Aquatic humus from an unpolluted Brazilian dark-brown stream: general characterization and size fractionation of bound heavy metals

The main pool of dissolved organic carbon in tropical aquatic environments, notably in dark-coloured streams, is concentrated in humic substances (HS). Aquatic HS are large organic molecules formed by micro-biotic degradation of biopolymers and polymerization of smaller organic molecules. From an environmental point of view, the study of metal-humic interactions is often aimed at predicting the effect of aquatic HS on the bioavailability of heavy metal ions in the environment. In the present work the aquatic humic substances (HS) isolated from a dark-brown stream (located in an environmental protection area near Cubatao city in São Paulo-State, Brazil) by means of the collector XAD-8 were investigated. FTIR studies showed that the carboxylic carbons are probably the most important binding sites for Hg(II) ions within humic molecules. C-13-NMR and H-1-NMR studies of aquatic HS showed the presence of constituents with a high degree of aromaticity (40% of carbons) and small substitution. A special five-stage tangential-flow ultrafiltration device (UF) was used for size fractionation of the aquatic HS under study and for their metal species in the molecular size range 1-100 kDa (six fractions). The fractionation patterns showed that metal traces remaining in aquatic HS after their XAD-8 isolation have different distributions. Generally, the major percentage of traces of Mn, Cd and Ni (determined by ICP-AES) was preferably complexed by molecules with relatively high molecular size. Cu was bound by fractions with low molecular size and Co showed no preferential binding site in the various humic fractions. Moreover, the species formed between aquatic HS and Hg(II), prepared by spiking (determined by CVAAS), appeared to be concentrated in the relatively high molecular size fraction F-1 (> 100 kDa).

Biodiversity of decapod crustaceans in the estuarine floodplain around the city of Belém (Pará) in Brazilian Amazonia

ABSTRACT: The present study focused on the decapod fauna of the fluvial-estuarine environment of the Guajará Bay, in the Brazilian state of Pará, where specimens were collected monthly from six sites, from May 2006 to April 2007. A total of 6,793 specimens were captured, belonging to 11 species of crab and shrimp: eight palaemonids - Macrobrachium amazonicum (Heller, 1862), Macrobrachium surinamicum Holthuis, 1948, Macrobrachium carcinus (Linnaeus, 1758), Macrobrachium rosenbergii (De Man, 1879), Macrobrachium spp. 1-4 -, one portunid - Callinectes bocourti A. Milne-Edwards, 1879 -, and two trichodactylids - Sylviocarcinus devileii H. Milne-Edwards, 1853 and Sylviocarcinus pictus (Milne-Edwards, 1853). While no significant differences were found in the ecological indices of diversity with respect to season, site, or trap size, a tendency for increased abundance and species richness was found during the dry season (August-November), in particular at some sites, apparently reflecting the influence of the estuary's saline wedge.

Length-weight relationship and reproduction of the guppy Poecilia reticulata (Cyprinodontiformes: Poeciliidae) in urban drainage channels in the Brazilian city of Belém

O presente trabalho tem por objetivo descrever aspectos populacionais relacionados ao estabelecimento da relação peso/comprimento, estimativa de tamanho de primeira maturação (L) e período reprodutivo de Poecilia reticulata encontrados em sistemas de coleta residual no campus da Universidade Federal do Pará, região metropolitana de Belém – PA (Brasil). Foram realizadas coletas mensais no período de junho de 2006 a março de 2007, utilizando um puçá, que resultou na captura de 1.936 exemplares, sendo 942 machos e 994 fêmeas. As fêmeas apresentaram-se maiores e mais pesadas que os machos. A relação peso/comprimento para machos foi estabelecida pela equação Pt = 5 × 10^-5× Ct^2,397 e para fêmeas esta foi dada pela fórmula Pt = 3 × 10^-6 × Ct3,419. Os valores estimados para L foi 17,5 mm para machos 20,4 mm para fêmeas, sugerindo que os machos iniciam atividades reprodutivas em tamanhos menores que as fêmeas. A frequência mensal de fêmeas maduras não variou significativamente. Além disso, também não foram encontradas diferenças na proporção sexual durante os períodos investigados, sendo no geral, a proporção de fêmeas iguais as de machos. Desta forma, verificamos que, apesar das condições presentes nos sistemas de coleta residual da UFPA, a espécie P. reticulata parece ter adaptado seus processos biológicos.

