Study of the spectroscopic properties and first hyperpolarizabilities of disperse azo dyes derived from 2-amino-5-nitrothiazole

The solvatochromism and other spectroscopic and photophysical characteristics of four azo disperse dyes, derived from 2-amino-5-nitrothiazole, were evaluated and interpreted with the aid of experimental data and quantum mechanical calculations. For the non-substituted compound two conformers, E and Z, were proposed for the isolated molecules, being the second one considerably less stable. The optimization of these structures in combination with a SCRF methodology (IEFPCM, Simulating the molecules in a continuum dielectric with characteristics of methanol), suggests that the Z form is not stable in solution. This same behaviour is expected for the substituted compounds, which is corroborated by experimental data presented in previous investigations [A.E.H. Machado, L.M. Rodrigues, S. Gupta, A.M.F. Oliveira-Campos, A.M.S. Silva, J. Mol. Struct. 738 (2005) 239-245]. For the substituted compounds, two forms derived from E conformer (A and R) are possible. Quantum mechanical data suggest for the isolated molecules, that the low energy absorption hand of the E conformers involve at least two close electronic states. having the low-lying excited state a (1)(n,pi*) nature, and being the S-2 state attributed to a (1)(pi,pi*) transition. The data also suggest a small energy gap between the absorption peaks of A and B, related to the easy conversion between these forms. For the structures optimized in combination with the applied SCRF methodology, an states inversion is observed for the Substituted compounds, with a considerable diminish of the energy gap between A and B absorption peaks. The electronic spectra of these compounds are quite sensitive to changes in the solvent polarity. The positive solvatochromism is more evident in aprotic solvents, probably due to the polarization induced by the solute. These compounds do not fluoresce at 298 K, but present a small but perceptible fluorescence at 77 K, which seems to be favoured by the nature of the group in the 2 `-position of the phenyl ring. Moreover, such compounds present expressive values for first hyperpolarizability, which implies in good non-linear optics (NLO) responses and photoswitching capability. (C) 2008 Elsevier B.V. All rights reserved.

Surface modification and crystallization of the BaO-B2O3-SiO2 glassy system using CO2 laser irradiation

The surface modification and crystallization process of BaO-B2O3-SiO2 glass compositions when exposed to CO2 laser irradiation was evaluated as a function of the laser power, irradiation time and surface condition. The glass surface was modified by the application of laser power exceeding 0.40 W and an irradiation time of more than 300 s. Micro-Raman and X-ray diffraction measurements revealed at high laser power the formation of beta-BaB2O4 (beta-BBO) crystalline phase. The crystallization of the irradiated region was enhanced when beta-BBO micrometer sized particles were dispersed on the surface of the glass sample. The intensity of the second harmonic generation observed in the crystallized region was found to depend mainly on the condition of the glassy surface prior to glass irradiation. (C) 2007 Elsevier B.V. All rights reserved.

Quantum computation with optical coherent states

We show that quantum computation circuits using coherent states as the logical qubits can be constructed from simple linear networks, conditional photon measurements, and "small" coherent superposition resource states.

Measuring a photonic qubit without destroying it

Measuring the polarization of a single photon typically results in its destruction. We propose, demonstrate, and completely characterize a quantum nondemolition (QND) scheme for realizing such a measurement nondestructively. This scheme uses only linear optics and photodetection of ancillary modes to induce a strong nonlinearity at the single-photon level, nondeterministically. We vary this QND measurement continuously into the weak regime and use it to perform a nondestructive test of complementarity in quantum mechanics. Our scheme realizes the most advanced general measurement of a qubit to date: it is nondestructive, can be made in any basis, and with arbitrary strength.

Optical quantum computation using cluster states

We propose an approach to optical quantum computation in which a deterministic entangling quantum gate may be performed using, on average, a few hundred coherently interacting optical elements (beam splitters, phase shifters, single photon sources, and photodetectors with feedforward). This scheme combines ideas from the optical quantum computing proposal of Knill, Laflamme, and Milburn [Nature (London) 409, 46 (2001)], and the abstract cluster-state model of quantum computation proposed by Raussendorf and Briegel [Phys. Rev. Lett. 86, 5188 (2001)].

High-fidelity Z-measurement error encoding of optical qubits

We demonstrate a quantum error correction scheme that protects against accidental measurement, using a parity encoding where the logical state of a single qubit is encoded into two physical qubits using a nondeterministic photonic controlled-NOT gate. For the single qubit input states vertical bar 0 >, vertical bar 1 >, vertical bar 0 > +/- vertical bar 1 >, and vertical bar 0 > +/- i vertical bar 1 > our encoder produces the appropriate two-qubit encoded state with an average fidelity of 0.88 +/- 0.03 and the single qubit decoded states have an average fidelity of 0.93 +/- 0.05 with the original state. We are able to decode the two-qubit state (up to a bit flip) by performing a measurement on one of the qubits in the logical basis; we find that the 64 one-qubit decoded states arising from 16 real and imaginary single-qubit superposition inputs have an average fidelity of 0.96 +/- 0.03.

