nm to 730 nm at 10 nm band resolution. In proglacial Lake Silvaplana, 99% of the sediment is lithoclastic prior to AD 1950. Therefore, we concentrate on absorption features that are characteristic for lithoclastic sediment fractions. In Lake Silvaplana, two significant correlations that are stable in time were found between RDA typical for lithoclastics and meteorological data: (1) the time series R 570 /R 630 (ratio between RDA at 570 nm and 630 nm) of varves in Lake Silvaplana and May to October temperatures at nearby station of Sils correlate highly significantly (calibration period AD 1864 – 1951, r = 0.74, p < 0.01 for 5ptsmoothed series; RMSE is 0.28 ̊C, RE = 0.41 and CE = 0.38), and (2) the minimum reflectance within the 690nm band (min690) data correlate with May to October (calibration period AD 1864 – 1951, r = 0.68, p < 0.01 for 5pt-smoothed series; RMSE = 0.22 ̊C, RE = 0.5, CE = 0.31). Both proxy series (min690nm and R 570 /R 630 values) are internally highly consistent (r = 0.8, p < 0.001). In proglacial Lake Silvaplana the largest amount of sediment is transported by glacial meltwater. The melting season spans approximately from May to October, which gives us a good understanding of the geophysical processes explaining the correlations between lithoclastic proxies and the meteorological data. The reconstructions were extended back to AD 1580 and show a broad corresponddence with fully independent reconstructions from tree rings and documentary data.

Sediment sources and the flood record from Wanghu lake, in the middle reaches of the Yangtze River

A sediment core was collected from the centre of Wanghu Lake, in the Middle Reaches of the Yangtze River. The recent part of the core was dated using a combination of Pb-210 and spheroidal carbonaceous particle (SCP) techniques. Extrapolating this chronology dated the laminated section of the core, between 723 and 881 mm, to the first half of the 18th century and this section was selected for detailed study. The thicknesses of the laminae were measured using reflecting and polarizing microscopes whilst geochemistry was determined by an electron probe. The thickness of the dark layers was found to be positively correlated with titanium concentrations, and negatively correlated with aluminium and potassium concentrations. The thickness of the light layers was found to be negatively correlated with the concentrations of titanium. It is concluded that the dark layers were deposited from the Fushui River, a tributary of the Yangtze River, under periods of normal flow whilst the light Layers were mainly deposited from the Yangtze River itself during flood periods. Documentary evidence for floods occurring in the take catchment corresponded with thick laminations of high titanium concentration. Further, two of the three thickest, light laminations with low titanium concentrations were found to be synchronous with recorded flood dates of the main Yangtze River in its Middle Reaches, but one was synchronous with a local drought. These data suggest that the Lake sediment provides an archive of the relative water levels of the Yangtze and Wanghu including floods of both the main Yangtze River and the local hydrological regime. (c) 2006 Elsevier B.V. All rights reserved.

Sedimentation rates, nitrogen and phosphorus retentions in the largest urban Lake Donghu, China

Sediment core samples were collected in the largest urban Lake Donghu (Stations I and II) in China, and the activities of Pb-210, Ra-226 and Cs-137 were measured by gamma-ray spectrometry. The sedimentation rates, calculated by 210Pb constant rate of supply (CRS) model, ranged from 0.11 to 0.65 (average 0.39) cm(.)y(-1) at Station I, and from 0.21 to 0.78 (average 0.46) cm(.)y(-1) at Station II. Sedimentation rate calculated by Cs-137 as a time marker was 0.55 cm(.)y(-1) at Station II. Based on the average sedimentation rate, we obtained 769 and 147 t(.)y(-1) for nitrogen and phosphorus retentions in Lake Donghu sediments, respectively.

Element enrichment and U-series isotopic characteristics of the hydrothermal sulfides at Jade site in the Okinawa Trough

The geochemical and U-series isotopic characteristics of hydrothermal sulfide samples from the Jade site (127A degrees 04.5'E, 27A degrees 15'N, water depth 1300-1450 m) at Jade site in the Okinawa Trough were analyzed. In the hydrothermal sulfide samples bearing sulfate (samples HOK1 and HOK2), the LREEs are relatively enriched. All the hydrothermal sulfide samples except HOK1 belong to Zn-rich hydrothermal sulfide. In comparison with Zn-rich hydrothermal sulfides from other fields, the contents of Zn, Pb, Ag, Cd, Au and Hg are higher, the contents of Fe, Al, Cr, Co, Ni, Sr, Te, Cs, Ti and U lower, and the Pb-210 radioactivity ratios and Pb-210/Pb ratios very low. In the hydrothermal sulfide mainly composed of sphalerite, the correlations between rare elements Hf and U, and Hf and Mn as well as that between dispersive elements Ga and Zn, are strongly positive; also the contents of Au and Ag are related to Fe-sulfide, because the low temperature promotes enrichment of Au and Ag. Meanwhile, the positive correlations between Fe and Bi and between Zn and Cd are not affected by the change of mineral assemblage. Based on the Pb-210/Pb ratios of hydrothermal sulfide samples (3.99x10(-5)-5.42x10(-5)), their U isotopic composition (U-238 content 1.15-2.53 ppm, U-238 activity 1.07-1.87 dpm/g, U-234 activity 1.15-2.09 dpm/g and U-234/U-238 ratio 1.07-1.14) and their Th-232 and Th-230 contents are at base level, and the chronological age of hydrothermal sulfide at Jade site in the Okinawa Trough is between 200 and 2000 yr.

