Chemical and isotopic compositions of authigenic carbonates from bottom sediments of Northwest Pacific marginal seas

The paper presents data on authigenic carbonate distribution in Holocene - Upper Pleistocene deposits of the Okhotsk, Japan, East China, Philippine and South China Seas. Description of carbonate samples, their chemical and isotope compositions are given. Chemical analysis of the samples indicates that almost all authigenic carbonates are composed of calcite or magnesian calcite; and only in one case, of siderite. Oxygen isotopic composition (d18O) ranges from +37.7 to +26.1 per mil (SMOW); it is, probably, connected with different temperatures of carbonate formation. A distinct geographic regularity is traced. Decrease in d18O values is observed from the cold Okhotsk Sea to the warm South China Sea. A very wide range of carbon isotopic composition (d13C from -42 to +3.8 per mil) indicates different sources of carbonic acid required for formation of these carbonates. As a basis for carbon isotopic composition we can distinguish three sources of carbonic acid in the studied sediments: microbiological methane oxidation, organic matter destruction during sediment diagenesis, and dissolved organogenic limestone. Thus, formation of authigenic carbonates in sediments from the marginal seas of the Northwest Pacific results from: 1) sediment diagenesis, 2) methane oxidation in zones of gas anomalies, 3) their precipitation from the supersaturated by carbonates sea shoal waters of tropical sea lagoons.

Dissolved organic carbon in waters of the Okhotsk and Bering Seas

A comparison was made of capability of two methods: photochemical oxidation and high-temperature catalytic combustion - to oxidize organic carbon in organic substances different in their element composition and in their degree of complexity. Results of measurements of dissolved organic carbon obtained by both of these methods in waters of the Black, Bering and Okhotsk Seas are presented. Varying oxidation degree of organic matter was shown to be dependent on the region and depth. A conclusion was made that the high-temperature catalytic combustion method was to be preferred for dissolved organic carbon determination due to its easier standardization, while values obtained by the wet-oxidation method may be influenced by a great number of factors that are difficult to be controlled.

Properties, sedimentation and accumulation rates, and chemical composition of bottom sediments from the Deryugin Basin, Sea of Okhotsk

Results of a study of contents and accumulation rates of Fe, Mn, and some trace elements in Upper Quaternary sediments of the Deryugin Basin are presented. Maps of average contents and accumulation rates of excessive Fe, Mn, Zn, Ba, Ni, Pb, Cu, and Mo in sediments of the first oxygen isotope stage (OIS) have been plotted. Anomalous contents and accumulation rates are confined to peripheral zones of the Deryugin sedimentary basin and large fracture zones. Different mechanisms of influence of fluid-dynamic processes on rate of hydrogenic and biogenic accumulation of ore elements are assumed.