Paleomagnetic of ODP Hole 133-823A

Hole 823A covers the upper 120 m (Subunits IA and IB) of Site 823 at the bottom of the Queensland Trough. This hole contains an abundance of gravity-flow deposits, but is thought to have a monotonic age sequence. Above 32 mbsf, a strong, stable (normal) magnetic remanence having a relatively small viscous remanent magnetization (VRM) is seen. Below 32 mbsf, the sediments are subject to widespread VRM, which appears to obliterate the primary magnetization and precludes identification of the Brunhes/Matuyama boundary. Progressive alternating field (AF) demagnetization is limited to low fields (typically <400 Oe) by the weak magnetization in these sediments. As a consequence, the possibility of a high-coercivity component of primary magnetization cannot be ruled out. Lowrie-Fuller tests indicate that this VRM overprinting does not have a multidomain origin. An approximately linear relationship exists between median destructive field (MDF) and the logarithm of the natural remanent magnetization (NRM). Carbonate dilution does not appear to be a dominant factor in controlling variations in concentration-dependent magnetic parameters, such as magnetic susceptibility. The sedimentological distinction between Subunits IA and IB does not show up in the magnetic record. However, a sharp change in magnetic properties does occur at 32 mbsf, with low background magnetizations below this level and high background magnetizations above it. The boundary coincides with a change from thick (>10 cm thick) to thin (<10 cm thick) turbidite deposition, and is also near the boundary separating the sulfate-reduction zone in the upper part of the sequence from the sulfate-free zone beneath. The abrupt nature of the magnetic boundary is evidence that nannofossil subzone CN14b is not condensed, but is missing in a hiatus at 32 mbsf. Nine peaks have been identified in the susceptibility (K) record that are superimposed on ôbackgroundö signals. ARM/K ratios are uniformly low for the background sediments below 32 mbsf, intermediate for strong susceptibility peaks, and high for background sediments above 32 mbsf and weak susceptibility peaks. Comparisons with results from Site 820 suggest that (1) the background sediments above 32 mbsf and the weak susceptibility peaks carry a stable single-domain magnetization, and (2) the high susceptibility peaks are caused by the addition of a superparamagnetic contribution. Expectations are that the distinctive features of the Hole 823A magnetic record are linked to major environmental changes.

Desarrollo de nuevos tratamientos térmicos para aleaciones avanzadas de interés aeroespacial