Characterization of atmospheric aerosols in the city of So Paulo, Brazil: comparisons between polluted and unpolluted periods

The objective of this study was to determine the size and composition of atmospheric aerosols in the downtown area of the city of So Paulo, Brazil, for a polluted and an unpolluted period. Aerosols were sampled with a portable air sampler (PAS), Micro-Orifice Uniform Deposit Impactor (MOUDI), and Scanning Mobility Particle Sizer. At the study site, air quality is poor, especially during the winter, high concentrations of pollutants being emitted primarily by the light- and heavy-duty vehicle fleet. We analyzed mass, black carbon (BC), Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sn, Zr, and Pb. During the polluted period, diurnal PM(10) was higher than nocturnal PM(10), whereas the inverse was true during the unpolluted period. The FPM was rich in BC, S, and Pb, whereas CPM was rich in Al, Si, Ca, Ti, and Fe. Mass balance was performed by category: ammonium sulfate, sodium chloride, crustal material, BC, and other. The PAS-determined FPM was mainly BC. The MOUDI-determined FPM crustal material explained more mass than did ammonium sulfate and BC during the polluted period, whereas ammonium sulfate had the largest mass during the unpolluted period. Crustal material was the major CPM component, followed by ammonium sulfate and BC. During the unpolluted period, FPM concentrations were lower, whereas those of ammonium sulfate were relatively higher, especially at night, and particle number was inversely proportional to particle size. Aerosol growth was more intense during the polluted period.

Recycling the city: a sustainable planning framework to reduce, reuse and recycle urban residual spaces

Cities are key locations where Sustainability needs to be addressed at all levels, as land is a finite resource. However, not all urban spaces are exploited at best, and land developers often evaluate unused, misused, or poorly-designed urban portions as impracticable constraints. Further, public authorities lose the challenge to enable and turn these urban spaces into valuable opportunities where Sustainable Urban Development may flourish. Arguing that these spatial elements are at the centre of SUD, the paper elaborates a prototype in the form of a conceptual strategic planning framework, committed to an effective recycling of the city spaces using a flexible and multidisciplinary approach. Firstly, the research focuses upon a broad review of Sustainability literature, highlighting established principles and guidelines, building a sound theoretical base for the new concept. Hence, it investigates origins, identifies and congruently suggests a definition, characterisation and classification for urban “R-Spaces”. Secondly, formal, informal and temporary fitting functions are analysed and inserted into a portfolio meant to enhance adaptability and enlarge the choices for the on-site interventions. Thirdly, the study outlines ideal quality requirements for a sustainable planning process. Then, findings are condensed in the proposal, which is articulated in the individuation of tools, actors, plans, processes and strategies. Afterwards, the prototype is tested upon case studies: Solar Community (Casalecchio di Reno, Bologna) and Hyllie Sustainable City Project, the latter developed via an international workshop (ACSI-Camp, Malmö, Sweden). Besides, the qualitative results suggest, inter alia, the need to right-size spatial interventions, separate structural and operative actors, involve synergies’ multipliers and intermediaries (e.g. entrepreneurial HUBs, innovation agencies, cluster organisations…), maintain stakeholders’ diversity and create a circular process open for new participants. Finally, the paper speculates upon a transfer of the Swedish case study to Italy, and then indicates desirable future researches to favour the prototype implementation.

DEVELOPMENT OF AN OPTIMIZATION MODEL FOR BIOFUEL FACILITY SIZE AND LOCATION AND A SIMULATION MODEL FOR DESIGN OF A BIOFUEL SUPPLY CHAIN

