(Table 1) Oxygen isotoic composition of interstitial watres from ODP Sites 128-798 and 128-799

Oxygen isotope compositions of the interstitial waters have been measured for 21 samples taken from the depth intervals of 1.5 to 398.9 mbsf at Site 798 (Oki Ridge) and 16.5 to 435.6 mbsf at Site 799 (Kita-Yamato Trough) in Japan Sea. The d18O values decrease with depth from -0.49 to -3.38 per mil (SMOW) at Site 798 and from -0.71 to -4.36 per mil (SMOW) at Site 799 corresponding to an average depletion gradient of -0.8 per mil per 100 m. Material balance calculations reveal that the d18O-variations at Sites 798 and 799 were principally controlled by low-temperature alteration of basement basalt and andesite, resulting in negative shifts in pore water d18O values, and by the polymorphic transformations of biogenic opal-A to opal-CT and opal-CT to microquartz, which tend to increase d18O of interstitial waters. Carbonate diagenesis and ash alteration also caused weakly negative shifts in pore water d18O values.

Geochemistry of sediments and interstitial waters of ODP Sites 128-798 and128-799

Interstitial waters in sediments below 400 (Site 798) and 435 meters below seafloor (Site 799) have chloride concentrations of 516-527 and 501-515 mM, respectively, lower than the 540 mM of the modern-day Japan Sea. The chemical composition of interstitial waters, bulk sediments, clay-size sediment fraction, and carbonate nodules from Oki Ridge (Site 798) and Kita-Yamato Trough (Site 799), Japan Sea, reflect in-situ diagenetic processes superimposed on geochemical signals that may indicate freshening of Miocene local marginal basin waters. Interstitial waters at both sites exhibit changes in chemical composition which coincide with the occurrence of low-porosity and high-bulk density layers composed of dolomite and opal-CT, which impede diffusive communication with the overlying interstitial waters. Based on interstitial water stable isotope evidence and mass-balance calculations of chloride dilution, diagenetic reactions that involve the release of structural bound water from opal-A and/or clay minerals contribute to the observed geochemical signals, but cannot account for all the measured chloride dilution.

Pleistocene planktonic foraminifera at ODP Site 128-798

ODP Site 798 on the Oki Ridge in the Southern Japan Sea yielded the first continuous and well-preserved record of Pleistocene planktonic foraminifers in the Northwestern Pacific Ocean region. Quantitative analysis of planktonic foraminifers completed for 122 samples from the 200-m-thick Pleistocene section cored at ODP Site 798 provides a proxy record of variations in sea-surface temperature, productivity, and circulation during the past 1.6 m.y. in an area beneath the track of the Tsushima Current. Faunal census data allow recognition of five distinct assemblages: (1) type A assemblages dominated by sinistrally coiling forms of Neogloboquadrina pachyderma representing polar-subpolar surface temperatures, (2) type B assemblages dominated by Globigerina bulloides and thought to represent periods of increased surface productivity and upwelling, (3) type C assemblages marked by significant abundances of dextrally coiling forms of N. pachyderma thought to represent the warm transitional waters of the Tsushima Current, (4) type D assemblages distinguished by relatively high percentages of dextral N. pachyderma and Globorotalia inflata that also represent warmer surface temperatures and increased flow of the Tsushima Current, and (5) type E assemblages marked by relatively large numbers of the delicate species Globigerina quinqueloba and Globigerinita spp., indicative of exceptional preservation conditions and/or episodic high production of these taxa. Early and middle Pleistocene coiling patterns of Neogloboquadrina pachyderma at Site 798 can be correlated with Pleistocene coiling trends and planktonic foraminiferal datums established in the onshore Oga Peninsula sequence of Northern Honshu and open-ocean N. pachyderma coiling dominance shifts in the North Pacific region. A sustained early Pleistocene warm period recognized in both the Oga Peninsula sequence and the Northern Pacific can clearly be recognized at Site 798. In addition, the late Pleistocene planktonic foraminiferal record at Site 798 shows good correlation with glaciation/deglaciation events for the Northern Hemisphere as delineated by oxygen isotopes and represents the first detailed analysis of Pleistocene sea-surface temperature changes in the Northwestern Pacific Ocean region.

Total organic carbon, bitumen ratio, hopane and sterane parameters of ODP Sites 128-798 and 128-799

Notable compositional changes of organic matter are observed below the silica transition zone in thermally immature sediments. The increase of bitumen ratio, and hopane and sterane isomerization parameters indicate an acceleration of the kinetics of the chemical reactions which transform the organic matter. This phenomenon is probably due to the numerous mineral and textural changes induced by the transformation of amorphous biogenic silica into crystalline authigenic silica.

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Includes index.