La corrosión bajo tensiones (SCC) es un problema de gran importancia en las aleaciones de aluminio de máxima resistencia (serie Al-Zn-Mg-Cu). La utilización de tratamientos térmicos sobremadurados, en particular el T73, ha conseguido prácticamente eliminar la susceptibilidad a corrosión bajo tensiones en dichas aleaciones pero a costa de reducir su resistencia mecánica. Desde entonces se ha tratado de optimizar simultáneamente ambos comportamientos, encontrándose para ello diversos inconvenientes entre los que destacan: la dificultad de medir experimentalmente el crecimiento de grieta por SCC, y el desconocimiento de las causas y el mecanismo por el cual se produce la SCC. Los objetivos de esta Tesis son mejorar el sistema de medición de grietas y profundizar en el conocimiento de la SCC, con el fin de obtener tratamientos térmicos que aúnen un óptimo comportamiento tanto en SCC como mecánico en las aleaciones de aluminio de máxima resistencia utilizadas en aeronáutica. Para conseguir los objetivos anteriormente descritos se han realizado unos cuarenta tratamientos térmicos diferentes, de los cuales la gran mayoría son nuevos, para profundizar en el conocimiento de la influencia de la microestructura (fundamentalmente, de los precipitados coherentes) en el comportamiento de las aleaciones Al-Zn-Mg-Cu, y estudiar la viabilidad de nuevos tratamientos apoyados en el conocimiento adquirido. Con el fin de obtener unos resultados aplicables a productos o semiproductos de aplicación aeronáutica, los tratamientos térmicos se han realizado a trozos grandes de una plancha de 30 mm de espesor de la aleación de aluminio 7475, muy utilizada en las estructuras aeronáuticas. Asimismo con el objeto de conseguir una mayor fiabilidad de los resultados obtenidos se han utilizado, normalmente, tres probetas de cada tratamiento para los diferentes ensayos realizados. Para la caracterización de dichos tratamientos se han utilizado diversas técnicas: medida de dureza y conductividad eléctrica, ensayos de tracción, calorimetría diferencial de barrido (DSC), metalografía, fractografía, microscopia electrónica de transmisión (MET) y de barrido (MEB), y ensayos de crecimiento de grieta en probeta DCB, que a su vez han permitido hacer una estimación del comportamiento en tenacidad del material. Las principales conclusiones del estudio realizado se pueden resumir en las siguientes: Se han diseñado y desarrollado nuevos métodos de medición de grieta basados en el empleo de la técnica de ultrasonidos, que permiten medir el crecimiento de grieta por corrosión bajo tensiones con la precisión y fiabilidad necesarias para valorar adecuadamente la susceptibilidad a corrosión bajo tensiones. La mejora de medida de la posición del frente de grieta ha dado lugar, entre otras cosas, a la definición de un nuevo ensayo a iniciación en probetas preagrietadas. Asimismo, se ha deducido una nueva ecuación que permite calcular el factor de intensidad de tensiones existente en punta de grieta en probetas DCB teniendo en cuenta la influencia de la desviación del plano de crecimiento de la grieta del plano medio de la probeta. Este aspecto ha sido determinante para poder explicar los resultados experimentales obtenidos ya que el crecimiento de la grieta por un plano paralelo al plano medio de la probeta DCB pero alejado de él reduce notablemente el factor de intensidades de tensiones que actúa en punta de grieta y modifica las condiciones reales del ensayo. Por otro lado, se han identificado los diferentes constituyentes de la microestructura de precipitación de todos los tratamientos térmicos estudiados y, en especial, se ha conseguido constatar (mediante MET y DSC) la existencia de zonas de Guinier-Preston del tipo GP(II) en la microestructura de numerosos tratamientos térmicos (no descrita en la bibliografía para las aleaciones del tipo de la estudiada) lo que ha permitido establecer una nueva interpretación de la evolución de la microestructura en los diferentes tratamientos. Al hilo de lo anterior, se han definido nuevas secuencias de precipitación para este tipo de aleaciones, que han permitido entender mejor la constitución de la microestructura y su relación con las propiedades en los diferentes tratamientos térmicos estudiados. De igual manera, se ha explicado el papel de los diferentes microconstituyentes en diversas propiedades mecánicas (propiedades a tracción, dureza y tenacidad KIa); en particular, el estudio realizado de la relación de la microestructura con la tenacidad KIa es inédito. Por otra parte, se ha correlacionado el comportamiento en corrosión bajo tensiones, tanto en la etapa de incubación de grieta como en la de propagación, con las características medidas de los diferentes constituyentes microestructurales de los tratamientos térmicos ensayados, tanto de interior como de límite de grano, habiéndose obtenido que la microestructura de interior de grano tiene una mayor influencia en el comportamiento en corrosión bajo tensiones que la de límite de grano. De forma especial, se ha establecido la importancia capital, y muy negativa, de la presencia en la microestructura de zonas de Guinier-Preston en el crecimiento de la grieta por corrosión bajo tensiones. Finalmente, como consecuencia de todo lo anterior, se ha propuesto un nuevo mecanismo por el que se produce la corrosión bajo tensiones en este tipo de aleaciones de aluminio, y que de forma muy resumida se puede concretar lo siguiente: la acumulación de hidrógeno (formado, básicamente, por un proceso corrosivo de disolución anódica) delante de la zonas GP (en especial, de las zonas GP(I)) próximas a la zona libre de precipitados que se desarrolla alrededor del límite de grano provoca enfragilización local y causa el rápido crecimiento de grieta característico de algunos tratamientos térmicos de este tipo de aleaciones. ABSTRACT The stress corrosion cracking (SCC) is a major problem in the aluminum alloys of high resistance (series Al-Zn-Mg-Cu). The use of overaged heat treatments, particularly T73 has achieved virtually eliminate the susceptibility to stress corrosion cracking in such alloys but at the expense of reducing its mechanical strength. Since then we have tried to simultaneously optimize both behaviors, several drawbacks found for it among them: the difficulty of measuring experimentally the SCC crack growth, and ignorance of the causes and the mechanism by which SCC occurs. The objectives of this thesis are to improve the measurement system of cracks and deeper understanding of the SCC, in order to obtain heat treatments that combine optimum performance in both SCC and maximum mechanical strength in aluminum alloys used in aerospace To achieve the above objectives have been made about forty different heat treatments, of which the vast majority are new, to deepen the understanding of the influence of microstructure (mainly of coherent precipitates) in the behavior of the alloys Al -Zn-Mg-Cu, and study the feasibility of new treatments supported by the knowledge gained. To obtain results for products or semi-finished aircraft application, heat treatments were performed at a large pieces plate 30 mm thick aluminum alloy 7475, widely used in aeronautical structures. Also in order to achieve greater reliability of the results obtained have been used, normally, three specimens of each treatment for various tests. For the characterization of these treatments have been used several techniques: measurement of hardness and electrical conductivity, tensile testing, differential scanning calorimetry (DSC), metallography, fractography, transmission (TEM) and scanning (SEM) electron microscopy, and crack growth tests on DCB specimen, which in turn have allowed to estimate the behavior of the material in fracture toughness. The main conclusions of the study can be summarized as follows: We have designed and developed new methods for measuring crack based on the use of the ultrasound technique, for measuring the growth of stress corrosion cracks with the accuracy and reliability needed to adequately assess the susceptibility to stress corrosion. Improved position measurement of the crack front has resulted, among other things, the definition of a new initiation essay in pre cracked specimens. Also, it has been inferred a new equation to calculate the stress intensity factor in crack tip existing in DCB specimens considering the influence of the deviation of the plane of the crack growth of the medium plane of the specimen. This has been crucial to explain the experimental results obtained since the crack growth by a plane parallel to the medium plane of the DCB specimen but away from it greatly reduces the stress intensity factor acting on the crack tip and modifies the actual conditions of the essay. Furthermore, we have identified the various constituents of the precipitation microstructure of all heat treatments studied and, in particular note has been achieved (by TEM and DSC) the existence of the type GP (II) of Guinier-Preston zones in the microstructure of several heat treatments (not described in the literature for alloys of the type studied) making it possible to establish a new interpretation of the evolution of the microstructure in the different treatments. In line with the above, we have defined new precipitation sequences for these alloys, which have allowed a better understanding of the formation of the microstructure in relation to the properties of different heat treatments studied. Similarly, explained the role of different microconstituents in various mechanical properties (tensile properties, hardness and toughness KIa), in particular, the study of the relationship between the tenacity KIa microstructure is unpublished. Moreover, has been correlated to the stress corrosion behavior, both in the incubation step as the crack propagation, with the measured characteristics of the various microstructural constituents heat treatments tested, both interior and boundary grain, having obtained the internal microstructure of grain has a greater influence on the stress corrosion cracking behavior in the grain boundary. In a special way, has established the importance, and very negative, the presence in the microstructure of Guinier-Preston zones in crack growth by stress corrosion. Finally, following the above, we have proposed a new mechanism by which stress corrosion cracking occurs in this type of aluminum alloy, and, very briefly, one can specify the following: the accumulation of hydrogen (formed basically by a corrosive process of anodic dissolution) in front of the GP zones (especially the GP (I) zones) near the precipitates free zone that develops around grain boundary causes local embrittlement which characterizes rapid crack growth of some heat treatments such alloys.