A range of societal issues have been caused by fossil fuel consumption in the transportation sector in the United States (U.S.), including health related air pollution, climate change, the dependence on imported oil, and other oil related national security concerns. Biofuels production from various lignocellulosic biomass types such as wood, forest residues, and agriculture residues have the potential to replace a substantial portion of the total fossil fuel consumption. This research focuses on locating biofuel facilities and designing the biofuel supply chain to minimize the overall cost. For this purpose an integrated methodology was proposed by combining the GIS technology with simulation and optimization modeling methods. The GIS based methodology was used as a precursor for selecting biofuel facility locations by employing a series of decision factors. The resulted candidate sites for biofuel production served as inputs for simulation and optimization modeling. As a precursor to simulation or optimization modeling, the GIS-based methodology was used to preselect potential biofuel facility locations for biofuel production from forest biomass. Candidate locations were selected based on a set of evaluation criteria, including: county boundaries, a railroad transportation network, a state/federal road transportation network, water body (rivers, lakes, etc.) dispersion, city and village dispersion, a population census, biomass production, and no co-location with co-fired power plants. The simulation and optimization models were built around key supply activities including biomass harvesting/forwarding, transportation and storage. The built onsite storage served for spring breakup period where road restrictions were in place and truck transportation on certain roads was limited. Both models were evaluated using multiple performance indicators, including cost (consisting of the delivered feedstock cost, and inventory holding cost), energy consumption, and GHG emissions. The impact of energy consumption and GHG emissions were expressed in monetary terms to keep consistent with cost. Compared with the optimization model, the simulation model represents a more dynamic look at a 20-year operation by considering the impacts associated with building inventory at the biorefinery to address the limited availability of biomass feedstock during the spring breakup period. The number of trucks required per day was estimated and the inventory level all year around was tracked. Through the exchange of information across different procedures (harvesting, transportation, and biomass feedstock processing procedures), a smooth flow of biomass from harvesting areas to a biofuel facility was implemented. The optimization model was developed to address issues related to locating multiple biofuel facilities simultaneously. The size of the potential biofuel facility is set up with an upper bound of 50 MGY and a lower bound of 30 MGY. The optimization model is a static, Mathematical Programming Language (MPL)-based application which allows for sensitivity analysis by changing inputs to evaluate different scenarios. It was found that annual biofuel demand and biomass availability impacts the optimal results of biofuel facility locations and sizes.

An evaluation of the impact of Inner City Development's Cooperative Home School: An educational alternative program to increase the quality and level of education in San Antonio's West Side community

The research study was intended to evaluate the effectiveness of Inner City Development's (I.C.D.) Cooperative Home School, an educational alternative program to the Title I public schools of San Antonio's West Side community. The study investigated students', parents' and tutors' perception of parental involvement and educational resources. The study also investigated each student's academic achievement. ^ The study found that students progressed toward expected math proficiency at a faster rate than they did in reading proficiency. However, because the target population size was small and a comparison group was not used, the results of this study are only suggestive. This research also indicated that study subjects believed students' quality and level of education increased substantially since program exposure. Study subjects mainly attributed the students' strides in academic performance to the increased amount of individualized attention students received in the small twelve-student class size. Study subjects were more satisfied with the home school's educational resources than those of the Title I public schools. Study subjects also perceived that parental involvement both at home and at school increased since enrollment in the home school program because: (1) there were more opportunities for involvement in the home school; and (2) parents felt closer to the tutors than the teachers in public school. ^ This evaluation also suggested improvements to program operations. With the help of additional volunteers, I.C.D. program operators could improve collection and organization of academic records. Furthermore, as suggested by program participants, science could be added to the curriculum. Lastly, a formal tutor orientation could be implemented to familiarize and train tutors on classroom management procedures. ^

On the sustainability of a monocentric city : lower transport costs from new transport facilities

This paper proposes a general equilibrium model of a monocentric city based on Fujita and Krugman (1995). Two rates of transport costs per distance and for the same good are introduced. The model assumes that lower transport costs are available at a few points on a line. These lower costs represent new transport facilities, such as high-speed motorways and railways. Findings is that new transport facilities connecting the city and hinterlands strengthen the lock-in effects, which describes whether a city remains where it is forever after being created. Furthermore, the effect intensifies with better agricultural technologies and a larger population in the economy. The relationship between indirect utility and population size has an inverted U-shape, even if new transport facilities are used. However, the population size that maximizes indirect utility is smaller than that found in Fujita and Krugman (1995).

Desarrollo de un modelo de evaluación de ciudades basado en el concepto de ciudad inteligente (Smart city)