Optimal photons for quantum-information processing

Photonic quantum-information processing schemes, such as linear optics quantum computing, and other experiments relying on single-photon interference, inherently require complete photon indistinguishability to enable the desired photonic interactions to take place. Mode-mismatch is the dominant cause of photon distinguishability in optical circuits. Here we study the effects of photon wave-packet shape on tolerance against the effects of mode mismatch in linear optical circuits, and show that Gaussian distributed photons with large bandwidth are optimal. The result is general and holds for arbitrary linear optical circuits, including ones which allow for postselection and classical feed forward. Our findings indicate that some single photon sources, frequently cited for their potential application to quantum-information processing, may in fact be suboptimal for such applications.

Using weak nonlinearity under decoherence for macroscopic entanglement generation and quantum computation

Recently, there have been several suggestions that weak Kerr nonlinearity can be used for generation of macroscopic superpositions and entanglement and for linear optics quantum computation. However, it is not immediately clear that this approach can overcome decoherence effects. Our numerical study shows that nonlinearity of weak strength could be useful for macroscopic entanglement generation and quantum gate operations in the presence of decoherence. We suggest specific values for real experiments based on our analysis. Our discussion shows that the generation of macroscopic entanglement using this approach is within the reach of current technology.

Loss-tolerant optical qubits

We present a linear optics quantum computation scheme that employs a new encoding approach that incrementally adds qubits and is tolerant to photon loss errors. The scheme employs a circuit model but uses techniques from cluster-state computation and achieves comparable resource usage. To illustrate our techniques we describe a quantum memory which is fault tolerant to photon loss.

Greenberger-Horne-Zeilinger-type and W-type entangled coherent states: Generation and Bell-type inequality tests without photon counting

We study Greenberger-Horne-Zeilinger-type (GHZ-type) and W-type three-mode entangled coherent states. Both types of entangled coherent states violate Mermin's version of the Bell inequality with threshold photon detection (i.e., without photon counting). Such an experiment can be performed using linear optics elements and threshold detectors with significant Bell violations for GHZ-type entangled coherent states. However, to demonstrate Bell-type inequality violations for W-type entangled coherent states, additional nonlinear interactions are needed. We also propose an optical scheme to generate W-type entangled coherent states in free-traveling optical fields. The required resources for the generation are a single-photon source, a coherent state source, beam splitters, phase shifters, photodetectors, and Kerr nonlinearities. Our scheme does not necessarily require strong Kerr nonlinear interactions; i.e., weak nonlinearities can be used for the generation of the W-type entangled coherent states. Furthermore, it is also robust against inefficiencies of the single-photon source and the photon detectors.

Interconvertibility of single-rail optical qubits

We show how to convert between partially coherent superpositions of a single photon with the vacuum by using linear optics and postselection based on homodyne measurements. We introduce a generalized quantum efficiency for such states and show that any conversion that decreases this quantity is possible. We also prove that our scheme is optimal by showing that no linear optical scheme with generalized conditional measurements, and with one single-rail qubit input, can improve the generalized efficiency. (c) 2006 Optical Society of America.

Universal quantum computation with continuous-variable cluster states

We describe a generalization of the cluster-state model of quantum computation to continuous-variable systems, along with a proposal for an optical implementation using squeezed-light sources, linear optics, and homodyne detection. For universal quantum computation, a nonlinear element is required. This can be satisfied by adding to the toolbox any single-mode non-Gaussian measurement, while the initial cluster state itself remains Gaussian. Homodyne detection alone suffices to perform an arbitrary multimode Gaussian transformation via the cluster state. We also propose an experiment to demonstrate cluster-based error reduction when implementing Gaussian operations.

Quantum optical systems for the implementation of quantum information processing

We review the field of quantum optical information from elementary considerations to quantum computation schemes. We illustrate our discussion with descriptions of experimental demonstrations of key communication and processing tasks from the last decade and also look forward to the key results likely in the next decade. We examine both discrete (single photon) type processing as well as those which employ continuous variable manipulations. The mathematical formalism is kept to the minimum needed to understand the key theoretical and experimental results.

Measuring nonlinear functionals of quantum harmonic oscillator states

Using only linear interactions and a local parity measurement we show how entanglement can be detected between two harmonic oscillators. The scheme generalizes to measure both linear and nonlinear functionals of an arbitrary oscillator state. This leads to many applications including purity tests, eigenvalue estimation, entropy, and distance measures-all without the need for nonlinear interactions or complete state reconstruction. Remarkably, experimental realization of the proposed scheme is already within the reach of current technology with linear optics.