Flammability conditions for ultra-lean hydrogen premixed combustion based on flame-ball analyses

It has been reasoned that the structures of strongly cellular flames in very lean mixtures approach an array of flame balls, each burning as if it were isolated, thereby indicating a connection between the critical conditions required for existence of steady flame balls and those necessary for occurrence of self-sustained premixed combustion. This is the starting assumption of the present study, in which structures of near-limit steady sphericosym-metrical flame balls are investigated with the objective of providing analytic expressions for critical combustion conditions in ultra-lean hydrogen-oxygen mixtures diluted with N2 and water vapor. If attention were restricted to planar premixed flames, then the lean-limit mole fraction of H2 would be found to be roughly ten percent, more than twice the observed flammability limits, thereby emphasizing the relevance of the flame-ball phenomena. Numerical integrations using detailed models for chemistry and radiation show that a onestep chemical-kinetic reduced mechanism based on steady-state assumptions for all chemical intermediates, together with a simple, optically thin approximation for water-vapor radiation, can be used to compute near-limit fuel-lean flame balls with excellent accuracy. The previously developed one-step reaction rate includes a crossover temperature that determines in the first approximation a chemical-kinetic lean limit below which combustión cannot occur, with critical conditions achieved when the diffusion-controlled radiation-free peak temperature, computed with account taken of hydrogen Soret diffusion, is equal to the crossover temperature. First-order corrections are found by activation-energy asymptotics in a solution that involves a near-field radiation-free zone surrounding a spherical flame sheet, together with a far-field radiation-conduction balance for the temperature profile. Different scalings are found depending on whether or not the surrounding atmosphere contains wáter vapor, leading to different analytic expressions for the critical conditions for flame-ball existence, which give results in very good agreement with those obtained by detailed numerical computations.

Dinámicas de ocupación urbana del Anillo Verde metropolitano, desde sus orígenes en el Plan General del Área Metropolitana de Madrid de 1963 hasta el Plan General de Ordenación Urbana de 1997