Sedimentary features of the Yangtze River-derived along-shelf clinoform deposit in the East China Sea

A predominant sigmoidal clinoform deposit extends from the Yangtze River mouth southwards 800 kin along the Chinese coast. This clinoform is thickest (similar to 40m) between the 20 and 30 m isobaths and progressively thins offshore, reaching water depths of 60 and 90 m and distances up to 100 km offshore. Clay mineral, heavy metal, geochemical and grain-size analyses indicate that the Yangtze River is the primary source for this longshore-transported clinoform deposit. Pb-210 chronologies show the highest accumulation rates (> 3 cm/yr) occur immediately adjacent to the Yangtze subaqueous delta (north of 30 degrees N), decreasing southward alongshore and eastward offshore. The interaction of strong tides, waves, the China Coastal Current, winter storms, and offshore upwelling appear to have played important roles in trapping most Yangtze-derived sediment on the inner shelf and transporting it to the south. (c) 2006 Elsevier Ltd. All rights reserved.

北黄海西部泥质沉积特征与成因探讨

本文的研究的主要目的是了解北黄海泥质区的沉积特征和形成的动力过程。基于此目的，在北黄海西部海区进行了两次海洋地质与地球物理调查，并根据对浅钻样品的粒度分析和~（210）Pb沉积速率的测定，结合浅地层剖面的解译以及ADCP流速资料的处理，探讨了北黄海西部的沉积层序，讨论了泥质区的物质来源与形成原因，分析了北黄海中部泥质沉积的~（210）Pb沉积速率在一定的动水条件下的可信度，并对柱状样粒度参数的相关分析与地层对比之间的关系进行了初步的阐述。浅地层剖面与岩芯粒度分析表明，北黄海西部的地层划分为三层：上层为粘土沉积，位于北黄海中部、山东半岛沿岸和辽东半岛东南岸；中层为粉砂沉积，分布区域与粘土沉积类似，或者位于粘土沉积之下，或者直接出露海底；下层为粗颗粒砂质沉积，颁上于整个海区，在粘土沉积和/或粉砂沉积存在的海域，砂质沉积位于这些沉积的下部，而在其他海域则直接出露海底。粘土沉积与粉砂沉积统称为泥质沉积，内部结构较均一，粒度的垂向变化不大，但两层之间在粒度和地层反射信号等方面的差异还是很明显的，在山东半岛沿岸构成了泥质沉积的两相结构。粗颗粒沉积的粒度垂向变化较大，与上层细颗粒沉积之间的差异显著。泥质沉积的厚度以山东半岛东端最大，约30m。而沉积速率却很小，在mm/a的量级上，因此在全新世最大海侵后的几千年内形成巨厚的沉积是不可能的，其主要物源可能是古河流。渤海海峡区泥质沉积厚度从南向北、从西向东逐渐变薄，从西向东沉积速率逐渐减小，但沉积速率的绝对值较大，可以在全新世最大海侵后的几千年内形成如此厚的沉积。北黄海中部泥质沉积厚度约在8m左右，位于泥质沉积边缘岩芯中泥炭层的~（14）C年代约10000aBP，而且~（210）Pb沉积速率较小，无法满足几千年内堆积厚层沉积的需要，因此，该处泥质沉积的主体并非全新世最大海侵后形成的，而是早全新世海侵过程中的海岸侵蚀与海底物质的再改造作用提供了沉积物质。整个北黄海西部的泥质沉积总量约有4.41 * 10~（11）t。对于两个沉积环境可能相似的柱状岩芯，利用粒度参数求取各个层位的最大相关系数，可以找到具有良好对应关系的层位，其沉积年龄相近。或者说，在已知一个岩芯的粒度参数和层位年龄的情况下，可以应用柱状样粒度参数的相关分析，推得另一个粒度参数已知的岩芯的年龄。理论上，这种方法适用于来自相同动力环境的岩芯。利用水动力条件与悬沙浓度计算北黄海中部泥质区的沉降通量，与~（210）Pb测得的结果对比，发现对于粘性颗粒两者的值非常近似，说明在该区的动水条件下~（210）Pb测年法对粘性沉积物的测定结果有很好的可信度。

