Influência da compactação de um solo arenoso na infiltração e retenção de carga orgânica de chorume

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Degradação de resíduos e alterações na resistividade elétrica, pH e Eh

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Método da eletrorresistividade aplicado no monitoramento temporal da pluma de contaminação em área de disposição de resíduos sólidos urbanos

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Relation between kinetic parameters for reactions of organic matter degradation in waste environmental matrix

The organic fraction of urban solid residues disposed of in sanitary landfills during the decomposition yields biogas and leachate, which are sources of pollution. Leachate is a resultant liquid from the decomposition of substances contained in solid residues and it contains in its composition organic and inorganic substances. Literature shows an increase in the use of thermoanalytical techniques to study the samples with environmental interest, this way thermogravimetry is used in this research. Thermogravimetric studies (TG curves) carried out on leachate and residues shows similarities in the thermal behavior, although presenting complex composition. Residue samples were collected from landfills, composting plants, sewage treatment stations, leachate, which after treatment, were submitted for thermal analysis. Kinetic parameters were determined using the Flynn-Wall-Ozawa method. In this case they show little divergence between the kinetic parameter that can be attributed to different decomposition reaction and presence of organic compounds in different phases of the decomposition with structures modified during degradation process and also due to experimental conditions of analysis.

Aplicabilidad del proceso de nitritación/desnitritación en el tratamiento de lixiviado de relleno sanitario

The biological nitritation/denitritation process in the removal of organic matter and nitrogen in a landfill leachate was studied, using an activated sludge sequencing batch reactor. Treatment cycles were formed by an anoxic and an aerobic phases, in which the conditions for oxidation of the influent N load and the prevalence of nitrite concentration at the end of aerobic treatment cycles were determined, as well as the use of organic matter present in the leachate as a carbon source for denitrifying organisms in the anoxic stage. The removal efficiencies of N-NO 2-at the end of the anoxic process (48h) ranged between 14 and 30%, indicating low availability of biodegradable organic matter in the leachate. As for the accumulation of N-NO 2-at the end of the aerobic phase (48h) of treatment cycles, imbalances were not observed, while 100% removal efficiencies of N and specific nitritation rates from 0.095 to 0.158kgN-NH 3/kgSSV per day were recorded, demonstrating the applicability of simplified nitrification in the treatment of effluents with low C/N ratios.

Monitoramento temporal da pluma de contaminação no aterro de resíduos urbanos de Rio Claro (SP) por meio do método geofísico da eletrorresistividade

Several factors have contributed to the increase the world production of urban solid waste, resulting in difficulties to the correct management and the final environmentally appropriate disposal, in addition to causing serious socio-economic, environmental, and public health troubles. The soil and groundwater contamination by leachate in waste disposal sites is almost always present, leveraging the emergence and/or adaptation of methodologies for environmental assessment of these areas. The geophysical methods, especially the electrical resistivity method, are fast, reliable and low-cost alternative for this purpose. This paper reports the methodology adopted for the temporal monitoring of the plume of contamination of controlled landfill in the municipality of Rio Claro (SP). Electrical resistivity data were obtained in 1999 and 2008, by the resistivity method, using the techniques of vertical electrical sounding and electrical profile. In both years, similar tests were carried out in the same locations within the disposal area. The results indicated that the plume of contamination has resistivity values less than or equal to 50 ohm.m and moves guided by 2 flows: the main, to the southeast, and the secondary, to the west. Relatively to the first series of tests in 1999, the plume of contamination was higher and deeper in 2008, contrary to what was expected for a landfill deactivated for at least 10 years.

Caracterização geofísica em aterro de resíduos sólidos para avaliação de condicionantes de instabilidade geotécnica

The disposal of solid waste can create environmental problems, in addition to the potential risk of instability even in planned geotechnical works, such as provisions in stacks or high ends of the landfill, because they represent mere adjustments in civil engineering works. The Leme city, SP, generates about 35 t/day of municipal waste, that are deposited in a landfill located in the Barro Preto neighborhood. This work conducted a geophysical survey, based on geotechnical instability evidence in area, for analysis of the conditioners that cause on the sides leachate resurgence landfill and its relationship to mass movements and ravines installation in cover soil, with consequent waste exposure. The results indicate horizons of low resistivity connected with resurgence points generated by the organic matter decomposition contained in the waste. Such horizons result in leachate concentration in some places, which, in turn, may lead to loss of cohesion of the materials constituting the residues mass. The results are areas with mass flow by rotational movements, which, together with the surface flow of rainwater, evolves into ravines and exposed residues, preferably at the resurgence point. The leachate flow on the surface affects areas beyond the limits at landfill with direct impact on local agriculture and risk to pedestrians using the highway bordered by the landfill beyond the soil and the local aquifer.

