Poluentes orgânicos persistentes em ar interior: desenvolvimento de método de extração em adsorvente para amostragem ativa

Persistent Organic Pollutants (POPs) are chemical substances extraordinarily toxic and persistent in the environment. Due to these properties, POPs are targets of the Stockholm Convention which aims to provide means to eliminate production and use by encouraging the reduction and, where possible, eliminating the release of these contaminants to the environment. One of the articles of this _Convention aims to assess the basal levels of such substances in the environment to monitor both the reduction of release to the environment, and to assess human exposure, using analyzes of milk and air for example. Although efforts to control POPs production and release to the environment have been made, data about their levels in Brazil are still scarce, mainly in the atmosphere or indoor environment. Considering the permanence of people inside its house, this study presents a method for POP extraction from XAD-2 sorbent employed in indoor air sampling, with identification and quantification by GC-ECD. GC-ECD linear range of the studied analytes, congeners of polychlorinated biphenyls (PCB) (28, 52, 101, 118, 138, 153 and 180), DDTs and their metabolites (DDDs, DDEs) and endosullan (isomers c - and 13 - and metabolite endosulfan sulfate) ranged between 0.5 and 16.0 ng mL-I with r2 > 0.967. The method developing consist of selecting the extraction solvent system by agitation (90 rpm, 1 hour) with n-hexan,e (2 mL) or n-hexane:acetone (1:1, v/v) (2 mL), concentration the extract with a gentle N2 stream, and evaluation of breakthrough with passage or air through the fortified XAD-2 cartridge before extraction, employing a low volume air suction pump (Pump Model 224 universal-PCXR8; 5-5000 mL min-1, SKC Inc., Eighty Four, PA, USA), Calibrator Dry-Cal DC-Lite (BIOS, Butler, NJ, USA)). Two fortification levels were employed, 15 and 30 ng. After selecting n-hexane as extraction solvent, with accuracy and precision ranging...

Integração da simulação termoenergética com o processo de projeto: a análise de 6 casos

This work consists of the integrated design process analyses with thermal energetic simulation during the early design stages, based on six practical cases. It aims to schematize the integration process, identifying the thermal energetic analyses contributions at each design phase and identifying the highest impact parameters on building performance. The simulations were run in the DesignBuilder energy tool, which has the same EnergyPlus engine, validated. This tool was chosen due to the flexible and user friendly graphic interface for modeling and output assessment, including the parametric simulation to compare design alternatives. The six case studies energy tools are three architectural and three retrofit projects, and the author the simulations as a consultant or as a designer. The case studies were selected based on the commitment of the designers in order to achieve performance goals, and their availability to share the process since the early pre-design analyses, allowing schematizing the whole process, and supporting the design decisions with quantifications, including energy targets. The thermoenergetic performance analyses integration is feasible since the early stages, except when only a short time is available to run the simulations. The simulation contributions are more important during the sketch and detail phases. The predesign phase can be assisted by means of reliable bioclimatic guidelines. It was verified that every case study had two dominant design variables on the general performance. These variables differ according the building characteristics and always coincide with the local bioclimatic strategies. The adaptation of alternatives to the design increases as earlier it occurs. The use of simulation is very useful: to prove and convince the architects; to quantify the cost benefits and payback period to the retrofit designer; and to the simulator confirm the desirable result and report the performance to the client

PERCEPÇÃO DO CONFORTO TÉRMICO NO BAIRRO JARDIM CLARET, RIO CLARO-SP

O solo é um recurso básico que suporta toda a cobertura vegetal da terra, sem a qual os seres vivos não poderiam existir. Nessa cobertura, incluem-se não só as culturas como, também, todos os tipos de árvores, gramíneas, raízes e herbáceas que podem ser utilizadas pelo homem. (BERTONI; LOMBARDI NETO, 1990). As cidades se fixaram e se expandiram ocupando o solo sem análise prévia da sua susceptibilidade, principalmente o entorno de rios e córregos, que na atualidade são protegidas por leis especificas (APP). Conforme a cidade se expandiu sem planejamento, o processo tornou-se degradante ao espaço natural. Este trabalho tem como objetivo analisar o conflito entre o uso e a ocupação do solo em Área de Preservação Permanente, e as leis que protegem esses espaços. Para atingir tais objetivos foi realizado pesquisa bibliográfica e trabalhos de campos para caracterizar o uso e ocupação do solo do entorno do rio Corumbataí próximo ao município de Rio Claro, São Paulo, Brasil. Na segunda etapa foram realizadas as análises pertinentes a discussão.