Isotopic feature and uranium dating of the volcanic rocks in the Okinawa Trough

Volcanic rocks from the northern and middle Okinawa Trough were dated by uranium-series dating method. Differential fractions using magnetic procedure were designed to separate samples. New report on the ages and isotopic data of rocks in the northern trough (especially black pumice) was discussed. Based on the uranium dates and Sr-Nd isotopic ratio, magmatic evolution process of the Okinawa Trough was noted. Firstly, there have been wide silicic volcanic activities in the Okinawa Trough from late Pleistocene to present, and the volcanic rocks can be divided into three subgroups. Secondly, magma generally came from PREMA source area under the Okinawa Trough. Magmatic evolution in the northern trough was similar to the middle, but different to the south. Finally, volcanic activities indicated that opening of the southern Okinawa Trough did not happen due to the collision between Luson Arc and Eurasian Plate until the early Pleistocene.

The characteristics of fluid potential in mud diapirs associated with gas hydrates in the Okinawa Trough

Many mud diapirs have been identified in the southern Okinawa Trough from a seismic survey using R/V KEXUE I in 2001. The movement and accumulation of free gas related to mud diapirs are discussed in detail by an analysis of fluid potential which is based upon velocity data. It can be found that free gas moves from the higher fluid potential strata to the lower ones and the gas hydrate comes into being during free gas movement meeting the proper criteria of temperature and pressure. In fact, gas hydrates have been found in the upper layers above the mud diapirs and in host rocks exhibiting other geophysical characteristics. As the result of the formation of the gas hydrate, the free gas bearing strata are enclosed by the gas hydrate bearing strata. Due to the high pressure anomalies of the free gas bearing strata the fluid potential increases noticeably. It can then be concluded that the high fluid potential anomaly on the low fluid potential background may be caused by the presence of the free gas below the gas hydrate bearing strata.

Bottom simulating reflector and gas seepage in Okinawa Trough: Evidence of gas hydrate in an active back-arc basin

To look for gas hydrate, 22 multi-channel and 3 single-channel seismic lines on the East China Sea (ECS) shelf slope and at the bottom of the Okinawa Trough were examined. It was found that there was indeed bottom simulating reflector (BSR) occurrence, but it is very rare. Besides several BSRs, a gas seepage was also found. As shown by the data, both the BSR and gas seepage are all related with local geological structures, such as mud diapir, anticline, and fault-controlled graben-like structure. However, similar structural "anomalies" are quite common in the tectonically very active Okinawa Trough region, but very few of them have developed BSR or gas seepage. The article points out that the main reason is probably the low concentration of organic carbon of the sediment in this area. It was speculated that the rare occurrence of gas hydrates in this region is governed by structure-controlled fluid flow. Numerous faults and fractures form a network of high-permeability channels in the sediment and highly fractured igneous basement to allow fluid circulation and ventilation. Fluid flow in this tectonic environment is driven primarily by thermal buoyancy and takes place on a wide range of spatial scales. The fluid flow may play two roles to facilitate hydrate formation: to help gather enough methane into a small area and to modulate the thermal regime.

Balanced cross section for restoration of tectonic evolution in the southwest Okinawa Trough

On the basis of the multi-channel seismic data and the other data, using 2DMove software, the tectonic evolution in three seismic profiles was restored since Pliocene. The tectonic restoration results show that: (1) the initial active center lay in the west slope and then was transferred to east and south via trough center during the evolution process; (2) several main normal faults controlled the evolution of the southern Okinawa Trough; (3) since Late Pliocene, the southern Okinawa Trough has experienced two spreading stages. The early is depression in Early-Middle Pleistocene and the late is back-are spreading in Late Pleistocene and Holocene, which is in primary oceanic crust spreading stage.

Contents and isotopic speciation of sedimentary carbon and nitrogen in sediment core MD01-2404, the Okinawa Trough

Total organic carbon to total nitrogen ratio (C/N) and their isotopic composition (d13CTOC vs. d15NTN) are oft-applied proxies to discern terrigenous from marine sourced organics and to unravel the ancient environmental information. In high depositional Asian marginal seas, matrixes, including N-bearing minerals, dilution leads to illusive and even contradictive interpretations. We use KOH-KOBr to separate operationally defined total organic matter into oxidizable (labile) and residual fractions for content and isotope measurements. In a sediment core in the Okinawa Trough, significant amounts of carbon and nitrogen existed in the residual phase, in which the C/N ratio was ~9 resembling most documented sedimentary bulk C/N ratios in the China marginal seas. Such similarity creates a pseudo-C/N interrupting the application of bulk C/N. The residual carbon, though composition unknown, it displayed a d13C range (-22.7 to -18.9 per mil, mean -20.7 per mil) similar to black carbon (-24.0 to -22.8 per mil) in East China Sea surface sediments. After removing residual fraction, we found the temporal pattern of d13CLOC in labile fraction (LOC) was more variable but broadly agreed with the atmospheric pCO2-induced changes in marine endmember d13C. Thus, we suggested adding pCO2-induced endmember modulation into two-endmember mixing model for paleo-environment reconstruction. Meanwhile, the residual nitrogen revealed an intimate association with illite content suggesting its terrestrial origin. Additionally, d15N in residual fraction likely carried the climate imprint from land. Further studies are required to explore the controlling factors for carbon and nitrogen isotopic speciation and to retrieve the information locked in the residual fraction.

