Nanostructured CexZn1-xO thin films: Influence of Ce doping on the structural, optical and electrical properties

Thin films of CexZn1-xO thin films were deposited on glass substrates at 400 degrees C by nebulizer spray pyrolysis technique. Ce doping concentration (x) was varied from 0 to 10%, in steps of 2.5%. X-ray diffraction reveals that all the films have polycrystalline nature with hexagonal crystal structure and high preferential orientation along (002) plane. Optical parameters such as; transmittance, band gap energy, refractive index (n), extinction coefficient (k), complex dielectric constants (epsilon(r), epsilon(i)) and optical conductivity (sigma(r), sigma(i)) have been determined and discussed with respect to Ce concentration. All the films exhibit transmittance above 80% in the wavelength range from 330 to 2500 nm. Optical transmission measurements indicate the decrease of direct band gap energy from 3.26 to 3.12 eV with the increase of Ce concentration. Photoluminescence spectra show strong near band edge emission centered similar to 398 nm and green emission centered similar to 528 nm with excitation wavelength similar to 350 nm. High resolution scanning electron micrographs indicate the formation of vertical nano-rod like structures on the film surface with average diameter similar to 41 nm. Electrical properties of the Ce doped ZnO film have been studied using ac impedance spectroscopy in the frequency range from 100 Hz-1 MHz at different temperatures. (C) 2013 Elsevier B.V. All rights reserved.

Rare-earth carboxylates, Ln(2)(III)(mu(3)-OH)(C4H4O5)(2)(C4H2O4)]center dot 2H(2)O Ln = Ce, Pr and Nd]: synthesis, structure and properties

A new series of inorganic-organic hybrid framework compounds, Ln(2)(mu(3)-OH)(C4H4O5)(2)(C4H2O4)]center dot 2H(2)O, (Ln = Ce, Pr and Nd), have been prepared employing a hydrothermal method. Malic acid and fumaric acid form part of the structure. The malate units connect the lanthanide centers forming Ln-O-Ln two-dimensional layers, which are cross-linked by the fumarate units forming the three-dimensional structure. Extra framework water molecules form a dimer and occupy the channels. The water molecules can be reversibly adsorbed. The dehydrated structure did not show any differences in framework structure/ connectivity. The presence of lattice water provides a pathway for proton conductivity. Optical studies suggest an up-conversion behavior involving more than one photon for a neodymium compound.

Ferroelectric instabilities and enhanced piezoelectric response in Ce modified BaTiO3 lead-free ceramics

The crystal structure, ferroelectric, and piezoelectric behaviors of the Ba(Ti1-xCex)O-3 solid solution have been investigated at close composition intervals in the dilute concentration regime. Ce concentration as low as 2 mol. % induces tetragonal-orthorhombic instability and coexistence of the phases, leading to enhanced high-field strain and direct piezoelectric response. Detailed structural analysis revealed tetragonal + orthorhombic phase coexistence for x = 0.02, orthorhombic for 0.03 <= x <= 0.05, and orthorhombic + rhombohedral for 0.06 <= x <= 0.08. The results suggest that Ce-modified BaTiO3 is a potential lead-free piezoelectric material. (C) 2015 AIP Publishing LLC.

The deciding role of texture on ductility in a Ce containing Mg alloy

This is the first successful attempt to produce Mg-Ce alloys of different texture through different processing routes while keeping the grain size and grain size distribution same. Tensile data shows that contribution of texture to ductility enhancement is primary and that of grain refinement is secondary. The texture resulting from multi-axial forging of extruded billets followed by annealing exhibits the highest ductility (similar to 40%) at room temperature. (C) 2015 Elsevier B.V. All rights reserved.

Indentation Creep Behavior in Ce-Based Bulk Metallic Glasses at Room Temperature

The room temperature creep behaviors of Ce-based bulk metallic glasses were examined by the use of nanoindentation. The creep rate and creep rate sensitivity of Ce-based BMGs were derived from indentation creep curves. The low creep rate sensitivity of Ce-based BMGs indicates that the room temperature creep is dominated by localized shear flow. The experimental creep curves can be described by a generalized Kelvin model. Furthermore, the creep retardation spectrum is calculated for the Ce-based metallic glasses. The results showed that creep retardation spectrum consists of two relatively separated peaks with the well defined characteristic relaxation times.

Strain Rate Dependence of Plastic Flow in Ce-based Bulk Metallic Glass During Nanoindentation

The strain rate dependence of plastic deformation of Ce60Al15CU10Ni15 bulk metallic glass was studied by nanoindentation. Even though the ratio of room temperature to the glass transition temperature was very high (0.72) for this alloy, the plastic deformation was dominated by shear banding under nanoindentation. The alloy exhibited a critical loading rate dependent serrated flow feature. That is, with increasing loading rate, the alloy exhibited a transition from less prominent serrated flow to pronounced serrated flow during continuous loading but from serrated to smoother flow during stepped loading.

An Improved Ce/Se Scheme And Its Application To Detonation Propagation

An improved two-dimensional space-time conservation element and solution element ( CE/ SE) method with second-order accuracy is proposed, examined and extended to simulate the detonation propagations using detailed chemical reaction models. The numerical results of planar and cellular detonation are compared with corresponding results by the Chapman-Jouguet theory and experiments, and prove that the method is a new reliable way for numerical simulations of detonation propagation.

Proyecto de investigación arqueológica : la organización de la tecnología lítica en la Quebrada de La Cueva (Departamento de Humahuaca, provincia de Jujuy)

Resumen: Se presenta el proyecto de investigación arqueológica en el área de la Quebrada de La Cueva (Departamento de Humahuaca, provincia de Jujuy). La aproximación se realiza desde la perspectiva de la organización de la tecnología lítica. En este marco, se describen brevemente los distintos sitios arqueológicos, se caracterizan algunas cuestiones teóricas y metodológicas de la investigación y se presentan los resultados preliminares alcanzados.