El Anillo Verde metropolitano, definido por el Plan General de Ordenación Urbana del Área Metropolitana de Madrid en 1963 siguiendo los modelos planteados por la cultura urbanística internacional, como armadura de la estructura urbana del AMM, espacio protagonista dentro del sistema de espacios libres, lugar de uso público destinado al recreo y contacto con la naturaleza de la población madrileña, se convierte en realidad en una reserva de suelo que va entrando en juego motivado por las alianzas entre el poder institucional y la clase social dominante actuando al margen del planeamiento, poniendo en evidencia la escasez de recursos legales y culturales disponibles para la salvaguarda de los intereses comunes y, donde los condicionantes geográficos y naturales del territorio madrileño han influido decisivamente en la especialización funcional y espacial del Área Metropolitana de Madrid. Así pues considerando esta idea como HIPÓTESIS, el objetivo de la TESIS sería demostrarla, para lo cual se hace necesario primero, acotar espacial y temporalmente el objeto de estudio, es decir, del Anillo Verde metropolitano1, segundo, contextualizar histórica y disciplinarmente los presupuestos teóricos que conformaban la idea del Anillo Verde, tercero, reconocer, localizar y documentar las piezas que han ido materializando la ocupación urbana del Anillo Verde, clasificándolas según parámetros temporales, funcionales, urbanísticos y, formales, lo que permite analizar la geografía, uso, instrumentación y forma de su transformación a escala general metropolitana y, cuarto, profundizar a modo de comprobación a escala municipal y urbana en dos escenarios representativos del conjunto metropolitano: el municipio de Pozuelo de Alarcón y el distrito de Hortaleza-Barajas. El contenido del documento se divide en tres bloques, el bloque I, se centra en las bases teóricas, el bloque II sitúa el hilo argumental de la tesis a escala metropolitana y el bloque III comprueba el fenómeno a escala municipal y urbana. De esta forma, se comienza por la comprensión del significado del concepto del Anillo Verde, que va más allá de la dimensión instrumental asignada de límite y contención urbana frente al crecimiento de la ciudad industrial de principios del siglo XX, basada en la descentralización de la ciudad tradicional, para adquirir un significado más complejo, como gran espacio de reserva y salvaguarda de valores naturales y culturales que se expresaban en su territorio y que permitirían alcanzar el equilibrio entre la ciudad y sus habitantes, es decir, entre el hombre y el espacio que habita. Se hace un recorrido por las principales corrientes urbanísticas que se van nutriendo de distintas disciplinas (economía, sociología, geografía, biología, ecología) para plantear teorías que permitieran materializar un nuevo orden urbano según principios de equidad social, económica y ambiental, en una secuencia donde Europa y Estados Unidos realizaban un constante intercambio -el movimiento de la Ciudad Jardín o el Regionalismo, que dieron paso a propuestas como el Greater London o el Gran Berlín, donde la figura del Anillo Verde tenía un papel protagonista, y del que también participaría nuestro país y la ciudad de Madrid, con modelos regionales como el Plan Besteiro y urbanos como el Plan Bidagor, antecedentes directos del Plan General de Ordenación Urbana del Área Metropolitana de Madrid de 1963 que pone en marcha la ordenación del crecimiento metropolitano de Madrid. El hilo argumental de la tesis se organiza en una doble aproximación: un acercamiento a escala metropolitana a partir del reconocimiento del modelo de ciudad definido en los distintos planes generales que acompañaron el desarrollo metropolitano (municipio de Madrid y de los siete términos municipales que rodeaban a este y que tenían suelo destinado a Anillo Verde), haciendo referencia además a las relaciones con el planeamiento regional, concretando en una escala de aproximación municipal que avanza hasta la interpretación urbana detallada. El primer acercamiento tiene lugar en el bloque II y se organiza en tres capítulos. El capítulo 4 se dedica al punto obligado de partida de la geografía local, describiendo las características biofísicas de los terrenos que formaban parte del Anillo Verde, que han marcado históricamente la forma de aprovechamiento del territorio, desde las extensiones de bosques mediterráneos al norte y al oeste continuación del Monte del Pardo, a los distintos tipos de cultivo que se adaptaban al sustrato geológico y la forma del terreno (de las suaves ondulaciones de sedimentos arcósicos al norte a las extensas plataformas arenosas y yesíferas del sur), además de las zonas de huertos aprovechando las depresiones y los cursos de agua (arroyo del Monte Carmelo, arroyo de Valdebebas, arroyo del Quinto, arroyo del Santo, arroyo Butarque, arroyo Meaques y arroyo Pozuelo). Una vez reconocida la realidad física, el capítulo 5, avanza en la descripción de los distintos modelos de ciudad propuestos desde el planeamiento urbanístico, en sus distintas escalas, la regional y la municipal, como respuesta a la coyuntura social, económica y política que ha caracterizado el proceso de ocupación del Anillo Verde al compás de la construcción del AMM. Se han reunido las propuestas de planeamiento municipal de los distintos municipios que disponían de terreno calificado como Anillo Verde: Madrid, Coslada, Getafe, Leganés, Alcorcón, Boadilla del Monte y Pozuelo de Alarcón. Además se han incorporado las distintas propuestas de ordenación territorial que han servido de referencia al planeamiento municipal, en todas sus versiones, desde las sectoriales, de mayor éxito y apoyo institucional, a los distintos intentos de ordenación integral, de mayor complejidad pero de menor calado, precisamente por la dificultad de consenso entre la ordenación física y el desarrollo económico, entre los intereses privados y el beneficio público. El primer horizonte, comienza con la formulación del Plan General de Ordenación Urbana del Área Metropolitana de Madrid de 1963, su desarrollo y la puesta en marcha de los primeros planes municipales en la década de los años setenta, donde se comprueba la necesidad de un marco regional que “ordene” el territorio de forma integral y sirva de referencia a las actuaciones sectoriales que habían marcado el primer desarrollo metropolitano. El segundo, se sitúa dos décadas más tarde con la aprobación del Plan General de Ordenación Urbana de Madrid de 1985 y el conjunto de planes municipales de los términos limítrofes, que siguen su filosofía de austeridad en cuanto a crecimiento territorial. El tercero se inicia en 1997 con la siguiente generación de planes de corte neoliberal que imponen un modelo territorial basado en las grandes operaciones metropolitanas de centralidad, infraestructuras y equipamiento, que consumen de forma indiscriminada la totalidad del territorio madrileño. Será en el último capítulo del segundo bloque (capítulo 6) donde se represente gráficamente a escala metropolitana y se