Sea surface temperature oscillations in southern Okinawa Trough during last 2700 years from ODP Hole 195-1202B

Most of the temperature reconstructions for the past two millennia are based on proxy data from various sites on land. Here we present a bidecadal resolution record of sea surface temperature (SST) in Southern Okinawa Trough for the past ca. 2700 years by analyzing tetraether lipids of planktonic archaea in the ODP Hole 1202B, a site under the strong influence of Kuroshio Current and East Asian monsoon. The reconstructed SST anomalies generally coincided with previously reported late Holocene climate events, including the Roman Warm Period, Sui-Tang dynasty Warm Period, Medieval Warm Period, Current Warm Period, Dark Age Cold Period and Little Ice Age. However, the Medieval Warm Period usually thought to be a historical analogue for the Current Warm Period has a mean SST of 0.6-0.8°C lower than that of the Roman Warm Period and Sui-Tang dynasty Warm Period. Despite an increase since 1850 AD, the mean SST in the 20th century is still within the range of natural variability during the past 2700 years. A close correlation of SST in Southern Okinawa Trough with air temperature in East China, intensity of East Asian monsoon and the El-Niño Southern Oscillation index has been attributed to the fluctuations in solar output and oceanic-atmospheric circulation.

(Table T1) Pore water chemistry of ODP Site 195-1202 sediments, southern Okinawa Trough

Pore water was collected from sediment cores from Holes 1202A and 1202D in the southern Okinawa Trough during Ocean Drilling Program (ODP) Leg 195. Because drilling at this site was completed only a few hours out of port during the end of the leg, whole rounds of sediment core 5 or 10 cm long were sealed and stored at ~3°C until pore water could be extracted from them during Leg 196, using a titanium squeezer designed by Manheim and Sayles (1974) and standard handling techniques (Shipboard Scientific Party, 2002, doi:10.2973/odp.proc.ir.195.103.2002).

Helium, neon and argon isotope compositions of fluid inclusions in massive sulfides from the Jade hydrothermal field, the Oldnawa Trough

Helium, neon and argon isotope compositions of fluid inclusions have been measured in massive sulfide samples from the Jade hydrothermal field in the central Okinawa Trough. Fluid-inclusion He-3/He-4 ratios are between 6.2 and 10.1 times the air value (Ra), and with a mean of 7.8Ra, which are consistent with the mid-ocean ridge basalt values [He-3/He-4 approximate to (6Rasimilar to 11Ra)]. Values for Ne-20/Ne-22 are from 10.7 to 11.3, which are significantly higher than the atmospheric ratio (9.8). And the fluid-inclusion Ar-40/Ar-36 ratios range from 287 to 334, which are close to the atmosperic values (295.5). These results indicate that the noble gases of trapped hydrothermal fluids in massive sulfides are a mixture of mantle- and seawater-derived components, and the helium of fluid inclusions is mainly from mantle, the nelium and argon isotope compositions are mainly from seawater.

The stability zone of gas hydrate in the slope of East China Sea and neighboring trough basin area

We analyze the distribution of temperature and heat flow of the sea floor sediment in the area of East China Sea slope and West basin area of the Okinawa Trough. Based on the Sonar Buoy and OBS data, 6 velocity layers are recognized, each of which has velocity of 1.8(1.8 similar to 2.2) km/s,2.2(2.0 similar to 2.5)km/s,2.8 (2.7 similar to 3.2)km/s,3.4 similar to 3.6km/s,4.2(4.1 similar to 4.7)km/s and 5.1km/s, respectively. The upper velocity layer of 1.8 similar to 2.2 km/s corresponds to the Quaternary sediment stratum. The layer with velocity 3.4 similar to 4.2km/s is the Pliocene sediment stratum. The area that is suitable for stable existence of gas hydrate by the temperature and pressure is 70,000km(2) about 1/10 the total area of East China Sea. The thickness of the stability zone ranges from 400m (Middle Part of Okinawa Trough) to 1100m (North and South Part of Okinawa Trough). The Quaternary and Pliocene layers are suitable for stable exitence of gas hydrate. According to the tectonic stability and heat flow, the north part and south part of the Okinawa Trough are the most perspective area for the gas hydrate explorations.