La presente tesis tiene por finalidad contribuir al conocimiento de los procesos de transformación de las ciudades convencionales en Ciudades Inteligentes o Smart Cities, el nuevo paradigma urbano, que surge como consecuencia de la utilización de las Tecnologías de la Información y de las Comunicaciones, las TIC, para mejorar la calidad de vida de las personas y aumentar la eficiencia y eficacia de los procesos, servicios e infraestructuras de la ciudad. El proceso de urbanización de la población mundial constituye una de las principales tendencias globales. Los retos a los que se enfrentan las urbes actuales para satisfacer las necesidades de sus habitantes, así como la forma en que cada ciudad aborda dichos retos, propician el desarrollo de estudios comparativos y rankings de ciudades. La oportunidad para llevar a cabo esta tesis deriva de: La novedad del concepto de Ciudad Inteligente. La necesidad de establecer estudios comparativos, respecto a dicho concepto, entre ciudades con características socioeconómicas y culturales comunes, dado que la mayoría de los estudios y rankings se desarrollan para conjuntos de ciudades cuyas características son muy dispares, pues, en general son seleccionadas por su condición de capitales de estados o de centros económicos-financieros. El interés de disponer de estudios sobre ciudades con tamaños de población medianos, inferiores al millón de habitantes, las cuales tienen baja presencia en los estudios comparativos. La inexistencia de estudios comparativos entre las ciudades españolas, en relación con el concepto de Ciudad Inteligente. La existencia de la Red Española de Ciudades Inteligentes, que permite disponer de una muestra de ciudades adecuada, para llevar a cabo un estudio comparativo de acuerdo con los puntos anteriores. El objetivo general de la presente tesis es contribuir al conocimiento de los procesos de transformación de la ciudad convencional en Ciudad Inteligente, a través de la formulación y aplicación de un modelo de evaluación, basado en el concepto holístico de Ciudad Inteligente o Smart City y desde la perspectiva del ciudadano. La metodología de trabajo seguida comprende, en primer lugar, la revisión del estado del arte, centrada en tres aspectos: la evolución del concepto Smart City, los estudios comparativos sobre Ciudades Inteligentes y las medidas que las ciudades españolas están implantando en la práctica para llevar a cabo su transformación en Ciudades Inteligentes. A continuación se lleva a cabo el diseño el modelo de evaluación. Este modelo refleja el carácter holístico del concepto de Ciudad Inteligente, para lo cual, de acuerdo con las definiciones que encontramos en la literatura, evalúa la situación de cada ciudad en relación con seis ejes o pilares, comúnmente aceptados por los diferentes autores: e-Gobierno y e-Gobernanza, Movilidad, Sostenibilidad Ambiental, Desarrollo Económico, Capital Intelectual y Calidad de Vida. El trabajo desarrollado implica un análisis, que se desarrolla de forma ordenada para cada uno de los ejes y, dentro de éstos, para sus correspondientes factores. En total se analizan 18 factores. Para cada uno de los ejes se lleva a cabo una revisión de las iniciativas más representativas para, a continuación, analizar y evaluar los correspondientes los factores. De forma complementaria al desarrollo del trabajo, se llevó a cabo una encuesta, dirigida a profesionales de diferentes áreas y sectores, todos ellos en el ámbito de las Ciudades Inteligentes. El objetivo de la encuesta es conocer, de acuerdo con la opinión de los profesionales, la situación actual en materia de despliegue de Ciudades Inteligentes, las actuaciones que consideran de mayor interés para la ciudad y las barreras del proceso de cambio. Una vez definido el modelo, se ha aplicado a las 62 ciudades que forman la Red Española de Ciudades Inteligentes (RECI), valorando los factores y los ejes para cada una de ellas. Así mismo, se ha analizado la influencia de las tres variables siguientes: tamaño de población, densidad de población y presupuesto municipal por habitante, determinando la relación entre el porcentaje de ciudades inteligentes de la muestra, en cada factor. Adicionalmente en el eje Capital Intelectual,se analizó la influencia del porcentaje de habitantes con estudios superiores. Las 62 ciudades RECI que componen la muestra evaluada, representan el 43 % de las ciudades españolas que cuentan con poblaciones superiores a los 50.000 habitantes. La población que abarca la muestra de ciudades estudiada representa el 35% de la población española. Finalmente, se ha determinado el ranking con las ciudades de RECI, de acuerdo con el modelo diseñado. Así mismo se ha llevado a cabo el análisis de sensibilidad, determinado el ranking resultante para la misma muestra de ciudades, aplicando la ponderación de los factores. Las principales aportaciones de la tesis son: Desarrollar un modelo de evaluación de ciudades basada en el concepto holístico de la Smart City y desde la perspectiva del ciudadano. Desarrollar una metodología de trabajo fundamentada en el análisis sistematizado de las web municipales, como medio para conocer la situación de las ciudades, en lugar de los datos estadísticos publicados, que son la fuente de información habitualmente empleada en los estudios comparativos. Disponer de un estudio comparativo específico de ciudades españolas. Llevar a cabo un estudio sobre una muestra de ciudades de tamaño medio, con características socioeconómicas y culturales comparables. Mejorar el conocimiento de los procesos que se están llevando a cabo en ciudades con poblaciones inferiores al millón de habitantes. The purpose of this thesis is to contribute to the knowledge of the cities and the transformation that is taking part in traditional cities becoming Smart Cities. The Smart City concept is the new urban paradigm that is born from the extensive use of Information Technologies (IT) in order to accomplish better citizen’s quality of life as well as improvements in urban processes, services and infrastructures. Several rankings and benchmarking studies are being conducted globally, in response to the increasing of urban population that is taking part around the world and the subsequent challenges to be confronted by the cities. This thesis aims to contribute to these studies. The opportunity for this thesis comes from: The Smart City concept as a new concept. The need of benchmarking studies focused on the Smart City concept, carried on cities with similar social and economic characteristics. The interest on benchmarking studies on medium size cities (with less than one million inhabitants). The absence of benchmarking studies on Spanish cities. The existence of the Spanish Smart Cities Network that can be considered an appropriate sample for a benchmark study. The main goal of this thesis is to develop a Smart Cities assessment model based on the citizen point of view and taking into account a holistic concept of Smart City. The thesis methodology starts with the state of the art revision, focused on three items: the Smart City concept, the benchmark studies and the projects actually developed by the Spanish cities under processes for becoming Smart Cities. The next step is the assessment model design, in accordance with the six main axes or pillars referred in the academic literature: e-Government and e-Governance, Mobility, Environmental Sustainability, Economic Development, Smart Citizens and Quality of Life. Also, a survey has been conducted and addressed to experts working on the different areas related to the Smart Cities. The aim of this survey is to know their opinion about the deployment of the Smart Cities, the priorities considered by the cities and the barriers that delay the change processes. Once the assessment model was ready, it was applied to the Spanish Smart Cities Network, with 62 member cities. Also, the bearing of three variables: city population, population density and city budget per inhabitant, are studied. The 62 cities studied are 43 % of the Spanish cities with population over 50.000 inhabitants. The population living in these cities is the 35% of total Spanish population. The main contribution of this thesis are: An assessment model for Smart Cities that takes into account the holistic concept of the Smart City as well as the citizen experience. A methodology that comprises municipal web analysis instead of statistics data, which are the usual source of data for current benchmarking studies. A Spanish Smart Cities benchmark. A benchmark on medium size cities with similar social and economic characteristics. A better understanding of the urban processes that are taking part on cities under one million inhabitants.