analicen las 229 piezas que han ido colmatando el espacio destinado a Anillo Verde, según los parámetros de estudio, en base a las cuales se plantean las primeras conclusiones generales de la tesis, poniendo de manifiesto que las alianzas entre los agentes soberanos en la construcción de la ciudad y su entorno han trasgredido sucesivamente las determinaciones del Planeamiento en su definición de modelo de ciudad y territorio, acusando la carencia de recursos instrumentales y jurídicos que alentaron el proceso de su desmantelamiento, y revelando la influencia de los condicionantes geográficos y naturales en la especialización funcional y segregación social en el conjunto del Área Metropolitana de Madrid. Se remata el discurso metropolitano con una batería de conclusiones que interpretan el fenómeno de ocupación del anillo de verdor metropolitano confirmando las hipótesis iniciales, reconociendo los valores medioambientales y culturales trasgredidos, sus diversos actores, las numerosas operaciones urbanísticas desarrolladas con distintos usos y envergadura, así como los instrumentos de planeamiento utilizados, en base a las cuales se materializa la construcción del AMM según un modelo extendido (spread), dibujando una mancha de aceite (o grase-spots según Geddes) que precisamente había querido evitarse desde el planeamiento urbanístico con la definición de un Anillo Verde, espacio inmune a la edificación, que se aleja de su papel estructurante (equilibrador entre la ciudad y sus habitantes) para convertirse en armadura de la estructura comunicativa, que una vez consolidada se convierte en la mejor aliada de la máquina inmobiliaria. El último paso, se desarrolla en el bloque III que se divide en los capítulo 7,8 y 9 y supone la comprobación de lo descrito en el conjunto de escala metropolitana, en dos aspectos fundamentales, la falta de consideración por los valores culturales y medioambientales que han modelado el territorio, imprimiéndole un carácter singular y específico y, la estructura del dominio del suelo, donde se reconoce de forma precisa el grupo social y los agentes encargados en cada momento de comercializar los suelos del anillo, que bajo el paraguas de la urgencia social y el engañoso beneficio popular, obtienen importantes beneficios económicos. Con esa intención, se da un salto hacia la escala municipal y urbana, seleccionando dos escenarios de estudio, el municipio de Pozuelo de Alarcón, que representa la materialización del crecimiento suburbano de la élite madrileña ocupando las zonas de mayor valor ecológico del anillo, y el distrito de Hortaleza-Barajas que ofrece su territorio a las grandes operaciones metropolitanas, apoyándose en el eje de actividad marcado por la conexión Madrid-Barcelona y el sistema aeroportuario de escala global, ambos situados al norte de la línea de borde entre la Sierra y la Mancha, ocupando por tanto los lugares más valiosos de la geografía madrileña (estructura funcional anticipada por Bidagor en 1946 en su modelo de ciudad adaptada al territorio madrileño) Una vez descrito este proceso trasgresor de límites, de normas, de conductas, y desde una perspectiva del fenómeno suficientemente documentada, en el capítulo 10, se realiza una reflexión sobre la incidencia real de la propuesta urbanística del Anillo Verde en la construcción del AMM, de la misma forma que se sugieren nuevos roles al planeamiento en un formato intencionado de largo recorrido en oposición a lo inmediato y circunstancial, que permita hacer una nueva lectura de los presupuestos teóricos que conformaban la idea del Anillo Verde, espacio articulador (medioambiental, social y cultural) del territorio madrileño. ABSTRACT The Metropolitan Greenbelt was defined by the 1963 Master Plan for the Madrid Metropolitan Area (MMA), following established international models of urban development, as the structural framework of the MMA, the principal open space within its network of open spaces and a public area of recreation and contact with nature for the residents of Madrid. In reality, however, it ha become a reserve of land in which various alliances between the institutional authorities and the dominant social class have been operating on the margin of the original plan, exposing a scarcity of legal and cultural resources for the safeguarding of common interests, and in which the geographical and natural characteristics of the territory itself have come to play an influential role in the functional specialization and spatial segregation of the MMA. With that idea as its HYPOTHESIS, the aim of this THESIS is to demonstrate its reality. The first step in this is to delineate, temporally and spatially, the object of study; i.e. the Metropolitan Greenbelt2. The second is to contextualize historically and disciplinarily those theoretical ideas which conform to the greenbelt concept. The third is to acknowledge, locate and document the elements which have characterized the urban occupation of the Greenbelt and classify these according to the parameters of time, function, urban development and form, which in turn would enable the geography, use, instrumentation and form of its transformation to be analysed on a general metropolitan scale. The fourth step, as a method of verification, is an in-depth analysis of two representative settings within the metropolitan network: the municipality of Pozuelo de Alarcón and the Hortaleza-Barajas district. The content of the document is divided into three parts. Part I focuses on the study’s theoretical foundations, Part II establishes a line of argument at the metropolitan level and Part III examines the phenomenon from a municipal and urban perspective. The thesis, then, begins with a study of the greenbelt concept itself and its meaning, which is far more complex than the accepted instrumental dimension of limiting and containing urbanization in response to the growth of the industrial city of the early 20th century, and which is based on a decentralization of the traditional city. This wider purpose is the setting aside of a large reserved space to safeguard the natural and cultural values of the region and thereby achieve a balance between the city and its residents; that is to say, between man and the space he inhabits. The principal currents of thought in urban planning will then be examined. These have drawn upon a variety of disciplines (economics, sociology, geography, biology, ecology) to develop theories for establishing a new urban order according to the principles of social, economic and environmental equity, and have involved a constant interchange between Europe and the United States. Thus, the City Garden and Regionalist movements would clear the way for proposals such as Greater London and Great Berlin, Chicago and Washington, in which the greenbelt would play a fundamental role. The participation of our own country and the city of Madrid is also discussed, through regional models such as the Besteiro Plan and urban ones like the Bidagor Plan, direct forerunners of 1963’s General Organizational