冲绳海槽北部PC-1岩芯24 cal.kaBP 以来孢粉记录的古环境信息

东海陆架是世界上最宽阔的陆架之一，面积达770 000 km2左右。在末次冰盛期（LGM），东海海平面下降120～130 m左右，绝大部分陆架暴露出海面。而冲绳海槽是第四纪以来一直保持海洋环境的东海深海区。本文以冲绳海槽北部PC-1岩芯为材料，通过分析该孔的孢粉，加上详细的AMS 14C测年，恢复了周边地区24 cal.kaBP以来的古植被，并推测古环境和古气候变化，重点讨论了LGM时期出露大陆架上发育的植被。 PC-1孔（31°27.5′N，128°24.8′E）位于黑潮支流对马暖流东侧，水深590 m，柱长812 cm。孢粉分析按间隔8 cm取样，个别为4~6 cm，共分析了103个孢粉样品。利用9个AMS 14C数据建立年龄标尺，用Calib5.1.0软件进行年龄校正。通过相邻样品深度的线性内插获得每个样品的年龄，采用外延法得到顶部和底部的校正年龄分别为351cal aBP、24 280 cal aBP，孢粉样品的时间分辨率平均为230 a。 根据孢粉百分比和沉积率的变化，可划分出四个带：Ⅰ带（812～715 cm，24.2～21.1 cal. kaBP）、Ⅱ带（715～451 cm，21.1～15.2 cal. kaBP）、Ⅲ带（451～251 cm，15.2～10.8 cal. kaBP）、Ⅳ带（251～0 cm，10.8～0.3 cal. kaBP），分别对应MIS 3末期、末次冰盛期、冰消期和全新世。末次冰盛期草本植物花粉占优势，孢粉沉积率较高，此时草本花粉主要来源于出露的大陆架，其上发育了以蒿属为主的草地植被，气候比较寒冷干燥；冰消期海平面开始回升，松属花粉含量升高，草本植物花粉含量下降；全新世以木本植物花粉占绝对优势，栗属－栲属花粉迅速增加，蕨类孢子含量升高，草本植物花粉含量锐减，孢粉沉积率降低，由于海平面回升，大陆架被淹没，此时孢粉主要来源于日本岛，九州地区生长了以栲属、栎属为主的常绿阔叶与落叶阔叶林，气候温暖湿润。 叶枝杉属花粉在整个岩芯中零星出现。叶枝杉属植物分布于菲律宾吕宋北部至塔斯马尼亚和新西兰气候潮湿的山地林中，该属花粉在岩芯中的出现，可能暗示了黑潮的影响或者是较强的夏季风。 草本植物与松属花粉百分比变化很好的反映了海平面的升降，松属花粉含量较高指示海平面较高。对岩芯中主要类型的花粉百分比进行了频谱分析，显示存在千年尺度的准周期变化，有明显的6.8，3.8，2.2，1.6 ka的周期。 孢粉样品中的炭屑统计表明，末次冰消期炭屑含量最高，可能因为末次冰消期降雨量增加，炭屑可被降水带到沉积地点沉积下来；全新世的炭屑浓度较高，尤其在晚全新世，出现了一个峰值，究其原因可能与气候变化和人类活动有关。

Tectonic geomorphology of the Ryukyu Trench-Arc-Backarc System: geological-geophysical exploration and mapping

OKINAWA TROUGH; BASIN

Formation and evolution of the modern warm current system in the East China Sea and the Yellow Sea since the last deglaciation

To reconstruct the formation and evolution process of the warm current system within the East China Sea (ECS) and the Yellow Sea (YS) since the last deglaciation, the paleoceangraphic records in core DGKS9603, core CSH1 and core YSDP102, which were retrieved from the mainstream of the Kuroshio Current (KC), the edge of the modern Tsushima Warm Current (TWC) and muddy region under cold waters accreted with the Yellow Sea Warm Current (YSWC) respectively, were synthetically analyzed. The results indicate that the formation and evolution of the modern warm current system in the ECS and the YS has been accompanied by the development of the KC and impulse rising of the sea level since the last deglaciation. The influence of the KC on the Okinawa Trough had enhanced since 16 cal kyr BP, and synchronously the modern TWC began to develop with the rising of sea level and finally formed at about 8.5 cal kyr BP. The KC had experienced two weakening process during the Heinrich event 1 and the Younger Drays event from 16 to 8.5 cal kyr BP. The period of 7-6 cal kyr BP was the strongest stage of the KC and the TWC since the last deglaciation. The YSWC has appeared at about 6.4 cal kyr BP. Thus, the warm current system of the ECS and the YS has ultimately formed. The weakness of the KC, indicated by the occurrence of Pulleniatina minimum event (PME) during the period from 5.3 to 2.8 cal kyr BP, caused the main stream of the TWC to shift eastward to the Pacific Ocean around about 3 cal kyr BP. The process resulted in the intruding of continent shelf cold water mass with rich nutrients. Synchronously, the strength of the YSWC was relatively weak and the related cold water body was active at the early-mid stage of its appearance against the PME background, which resulted in the quick formation of muddy deposit system in the southeastern YS. The strength of the warm current system in the ECS and the YS has enhanced evidently, and approached to the modern condition gradually since 3 cal kyr BP.