Plastic deformation in Ce-based bulk metallic glasses during depth-sensing indentation

The deformation behavior and the effect of the loading rate on the plastic deformation features in (numbers indicate at.%) Ce60Al15Cu10Ni15, Ce65Al10Cu10Ni10Nb5, Ce68Al10Cu20Nb2, and Ce70Al10Cu20 bulk metallic glasses (BMGs) were investigated through nanoindentation. The load-displacement (P-h) curves of Ce65Al10Cu10Ni10Nb5, Ce68Al10Cu2, and Ce70Al10Cu20 BMGs exhibited a continuous plastic deformation at all studied loading rate. Whereas, the P-h curves of Ce60Al15Cu10Ni15 BMG showed a quite unique feature, i.e. homogeneous plastic deformation at low loading rates, and a distinct serrated flow at high strain rates. Moreover, a creep deformation during the load holding segment was observed for the four Ce-based BMGs at room temperature. The mechanism for the appearance of the "anomalous" plastic deformation behavior in the Ce-based BMGs was discussed. (c) 2006 Elsevier B.V. All rights reserved.

Aspectos simbólicos prehispánicos en la Quebrada de la Cueva : una mirada arqueológica

Resumen: El trabajo presenta una aproximación al estudio de algunos aspectos simbólicos arqueológicos en la quebrada de La Cueva, Humahuaca, Jujuy. En primer término se estudian y discuten los contextos funerarios recuperados en el pasado y presente en el Pukara de La Cueva, en el marco de la denominada Arqueología de la Muerte. En segunda instancia, se analiza el hallazgo de un molusco fósil dentro de un contexto habitacional del mismo sitio, para el cual se postulan y discuten posibles connotaciones simbólicas. Con esta investigación buscamos trascender la presentación de datos puramente materiales, para penetrar en la esfera de la ideología, el simbolismo y las relaciones sociales de los grupos prehispánicos que habitaron la quebrada de La Cueva.

Simple phenomenological determination of contact stiffness and elastic modulus of Ce-based bulk metallic glasses through nanoindentation

The viscoelastic deformation of Ce-based bulk metallic glasses (BMGs) with low glass transition temperature is investigated at room temperature. Contact stiffness and elastic modulus of Ce-based BMGs cannot be derived using the conventional Oliver-Pharr method [W. C. Oliver and G. M. Pharr, J. Mater. Res. 7, 1564 (1992)]. The present work shows that the time dependent displacement of unloading segments can be described well by a generalized Kelvin model. Thus, a modified Oliver-Pharr method is proposed to evaluate the contact stiffness and elastic modulus, which does, in fact, reproduce the values obtained via uniaxial compression tests. (c) 2007 American Institute of Physics.

Caracterización de la crianza de Chompipe doméstico (Meleagris gallo-pavo) en la Comarca de Quebrada Honda, Masaya

Este estudio describe la crianza de chompipe doméstico (Meleagris gallo-pavo) en la comarca de Quebrada Honda municipio de Masaya, de noviembre del 2014 a junio del 2015. Se seleccionaron 25 familias bajo criterios previos: anuencia y experiencia en el manejo de los mismos. Para recabar información utilizamos guías de observación, entrevista. Para el procesamiento e interpretación de la información, se utilizó estadística descriptiva, usando gráficos, tablas de frecuencia y datos porcentuales. Las variables evaluadas: cantidad de chompipe, importancia de la crianza, manejo, parámetros productivos y reproductivos y enfermedades que los afectan. Los resultados obtenidos fueron: Población total de chompipes 187,entre ellos 155 adultos, 20 pichones y 12 crías. La importancia de la crianza de chompipe para las familias se determinó por las causas que expresan, donde el 68% de las familias opinaron que los crían para venta, el 20% para consumo, 12% refieren que los crían por ornamento y guardianes. Las principales características de estas aves son: rusticidad, resistentes a enfermedades y de fácil manejo. De la carne y huevos, las familias desconocen el valor nutricional, pero ponderan el sabor de la carne con respecto al de la gallina india. El destino de la producción de huevos es principalmente para la reproducción, El manejo proporcionado a los chompipes es rudimentario, característico de un sistema extensivo. El alimento suministrado, es maíz o sorgo, además desperdicios de cocina, No construyen instalaciones ni equipos para las aves. Durante el pastoreo consumen insectos, follajes y frutas, entre otros. El peso del huevo es de 74 g y ponen un promedio de 45-60 h/año. La incubación dura 28-30 días y su reproducción es durante todo el año con una buena alimentación. La relación hembra/ macho es 3-1 h/m. La madurez sexual de la hembra y del macho oscila entre 6-9 meses de edad.

Ce基大块非晶合金在纳米压人过程中的变形行为

利用纳米压入技术研究了Ce基大块非晶合金的变形行为,以及加载速率对塑性变形行为的影响规律.结果表明,Ce基大块非晶合金在纳米压入过程中表现出的变形行为与其他体系大块非晶有显著差别.Ce60Al15Cu10Ni15合金在低加载速率下为连续的塑性变形,在高加载速率下表现出显著的锯齿流变特征;而Ce65Al10Cu10Ni10Nb5合金,在所研究的加载速率范围内均为连续的塑性变形．但是,这两种合金都出现了室温蠕变现象．另外,探讨了Ce基大块非晶合金的反常塑性变形行为的产生机理．