315 resultados para Corante lipossolúvel


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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Pós-graduação em Química - IQ

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Pós-graduação em Química - IQ

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O objetivo deste trabalho foi avaliar o pH e a densidade óptica das soluções de azul de metileno a 1% e 2% (tamponadas e não tamponadas) após a imersão de três cimentos endodônticos. Foram preparados oitenta espécimes de cada cimento endodôntico (Endofill, AH Plus e Sealapex), os quais foram imersos nas soluções corantes. As soluções foram analisadas antes e após a imersão dos materiais nos períodos de tempo de 0, 24, 48 e 72h. Foram realizadas avaliações do pH utilizando um pHmetro e da densidade óptica utilizando um espectofotômetro ajustado em 596nm. Os dados de pH foram analisados através de estatística descritiva e os dados da densidade óptica foram analisados pela ANOVA e teste de Tukey 5%. Pôde-se verificar que as soluções corantes de azul de metileno tamponadas e não tamponadas apresentaram pequena variação nos valores de pH e densidade óptica antes do contato com os cimentos endodônticos. As soluções corantes não tamponadas apresentaram valores de pH menores que as tamponadas, independentemente do contato com qualquer cimento endodôntico. Os cimentos endodônticos promoveram alterações nos valores de pH das soluções corantes, sendo que as maiores alterações ocorreram nas soluções não tamponadas. Ocorreram alterações nos valores da densidade óptica das soluções corantes tamponadas e não tamponadas nos diferentes períodos de tempo de análise, sendo diferentes para cada cimento endodôntico utilizado

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The industrial development has created many environmental problems that can be observed through the changes in air, soil and water. The pollution of water bodies with compounds present in textile effluents cause beyond the visual pollution, changes in biological cycles, mainly by changing the process of photosynthesis. Due to these environmental implications it is necessary a treatment of livestock manure. The process of adsorption of the dye is a technique that has been successfully employed for effective removal of the color of the effluent. The purpose of this study was to investigate the application of a polyurethane foam plant of castor oil as an alternative adsorbent for removal of dyes in textile effluents. The study was conducted with the dye “luganil azul”, as adsorbent and the foam in a flexible manner and sprayed. It also investigated the influence of pH on the adsorption dye. The kinetic data were obtained, noting that the pH influence on adsorption. Adsorption isotherms of the dye in aqueous solution using the foam in a flexible manner also were determined experimentally.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Métodos comparativos foram desenvolvidos para detectar e quantificar o corante solvente azul 14 (SA-14) em amostras de combustíveis. O método eletroanalítico foi baseado na técnica de voltametria de onda quadrada (VOQ) com detecção em +0,60 V vs. Ag/AgCl sobre o eletrodo de carbono vítreo, usando tampão Britton-Robinson e N, N-dimetilformamida (1:1, v/v) como eletrólito suporte. Para metodologia, envolvendo a cromatografia líquida de alta performance (CLAE) foi empregada uma fase móvel composta de acetonitrila e cloreto de lítio (85:15, v/v) e a detecção eletroquímica foi realizada em um potencial de oxidação em +0,65 V vs. Ag/AgCl. Sob as melhores condições de trabalho curvas de calibração foram obtidas, para ambos os métodos, as quais foram lineares na faixa de concentração de 5,0×10 -7 a 6,0×10 -6 mol L-1 (VOQ) e 8,0×10 -8 a 3,0×10 -6 mol L-1 (CLAE). Os métodos foram aplicados para quantificar o corante em amostras de álcool e querosene após um simples processo de extração em fase sólida com resultados de recuperação satisfatórios.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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One of the most primal ways of human work already known is the tessellation and ginning for the production of fabric and clothing - what used to be, back in those days, statement of power and status. The arrival of the Industrial Revolution - in the middle of the XVIII century at Britain - increased the textile industry production, and what used to be manufactured and hard to obtain, starts then to be produced in mechanical ways and large-scale. Despite all the boost given to the economy of an expanding capitalist market, it should be pointed out the consequences of this major industrialization, especially the environmental ones, more and more concerning nowadays. The emissions of waste - that sometimes could be toxic - in effluents can possibly contaminate the aquatic ecosystems, causing a huge damage to its fauna and flora, affecting therefore all the biodiversity, reaching inclusively the humans. To avoid these problems, a few strategies have been taking place in the attempt to eliminate - or at least reduce - the amount of dye found in the effluents, and as the textile industry constantly leaves waste, efficient methods - that present good results in a short period of time - with a low cost are needed. The present study will test the bioremoval capacity of yeast (Saccharomyces cerevisiae) in contact with dyes in a fix concentration, diluted in water with three different pH values. The tests will be done duplicate, and after the concentration analyses - made by spectrophotometry - it will be analyzed which pH shows major efficiency in the dye removal and what is the influence of the biomass in this process

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The purpose of this study was to evaluate the apical sealing ability and the marginal adaptation of five dental materials used in retrofillings or applied to the bevelled root surface. One hundred and forty extracted single rooted human teeth were used, divided into seven groups of twenty each. ln the first, second, third and fourth groups, the teeth were apicoectomized, submitted to cavity preparations and retrofilled with one of the following materiais: zinc free silver amalgam, a dentin bonding system plus composite resin, a glass ionomer cement ora compomer. In the fifth, sixth and seventh groups, the teeth were apicoectomized and capped on the bevelled root surface with one of the following materiais: a dentin bonding system plus composite resin, a glass ionomer cement or a compomer. Two specimens of each experimental group were evaluated for the marginal adaptation using scanning electron microscopy. The remaining 126 specimens were immersed in 2% methylene blue dye, stored for one week at 37ºC and the infiltration was evaluated with a stereomicroscope. The results showed that the glass ionomer cement presented the lowest values of marginal infiltration when used as retrofilling material, with a significant statistical difference when compared with the others tested materials. When used as apical capping, the glass ionomer cement and the compomer were equivalent and significantly better than the dentin bonding system plus composite resin. Using scanning electron microscopy, all the materials showed some slight adjustment problem. ln the retrofilling, the smallest marginal gaps were observed with the compomer and the dentin bonding system plus composite resin, while the largest were observed with the glass ionomer cement and zinc free silver amalgam. ln the apical capping, the smallest marginal gaps were observed with the compomer and the dentin bonding system plus composite resin and ...

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DEVELOPMENT AND EVALUATION OF GAS DIFFUSION ELECTRODES (GDE) FOR GENERATION OF H2O2 IN SITU AND THEIR APPLICATION IN THE DEGRADATION OF REACTIVE BLUE 19 DYE. This work reports the development of GDE for electrogeneration of H2O2 and their application in the degradation process of Reactive Blue 19 dye. GDE produced by carbon black with 20% polytetrafluoroethylene generated up to 500 mg L-1 of H2O2 through the electrolysis of acidic medium at -0.8 V vs Ag/AgCl. Reactive Blue 19 dye was degraded most efficiently with H2O2 electrogenerated in the presence of Fe(II) ions, leading to removal of 95% of the original color and 39% of TOC at -0.8 V vs Ag/AgCl.