The history of the Yangtze River entering sea since the last glacial maximum: a review and look forward

This review paper provides a brief review on the development of ideas in the fields of the sea level change of the ECS (East China Sea), the history of the Yangtze River entering the sea and paleochannels in the shelf of the ECS since the Last Glacial Maximum (LGM). The paper summarizes two opposite theories about the Yangtze River entering the sea during the LGM. One theory is that the Yangtze River input a lacustrine in the north of Jiangsu province which was defunct in middle Holocene, and the river was once dry. The other was that the Yangtze River still existed and entered into the Okinawa Trough during the LGM, but scholars share different opinions on which course the river ran across and which place the river input the trough. This paper concludes future work is to study the evolution of the Yangtze River and the paleoclimate and the corresponding events as a whole from the view of regional and even global change, and more attention should be paid to the study on mud sediment, the Yangtze River's response to the changes in climate and sea-level, and the channel metamorphosis.

Radiolarian fauna in surface sediments of the northeastern East China Sea

Radiolarian abundance and species composition have been determined in 72 surface: sediment samples from the northeastern East China Sea. The results are compared with chemical and physical properties of the overlying water masses, and with sediment conditions. In the study area, radiolarian abundance and species number increase markedly from northwest to southeast, and their distributions can be divided into three provinces: the low-density zone corresponding to the shelf, the middle-density zone corresponding to the western slope of the Okinawa Trough and the high-density zone corresponding to the central part of the Okinawa Trough. The distribution of radiolarians correlates well with modem sea surface temperature and sea surface salinity, but shows a negative relation with nutrients and primary productivity of the overlying water. This distribution pattern is also strongly affected by the sediment type and terrigenous material input. Also, the Kuroshio Current has an important effect on controlling the distribution and species composition of radiolarian fauna in this area. Based on three Q-mode factors (accounting for 90.2% of the variance), three radiolarian assemblages have been distinguished, and their distributions are clearly correlated with oceanographic current patterns in the region. The mixed water assemblage dominated by Tetrapyle circularis, Tetrapyle quadriloba and Ommatartus tetrathalamus tetrathalamus is restricted to the area of the Mixed Water, but mainly influenced by the Shelf Water. The Kuroshio Water assemblage, which is dominated by Lithelius minor, Dictyocoryne profunda, Stylodictya multispina, Acrosphaera spinosa, Dictyocoryne truncatum, Spongaster tetrars, Stylodictya arachnia and Ommatartus tetrathalamus tetrathalamus, is basically controlled by the Kuroshio Surface Water. And the transition assemblage dominated by Tetrapyle quadriloba and Monozonium pachystylum is associated with the Tsushima Warm Current Water. The boundaries among these assemblages approximately coincide with the oceanographic front. And the changes in the distribution of these assemblages could be,regarded as-not only modifications of the water masses, but also indicators of the possible movements of the oceanic front. (C) 2003 Elsevier Science B.V. All rights reserved.

Preliminary analysis of grain-size populations with environmentally sensitive terrigenous components in marginal sea setting

Terrigenous components were separated from the bulk sediment of Core A7 from the Okinawa Trough and Core A37 from the Ryukru Trench and grain-size distributions of these sub-samples were analyzed. Based upon an analysis of the grain-size data of the two sedimentary sequences, grain-size populations are identified to be sensitive to sedimentary environmental changes. The modal values and size ranges of the two main grain-size populations in Core A7 are evidently different from those of Core A37, indicating the spatial variability of sediment sources and transport processes between the two places. The downcore variations in the content of the environmentally sensitive grain-size populations reveal that during the accumulation of sedimentary material the environment remained relatively stable at the site where Core A7 was collected, except for the apparent events for the formation of two turbidite layers and a volcanic ash layer. However, the sedimentary sequence of Core A37 shows six sedimentary cycles, indicating a highly variable sedimentary environment at this location.