Plan for the Madrid Metropolitan Area, which would set into motion the organization of Madrid’s metropolitan growth. The line of argument followed in this thesis is two-fold: first, an examination of metropolitan development in keeping with the city model as defined in the various General Plans for the development of both the municipality of Madrid and the seven surrounding municipalities which have land designated for its Greenbelt; and second, an examination of this growth in relation to Regional Planning measures, is detailed on a smaller scale (municipal and district), where the conditioning factors affecting the land property structure and the network of biophysical units may be analysed in depth. The first of these is dealt with in Part II and organized into three chapters (4, 5 and 6). Chapter 4 is dedicated to the obligatory starting point of the geographical setting itself. The biophysical characteristics of the territories set aside for the Greenbelt, and which historically have played a role in the area’s exploitation, are described here. These range from expanses of Mediterranean woodland to the north and west of Monte del Pardo to the various types of farmland that have been adapted to the geological substratum and the contours of the terrain (gentle undulations of arkosic sediment in the north, and wide sandy and gypsiferous tableland in the south), as well as orchards planted in low valleys and along watercourses (the creeks of Monte Carmelo, Valdebebas, Quinto, Santo, Butarque, Meaques and Pozuelo). Once this physical reality ha been detailed, in Chapter 5 will examine the various city models proposed by urban planners, both regionally and municipally, in response to the confluence of social, economic and political interests that have characterized the process of occupation in the Greenbelt area during the construction of the MMA. Municipal planning proposals will be collected and examined for the various municipalities which have land designated for the Greenbelt: Madrid, Coslada, Getafe, Leganés, Alcorcón, Boadilla del Monte and Pozuelo de Alarcón. Furthermore, the various territorial organization proposals which have served as references for municipal planning will also be addressed here, in all of their versions –from the sectorial, which have met with more success and institutional approval, to the many attempts at integration, which have been more complex but less influential, precisely for the difficulty of reconciling physical organization with economic development, and private interest with public benefit. The first period in this process was the development of the General Plan of 1963, followed by the first municipal development plans of the 1970s, in which the need for a regional framework that “organized” the territory in an integral fashion was defined. This would serve as a reference for the sectorial actions that marked the metropolitan area’s initial development. The second came two decades later with the approval of the General Plan of 1985, and the network of municipal plans for the surrounding communities, which followed the same philosophy of austerity with regard to territorial growth. The third would begin to take form in 1997, as a new generation of neo-liberal development plans imposed a territorial model based on centralized large-scale metropolitan operations of infrastructure and equipment, which would indiscriminately consume the totality of Madrid’s land. At the end of the Part II, in Chapter 6, the metropolitan area will be represented graphically and the 229 pieces that have been gradually encroaching upon land designated for the Greenbelt will be analysed. This analysis will be carried out according to the parameters defined for the study, and the first general conclusions of the thesis will be based on its findings. It will show how alliances between the various governing authorities in the construction of the city and its environment have successively violated established plans with regard to the definitions of city and territory, how shortages of instrumental and judicial resources have accentuated the dismantling process, and how natural and geographical factors have influenced functional specialization and social segregation in the Madrid Metropolitan Area. The final step, detailed in Part III, will address two fundamental aspects of what has just been described: the lack of consideration for the cultural and environmental values which have shaped this territory and imprinted upon it a specific and unique character; and the structure of land domination, with a precise identification of the social group and agents responsible at each stage of the Greenbelt’s commercialization, who, under an umbrella of social urgency and deceptive public benefit, have used it to obtain substantial financial rewards. For this purpose, a closer look is taken at two specific areas: the municipality of Pozuelo de Alarcón, representative of the suburban growth of an elite population which has occupied the Greenbelt areas of the greatest ecological value; and the Hortaleza-Barajas district, which has offered its territory to large metropolitan business interests, based on activities centred on the connection between Madrid and Barcelona and the system of international air travel. Both of these settings are located to the north of the line which divides the Sierra from La Mancha, and thus occupy the most valuable land in the Madrid region (a functional structure anticipated by Bidagor in 1946, with his city model adapted to the territory of Madrid). Finally, an attempt will be made to interpret the phenomenon of metropolitan Greenbelt occupation, confirming initial hypotheses, specifying the environmental and cultural values that have been violated, and identifying the various players involved, as well as numerous urbanization operations of varying sizes and interests, and the instruments of planning they have used. It will be seen from this that the construction of the MMA has in fact followed a “spread” model, a “grease spot” (as Geddes calls it) which, from the outset of the planning process and according to the definition of a greenbelt as a construction-free zone, was precisely to be avoided. This structural role (to provide a balance between a city and its residents) has thus been abandoned and the Greenbelt converted instead into a communicative framework which, once consolidated, has become the greatest ally of the real estate machine. After this process of violating limits, norms and established behaviour has been described and solidly documented, a reflection will be made on the real influence of the Greenbelt proposal in the construction of the MMA. At the same time, new roles will be suggested for future planning, roles which are deliberate and long term, in opposition to the immediate and circumstantial. This will enable a new interpretation of the theoretical principles behind the greenbelt concept, a space designed to connect the territory of Madrid environmentally, socially and culturally.