Environmental changes reflected by sedimentary geochemistry in recent hundred years of Jiaozhou Bay, North China

Sediment geochemical technique was employed to assess how the sediment records reflect the environmental changes of Jiaozhou Bay, a semi-enclosed bay adjacent to Qingdao, China. In the past hundred years, Jiaozhou Bay has been greatly impacted by human interventions. A dated core sediment by Pb-210 chronology was analyzed for trace metals including Li, Cd, Cr, Pb, Cu, Ni, Co, Zn together with C, N, P and BSi. Based on the research, the development of Jiaozhou Bay environment in the past hundred years can be divided into three stages: (1) before the 1980s characterized by relatively low sedimentation rate, weak heavy metal pollution and scarce eutrophication; (2) from the 1980s to 2000, accelerating in the 1990s, during which high sedimentation rates, polluted by heavy metals and the frequent occurrence of red tide; (3) after 2000, the period of the improvement of environment, the whole system has been meliorated including the heavy metal pollution and hypernutrification. (c) 2006 Elsevier Ltd. All rights reserved.

Response of the diatom flora in Jiaozhou Bay, China to environmental changes during the last century

The diatom flora in a 164 cm long sediment core obtained from Jiaozhou Bay (Yellow Sea, China) was analyzed in order to trace the response of diatoms to environmental changes over the past 100 years. The sediment core was dated by Pb-210 and Cs-137 and represented approximately 100 years (1899-2001 A.D.). The flora was mainly composed of centric diatoms (59-96%). The concentration of diatoms declined sharply above 30 cm (after similar to 1981 A.D.), while the dominant species changed from Thalassiosira anguste-lineatus, Thalassiosira eccentria, Coscinodiscus excentricus, Coscinodiscus concinnus and Diploneis gorjanovici to Cyclotella stylorum and Paralia sulcata. Species richness decreased slightly, and the cell abundance of warm-water species increased. We argue that these floral changes were probably caused by climate change in combination with eutrophication resulting from aquaculture and sewage discharge. (c) 2007 Elsevier B.V. All rights reserved.

微量样品钕-锶-铅同位素分析方法在黄河下游悬浮颗粒物及沉积物的应用

Aim in Rb-Sr-REE-Pb isotopic analysis of river material, a single-stage, highly efficient and rapid chemical separation method of Rb-Sr-REE-Pb has been established by a combination of the SR special resin and the RE resin. At the same time, Feasibility of high precision analysis on micro-size Nd samples，which were chemically separated by using the LN resin, were systematicly studied using the NdO+ technique in thermal ionization mass spectrometer (TIMS). Results show that high precision measurement of Nd isotopic ratios can be successfully achieved on micro-sample of 1 ng size lever, by systematic experiments on isobar interferences and optimizing separation and measurement conditions. This method will greatly extend the application prospect of the NdO+ technique. Sr-Nd-Pb isotopic composition of suspending particle material (SPM) and sediment and Sr isotopic composition of river water in the low reaches of the Yellow Rriver have been systematically analysed in this study. Results can indicate followings: (1) relative stable Sr isotopic ratios around 0.7112 of river water suggest great influcence from dissolution of carbonate component of loss material on Sr isotopic composition of river water; (2) Nd isotopic compositions of SPM and sediment of the Yellow river are is similar, mean εNd value of SPM around -11.5 and mean εNd value of sediment -12.7, slightly lower than that of SPM. Nd isotopic composition of the Yellow River material is simarlar to or slightly lower than loss material (-9.5); (3) evidence of Sr and Pb isotopic compositions of both SPM and sediment reveals a mixing trend of two endmembers. Sr isotopic ratios of SPM after leaching are significantly different that those without leaching, possibly suggesting strong alteration of river water. Pb isotopic ratios of SPM remain unchangable after leaching compared with unleached SPM; (4) Pb-contents of SPM are commonly higher than those of sediments, while Pb isotopic ratios of SPM are significantly lower. Pb isotopic composition of the Yellow River is relatively constant, which can be a useful provenance indicator between the Changjiang and Yellow Rivers.

