(Table 1) Occurrences of volcanic ash at DSDP Leg 78A Holes

Air-fall volcanic ash recovered at Deep Sea Drilling Project Sites 541, 542, and 543 on and east of the toe of the Barbados Ridge delineate middle and late Miocene, early Pliocene, and Pleistocene-Quaternary pulses of explosive volcanism in the Lesser Antilles arc. The ash beds at Site 541 allow precise correlation of intervals repeated by a probable reverse fault at this convergent margin.

Geochemistry of the oldest Atlantic oceanic crust

Controversy has surrounded the issue of whether mantle plume activity was responsible for Pangaean continental rifting and massive flood volcanism (resulting in the Central Atlantic Magmatic Province or CAMP, emplaced around 200 Ma) preceding the opening of the central Atlantic Ocean in the Early Mesozoic. Our new Sr-Nd-Pb isotopic and trace element data for the oldest basalts sampled from central Atlantic oceanic crust by deep-sea drilling show that oceanic crust generated from about 160 to 120 Ma displays clear isotopic and chemical signals of plume contamination (e.g., 87Sr/86Sr(i) = 0.7032-0.7036, epsilonNd(t) =+6.2 to +8.2, incompatible element patterns with positive Nb anomalies), but these signals are muted or absent in crust generated between 120 and 80 Ma, which resembles young Atlantic normal mid-ocean ridge basalt. The plume-affected pre-120 Ma Atlantic crustal basalts are isotopically similar to lavas from the Ontong Java Plateau, and may represent one isotopic end-member for CAMP basalts. The strongest plume signature is displayed near the center of CAMP magmatism but the hotspots presently located nearest this location in the mantle reference frame do not appear to be older than latest Cretaceous and are isotopically distinct from the oldest Atlantic crust. The evidence for widespread plume contamination of the nascent Atlantic upper mantle, combined with a lack of evidence for a long-lived volcanic chain associated with this plume, leads us to propose that the enriched signature of early Atlantic crust and possibly the eruption of the CAMP were caused by a relatively short-lived, but large volume plume feature that was not rooted at a mantle boundary layer. Such a phenomenon has been predicted by recent numerical models of mantle circulation.

Magnetic properties of Cenozoic MORB and Cretaceous MORB from DSDP and ODP holes

The fact that the natural remanent magnetization (NRM) intensity of mid-oceanic-ridge basalt (MORB) samples shows systematic variations as a function of age has long been recognized: maximum as well as average intensities are generally high for very young samples, falling off rather rapidly to less than half the recent values in samples between 10 and 30 Ma, whereupon they slowly rise in the early Tertiary and Cretaceous to values that approach those of the very young samples. NRM intensities measured in this study follow the same trends as those observed in previous publications. In this study, we take a statistical approach and examine whether this pattern can be explained by variations in one or more of all previously proposed mechanisms: chemical composition of the magnetic minerals, abundance of these magnetization carriers, vectorial superposition of parallel or antiparallel components of magnetization, magnetic grain or domain size patterns, low-temperature oxidation to titanomaghemite, or geomagnetic field behavior. We find that the samples do not show any compositional, petrological, rock-magnetic, or paleomagnetic patterns that can explain the trends. Geomagnetic field intensity is the only effect that cannot be directly tested on the same samples, but it shows a similar pattern as our measured NRM intensities. We therefore conclude that the geomagnetic field strength was, on-average, significantly greater during the Cretaceous than during the Oligocene and Miocene.

Trace element concentrations and Li isotope composition in DSDP and ODP sediments from island arcs

We have studied the sedimentary and basaltic inputs of lithium to subduction zones. Various sediments from DSDP and ODP drill cores in front of the Mariana, South Sandwich, Banda, East Sunda and Lesser Antilles island arcs have been analysed and show highly variable Li contents and d7Li values. The sediment piles in front of the Mariana and South Sandwich arcs largely consist of pelagic sediments (clays and oozes). The pelagic clays have high Li contents (up to 57.3 ppm) and Li isotope compositions ranging from +1.3? to +4.1?. The oozes have lower Li contents (7.3-16 ppm) with d7Li values of the diatom oozes from the South Sandwich lower (+2.8? to +3.2?) than those of the radiolarian oozes from the Mariana arc (+8.1? to +14.5?). Mariana sediment also contains a significant portion of volcanogenic material, which is characterised by a moderate Li content (14 ppm) and a relatively heavy isotope composition (+6.4?). Sediments from the Banda and Lesser Antilles contain considerable amounts of continental detritus, and have high Li contents (up to 74.3 ppm) and low d7Li values (around 0?), caused by weathering of continental bedrock. East Sunda sediments largely consist of calcareous oozes. These carbonate sediments display intermediate to high Li contents (2.4-41.9 ppm) and highly variable d7Li values (-1.6? to +12.8?). Basaltic oceanic crust samples from worldwide DSDP and ODP drill cores are characterised by enrichment of Li compared to fresh MORB (6.6-33.1 vs. 3.6-7.5 ppm, respectively), and show a large range in Li isotope compositions (+1.7? to +11.8?). The elemental and isotopic enrichment of Li in altered basalts is due to the uptake of isotopically heavy seawater Li during weathering. However, old oceanic crust samples from Sites 417/418 exhibit lighter Li isotope compositions compared to young basaltic crust samples from Sites 332B and 504B. This lighter Li isotope signature in old crust is unexpected and further research is needed to explore this issue.