Paleotemperature reconstructions of the Atlantic Sector of the Southern Ocean

Diatom assemblages from ODP Leg 177 sites 1093, 1094 and core PS2089-2, from the present Antarctic sea ice free zone and close to the Polar Front, were analyzed in order to reconstruct the climate development around the Mid-Brunhes Event 400 000 yr ago, as reflected by summer sea surface temperature (SSST) and sea ice distribution. Dense sample spacing allows a mean temporal resolution during Marine Isotope Stage (MIS) 11 (423-362 ka) of 300-400 yr. SSST values were estimated from diatom assemblages using a transfer function technique. The distribution pattern of sea ice diatoms indicates that the present-day ice free Antarctic Zone was seasonally covered by sea ice during the cold MIS 12 and MIS 10. These glacial periods are characterized by sea ice fluctuations with a periodicity of 3 and 1.85 kyr, suggesting the occurrence of Dansgaard-Oeschger-style millennial-scale oscillations in the Atlantic sector of the Southern Ocean during the glacial stages MIS 12 and MIS 10. Termination V (MIS 12/11) is characterized by a distinct temperature increase of 4-6°C, intersected especially at the southern site 1094 and core PS2089-2 by two distinct cooling events reminiscent of the Younger Dryas, which are associated with a northward shift of the winter sea ice edge in the Antarctic Zone. The SSST record is characterized by distinct temperature intervals bounded by stepwise, rapid changes. Maximum temperatures were reached during Termination V and the early MIS 11, exceeding modern values by 2°C over a period of 8 kyr. This pattern indicates a very early response of the Southern Ocean to global climate on Milankovitch-driven climate variability. The SSST optimum is marked by millennial-scale temperature oscillations with an amplitude of ca. 1°C and periodicities of ca. 1.85 and 1.47 kyr, probably reflecting changes in the ocean circulation system. The SSSTs during the MIS 11 temperature optimum do not exceed values obtained from other interglacial optima such as the early periods of MIS 5 or MIS 1 from the Antarctic Zone. However, the total duration of the warmest period was distinctly longer than observed from other interglacials. The comparison of the South Atlantic climate record with a high-resolution record from ODP Leg 162, site 980from the North Atlantic shows a strong conformity in the climate development during the studied time interval.

Free surface vibration in oscillatory convection of half floating zone

Projecting an orthographical grating mask (20pl/mm) on the surface of a small liquid bridge and receiving the reflected distortion image, one can calculate out reversely the shape of free surface of a liquid bridge. In this way we measured the surface shape of a small floating zone and the two-dimensional deformation of its vibration. The mechanism of thermocapillary oscillatory convection and the three-dimensional variation of the free surface are revealed experimentally. The principle for space experiment has been studied in our laboratory.

Free surface oscillation of thermocapillary convection in liquid bridge of half-floating-zone

Free surface deformations of thermocapillary convection in a small liquid bridge of half floating-zone are studied in the present paper. The relative displacement and phase difference of free surface oscillation are experimentally studied, and the features of free surface oscillation for various applied temperature differences are obtained. It is discovered that there is a sort of surface waves having the character of small perturbation, and having a wave mode of unusually large amplitude in one corner region of the liquid bridge.