The Behavior of Hydroxyl Units of Synthetic Goethite and its Dehydroxylated Product Hematite

The behavior of the hydroxyl units of synthetic goethite and its dehydroxylated product hematite was characterized using a combination of Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD) during the thermal transformation over a temperature range of 180-270 degrees C. Hematite was detected at temperatures above 200 degrees C by XRD while goethite was not observed above 230 degrees C. Five intense OH vibrations at 3212-3194, 1687-1674, 1643-1640, 888-884 and 800-798 cm(-1), and a H2O vibration at 3450-3445 cm(-1) were observed for goethite. The intensity of hydroxyl stretching and bending vibrations decreased with the extent of dehydroxylation of goethite. Infrared absorption bands clearly show the phase transformation between goethite and hematite: in particular. the migration of excess hydroxyl units from goethite to hematite. Two bands at 536-533 and 454-452 cm(-1) are the low wavenumber vibrations of Fe-O in the hematite structure. Band component analysis data of FTIR spectra support the fact that the hydroxyl units mainly affect the a plane in goethite and the equivalent c plane in hematite.

‘Beijing bling’: creative details and consumer choices in contemporary China : an interview with Hung Huang

This edited interview with Hung Huang, CEO of China Interactive Media Group (CIMG), was conducted by Lucy Montgomery in Beijing on 12 August 2005. It was done as part of the ARC Discovery research project, Internationalising Creative Industries: China, the WTO and the Knowledge Economy, led by John Hartley. That project is investigating the development of creative industries in China by focusing on a number of creative services including fashion magazines. Huang’s group publishes five fashion magazines in China, including i-Look, Youth International (Qingnian Yizu), which is the Chinese edition of Seventeen (originally founded by TV-Guide mogul Walter Annenberg), and the Beijing and Shanghai versions of London’s Time Out. It also produces TV programs under the same media brands. The company is based in the stylish Bauhaus-designed former factory 798-Space in the district of Dashanzi, Beijing (see www.798space.com). Huang went to school in Greenwich Village and graduated from Vassar College in New York. She is the daughter of Zhang Hanzhi, who was Mao Zedong’s personal English teacher, and stepdaughter of Qiao Guanhua, Foreign Minister of China during the 1970s at the time of the Nixon visit. Her book My Abnormal Life sold 200,000 copies in China.

Raman spectroscopic study of the mixed anion mineral Yecoraite Bi5Fe3O9(Te4+O3)(Te6+O4)2•9H2O

Tellurates are rare minerals as the tellurate anion is readily reduced to the tellurite ion. Often minerals with both tellurate and tellurite anions in the mineral are found. An example of such a mineral containing tellurate and tellurite is yecoraite. Raman spectroscopy has been used to study this mineral, the exact structure of which is unknown. Two Raman bands at 796 and 808 cm-1 are assigned to the ν1 (TeO4)2- symmetric and ν3 (TeO3)2- antisymmetric stretching modes and Raman bands at 699 cm-1 are attributed to the the ν3 (TeO4)2- antisymmetric stretching mode and the band at 690 cm-1 to the ν1 (TeO3)2- symmetric stretching mode. The intense band at 465 cm-1 with a shoulder at 470 cm-1 is assigned the (TeO4)2- and (TeO3)2- bending modes. Prominent Raman bands are observed at 2878, 2936, 3180 and 3400 cm-1. The band at 3936 cm-1 appears quite distinct and the observation of multiple bands indicates the water molecules in the yecoraite structure are not equivalent. The values for the OH stretching vibrations listed provide hydrogen bond distances of 2.625 Å (2878 cm-1), 2.636 Å (2936 cm-1), 2.697 Å (3180 cm-1) and 2.798 Å (3400 cm-1). This range of hydrogen bonding contributes to the stability of the mineral. A comparison of the Raman spectra of yecoraite with that of tellurate containing minerals kuranakhite, tlapallite and xocomecatlite is made.

A population survey of the penetrance of contact lens wear in Australia : rationale, methodology and results

Purpose: A population based, cross-sectional telephone survey was conducted to estimate the total penetrance of contact lens wear in Australia. Methods: A total of 42,749 households around Australia were randomly selected from the national electronic telephone directory based on postcode distribution. Before contact was attempted, letters of introduction were sent. The number of individuals and contact lens wearers in each household was ascertained and lens wearers were interviewed to determine details of lens type and mode of wear using a structured questionnaire. Results: Of households contacted, 59.2% (19,171/32,405) agreed to participate. Response rates were only marginally higher amongst households that first received a letter of introduction. In these households, 35,914 individuals were identified, of which, 1,798 were contact lens wearers. The penetrance of contact lens wear during the study period was 5.01% (95% CI: 4.78-5.24). Soft hydrogel lenses had the largest penetrance in the community, (66.7% of all wearers), however, their market share decreased significantly over the study period with increased uptake of newly introduced lens types. Conclusions: The penetrance of contact lens wear concurs with market estimates and equates to approximately 680,000 contact lens wearers aged between 15 and 64 years in Australia. The low response rate obtained in this study highlights the difficulty in contemporary use of telephone survey methodology