City of Ann Arbor, Washtenaw County, Michigan

Map shows size city wards, township sections, lot boundaries, buildings and other cultural features, and sections of land annexed by the city.

Long-term effects of beach nourishment on the benthic fauna of Panama City Beach, Florida /

The long-term effects of beach nourishment on the benthic infauna and surface sediments of Panama City beaches were investigated. Forty-seven stations located on nine transects between West Pass and Philips Inlet, and two nourishment borrow sites were sampled in November-December 1979 and May 1980. The data collected were compared to prenourishment base-line information collected by Saloman (1976). Abiotic parameters, water temperature, dissolved oxygen and salinity were measured. Sediments were analyzed for particle-size distribution, percent organic carbon and percent carbonate. Benthic macroinvertebrates were represented by 162 taxa of 14 major animal phyla. Species composition and faunal densities varied seasonally. Polychaetes and amphipods were the most abundant animal groups; a small number of species were dominant at nearly all stations. Species diversity was lowest in the swash zone and sandbar stations and highest offshore. Sediment composition was similar to that of Saloman's (1976) study within limits of sampling and processing errors. Faunal composition was found to be different from 1976 but was attributed to normal seasonal and spatial variations. Based on benthic community analyses and sediment parameters, no significant differences were found between nourishment borrow sites and surrounding areas and in the nearshore areas where beach nourishment was conducted. No long-term adverse effects of beach nourishment were detected. (Author).

Benthic community response to dredging borrow pits, Panama City Beach, Florida /

This report gives biological and physical oceanographic data from baseline work, and studies of dredged and undredged sediments before and after dredging (9-meter contour) for beach nourishment at Panama City Beach, Florida. These studies were designed to show major short-term environmental effects of offshore dredging and included analyses of hydrology, sediments, and benthos. (Author).

Annual report of the Board of Harbor Commissioners of the City of Los Angeles, California.

Quarto size: 1954/55.

Report of the Comptroller of the City of New York, for the year ending ...

Quarto size: 1911-1939/1940