The methane hydrate formation and the resource estimate resulting from free gas migration in seeping seafloor hydrate stability zone

It is a typical multiphase flow process for hydrate formation in seeping seafloor sediments. Free gas can not only be present but also take part in formation of hydrate. The volume fraction of free gas in local pore of hydrate stable zone (HSZ) influences the formation of hydrate in seeping seafloor area, and methane flux determines the abundance and resource of hydrate-bearing reservoirs. In this paper, a multiphase flow model including water (dissolved methane and salt)-free gas hydrate has been established to describe this kind of flow-transfer-reaction process where there exists a large scale of free gas migration and transform in seafloor pore. In the order of three different scenarios, the conversions among permeability, capillary pressure, phase saturations and salinity along with the formation of hydrate have been deducted. Furthermore, the influence of four sorts of free gas saturations and three classes of methane fluxes on hydrate formation and the resource has also been analyzed and compared. Based on the rules drawn from the simulation, and combined information gotten from drills in field, the methane hydrate(MH) formation in Shenhu area of South China Sea has been forecasted. It has been speculated that there may breed a moderate methane flux below this seafloor HSZ. If the flux is about 0.5 kg m-2 a-1, then it will go on to evolve about 2700 ka until the hydrate saturation in pore will arrive its peak (about 75%). Approximately 1.47 109 m3 MH has been reckoned in this marine basin finally, is about 13 times over preliminary estimate.

Physical interpretation of the spectral radiative signature in the transition zone between cloud-free and cloudy regions

One-second-resolution zenith radiance measure- ments from the Atmospheric Radiation Measurement pro- gram’s new shortwave spectrometer (SWS) provide a unique opportunity to analyze the transition zone between cloudy and cloud-free air, which has considerable bearing on the aerosol indirect effect. In the transition zone, we find a re- markable linear relationship between the sum and difference of radiances at 870 and 1640 nm wavelengths. The intercept of the relationship is determined primarily by aerosol prop- erties, and the slope by cloud properties. We then show that this linearity can be predicted from simple theoretical con- siderations and furthermore that it supports the hypothesis of inhomogeneous mixing, whereby optical depth increases as a cloud is approached but the effective drop size remains un- changed.

Role of free volume in strain softening of as-cast and annealed bulk metallic glass

Plasticity in amorphous alloys is associated with strain softening, induced by the creation of additional free volume during deformation. In this paper, the role of free volume, which was a priori in the material, on work softening was investigated. For this, an as-cast Zr-based bulk metallic glass (BMG) was systematically annealed below its glass transition temperature, so as to reduce the free volume content. The bonded-interface indentation technique is used to generate extensively deformed and well defined plastic zones. Nanoindentation was utilized to estimate the hardness of the deformed as well as undeformed regions. The results show that the structural relaxation annealing enhances the hardness and that both the subsurface shear band number density and the plastic zone size decrease with annealing time. The serrations in the nanoindentation load-displacement curves become smoother with structural relaxation. Regardless of the annealing condition, the nanohardness of the deformed regions is similar to 12-15% lower, implying that the prior free volume only changes the yield stress (or hardness) but not the relative flow stress (or the extent of strain softening). Statistical distributions of the nanohardness obtained from deformed and undeformed regions have no overlap, suggesting that shear band number density has no influence on the plastic characteristics of the deformed region.

K-Ar ages of biotite and muscovite from Pangong metamorphic complex, Shyok suture zone, India: Implications for the youngest post-collision metamorphic event in Ladakh Himalaya

The garnet-kyanite-staurolite and garnet-biotite-staurolite gneisses were collected from a locality within Lukung area that belongs to the Pangong metamorphic complex in Shyok valley, Ladakh Himalaya. The kyanite-free samples have garnet and staurolite in equilibrium, where garnets show euhedral texture and have flat compositional profile. On the other hand, the kyanite-bearing sample shows equilibrium assemblage of garnet-kyanite-staurolite along with muscovite and biotite. In this case, garnet has an inclusion rich core with a distinct grain boundary, which was later overgrown by inclusion free euhedral garnet. Garnet cores are rich in Mn and Ca, while the rims are poor in Mn and rich in Fe and Mg, suggesting two distinct generations of growth. However, the compositional profiles and textural signature of garnets suggests the same stage of P -T evolution for the formation of the inclusion free euhedral garnets in the kyanite-free gneisses and the inclusion free euhedral garnet rims in the kyanite-bearing gneiss. Muscovites from the four samples have consistent K-Ar ages, suggesting the cooling age (∼ 10 Ma) of the gneisses. These ages make a constraint on the timing of the youngest post-collision metamorphic event that may be closely related to an activation of the Karakoram fault in Pangong metamorphic complex.