Tratamiento de lixiviados de residuos de origen urbano mediante MBR

Se ha utilizado una planta de tratamiento a escala laboratorio consiste en un biorreactor de membrana (MBR). Esta planta está compuesta por un reactor biológico de 25 L de capacidad. Se utilizó una membrana plana de micro filtración marca Kubota de polietileno clorado, tamaño de poro 0,1 μm y área de filtración 0.116 m2. Se utilizaron como condiciones de operación: tiempo de residencia hidráulico 3 días, caudal de permeado 0.35 L/h y LMH 3 L/m2h. Se ha podido comprobar que es posible adaptar una población microbiológica a las particulares características químicas del lixiviado procedente de la planta y tratar estos lixiviados en un reactor biológico de membrana sumergida operando en condiciones habituales de sólidos en suspensión en el reactor entre 8-12 g/L durante un periodo de 6 meses. El proceso utilizado permite reducir la materia orgánica (97% DBO5 y 40% DQO) presente en estas corrientes residuales, agotando prácticamente toda la materia biodegradable. Respecto a los contenidos de nutrientes, el tratamiento MBR ensayado permite reducir de 35-40% el nitrógeno total, 45-50% el nitrógeno amoniacal y un 65-70% el fósforo total. Los sólidos en suspensión se han reducido en el efluente tratado en más de un 99%.

Risk Based Post Closure Care Analysis for Florida Landfills

Subtitle D of the Resource Conservation and Recovery Act (RCRA) requires a post closure period of 30 years for non hazardous wastes in landfills. Post closure care (PCC) activities under Subtitle D include leachate collection and treatment, groundwater monitoring, inspection and maintenance of the final cover, and monitoring to ensure that landfill gas does not migrate off site or into on site buildings. The decision to reduce PCC duration requires exploration of a performance based methodology to Florida landfills. PCC should be based on whether the landfill is a threat to human health or the environment. Historically no risk based procedure has been available to establish an early end to PCC. Landfill stability depends on a number of factors that include variables that relate to operations both before and after the closure of a landfill cell. Therefore, PCC decisions should be based on location specific factors, operational factors, design factors, post closure performance, end use, and risk analysis. The question of appropriate PCC period for Florida’s landfills requires in depth case studies focusing on the analysis of the performance data from closed landfills in Florida. Based on data availability, Davie Landfill was identified as case study site for a case by case analysis of landfill stability. The performance based PCC decision system developed by Geosyntec Consultants was used for the assessment of site conditions to project PCC needs. The available data for leachate and gas quantity and quality, ground water quality, and cap conditions were evaluated. The quality and quantity data for leachate and gas were analyzed to project the levels of pollutants in leachate and groundwater in reference to maximum contaminant level (MCL). In addition, the projected amount of gas quantity was estimated. A set of contaminants (including metals and organics) were identified as contaminants detected in groundwater for health risk assessment. These contaminants were selected based on their detection frequency and levels in leachate and ground water; and their historical and projected trends. During the evaluations a range of discrepancies and problems that related to the collection and documentation were encountered and possible solutions made. Based on the results of PCC performance integrated with risk assessment, projection of future PCC monitoring needs and sustainable waste management options were identified. According to these results, landfill gas monitoring can be terminated, leachate and groundwater monitoring for parameters above MCL and surveying of the cap integrity should be continued. The parameters which cause longer monitoring periods can be eliminated for the future sustainable landfills. As a conclusion, 30 year PCC period can be reduced for some of the landfill components based on their potential impacts to human health and environment (HH&E).

Effect of leachate recirculation and extent of degradation on the stability of bioreactor landfill slopes

The stability of a bioreactor landfill slope is influenced by the quantity and method of leachate recirculation as well as on the degree of decomposition. Other factors include properties variation of waste material and geometrical configurations, i.e., height and slope of landfills. Conventionally, the stability of slopes is evaluated using factor of safety approach, in which the variability in the engineering properties of MSW is not considered directly and stability issues are resolved from past experiences and good engineering judgments. On the other hand, probabilistic approach considers variability in mathematical framework and provides stability in a rational manner that helps in decision making. The objective of the present study is to perform a parametric study on the stability of a bioreactor landfill slope in probabilistic framework considering important influencing factors, such as, variation in MSW properties, amount of leachate recirculation, and age of degradation, in a systematic manner. The results are discussed in the light of existing relevant regulations, design and operation issues.