湖光岩玛珥湖沉积物硅藻硅同位素研究

本论文选取我国的典型玛珥湖－湖光岩玛珥湖为研究对象，在国内外率先系统开展湖泊沉积物硅藻硅同位素研究。为获取过去2000a来的气候环境记录，对原有沉积物-水界面采样装置进行了改进，将沉积物柱芯无扰动采集深度从60cm提高到150cm。建立了一套有效的五阶段硅藻提纯方法，成功从初始硅藻含量大于7%的沉积物中提取出纯度达90％以上的硅藻样品，为广泛开展沉积物硅藻硅氧同位素研究奠定了基础。放射性核素Pb-210、Cs-137、C-14计年结果表明，该湖沉积物堆积速率稳定，具连续、稳定的堆积特点，是气候和环境变化的良好记录体。湖光岩玛珥湖沉积物硅藻硅同位素记录了硅藻利用水体溶解硅的比例变化。沉积物硅藻硅同位素与生物硅含量的变化关系为揭示湖泊古环境提供了重要线索。当硅藻硅同位素组成与生物硅含量呈正相关变化时，湖水溶解硅利用比例主要受温度控制，硅藻硅同位素可反映古温度变化。当硅藻硅同位素组成与生物硅含量不呈相似变化时，湖水溶解硅利用比例主要受有效养分控制，沉积物硅藻硅同位素仅仅反映硅藻利用水体溶解硅的比例，不反映古温度变化。湖光岩玛珥湖沉积物柱芯硅藻硅同位素组成的变化范围为 -0.6‰～1.1‰，其最小值出现于1580～1920年间，指示了1580～1920年为湖光岩地区过去2000年来最冷的时期，为中国南方热带地区现代小冰期的存在提供了新的证据。

Nineteenth and twentieth century sea-level changes in Tasmania and New Zealand

Positive deviations from linear sea-level trends represent important climate signals if they are persistent and geographically widespread. This paper documents rapid sea-level rise reconstructed from sedimentary records obtained from salt marshes in the Southwest Pacific region (Tasmania and New Zealand). A new late Holocene relative sea-level record from eastern Tasmania was dated by AMS(14)C (conventional, high precision and bomb-spike), Cs-137, Pb-210, stable Pb isotopic ratios, trace metals, pollen and charcoal analyses. Palaeosea-level positions were determined by foraminiferal analyses. Relative sea level in Tasmania was within half a metre of present sea level for much of the last 6000 yr. Between 1900 and 1950 relative sea level rose at an average rate of 4.2 +/- 0.1 mm/yr. During the latter half of the 20th century the reconstructed rate of relative sea-level rise was 0.7 +/- 0.6 mm/yr. Our study is consistent with a similar pattern of relative sea-level change recently reconstructed for southern New Zealand. The change in the rate of sea-level rise in the SW Pacific during the early 20th century was larger than in the North Atlantic and could suggest that northern hemisphere land-based ice was the most significant melt source for global sea-level rise. (C) 2011 Elsevier B.V. All rights reserved.

Flow injection analysis (FIA) determination of lead by hydride generation in banded coral skeletons /

A flow injection hydride generation direct current plasma atomic emission spectrometric (FI-HG-DCP-AES) method was developed for the determination of lead at ng.ml-l level. Potassium ferricyanide (K3Fe(CN)6) was used along with sodium tetrahydroborate(III) (NaBH4) to produce plumbane (PbH4) in an acid medium. The design of a gas-liquid separator (hydride generator) was tested and the parameters of the flow injection system were optimized to achieve a good detection limit and sample throughput. The technique developed gave a detection limit of 0.7 ng.ml-l(3ob). The precision at 20 ng.ml"* level was 1.6 % RSD with 1 1 measurements (n=l 1). Volume of sample loop was 500 |J.l. A sample throughput of 120 h"^ was achieved. The transition elements, Fe(II), FeOH), Cd(n), Co(II), Mn(n), Ni(II) and Zn(n) do not interfere in this method but 1 mg,l'l Cu(II) will suppress 50 % of the signal from a sample containing 20 ng.ml'l Pb. This method was successfully applied to determine lead in a calcium carbonate (CaC03) matrix of banded coral skeletons from Si-Chang Island in Thailand.

Onset of recent rapid sea-level rise in the western Atlantic Ocean

A high-resolution record of sea-level change spanning the past 1000 years is derived from foraminiferal and chronological analyses of a 2m thick salt-marsh peat sequence at Chezzetcook, Nova Scotia, Canada. Former mean tide level positions are reconstructed with a precision of +/- 0.055 in using a transfer function derived from distributions of modern salt-marsh foraminifera. Our age model for the core section older than 300 years is based on 19 AMS C-14 ages and takes into account the individual probability distributions of calibrated radiocarbon ages. The past 300 years is dated by pollen and the isotopes Pb-206, Pb-207, Pb-210, Cs-137 and Am-241. Between AD 1000 and AD 1800, relative sea level rose at a mean rate of 17cm per century. Apparent pre-industrial rises of sea level dated at AD 1500-1550 and AD 1700-1800 cannot be clearly distinguished when radiocarbon age errors are taken into account. Furthermore, they may be an artefact of fluctuations in atmospheric C-14 production. In the 19th century sea level rose at a mean rate of 1.6mm/yr. Between AD 1900 and AD 1920, sea-level rise accelerated to the modern mean rate of 3.2mm/yr. This acceleration corresponds in time with global temperature rise and may therefore be associated with recent global warming. (c) 2005 Elsevier Ltd. All rights reserved.